WO2004087393B1 - Abrasion-resistant composites with in-situ activated binder resin - Google Patents

Abrasion-resistant composites with in-situ activated binder resin

Info

Publication number
WO2004087393B1
WO2004087393B1 PCT/US2004/009657 US2004009657W WO2004087393B1 WO 2004087393 B1 WO2004087393 B1 WO 2004087393B1 US 2004009657 W US2004009657 W US 2004009657W WO 2004087393 B1 WO2004087393 B1 WO 2004087393B1
Authority
WO
WIPO (PCT)
Prior art keywords
binder resin
abrasion
resin
web
fibers
Prior art date
Application number
PCT/US2004/009657
Other languages
French (fr)
Other versions
WO2004087393A2 (en
WO2004087393A3 (en
Inventor
Stephen H Tsiarkezos
Dimitri P Zafiroglu
Original Assignee
Xymid Llc
Stephen H Tsiarkezos
Dimitri P Zafiroglu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xymid Llc, Stephen H Tsiarkezos, Dimitri P Zafiroglu filed Critical Xymid Llc
Priority to EP20040758566 priority Critical patent/EP1610942A4/en
Priority to CA 2518172 priority patent/CA2518172A1/en
Priority to JP2006509460A priority patent/JP2006522239A/en
Publication of WO2004087393A2 publication Critical patent/WO2004087393A2/en
Publication of WO2004087393A3 publication Critical patent/WO2004087393A3/en
Publication of WO2004087393B1 publication Critical patent/WO2004087393B1/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H11/00—Non-woven pile fabrics
    • D04H11/08—Non-woven pile fabrics formed by creation of a pile on at least one surface of a non-woven fabric without addition of pile-forming material, e.g. by needling, by differential shrinking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/24—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least three directions forming a three dimensional structure
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/48—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0087—Wear resistance
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23957—Particular shape or structure of pile
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23979—Particular backing structure or composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23986—With coating, impregnation, or bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24033—Structurally defined web or sheet [e.g., overall dimension, etc.] including stitching and discrete fastener[s], coating or bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/273—Coating or impregnation provides wear or abrasion resistance
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/659—Including an additional nonwoven fabric
    • Y10T442/66—Additional nonwoven fabric is a spun-bonded fabric
    • Y10T442/662—Needled
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/659—Including an additional nonwoven fabric
    • Y10T442/666—Mechanically interengaged by needling or impingement of fluid [e.g., gas or liquid stream, etc.]
    • Y10T442/667—Needled
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/682—Needled nonwoven fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/682—Needled nonwoven fabric
    • Y10T442/684—Containing at least two chemically different strand or fiber materials

Abstract

A composite sheet is disclosed. The composite sheet comprises an open random fibrous web having substantially vertical fibers near a top surface, a first binder resin and a second binder resin, wherein the first binder resin has a melting point lower than the melting point of the second binder resin, wherein the melting point of the second resin is lower than the melting point of the web, wherein the resins are activated in situ with the web fibers to form a resin-fiber rich region on the top surface and wherein the abrasion-resistant sheet can withstand at least about 3,000 cycles on the Wyzenbeek abrasion test using 80-grit abrasive paper. An abrasion-resistant sheet comprising a single binder resin and other abrasion-resistant sheets are also disclosed. Processes for making these abrasion-resistant sheets are further disclosed herein.

Claims

AMENDED CLAIMS [received by the International Bureau on 09 April 2005 (09.04.05); Claims 1-13 unchanged; claims 14-20 added; (3 pages)]
8, The process of claim 7 in which the open random fibrous web further comprises a second binder resin having a melting temperature lower than the melting temperature of the fibers and higher than the melting temperature of the first resin binder and which process further comprises a step (d) of at least partially activating the second binder resin to form a fiber-resin rich region on top of the web.
9. The process of claim 7 or 8 in which the step of activating the binder resin comprises hot pressing the abrasive-resistant sheet to form a thin densified layer on the top surface.
10. The process of any of claims 7-9 in which the reinforcing step comprises at least one of (i) stitchbonding the web and (ii) contracting the web.
11. The process of any of claims 7- 10 in which the providing step (a) comprises dusting the first binder resin in fine solid form on the fibers of the open random fibrous web.
12. The process of any of claims 7-1 1 which furthers comprises the step of embossing the abrasion-resistant sheet to an embossing factor of greater than about 2.
13. The process of any of claims 7- 12 in which the step of activating the binder resin includes forming a gradient across the thickness of the web from a lower extent of activation of the resin binder at a position within the web to a higher extent of activation of the resin binder at another position within the web.
14. An abrasion-resistant sheet comprising an open random fibrous web having substantially vertical fibers near a top surface and a solid binder resin intimately intermixed within the open random fibrous webs wherein the melting temperature of the binder resin is lower than the melting temperature of the web fibers in the open random fibrous web and wherein the web fibers and the binder resin near the top surface form a thin densified βber-resin rich skin and wherein the abrasion-resistant sheet can withstand at least about 3,000 cycles on the Wyzenbeek abrasion test using 80-grit abrasive paper.
37
15. An abrasion-resistant sheet comprising an open random fibrous web having substantially vertical fibers near a top surface, at least a first binder resin, wherein the first binder resin has a meltirig temperature lower than the melting temperature of the web fibers of the open random fibrous web and wherem the resin and the fibers form a resin-fiber rich region on the top surface, and wherein the total amount of binder resin makes up less than 30% by weight of the abrasion-resistant sheet and wherem the abrasion-resistant sheet can withstand at least about 3,000 cycles on the Wyzenbeek abrasion test using 80-grit abrasive paper.
16. A composite sheet comprising an open random fibrous web having substantially vertical fibers near a top surface, a first binder resin and a second binder resin, wherein the first binder resin has a melting point lower than the melting point of the second binder resin, wherein the melting point of the second resin is lower than the melting point of the web fibers of the open random fibrous web, wherein the resins arc activated in situ with the web fibers to form a resin-fiber rich region on or near the top surface and wherein the abrasion-resistant sheet can withstand at least about 3,000 cycles on the Wyzenbeek abrasion test using 80-grit abrasive paper.
17. An abrasion-resistant sheet comprising an open random fibrous web having substantially vertical fibers near a top surface, at least a first binder resin, wherein the first binder resin has a melting temperature lower than the melting temperature of the web fibers of the open random fibrous web and wherein the resin and the fibers form a resin-fiber rich region on the top surface, wherein the melt flow index of the binder resin is greater than about 5 grams per 10 minutes, and wherein the abrasion-resistant sheet can withstand at least about 3,000 cycles on the Wyzenbeek abrasion test using 80-grit abrasive paper.
38 18, An abrasion-resistant sheet comprising an open raudoni fibrous web having substantially vertical fibers near a top surface, at least a first binder resin, wherein the first binder resin has a melting temperature lower than the melting temperature of the web fibers of the open random fibrous web and wherein the resin and the fibers form a resin-fiber rich region on the top surface, wherein the activation of the first binder resin follows a gradient within the open random fibrous web, and wherein the abrasion- resistant sheet can withstand at least about 3,000 cycles on the Wyzenbeek abrasion test using 80-grit abrasive paper.
19, An abrasion-resistant sheet comprising an open random fibrous web having substantially vertical fibers near a top surface, at least a first binder resin, wherein the first binder resin has a melting temperature lower than the melting temperature of the web fibers of the open random fibrous web and wherein the resin and the fibers form a resin-fiber rich region on the top surface, wherein the abrasion-resistant sheet can withstand at least about 3,000 cycles on the Wyzenbeek abrasion test using 80-grit abrasive paper, and wherein the abrasion-resistant sheet has an embossing factor greater than about 2.
2 , An abrasion-resistant sheet comprising an open random fibrous web having substantially vertical fibers near a top surface, at least a first binder resin, wherein the first binder resin has a melting temperature lower than the melting temperature of the web fibers of the open random fibrous web and wherein the resin and the fibers form a resin-fiber rich region on the top surface, wherein the abrasion-resistant sheet can withstand at least about 3,000 cycles on the Wyzenbeek abrasion test using 80-grit abrasive paper, and wherein the abrasion-resistant sheet exhibits at least 20% stretch with at least 90% recovery in at least one direction after being embossed.
PCT/US2004/009657 2003-03-31 2004-03-30 Abrasion-resistant composites with in-situ activated binder resin WO2004087393A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP20040758566 EP1610942A4 (en) 2003-03-31 2004-03-30 Abrasion-resistant composites with in-situ activated binder resin
CA 2518172 CA2518172A1 (en) 2003-03-31 2004-03-30 Abrasion-resistant composites with in-situ activated binder resin
JP2006509460A JP2006522239A (en) 2003-03-31 2004-03-30 Abrasion-resistant composite material containing binder resin activated at the processing site

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/403,208 2003-03-31
US10/403,208 US7264861B2 (en) 2003-03-31 2003-03-31 Abrasion-resistant composites with in-situ activated matrix resin

Publications (3)

Publication Number Publication Date
WO2004087393A2 WO2004087393A2 (en) 2004-10-14
WO2004087393A3 WO2004087393A3 (en) 2005-04-28
WO2004087393B1 true WO2004087393B1 (en) 2005-06-23

Family

ID=32989883

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/009657 WO2004087393A2 (en) 2003-03-31 2004-03-30 Abrasion-resistant composites with in-situ activated binder resin

Country Status (5)

Country Link
US (1) US7264861B2 (en)
EP (1) EP1610942A4 (en)
JP (1) JP2006522239A (en)
CA (1) CA2518172A1 (en)
WO (1) WO2004087393A2 (en)

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Also Published As

Publication number Publication date
US20040191470A1 (en) 2004-09-30
WO2004087393A2 (en) 2004-10-14
EP1610942A2 (en) 2006-01-04
US7264861B2 (en) 2007-09-04
WO2004087393A3 (en) 2005-04-28
JP2006522239A (en) 2006-09-28
EP1610942A4 (en) 2010-10-27
CA2518172A1 (en) 2004-10-14

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