WO2004098793A3 - Polymerdispersion mit farbeffekt - Google Patents

Polymerdispersion mit farbeffekt Download PDF

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Publication number
WO2004098793A3
WO2004098793A3 PCT/EP2004/004707 EP2004004707W WO2004098793A3 WO 2004098793 A3 WO2004098793 A3 WO 2004098793A3 EP 2004004707 W EP2004004707 W EP 2004004707W WO 2004098793 A3 WO2004098793 A3 WO 2004098793A3
Authority
WO
WIPO (PCT)
Prior art keywords
monomers
polymerisation
colour
polymer dispersion
core
Prior art date
Application number
PCT/EP2004/004707
Other languages
English (en)
French (fr)
Other versions
WO2004098793A2 (de
Inventor
Xu He
Reinhold J Leyrer
Holger Schoepke
Original Assignee
Basf Ag
Xu He
Reinhold J Leyrer
Holger Schoepke
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Xu He, Reinhold J Leyrer, Holger Schoepke filed Critical Basf Ag
Priority to EP04730980A priority Critical patent/EP1624974B1/de
Priority to JP2006505364A priority patent/JP2006526039A/ja
Priority to US10/553,793 priority patent/US7776237B2/en
Priority to DE502004004095T priority patent/DE502004004095D1/de
Publication of WO2004098793A2 publication Critical patent/WO2004098793A2/de
Publication of WO2004098793A3 publication Critical patent/WO2004098793A3/de

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902Core-shell

Abstract

Verfahren zur Verbesserung der Farbbrillanz und der Stabilität eines farbigen Polymersystems, welches aus einer Matrix und diskreten Polymerteilchen, welche gemäss einer definierten Raumgitterstruktur in der Matrix verteilt sind, besteht und durch Verfilmung eines Emulsionspolymerisats mit Kern/Schale Aufbau erhalten wird, dadurch gekennzeichnet, dass, das Emulsionspolymerisat erhältlich ist durch Polymerisation von Monomeren in mindestens einer ersten Stufe (Monomere des Kerns), anschliessende Polymerisation von Monomeren in mindestens einer weiteren, zweiten Stufe (Ubergangsstufe) und abschliessende Polymerisation von Monomeren in einer dritten Stufe (Monomere der Schale), wobei, bezogen auf die prozentuale Zusammensetzung der Monomerengemische der drei Stufen, maximal 30 Gew.-% der Monomeren der ersten Stufe mit denen der dritten Stufe übereinstimmen und die Monomeren der zweiten Stufe jeweils zu mindestens 5 Gew.-% mit denen der ersten und denen der dritten Stufe übereinstimmen, wobei es sich bei maximal 60 Gew.-% der Monomeren der 2. Stufe um Monomere handelt, die weder in der 1. noch in der 3. Stufe vorhanden sind.
PCT/EP2004/004707 2003-05-09 2004-05-04 Polymerdispersion mit farbeffekt WO2004098793A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP04730980A EP1624974B1 (de) 2003-05-09 2004-05-04 Polymerdispersion mit farbeffekt
JP2006505364A JP2006526039A (ja) 2003-05-09 2004-05-04 色彩効果を有するポリマー分散液
US10/553,793 US7776237B2 (en) 2003-05-09 2004-05-04 Polymer dispersion with a colour effect
DE502004004095T DE502004004095D1 (de) 2003-05-09 2004-05-04 Polymerdispersion mit farbeffekt

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10321083A DE10321083A1 (de) 2003-05-09 2003-05-09 Polymerdispersion mit Farbeffekt
DE10321083.0 2003-05-09

Publications (2)

Publication Number Publication Date
WO2004098793A2 WO2004098793A2 (de) 2004-11-18
WO2004098793A3 true WO2004098793A3 (de) 2004-12-16

Family

ID=33394451

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/004707 WO2004098793A2 (de) 2003-05-09 2004-05-04 Polymerdispersion mit farbeffekt

Country Status (7)

Country Link
US (1) US7776237B2 (de)
EP (1) EP1624974B1 (de)
JP (1) JP2006526039A (de)
AT (1) ATE364454T1 (de)
DE (2) DE10321083A1 (de)
ES (1) ES2286633T3 (de)
WO (1) WO2004098793A2 (de)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7635727B2 (en) * 2003-06-24 2009-12-22 Ppg Industries Ohio, Inc. Composite transparencies
US7605194B2 (en) 2003-06-24 2009-10-20 Ppg Industries Ohio, Inc. Aqueous dispersions of polymer-enclosed particles, related coating compositions and coated substrates
US20100184911A1 (en) * 2009-01-22 2010-07-22 Ppg Industries Ohio, Inc. Aqueous dispersions of polymer-enclosed particles, related coating compositions and coated substrates
DE102005023806A1 (de) * 2005-05-19 2006-11-23 Basf Ag Farbiges Polymersystem mit verbesserter Farbbrillianz
DE102005023804A1 (de) * 2005-05-19 2006-11-23 Basf Ag Farbiges Polymersystem mit verbesserter Elastizität
DE102005041402A1 (de) * 2005-09-01 2007-03-08 Röhm Gmbh Formkörper mit Lichtstreueigenschaften
US8133938B2 (en) * 2005-11-01 2012-03-13 Ppg Industries Ohio, Inc. Radiation diffraction colorants
EP1989050A1 (de) * 2006-02-21 2008-11-12 Basf Se Verwendung von farbigen polymersystemen für verpackungen
US20090012207A1 (en) * 2006-02-21 2009-01-08 Basf Se Use of coloured polymeric systems for medical or hygiene articles
US20070219307A1 (en) * 2006-03-17 2007-09-20 Yong Yang Emulsion polymer blend coating compositions and methods for increasing chalky substrate adhesion
US20080058473A1 (en) * 2006-08-31 2008-03-06 Yakov Freidzon Latex for low VOC paint having improved block resistance, open time and water-softening resistance
EP2108463B8 (de) 2008-04-11 2019-10-09 BASF Coatings GmbH Verfahren zur Herstellung von Effektlackierungen und ihre Verwendung
US8507050B2 (en) * 2008-11-12 2013-08-13 Ppg Industries Ohio, Inc. Methods for depositing ultra thin coatings exhibiting low haze and methods for the preparation of such coatings
US8252412B2 (en) * 2009-06-16 2012-08-28 Ppg Industries Ohio, Inc Angle switchable crystalline colloidal array films
US20110135888A1 (en) * 2009-12-04 2011-06-09 Ppg Industries Ohio, Inc. Crystalline colloidal array of particles bearing reactive surfactant
US8582194B2 (en) 2010-04-29 2013-11-12 Ppg Industries Ohio, Inc. Thermally responsive crystalline colloidal arrays
EP2431422A3 (de) * 2010-09-21 2013-07-10 Rohm and Haas Company IR-reflektierende Zusammensetzungen
EP2431424A3 (de) * 2010-09-21 2014-03-05 Rohm and Haas Company UV-reflektierende Zusammensetzungen
US9022648B2 (en) 2010-11-11 2015-05-05 Prc-Desoto International, Inc. Temperature sensitive composite for photonic crystals
MY162805A (en) * 2011-01-05 2017-07-14 Kaneka Corp Polymer microparticle-dispersed resin composition and method for producing same
US8641933B2 (en) 2011-09-23 2014-02-04 Ppg Industries Ohio, Inc Composite crystal colloidal array with photochromic member
US20130077169A1 (en) 2011-09-23 2013-03-28 Ppg Industries Ohio, Inc. Hollow particle crystalline colloidal arrays
CN102603960B (zh) * 2012-03-02 2014-04-02 上海三瑞高分子材料有限公司 一种可再分散胶粉用核壳结构丙烯酸乳液的制备方法
WO2014075969A1 (de) 2012-11-15 2014-05-22 Basf Se Verwendung wässriger polymerisatdispersion in beschichtungsmitteln zur verbesserung der farbtonstabilität (color retention)
KR102111120B1 (ko) * 2018-02-02 2020-06-08 주식회사 엘지화학 그라프트 공중합체의 제조방법, 그라프트 공중합체 및 열가소성 수지 성형품

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0441559A2 (de) * 1990-02-03 1991-08-14 MITSUI TOATSU CHEMICALS, Inc. Kern-Multischalen-Teilchen in Emulsion, Verfahren zu ihrer Herstellung und sie enthaltende Harzzusammensetzung
EP0451940A2 (de) * 1990-03-30 1991-10-16 Tioxide Group Limited Herstellung von Polymerteilchen
US5157084A (en) * 1990-10-12 1992-10-20 The Dow Chemical Company Process of making hollow polymer latex particles
EP1197503A2 (de) * 2000-10-12 2002-04-17 Rohm And Haas Company Verfahren zur Herstellung von wässrigen Polymerdispersionen

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19717879A1 (de) 1997-04-28 1998-10-29 Basf Ag Organisches, mehrphasiges Effektfarbmittel, seine Herstellung und seine Verwendung
DE19820302A1 (de) 1998-05-04 2000-02-24 Basf Ag Kern/Schale-Partikel, ihre Herstellung und Verwendung
DE19834194B4 (de) 1998-07-29 2009-03-05 Basf Se Farbmittel enthaltende Dispersionen von Kern/Schale-Partikeln und Kern/Schale-Partikel
DE10229732A1 (de) 2002-07-02 2004-01-22 Basf Ag Optische Anzeigeelemente auf Basis wässriger Polymerdispersionen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0441559A2 (de) * 1990-02-03 1991-08-14 MITSUI TOATSU CHEMICALS, Inc. Kern-Multischalen-Teilchen in Emulsion, Verfahren zu ihrer Herstellung und sie enthaltende Harzzusammensetzung
EP0451940A2 (de) * 1990-03-30 1991-10-16 Tioxide Group Limited Herstellung von Polymerteilchen
US5157084A (en) * 1990-10-12 1992-10-20 The Dow Chemical Company Process of making hollow polymer latex particles
EP1197503A2 (de) * 2000-10-12 2002-04-17 Rohm And Haas Company Verfahren zur Herstellung von wässrigen Polymerdispersionen

Also Published As

Publication number Publication date
EP1624974B1 (de) 2007-06-13
DE10321083A1 (de) 2004-11-25
US7776237B2 (en) 2010-08-17
US20060191442A1 (en) 2006-08-31
EP1624974A2 (de) 2006-02-15
DE502004004095D1 (de) 2007-07-26
WO2004098793A2 (de) 2004-11-18
ES2286633T3 (es) 2007-12-01
ATE364454T1 (de) 2007-07-15
JP2006526039A (ja) 2006-11-16

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