WO2004099225A1 - Process for the production of halide metallocene compounds - Google Patents
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- WO2004099225A1 WO2004099225A1 PCT/EP2004/004525 EP2004004525W WO2004099225A1 WO 2004099225 A1 WO2004099225 A1 WO 2004099225A1 EP 2004004525 W EP2004004525 W EP 2004004525W WO 2004099225 A1 WO2004099225 A1 WO 2004099225A1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
Definitions
- the present invention relates to a process for the production of halide metallocene compounds in high purity and in high yields.
- Metallocene compounds are well known in the art as catalyst components for the polymerization of olefins.
- the European Patent Application EP 0 129 368 discloses catalysts comprising mono- and di-cyclopentadienyl coordination complexes with a transition metal in combination with an alumoxane.
- the central metal is coordinated with one or more ⁇ - bonded ligands, usually cyclopentadienyl moieties, and with one or more sigma-bonded ligands.
- the latter are usually halogen, preferably chlorine.
- the lithium salts of the ligands are contacted with a tetrahalide of the metal. This process generates LiCl as a by-product that is difficult to separate because of the low solubility of the dihalide metallocene compounds in the usual solvents, and often the yield of the process is not satisfactory.
- dialkyl metallocene compounds are treated with a halogenating agent such as HC1, transition metal halides, BC1 and the like in order to obtain a monohalide or dihalide compound in high yields. It has now been found that, by using different halogenating agents, the yields of that process can be further increased.
- a halogenating agent such as HC1, transition metal halides, BC1 and the like
- the present invention provides a process for preparing halide metallocene compounds of formula (I):
- Cp is an unsubstituted or substituted cyclopentadienyl group, optionally condensed to one or more unsubstituted or substituted, saturated, unsaturated or aromatic rings, containing from 4 to 6 carbon atoms, optionally containing one or more heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements;
- A is O, S, NR 2 or PR 2 , R 2 being hydrogen, a linear or branched, saturated or unsaturated - C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C -C 20 alkylaryl or C 7 -C 20 arylalkyl, or A has the same meaning of Cp;
- M is zirconium, titanium or hafnium;
- the L substituents, equal to or different from each other, preferably equal, are chlorine, bromine, iodine, preferably chlorine;
- L' is hydrogen, or a linear or branched, saturated or unsaturated C ⁇ -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 2 o aryl, C 7 -C 20 alkylaryl or C -C 20 arylalkyl group, optionally containing one or more Si or Ge atoms; preferably L' is methyl, ethyl, n-butyl, sec-butyl, phenyl, benzyl or - CH 2 Si(CH ) 3 ; more preferably L' is methyl; m is 1 or 2 depending on the oxidation state of Z, more specifically it is 1 when Z is N or P, and it is 2 when Z is C, Si or Ge; n is 0, 1, 2, 3 or 4, preferably it is 0, 1 or 2; being 0 when r is 0 or 2; r is 0, 1 or 2, preferably being 0 or 1 ; more preferably r is 1 ; y is 1,2, or 3;
- Cp, Z, R 1 , A, M, L', m, r, and n have the same meaning as above; and p is equal to the oxidation state of the metal M minus 1+r; preferably p is 2; with at least p-t equivalents, with respect to the metal M of the compound of formula (II), of an halogenating agent of formula (III):
- R 3 x TLw (III) or an adduct containing the compound of formula (III); wherein: L has the same meaning as above;
- R 3 is hydrogen, or a linear or branched, saturated or unsaturated C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 alkylaryl or C 7 -C 20 arylalkyl group; preferably R 3 is methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, phenyl or benzyl; more preferably R 3 is methyl, ethyl, n-propyl, isopropyl, n-butyl or isobutyl;
- T is a metal of groups 2-14 of the periodic table of the elements; preferably T is a metal of groups 11-14 of the periodic table of the elements; more preferably T is aluminum, zinc, tin, germanium or copper; x is >1 and w is ⁇ i so that x+w is equal to the oxidation state of the metal T; preferably x is 1.
- the compounds of formula (II) can be prepared according to known methods, as described, for example, in WO 99/36427, WO 00/75151 and WO 03/057705.
- the process of the present invention can be also the last step of a "one pot" process in which the compound of formula (I) is prepared according to WO 99/36427, WO 00/75151 and WO
- a further object of the present invention is a process for preparing halide metallocene compounds of formula (I):
- aprotic solvent is preferably an aromatic or aliphatic hydrocarbon, optionally halogenated, or an ether, more preferably it is selected from the group consisting of benzene, toluene, pentane, hexane, heptane, cyclohexane, dichloromethane, chlorobenzene, diethylether, tetrahydrofuran or mixtures thereof.
- the amount of the halogenating agent to be used depends from the type of compound.
- the term "equivalent of an halogenting agent” is referred to the equivalents of active groups L i.e. the groups L in the compound of formula (III) that are able to react.
- the number of active group L can be equal to or less than w. In any case excess of halogenating agent can also be used.
- the Y leaving group is preferably hydrogen or a trialkylsilyl group.
- the ML" 4 reactant is preferably selected from the group consisting of TiCl 4 , ZrCLt, HfCL ⁇ . It can be used even in the form of a stabilized derivative, such as an etherate complex of ML" 4 , easily available on the market.
- L' j B and L'"MgL' are alkylating agents.
- L' is selected from the group consisting of methyl, ethyl, n-butyl, sec-butyl, phenyl, benzyl and -CH 2 Si(CH ) . More preferably L' is methyl or butyl.
- B is an alkali or alkaline-earth metal, preferably Li or Mg; j can be 1 or 2, as already reported.
- L'"MgL' is a Grignard reagent, wherein Mg is magnesium and L'" and L' have the meanings reported above.
- L'" is preferably bromine or iodine.
- said alkylating agent is the compound of formula L' j B, more preferably butyl lithium or methyllithium.
- step a) of the above process is carried out in two substeps: a-1) reacting, at a temperature of between -10°C and 70°C, a ligand of formula (Y- Cp)(ZR 1 m )n(A-Y) r or when n is 0 a mixture of ligands Y-Cp and r(A-Y) with an amount EQ of a compound of formula L' j B or L'MgL'" such that EQ is about 1+r molar equivalents with respect to Cp; and a-2) after the reaction has been completed, i.e.
- the alkylating agents used in substeps a-1) and a-2) can be the same or different.
- butylithium or sodium hydride can be used in step a-1) and methyl lithium can be used in step a-2). This gives rise to the advantage that it is possible to use stronger and sometimes less expensive reagents in step a-1) without influencing the choice of the substituents L' in step a-2).
- the alkylating agent is preferably added in the form of a solution in one of the above mentioned aprotic solvents, preferably dropwise.
- step (b) the mixture obtained from step (a) is preferably heated at a temperature comprised between 0°C and 80°C, and more preferably between 20°C and 74°C. Afterwards the compound ML" 4 is quickly added to the slurry in the form of a solution or a slurry in one of the above mentioned aprotic solvents, preferably pentane, hexane, heptane or toluene. The reaction mixture is then allowed to react for a period ranging from 10 minutes to 36 hours, and more preferably from 1 hour to 18 hours.
- aprotic solvents preferably pentane, hexane, heptane or toluene.
- the temperature ranges from -50°C to +150°C, preferably from 0°C to 100°C, more preferably from 20°C to 75°C.
- the halogenating agent is generally added dropwise and then the reaction mixture is preferably allowed to react, under stirring, for a period ranging from 1 to 6 hours, more preferably from 2 to 3 hours, at a temperature comprised between -10°C and +80°C.
- Non limiting examples of halogenating agents of formula (III) are: MeAlCl 2 , EtAlCl 2 , Me 2 AlCl, MeZnCl, Et 2 AlCl, Et 2 AlCl'EtAlCl 2 , Me 2 AlCl-MeAlCl 2 , n- Pr 2 AlCl, n-PrAlCl 2 , n-Bu 2 AlCl, n-BuAlCl 2 , , i-Pr 2 AlCl, i-PrAlCl 2 , i-Bu 2 AlCl, i- BuAlCl 2 Me 2 , GeCl 2 , Me 2 SnCl 2 , EtGeCl 3 , MeSnCl 3 , n-BuSnCl 3 , i-BuSnCl 3 .
- the purification of the reaction mixture is preferably carried out by simply filtering the solution in order to remove the salts.
- other systems of purification can be used, for example a suitable solvent can be added in order to precipitate the undesired by products with subsequently filtration.
- a suitable solvent can be added in order to precipitate the undesired by products with subsequently filtration.
- the divalent bridge (ZR' m ) n is preferably selected from the group consisting of CR' 2 , (CR ⁇ , (CR 1 2 ) 3 , SiR' 2 , GeR' 2 , NR 1 and PR 1 , R 1 having the meaning reported above. More preferably, said divalent bridge is Si(CH ) 2 , SiPh 2 , CH 2 ,
- variable m is 1 or 2; the variable n ranges from 0 to 4 preferably is 1 or 2, when n > 1, the atoms Z can be the same or different from each other, such as in divalent bridges -CH 2 -O-, -
- the ligand Cp which is ⁇ -bonded to said metal M, is preferably selected from the group consisting of cyclopentadienyl, mono-, di-, hi- and tetra- methyl cyclopentadienyl; 4-tertbutyl-cyclopentadienyl; 4-adamantyl-cyclopentadienyl; indenyl; mono-, di-, tri- and tetra-methyl indenyl; 2-methyl-4-phenyl indenyl, in which the phenyl can be alkyl substituted; 2-isopropyl-4-phenyl indenyl, in which the phenyl can be alkyl substituted; 4,5,6,7-tetrahydroindenyl fluorenyl; 5,10-dihydroindeno[l,2-b]indol-10-yl;
- the group A has preferably the same meaning of Cp, or it is N- methyl, N-ethyl, N-isopropyl,
- N-butyl N-phenyl, N-benzyl, N-cyclohexyl and N-cyclododecyl.
- R a , R b , R c , R d and R e are hydrogen atoms or linear or branched, saturated or unsaturated C ⁇ -C 4 o-alkyl, C 3 -C 40 -cycloalkyl, C 6 -C 4 o-aryl, C 7 -C 40 -alkylaryl or C 7 -C 40 -arylalkyl radicals, optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; two vicinal R a , R b , R c , R d and R can also form one or more condensed 5 or 6 membered saturated or unsaturated rings optionally containing heteroatoms belonging to groups 13-16 of the Periodic Table of the Elements, said rings can bear C ⁇ -C 20 alkyl or C 6 -C 20 aryl arylalkyl or alkylaryl substituents; R e can also be a single bond that links the
- R 4 is a hydrogen atom or a linear or branched, saturated or unsaturated C ⁇ -C 20 -alkyl, C -C 20 -cycloalkyl, C 6 -C 20 -aryl, C 7 -C 2 o-alkylaryl or C -C 2 o-arylalkyl radical, optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements;
- R 5 , R 6 , R 7 , R 8 and R 9 are hydrogen atoms or linear or branched, saturated or unsaturated C ⁇ -C 2 o-alkyl, C 3 -C 2 o-cycloalkyl, C 6 -C 2 o-aryl, C 7 -C 2 o-alkylaryl or C 7 -C 2G -arylalkyl radicals, optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; two vicinal R 5 , R 6 , R 7 , R 8 and R 9 can also form one or more condensed 5 or 6 membered saturated or unsaturated rings optionally containing heteroatoms belonging to groups 13-16 of the Periodic Table of the Elements, said rings can bear C ⁇ -C 40 alkyl substituents;
- R 4 is a C ⁇ -C 20 -alkyl radical; more preferably the two R 4 moieties, equal to or different from each other, are methyl ethyl or isopropyl radicals;
- R 6 is preferably a C ⁇ -C 20 -alkyl, C 6 -C 20 -aryl or C 7 -C 2 o-arylalkyl radicals; more preferably R 6 is a phenyl or a 4-C ⁇ -C] 0 alkyl substituted phenyl radical such as 4-tertbutyl-phenyl radical.
- Non limiting examples of metallocene compounds of formula (I) are the racemic and the meso form (when present) of the following compounds: bis(cyclopentadienyl)zirconium dichloride; bis(indenyl)zirconium dichloride; bis(tetrahydroindenyl)zirconium dichloride; bis(fluorenyl)zirconium dichloride; dimethylsilanediylbis(indenyl)zirconium dichloride, dimethylsilanediylbis(2-methyl-4-phenylindenyl)zirconium dichloride, dimethylsilanediylbis(4-naphthylindenyl)zirconium dichloride, dimethylsilanediylbis(2-methylindenyl)zirconium dichloride, dimethylsilanediylbis(2-methylindenyl)zirconium dichloride, dimethylsilanediylbis(2-
- the process according to the present invention shows several advantages with respect to the processes generally known in the state of the art.
- the overall yields starting from the ligands are generally higher than those reported in the art.
- it is easier to purify the desired product due to the better solubility of the formed intermediate alkylated metallocene with respect to the dihalide or monohalide product.
- metallocene compounds obtained with the process according to the present invention in combination with a suitable activator such as an alumoxane, or compound able to form alkylmetallocene cation can be used as a catalyst for the polymerization of olefins. Particularly, they can be used for the homo or co-polymerization of alpha-olefins of formula
- CH 2 CHR wherein R is hydrogen or a C ⁇ -C 2 o alkyl, such as propylene, 1-butene, 1-pentene,
- An interesting use is for the production of isotactic, syndiotactic or atactic polypropylene.
- Another interesting use is for the copolymerization of ethylene with alpha-olefins, such as propylene, 1-butene, 1-pentene, 4-methyl-l-pentene, 1-hexene and 1-octene, with cycloolefins, such as cyclopentene, cyclohexene, norbornene and 4,6-dimethyl-l-heptene, or with polyenes, such as 1,4-hexadiene, isoprene, 1,3-butadiene, 1,5-hexadiene and 1,6-heptadiene.
- alpha-olefins such as propylene, 1-butene, 1-pentene, 4-methyl-l-pentene, 1-hexene and 1-octene
- cycloolefins such as cyclopentene, cyclohexene, norbornene and 4,6-dimethyl-l-heptene
- polyenes such as 1,
- alumoxanes that can be used are considered to be linear, branched or cyclic compounds containing at least one group of the type:
- U substituents are hydrogen atoms, halogen atoms, C]-C 20 - alkyl, C -C 2 o-cyclalkyl, C 6 -C 2 o-aryl, C 7 -C 20 -alkylaryl or C 7 -C 2 o-arylalkyl radicals, optionally containing silicon or germanium atoms, with the proviso that at least one U is different from halogen.
- n 1 is 0 or an integer of from 1 to 40 and the substituents U are defined as above; or alumoxanes of the formula:
- (Al— O)n 2 can be used in the case of cyclic compounds, wherein n is an integer from 2 to 40 and the U substituents are defined as above.
- Non-limiting examples of compounds able to form an alkylmetallocene cation are compounds of formula D + E " , wherein D + is a Br ⁇ nsted acid, able to donate a proton and to react irreversibly with a substituent X of the metallocene of formula (I) and E " is a compatible anion, which is able to stabilize the active catalytic species originating from the reaction of the two compounds, and which is sufficiently labile to be removed by an olefinic monomer.
- the anion E " comprises one or more boron atoms. More preferably, the anion E " is an anion of the formula BAr 4 , wherein the substituents Ar which can be identical or different are aryl radicals such as phenyl, pentafluorophenyl or bis(trifluoromethyl)phenyl. Tetrakis- pentafluorophenyl borate is particularly preferred compound, as described in WO 91/02012. Moreover, compounds of formula BAr 3 can be conveniently used. Compounds of this type are described, for example, in the International patent application WO 92/00333.
- the catalyst component formed by contacting a metallocene compound and an alumoxane or a compound able to form an alkylmetallocene cation can suitably be used on inert supports, such as silica, alumina, styrene/divinylbenzene copolymers, polyethylene or polypropylene, particularly for use in the gas phase polymerizations.
- the olefin polymerization processes can be carried out in liquid phase, optionally in the presence of an inert hydrocarbon solvent, either aromatic (e.g. toluene) or aliphatic (e.g. propane, hexane, heptane, isobutane, cyclohexane and 2,2,4-trimethylpentane).
- an inert hydrocarbon solvent either aromatic (e.g. toluene) or aliphatic (e.g. propane, hexane, heptane, isobutane, cyclohexane and 2,2,4-trimethylpentane).
- the polymerization temperature generally ranges from about 0°C to about 250°C, and preferably from 20 to l50°C.
- the proton spectra of ligands and metallocenes were obtained on a Bruker DPX 200 spectrometer operating in the Fourier transform mode at room temperature at 200.13 MHz.
- the samples were dissolved in CD 2 C1 2 (Aldrich, 99.5 atom % D) or 1,1,2,2- tetrachloroethane-d (Acros, 99 atom % D). Preparation of the samples was carried out under nitrogen using standard inert atmosphere techniques.
- the residual peak of CHDC1 2 or C 2 HDC1 4 in the 1H spectra (5.35 ppm and 5.95 ppm, respectively) were used as a reference.
- Dimethylsilanediyl [2-methyl-4-(4'-t ⁇ rt-butylphenyl)indenyl] [2-isopropyl-4-(4'-tert- butylphenyl)indenyl)] dimethyl zirconium is prepared following the same procedure described in example 5 of PCT/EP02/14899 by using [2-methyl-4-(4'-tert- butylphenyl)indenyl] [2-isopropyl-4-(4'-tert-butylphenyl)indenyl)]dimethylsilane instead of bis(2-methyl-indene)dimethylsilane.
- Dimethylsilanediyl bis[2-methyl-(4,5-benzoindenyl)] dimethyl zirconium is prepared following the same procedure described in example 5 of PCT/EP02/ 14899 by using bis[2- methyl-(4,5-benzoindenyl)] dimethylsilane instead of bis(2-methyl-indenyl)dimethylsilane.
- Example 1 Dimethylsilanediyl bis[2-methyl-(4,5-benzoindenyl)] dimethyl zirconium is prepared following the same procedure described in example 5 of PCT/EP02/ 14899 by using bis[2- methyl-(4,5-benzoindenyl)] dimethylsilane instead of bis(2-methyl-indenyl)dimethylsilane.
- the reaction mixture was heated at 40°C for 2 h: a 1H NMR analysis in CD 2 C1 showed conversion of the dimethyl complex into the dichloride complex (rac/meso 56/44), impure of by-products not yet identified.
- the final suspension was added of 60 mL of toluene, heated at 60°C, stirred for 15 min at this temperature and filtered on a G4 frit. The residue was discarded, whereas the filtrate was dried in vacuo and subsequently treated with ethyl ether. The resulting suspension was stirred at room temperature for 15 min and then filtered on a G4 frit: the residue was dried under vacuo giving 0.31 g of an orange powder.
- the final suspension was added of 80 mL of toluene, heated at 60°C, stirred for 30 min at this temperature and filtered on a G4 frit. The filtrate was discarded, whereas the residue was further extract with toluene and dried in vacuo. The extract was subsequently treated with 20 mL of ethyl ether. The resulting suspension was stirred at room temperature for 20 min and then filtered on a G4 frit: the residue was dried under vacuo giving 0.34 g of a yellow powder.
- reaction mixture was stirred for 2 h with final formation of an orange-red solution.
- the slurry containing ZrCl 4 (THF) 2 was allowed to warm up to room temperature and stirred for 1 h. Then the ZrCl 4 (THF) 2 slurry was slowly added at room temperature to the ligands solution containing a 2-fold MeLi excess. The resulting reaction mixture was heated at 65°C and stirred for 12 h at this temperature. A 1H NMR analysis in CD 2 CI 2 showed nearly quantitative conversion of the starting ligand to the dimethyl complex. The reaction mixture was then concentrated in vacuum up to 10% of the total volume (ca. 15 mL); pentane (ca. 50 mL) was added and the resulting suspension stirred for 15 min at room temperature.
Abstract
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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AT04730240T ATE471332T1 (en) | 2003-05-08 | 2004-04-29 | METHOD FOR PRODUCING HALIDE METALLOCENE COMPOUNDS |
EP04730240A EP1620448B1 (en) | 2003-05-08 | 2004-04-29 | Process for the production of halide metallocene compounds |
US10/555,434 US7468451B2 (en) | 2003-05-08 | 2004-04-29 | Process for the production of halide metallocene compounds |
DE602004027722T DE602004027722D1 (en) | 2003-05-08 | 2004-04-29 | METHOD FOR PRODUCING HALOGENIDE METALOCE COMPOUNDS |
JP2006505316A JP2006525264A (en) | 2003-05-08 | 2004-04-29 | Method for producing halogenated metallocene compound |
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EP03101268.5 | 2003-05-08 | ||
EP03101268 | 2003-05-08 | ||
US46919103P | 2003-05-09 | 2003-05-09 | |
US60/469,191 | 2003-05-09 |
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US (1) | US7468451B2 (en) |
EP (1) | EP1620448B1 (en) |
JP (1) | JP2006525264A (en) |
CN (1) | CN101341162A (en) |
AT (1) | ATE471332T1 (en) |
DE (1) | DE602004027722D1 (en) |
RU (1) | RU2335504C2 (en) |
WO (1) | WO2004099225A1 (en) |
Cited By (2)
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US7465688B2 (en) | 2003-09-29 | 2008-12-16 | Basell Polyolefine Gmbh | Process for the isomerization of metallocene compounds |
EP3252061A4 (en) * | 2015-08-24 | 2018-06-27 | LG Chem, Ltd. | Transition metal compound, catalyst composition comprising same, and method for producing olefin polymer using same |
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MY173869A (en) | 2009-06-16 | 2020-02-25 | Chevron Phillips Chemical Co Lp | Oligomerization of alpha olefins using metallocene-ssa catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends |
EP2485839A1 (en) * | 2009-10-06 | 2012-08-15 | Chevron Phillips Chemical Company LP | Oligomerization of olefin waxes using metallocene-based catalyst systems |
US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
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2004
- 2004-04-29 DE DE602004027722T patent/DE602004027722D1/en not_active Expired - Lifetime
- 2004-04-29 RU RU2005138107/04A patent/RU2335504C2/en active
- 2004-04-29 WO PCT/EP2004/004525 patent/WO2004099225A1/en active Application Filing
- 2004-04-29 US US10/555,434 patent/US7468451B2/en not_active Expired - Fee Related
- 2004-04-29 EP EP04730240A patent/EP1620448B1/en not_active Expired - Lifetime
- 2004-04-29 AT AT04730240T patent/ATE471332T1/en not_active IP Right Cessation
- 2004-04-29 JP JP2006505316A patent/JP2006525264A/en active Pending
- 2004-04-29 CN CNA2004800124121A patent/CN101341162A/en active Pending
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WO1995019984A2 (en) * | 1994-01-25 | 1995-07-27 | The Dow Chemical Company | Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides |
WO2002083699A2 (en) * | 2001-04-10 | 2002-10-24 | Basell Polyolefine Gmbh | Process for the production of monohalide or dihalide metallocene compounds |
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Also Published As
Publication number | Publication date |
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US7468451B2 (en) | 2008-12-23 |
EP1620448A1 (en) | 2006-02-01 |
RU2335504C2 (en) | 2008-10-10 |
EP1620448B1 (en) | 2010-06-16 |
ATE471332T1 (en) | 2010-07-15 |
US20070043228A1 (en) | 2007-02-22 |
RU2005138107A (en) | 2006-04-27 |
JP2006525264A (en) | 2006-11-09 |
DE602004027722D1 (en) | 2010-07-29 |
CN101341162A (en) | 2009-01-07 |
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