WO2004102059A1 - Mid-line connector and method for pipe-in-pipe electrical heating. - Google Patents

Mid-line connector and method for pipe-in-pipe electrical heating. Download PDF

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Publication number
WO2004102059A1
WO2004102059A1 PCT/US2004/013353 US2004013353W WO2004102059A1 WO 2004102059 A1 WO2004102059 A1 WO 2004102059A1 US 2004013353 W US2004013353 W US 2004013353W WO 2004102059 A1 WO2004102059 A1 WO 2004102059A1
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WO
WIPO (PCT)
Prior art keywords
pipe
connector
pocket
mid
pipeline
Prior art date
Application number
PCT/US2004/013353
Other languages
French (fr)
Inventor
David Martin March
Original Assignee
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V. filed Critical Shell Internationale Research Maatschappij B.V.
Priority to GB0521087A priority Critical patent/GB2416016B/en
Publication of WO2004102059A1 publication Critical patent/WO2004102059A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/18Double-walled pipes; Multi-channel pipes or pipe assemblies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L25/00Constructive types of pipe joints not provided for in groups F16L13/00 - F16L23/00 ; Details of pipe joints not otherwise provided for, e.g. electrically conducting or insulating means
    • F16L25/01Constructive types of pipe joints not provided for in groups F16L13/00 - F16L23/00 ; Details of pipe joints not otherwise provided for, e.g. electrically conducting or insulating means specially adapted for realising electrical conduction between the two pipe ends of the joint or between parts thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L53/00Heating of pipes or pipe systems; Cooling of pipes or pipe systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L53/00Heating of pipes or pipe systems; Cooling of pipes or pipe systems
    • F16L53/30Heating of pipes or pipe systems
    • F16L53/35Ohmic-resistance heating
    • F16L53/37Ohmic-resistance heating the heating current flowing directly through the pipe to be heated

Definitions

  • the present invention relates to electrical heating of subsea pipelines. More particularly the invention relates to electrical heating with a pipe-inside-pipe configuration and a connector to the pipes about midway between bulkheads at each end.
  • Background of the Invention Due to cool water temperatures (about 40° F (4.4° C)) in deep water offshore hydrocarbon recovery operations, hydrocarbon fluids flowing through subsea pipelines become very viscous or deposit paraffin when the temperature of the fluid drops, adversely affecting fluid flow in the pipeline. Hydrocarbon gas under pressure combines with water at reduced temperatures to form a solid material, called a "hydrate.” Hydrates can plug pipelines and the plugs may be very difficult to remove.
  • SHIP Single Heated Insulated Pipe
  • EHPIP pipe-in-pipe system
  • An EHPIP subsea pipeline has a flow line or inner pipe for transporting well fluids which is surrounded concentrically by and electrically insulated from an electrically conductive outer pipe until the two pipes are electrically connected at one end. Voltage is applied between the inner and outer pipes at the opposite end and electrical current flows along the exterior surface of the inner pipe and along the interior surface of the outer pipe.
  • This pipe-in-pipe method of heating is disclosed, for example, in U.S. Patent No. 6,142,707, which is hereby incorporated by reference. U.S.
  • Flow pipe 12 is positioned concentrically within outer pipe 14, so that annulus 13 is defined between the pipes.
  • Concentric pipes 12 and 14 are electrically isolated except at bulkheads 16, which are placed at each end of the selected segment 10 of pipeline to be heated.
  • Electrical power supply 6 supplies voltage at a selected voltage and frequency (including Direct Current) between flow pipe 12 and outer pipe 14 to a selected point on the pipes. Typically, the electrical voltage is supplied to the heating segment 10 at the mid-point between bulkheads 16.
  • voltage may also be supplied at a location offset from the mid-point between bulkheads 16, such that a difference in electrical impedance between each portion of the segment to be heated is taken into account (for example, to allow equal current flow in each portion of the heated segment, even though impedance is different) or to provide more power for heating in one portion of the selected segment.
  • voltage may be supplied anywhere, in this disclosure an electrical connector between bulkheads will be referred to as a "mid-line connector".
  • Adjoining heating segments may be electrically heated.
  • a single bulkhead between two heating sections may complete two electrical circuits, such that electrical current from both segments passes through the single bulkhead.
  • the length of a heating segment may be from a few feet, for example about 50 feet (15.2 m), to 40 miles (64.4 km) or more, depending on the requirements for heating the pipeline. More typically, the length of heating segments range from about 1 mile (1.6 km) to about 10 miles (16.1 km).
  • a pipeline 2 is deployed normally thousands of feet below sea surface 1 having a first end near platform 3, a floating facility or other host facility, and having a second end on the sea floor 4.
  • Platform 3 is anchored to sea floor 4.
  • Riser 5 connects heating segment 10 to the top side of platform 3 or other facility.
  • Riser 5 may also be heated using the pipe-in-pipe configuration, in which case it will be treated as a heating segment 10 of the pipeline 2.
  • Electrical generator 6 is supported on platform 3, among other equipment. Electrical generator 6 is connected electrically by cable 7 to mid- line connectors 20. Heating segments 20 are separated by bulkhead 16.
  • the total voltage drop is maintained at the power supply-end of the pipe segment to be heated.
  • the voltage drop at the power input end of a heated segment detennines the amount of heating available and the length of a segment that can be heated. Voltage drop is limited by the dielectric strength and thickness of electrical insulation available.
  • a configuration for minimizing voltage required with the pipe-in-pipe method is needed. Also, there is a need for an apparatus and method that allow heating selected segments of a pipeline that is heated by the pipe-in- pipe method.
  • a pipe-in-pipe mid-line connector is needed which may be connected to the electrical cable after the pipe-in-pipe is deployed to the sea floor.
  • a pipe-in-pipe mid-line connector is also needed which provides relative axial movement between the flow pipe and the outer pipe to avoid structural failures.
  • the pipe-in-pipe pipeline must endure bending stresses and tensile stresses which are significant.
  • a mid- line connector is needed which enables flexibility between the flow pipe and the outer pipe but also enables both the flow pipe and the outer pipe to share the tensile loads.
  • a mid- line connector which reduces local heating caused by poor contact resistance is also needed. Further, there is a need for a mid-line connector which protects the flow pipe from local corrosion and build-up of oxidation particles within the mid-line connector.
  • mid-line connector may be electrically unused for long periods of time, a mid- line connector which will not allow its electrical contacts to become corroded is needed. Because mid-line connectors are the electrical power supply points for pipeline heating segments, a mid-line connector which controls stray current effects on the mid-line connector is needed. Still further, a pipe-in-pipe system is needed which immobilizes intra pipe movement between the flow pipe and the outer pipe.
  • the present invention involves a variety of mid-line connectors for pipe-in-pipe pipelines. More specifically, a connector of an electrical cable to a pipe-in-pipe pipeline, wherein the pipeline comprises an inner pipe and an outer pipe, said connector comprising: a connector housing joinable to the outer pipe of the pipeline; a blank pipe positioned within said connector housing and joinable to the inner pipe of the pipeline; at least one pocket mounted in said connector housing, wherein the cable is mateable with the at least one pocket; a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe; and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe.
  • the mid-line connector may be connected easily to a power generator with an electric cable.
  • the mid-line connector may have an electrically conductive flexible inner pipe connection which enables relative movement between the inner pipe and the outer pipe.
  • the mid-line connector may have a layer of copper coating on the inner pipe where the electric conductor is connected to the inner pipe so as to reduce local hating caused by poor contact resistance.
  • the mid-line connector may also have a moisture control protective layer coated on the exterior of the inner pipe to prevent the inner pipe from oxidation, corrosion and/or build up of oxidation particles.
  • the mid-line connector may be capable of high axial loading.
  • the mid-line connector may also be equipped with dummy plugs to prevent electrical couplers from decay.
  • the mid-line connector may be oriented when placed on the sea floor so that electrical couplers are easily accessible on top of the mid-line connector.
  • the mid-line connector may also have its exterior surfaces deliberately left bare so that potential difference may exist over a large surface area, preventing localized accumulation of stray current.
  • the mid-line connector may also have inner and outer body configurations adaptable to different flowline diameters without modifying shape, strength, or geometry of the connector.
  • the pipe-in-pipe heating system may also have foam in an annulus between the pipes to prevent relative movement between the pipes.
  • a connector of an electrical cable to a pipe-in-pipe pipeline wherein the pipeline has an inner pipe and an outer pipe
  • the connector having several parts including: a connector housing joinable to the outer pipe of the pipeline; a blank pipe positioned within the connector housing and joinable to the inner pipe of the pipeline; at least one pocket mounted in the connector housing, wherein the cable is mateable with at least one pocket; a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe; and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe.
  • a heated pipe-in-pipe pipeline and cable system having: an outer pipe; an inner pipe concentric within the outer pipe and forming an annulus between the pipes; a connector including several parts: a connector housing joined to the outer pipe, a blank pipe positioned within the comiector housing and joined to the inner pipe, at least one pocket mounted in the connector housing, wherein the cable is mated with the at least one pocket, a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe, and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe; and a bulkhead electrically connecting the outer pipe to the inner pipe.
  • a further aspect of the invention is a method for heating a pipe-in-pipe pipeline with steps including: placing on a sea floor a pipe-in-pipe pipeline comprising a mid-line connector and an electrically conductive bulkhead; removing a dummy plug from the mid- line connector; mating a cable with the mid-line connector; and supplying electric power to the mid-line connector through the cable.
  • the bulkhead is made of steel and is joined to the flow pipe and the outer pipe.
  • Another aspect of the invention is a mid-line connector for a pipe-in-pipe heating system, wherein the mid-line connector housing has bare exterior surfaces and a sacrificial electrode.
  • a further aspect of the present invention is a mid-line connector for a pipe-in-pipe heating system, wherein a blank pipe of the mid-line connector has a blank pipe for connection to the flow pipe with an electrically conductive coating on an exterior surface proximate a couple location of a blank pipe electrical conductor to the blank pipe and a corrosion protective coating on an exterior surface.
  • one aspect is a mid-line connector for a pipe-in-pipe heated pipeline wherein an interior compartment of the mid-line connector which houses electrically conductive components is completely sealed to prevent sea water penetration.
  • Still another aspect of the invention is a mid-line connector equipped with dummy plugs in electric couplers or pockets to prevent deterioration of the couplers or pockets during periods of electrical inactivity.
  • a mid-line connector for a pipe-in-pipe heating system, wherein the connector has two wet-mateable electric coupler devices which are mounted to the mid-line connector housing in directions opposite to each other and parallel to the longitudinal axis of said connector housing.
  • Figure 1 is a cross-sectional, side view of a heating segment of a pipeline.
  • Figure 2 is an illustration of an offshore application of a pipe-in-pipe heated pipeline with mid-line connectors.
  • Figure 3 is a cut-away, perspective view of a mid-line connector of the present invention with connection pockets aligned with the longitudinal axis of the pipeline, and electrical connections to the inner and outer pipes of the pipelines.
  • Figure 4 is a cross-sectional, side view of a mid-line connector of the present invention with connection pockets, electrical connections to the inner and outer pipes of the pipelines, coatings on the imier pipe, and seals in the annulus between the pipes.
  • Figure 5 is a side view of a mid-line connector of the present invention having bare external surfaces.
  • Figure 6 is an end view of a mid-line connector placed on a sea floor and oriented with the connection pockets toward the top of the connector.
  • Figure 7 is an end view of a mid-line connector placed on a sea floor and oriented with the connection pockets toward the bottom of the connector.
  • FIG. 3 a perspective view of an embodiment of a mid-line connector of the present invention is illustrated.
  • the mid-line connector 20 is inserted into a heating segment 10 of a pipeline 2 between adjacent pipe sections of the pipeline 2.
  • Adjacent sections of the flow line 12 are connected to each other by a blank pipe section 21 which is welded to the ends of the adjacent sections of the flow pipe 12.
  • the adjacent sections of the outer pipe 14 are connected to each other by a connector housing 22 which is welded to the sections of the outer pipe 14.
  • an annulus 13 is defined between the flow pipe 12 and the outer pipe 14. This annulus is similarly defined between the blank pipe section 21 and the connector housing 22.
  • Spacer rings 23 may be positioned in the annulus 13 to ensure proper distance is maintained between the blank pipe section 21 and the connector housing 22.
  • the spacer rings 23 may be non-conducting centralizers which maintain the inner pipe concentric to the outer pipe and to electrically insulate the pipes from each other. Some embodiments of the invention have nonconducting "shear stops” or “water stops” placed at selected intervals in the annulus. Shear stops are commonly plastic material. Water stops may be used to prevent complete water flooding of the annulus in the event of a breach in the outer pipe or other components of the pipe-in-pipe system. In the embodiment shown, the spacer rings 23 form a seal between the blank pipe section 21 and the connector housing 22 to prevent sea water penetration into the inner compartment of the mid-line connector.
  • the outer pipe of the pipeline may be thermally insulated to minimize heat loss and to reduce the amount of electrical current necessary to heat the contents of the pipe.
  • outer surfaces of the connector housing may be thermally insulated.
  • the outer surface of the flow pipe may be provided with an electrically insulating coating, for example, a fusion bonded epoxy.
  • Such coating when applied with an appropriate thickness, such as 20 mils (0.51 mm) or more, can withstand up to 8000 volts before failing, even after being wetted for several days.
  • the flow pipe may also have a thermally insulating layer and perhaps even a co-extruded solid skin outer surface which protects the insulating layer.
  • the solid skin may be a water barrier to protect the insulating layer if its is porous and provides an additional layer of electrical insulation.
  • the blank pipe section 21 of the mid-line connector may also have these noted layers and coatings.
  • Intra pipe movement between the flow pipe 12 and the outer pipe 14 may be entirely immobilized using a man made syntactic foam 34 or similar curing foam 34 that is poured in place after assembly of the mid-line connector 20.
  • the foam 34 is a two-part syntactic foam insulation (epoxy resin, s.g 0.76) containing glass microsphere filler that is a pour-in-place between the centralized blank pipe section 21 and connector housing 22. custom jigs may be employed to guarantee centralization and prevention of creep during the pouring or curing activity. Atmospheric conditions are controlled for optimal curing results and the mobilization of maximum shear capacity.
  • the foam 34 acts as an intra pipe shear stop.
  • Foams acceptable for this purpose have high insulating capacity for the flow pipe contents, low water absorption characteristics, a resistance to charring and short circuit due to arcing across the surface. Foam properties should be verified before a particular foam is used to guarantee the effectiveness and reliability of the selected material, as is known to those of skill in the art.
  • the foam average delivered shear stress for this application is in the range of 180 to 200 psi (1.24 - 1.38 mpa). Quality of selected materials should be useful for installation in the marine environment, variances in recipe and capable of adherence to bare gritblasted steel and coated steel surfaces with epoxy based paints or other similar protective coverings. Methods of centralizing the flow pipe 12 in the outer pipe 14 are carefully controlled to maintain concentricity and thereby continue to deliver the alignment of flow pipe 12 and the outer pipe 14 for welding.
  • the connector housing 22 also has a flow pipe connection pocket 24 and an outer pipe connection pocket 28.
  • the connection pockets 24 and 28 are wet mate receptacles.
  • the connection pockets 24 and 28 are female electrical couplers into which male couplers are inserted to establish electrical communication between a cable 7 (see Figure 2) and the mid-line coimector 20.
  • a dummy plug 25 is shown inserted into the flow pipe connection pocket 24.
  • a live plug 29 is shown inserted into outer pipe connection pocket 28.
  • Dual elastomeric seals are positioned on the inside of the connection pockets to form a seal between the connection pockets and the plugs upon insertion.
  • Electric leads 27 are located at the distal ends of the plugs for mating with leads in the bottoms of the connection pockets.
  • the flow pipe connection pocket 24 is electrically coupled to the blank pipe section 21 by a braided strap 30.
  • One end of the braided strap 30 is bolted to the flow pipe connection pocket 24, and the other end is bolted to the blank pipe section 21 by a connection block 31.
  • the outer pipe connection pocket 28 is electrically coupled to the connector housing 22 by a connection disc 32 mounted in the connector housing 22 proximate the outer pipe connection pocket 28.
  • a copper coating 35 is also affixed to the exterior of the blank pipe section 21 in the vicinity of the connection with the braided strap 30.
  • a moisture control coating 36 is also affixed to the blank pipe section 21 in the vicinity of the connection with the braided strap 30. The surface area covered by the moisture control coating 36 is greater than the surface area covered by the copper coating 35.
  • the flow pipe connection is coated with a layer of copper spray 35 (see Figures 3 and 4).
  • the purpose of the copper spray 35 is to reduce local heating caused by poor contact resistance. Local heating, caused by contact resistance (changes in section and shape of electrical conducting materials), is a measured and understood condition that is controlled to protect non-metallic parts in the connector cavity and the wet mateable connections from overheating. Localized overheating of non- metallic components is defined as temperatures above 250 degrees F (121 degrees C). The purity of the copper spray is monitored as part of the process.
  • a copper layer approximately 15 mis (0.381 mm) thick is adhered to the outside surface of the blank pipe section covering an area about 3 inches (7.6 cm) in all directions around the connection block 31 and over the connection block 31.
  • the connector housing 22 is made of two sections which are welded together during the assembly process. Each of the two sections has a cylindrical pipe section the same diameter as the outer pipe of the pipe-in-pipe pipeline, a larger pipe section, and a taper or conical section which joins the different sized pipe sections.
  • the blank pipe section 21 and the connector housing 22 are butt welded to the flow pipe 12 and outer pipe 14. Any means known to those of skill in the art for connecting pipe sections may also be used.
  • the mid-line connector 20 may consist of an outer body forging and an inner body forging.
  • the inner body forging may be a carbon steel component (ASTM A694) and the flow pipe may be API 5L X70.
  • the blank pipe section 21 is made identical to the flow pipe bore allowing routine pigging operations.
  • the diameter of the outer body forging is selected to accommodate the two electrical connection points or connection pockets 24 and 28.
  • the electrical connection points may be sub-assemblies that are installed with mechanical fasteners and include dual elastomeric seals 26. Redundancy in sealing arrangements is a conventional engineering practice, however in this application, the assembly procedure is simple and modular using this teclmique.
  • the seals may be selected for field life and durable to operating conditions (40 degrees F to 250 degrees F; 4.5 degrees C to 121 degrees C) on the seafloor.
  • the inner body forging and outer body forging are designed for simplicity in connection to the adjacent flowline pipe using butt welds or full penetration pressure containing welds.
  • the mid-line connector is normally deployed within the pipeline 2 and affixed by annular welding and non-destructive examination of the welds on an installation vessel before deployment.
  • FIG. 4 a side cross-sectional view of an embodiment of a mid-line connector of the present invention is shown.
  • the flow pipe 12 extends through the inside of the connector 20, while the outer pipe 14 comprises the exterior of the connector 20.
  • Foam 34 fills the annulus 13 between the flow pipe 12 and the outer pipe 14.
  • Spacer rings 23 also stabilize the pipes relative to each other and seal the interior of the housing.
  • the end of the cable 7 has two electrical cables carrying an electrical supply from the electrical power supply 6.
  • the cable 7 splits into branch cables 8 and 9 for insertion into the flow pipe connection pocket 24 and the outer pipe connection pocket 28, respectively.
  • the flow pipe connection pocket 24 is electrically coupled to the flow pipe 12 by strap 30. The power is energized after both connections are made to the pipe-in-pipe heating segment 10 through two separate electrical leads inserted into the mid-line connector 20.
  • the connection between the cable 7 and the mid-line connector 20 may be made by a single remotely operated vehicle (ROV) equipped with two manipulator arms. Each connection is gripped in a manipulator using an ROV interface handle. Interface handles are commonplace to the subsea intervention industry and vary to suit the vehicle type on station.
  • the cable may be buoyed so that it is more easily accessed by the ROV.
  • wet-mate connectors enable underwater connection by ROV as a routine task.
  • the wet-mate connector aligns the plug using a guiding barrel and protects a central power conduction pin. During the plug travel the power conducting surfaces are wiped clean of moisture by two seals combined with a pressure compensated oil filled chamber where a conducting shuttle pin comes to rest in the plug. The plug is held in place using two spring loaded latches riding against detents. Plug rotation is limited by a key and corresponding keyway in the wet-mate connector.
  • the mid-line connector is deployed such that it arrives on the seabed with the connection pockets in the top position, clear from the seafloor and accessible by the ROV, as shown in Figure 6. If for some inadvertent reason, e.g., residual pipe bending, curvature of the flowline, the mid-line connector 20 is laid down with a different orientation (see Figure 7), the connection pockets can still be successfully made by an ROV submarine. In some applications of the invention, it is a matter of random deposition on the sea floor 4, so that the ROV should be capable of connecting the cable 7 to the mid- line connector 20 regardless of its orientation. This is accomplished by excavation of the seabed material locally through dredging equipment attached to the ROV or any other method known to those of skill in the art.
  • Dummy plugs 25 are illustrated in Figures 3 and 4.
  • connection pockets 24 and 28 may be protected from the marine environment over the life of field by long term dummy plugs 25.
  • a typical life of field is 20 years with the electrical connection lying on the seafloor.
  • Dummy plugs prevent calcareous type deposition on the conducting surfaces of the wet- mateable connector, particularly the silver plate on a central conducting pin.
  • the long term dummy plugs 25 are equipped with two wiping seals 26 and encapsulate the critical electrical contact pin in an oil filled chamber, as noted above. In some applications it is advantageous to protect the pins and surfaces. This is particularly true during long dormant periods of no heating activity.
  • connection pockets 24 and 28 face out in a horizontal aspect in parallel with the axis of the flow pipe 12. This orientations enables a minimum pipe swelling overall diameter.
  • the principle of maintaining electrical isolation between the pipes is respected by the details of this connection device. The also enables easier access to the connection pockets by the ROV.
  • connection of electrical power to the flowline is made in an underwater environment at great depth, up to 6300 feet (1920 metres), or even as great as 8700 feet (2652 metres).
  • Electrical couplings which join the cable 7 (see Figure 2) to the mid-line connector 20 (see Figures 3 and 4) may be wet- mateable devices. Any electrical couplings suitable for underwater applications may also be used.
  • the electrical couplings may be designed for rated current and voltage and provided as sub-assemblies for insertion into the connection assembly. Depending upon the particular subsea environments, the electrical couplings may be designed for use in thousands of feet of water.
  • the flow pipe connection pocket carries the delivered single phase alternating current and voltage to the flow pipe.
  • This connection is subjected to voltage up to 1200 volts and single phase alternating current up to 1100 A.
  • the flow pipe connection consists of a welded block with bolt fastenings.
  • the bolt fastenings hold a copper braided strap in place 30, in a compliant 'U' shape.
  • the copper braided strap 30 connects between the wet-mateable electrical connection and the flow pipe.
  • the configuration of the strap enables some axial movement of the pipe during heating.
  • the copper braided strap 30 may be covered in a protective jacket to prevent any inadvertent damage during welding up of the unit.
  • the blank pipe section 21 is coated with a moisture control seal 36 (see Figures 3 and 4) or other protective coating on its external surface to protect the surface from local corrosion and build-up of oxidation particles in the cavity.
  • the coating 36 is a 12-15 mils (.30 mm - .38 mm) coat of epoxy paint.
  • the coating 36 serves to keep the blank pipe section 21 clean and dry during the assembly process and during operation.
  • the coating 36 should maintain its integrity even though surfaces may reach temperatures of 250 °F (121 °C) during electrical heating operations.
  • Some embodiments of the invention include non-metallic spacer rings 23 with seals to prevent moisture collection or contamination of the electrified compartment or spaces.
  • the mid-line connector 20 is some embodiments of the invention is a robust structural assembly suitable for launching from an installation vessel, with typical loads up to and including 400 US tons (362.9 tonne) in 6000 ft (1829 meters) of water depth.
  • the design of the mid-line electrical connector is such that the inner and outer body can be adapted to different flow pipe diameters without changing the shape, strength, or the geometry of the electrical connections and their individual attachment to the flow and outer pipes.
  • concentric metallic reducers may be employed to adapt the diameter of the electrically heated flow pipe. Typical combinations include 6 inch pipe inside 10 inch pipe, 8 inch pipe inside 12 inch pipe, and 10 inch pipe inside 16 inch pipe (15.24 cm pipe inside 25.4 cm pipe, 20.32 cm pipe inside 30.48 cm pipe, and 25.4 cm pipe inside 40.64 cm pipe). Other combinations are also possible. Larger diameters of pipe require higher levels of current and voltage delivery to create the heating effect.
  • Metallic reducers may be employed to achieve the adaptability of the mid-line coimector. The reducers may be substantially joined into the flow pipe using full butt welded connections and proven by non-destructive examination methods and further by externally applied proof pressure test.
  • Environmental barriers may comprise more than one sublayer, each of which may optionally be directed toward a particular environmental protective function, e.g., abrasion resistive material, tear resistant material, water and moisture proof material, stray current protective material, thermal protection material, or chemical protection material.
  • abrasion resistive material e.g., abrasion resistive material, tear resistant material, water and moisture proof material
  • stray current protective material e.g., stray current protective material
  • thermal protection material e.g., thermal protection material, or chemical protection material.
  • chemical protection material e.g., Polyethylene, with an encasement standard of 800 v/mil dielectric resistance, is a good example of a stray current protective material for pipelines.
  • the outer surfaces of the mid-line connector are similarly covered with a stray current protective material.
  • a defect-free bonded coating is impossible to economically obtain.
  • a side view of the outside of a mid-line connector 20 of the present invention is shown.
  • outside surfaces of mid-line connector are deliberately left exposed.
  • the bare area of the mid-line connector i.e., an area without any coating over the metal, is provided to serve as a discharge electrode.
  • the area of the discharge electrode or the bare housing is selected to decrease current density from seawater to the area of the heated segment where leakage current leaves or enters the mid- line connector.
  • the outside surfaces are bare over a distance 33 such that during electrical heating activity, the phenomena of stray current may be accommodated by the larger surface area of steel over which potential difference could exist.
  • a stray current protective material 38 is adhered to the exterior of the connector housing 22 and/or outer pipe 14 in areas not deliberately left bare. While the outside surface is deliberately left bare or exposed for heating, it may be protected from normal conditions of ferrous material in seawater, using sacrificial anodes attached to the mid-line connector adjacent to the midpoint and sized for the life of field. In some cases, the sacrificial anode is sized for 20 years of flowline operation.
  • the current density is decreased to a value that provides corrosion rates not greatly affected by the current flow through the surface of the sacrificial electrode or bare mid-line connector.
  • the required area of the sacrificial electrode or bare mid-line connector may be estimated from calculations of current density at different values of electric field along the pipeline and calculations or measurements of electric field near the ends of the heated segment of the pipeline, along with results of measurements of corrosion rates versus current density. Measurements of electric field along the pipeline are preferably made for the pipeline to be used.

Abstract

For heating a pipe-in-pipe pipeline with power provided through an electric cable, mid-line connector is provided including: a connector housing joinable to the outer pipe of the pipeline; a blank pipe positioned within the connector housing and joinable to the inner pipe of the pipeline; at least one pocket mounted in the connector housing, wherein the cable is mateable with the at least one pocket; a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe; and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe.

Description

MID-LINE CONNECTOR AND METHOD FOR PIPE-IN- PIPE ELECTRICAL HEATING
Field of the Invention
The present invention relates to electrical heating of subsea pipelines. More particularly the invention relates to electrical heating with a pipe-inside-pipe configuration and a connector to the pipes about midway between bulkheads at each end. Background of the Invention Due to cool water temperatures (about 40° F (4.4° C)) in deep water offshore hydrocarbon recovery operations, hydrocarbon fluids flowing through subsea pipelines become very viscous or deposit paraffin when the temperature of the fluid drops, adversely affecting fluid flow in the pipeline. Hydrocarbon gas under pressure combines with water at reduced temperatures to form a solid material, called a "hydrate." Hydrates can plug pipelines and the plugs may be very difficult to remove.
One solution involves electrical heating of the subsea pipeline to prevent excessive cooling of the fluid hydrocarbons. Heating by a variety of electrical methods has been known. Two configurations for electrical heating have been considered. One configuration, called a Single Heated Insulated Pipe (SHIP) system uses a single, electrically insulated flowline with current passing along the flowline. Another configuration is called a pipe-in-pipe system (EHPIP).
An EHPIP subsea pipeline has a flow line or inner pipe for transporting well fluids which is surrounded concentrically by and electrically insulated from an electrically conductive outer pipe until the two pipes are electrically connected at one end. Voltage is applied between the inner and outer pipes at the opposite end and electrical current flows along the exterior surface of the inner pipe and along the interior surface of the outer pipe. This pipe-in-pipe method of heating is disclosed, for example, in U.S. Patent No. 6,142,707, which is hereby incorporated by reference. U.S. Patents 6,161,025, 6,179,523, 6,264,401, 6,292,627, 6,315,497, 6,371,693; and commonly owned patent applications titled "Annulus for Electrically Heated Pipe-in-Pipe Pipeline", Serial No. 09/910,696; "Method of Installation of Electrically Heated Pipe-in-Pipe Subsea Pipeline", Serial No. 09/910,678, Publication No. US2003/0017007A1; "Method for Commissioning and Operating an Electrically Heated Pipe-in-Pipe Subsea Pipeline", Serial No. 09/910,622, Publication No. US2003/0020499A1; "Corrosion Protection of Electrically Heated Pipe- in-Pipe Subsea Pipeline", Serial No. 09/910,489, Publication No. US2003/0015436A1; "Power Supply for Electrically Heated Subsea Pipeline", Serial No. 09/910,625, Publication No. US2003/0015519A1; "Apparatus and Method for Electrically Testing of Electrically Heated Pipe-in-Pipe Pipeline", Serial No. 09/910,295, Publication No. US2003/0016028A1 , are all hereby incorporated by reference.
Referring to Figure 1, the general concept a pipe-in-pipe heating segment 10 is illustrated. Flow pipe 12 is positioned concentrically within outer pipe 14, so that annulus 13 is defined between the pipes. Concentric pipes 12 and 14 are electrically isolated except at bulkheads 16, which are placed at each end of the selected segment 10 of pipeline to be heated. Electrical power supply 6 supplies voltage at a selected voltage and frequency (including Direct Current) between flow pipe 12 and outer pipe 14 to a selected point on the pipes. Typically, the electrical voltage is supplied to the heating segment 10 at the mid-point between bulkheads 16. However, voltage may also be supplied at a location offset from the mid-point between bulkheads 16, such that a difference in electrical impedance between each portion of the segment to be heated is taken into account (for example, to allow equal current flow in each portion of the heated segment, even though impedance is different) or to provide more power for heating in one portion of the selected segment. While voltage may be supplied anywhere, in this disclosure an electrical connector between bulkheads will be referred to as a "mid-line connector". Adjoining heating segments may be electrically heated. A single bulkhead between two heating sections may complete two electrical circuits, such that electrical current from both segments passes through the single bulkhead. The length of a heating segment may be from a few feet, for example about 50 feet (15.2 m), to 40 miles (64.4 km) or more, depending on the requirements for heating the pipeline. More typically, the length of heating segments range from about 1 mile (1.6 km) to about 10 miles (16.1 km).
Referring to Figure 2, a system implementing a mid-line pipe-in-pipe electrically heated system is shown. A pipeline 2 is deployed normally thousands of feet below sea surface 1 having a first end near platform 3, a floating facility or other host facility, and having a second end on the sea floor 4. Platform 3 is anchored to sea floor 4. Riser 5 connects heating segment 10 to the top side of platform 3 or other facility. Riser 5 may also be heated using the pipe-in-pipe configuration, in which case it will be treated as a heating segment 10 of the pipeline 2. Electrical generator 6 is supported on platform 3, among other equipment. Electrical generator 6 is connected electrically by cable 7 to mid- line connectors 20. Heating segments 20 are separated by bulkhead 16.
In typical pipe-in-pipe methods of heating, the total voltage drop is maintained at the power supply-end of the pipe segment to be heated. The voltage drop at the power input end of a heated segment detennines the amount of heating available and the length of a segment that can be heated. Voltage drop is limited by the dielectric strength and thickness of electrical insulation available. A configuration for minimizing voltage required with the pipe-in-pipe method is needed. Also, there is a need for an apparatus and method that allow heating selected segments of a pipeline that is heated by the pipe-in- pipe method.
A pipe-in-pipe mid-line connector is needed which may be connected to the electrical cable after the pipe-in-pipe is deployed to the sea floor. A pipe-in-pipe mid-line connector is also needed which provides relative axial movement between the flow pipe and the outer pipe to avoid structural failures. During deployment, the pipe-in-pipe pipeline must endure bending stresses and tensile stresses which are significant. A mid- line connector is needed which enables flexibility between the flow pipe and the outer pipe but also enables both the flow pipe and the outer pipe to share the tensile loads. A mid- line connector which reduces local heating caused by poor contact resistance is also needed. Further, there is a need for a mid-line connector which protects the flow pipe from local corrosion and build-up of oxidation particles within the mid-line connector. Because mid-line connector may be electrically unused for long periods of time, a mid- line connector which will not allow its electrical contacts to become corroded is needed. Because mid-line connectors are the electrical power supply points for pipeline heating segments, a mid-line connector which controls stray current effects on the mid-line connector is needed. Still further, a pipe-in-pipe system is needed which immobilizes intra pipe movement between the flow pipe and the outer pipe. Summary of the Invention
The present invention involves a variety of mid-line connectors for pipe-in-pipe pipelines. More specifically, a connector of an electrical cable to a pipe-in-pipe pipeline, wherein the pipeline comprises an inner pipe and an outer pipe, said connector comprising: a connector housing joinable to the outer pipe of the pipeline; a blank pipe positioned within said connector housing and joinable to the inner pipe of the pipeline; at least one pocket mounted in said connector housing, wherein the cable is mateable with the at least one pocket; a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe; and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe.
The mid-line connector may be connected easily to a power generator with an electric cable. The mid-line connector may have an electrically conductive flexible inner pipe connection which enables relative movement between the inner pipe and the outer pipe.
The mid-line connector may have a layer of copper coating on the inner pipe where the electric conductor is connected to the inner pipe so as to reduce local hating caused by poor contact resistance. The mid-line connector may also have a moisture control protective layer coated on the exterior of the inner pipe to prevent the inner pipe from oxidation, corrosion and/or build up of oxidation particles. The mid-line connector may be capable of high axial loading. The mid-line connector may also be equipped with dummy plugs to prevent electrical couplers from decay. The mid-line connector may be oriented when placed on the sea floor so that electrical couplers are easily accessible on top of the mid-line connector. The mid-line connector may also have its exterior surfaces deliberately left bare so that potential difference may exist over a large surface area, preventing localized accumulation of stray current. The mid-line connector may also have inner and outer body configurations adaptable to different flowline diameters without modifying shape, strength, or geometry of the connector. The pipe-in-pipe heating system may also have foam in an annulus between the pipes to prevent relative movement between the pipes.
According to one aspect of the invention, there is provided a connector of an electrical cable to a pipe-in-pipe pipeline, wherein the pipeline has an inner pipe and an outer pipe, the connector having several parts including: a connector housing joinable to the outer pipe of the pipeline; a blank pipe positioned within the connector housing and joinable to the inner pipe of the pipeline; at least one pocket mounted in the connector housing, wherein the cable is mateable with at least one pocket; a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe; and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe. According to another aspect of the invention, there is a heated pipe-in-pipe pipeline and cable system having: an outer pipe; an inner pipe concentric within the outer pipe and forming an annulus between the pipes; a connector including several parts: a connector housing joined to the outer pipe, a blank pipe positioned within the comiector housing and joined to the inner pipe, at least one pocket mounted in the connector housing, wherein the cable is mated with the at least one pocket, a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe, and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe; and a bulkhead electrically connecting the outer pipe to the inner pipe. A further aspect of the invention is a method for heating a pipe-in-pipe pipeline with steps including: placing on a sea floor a pipe-in-pipe pipeline comprising a mid-line connector and an electrically conductive bulkhead; removing a dummy plug from the mid- line connector; mating a cable with the mid-line connector; and supplying electric power to the mid-line connector through the cable. In some embodiments, the bulkhead is made of steel and is joined to the flow pipe and the outer pipe.
Another aspect of the invention is a mid-line connector for a pipe-in-pipe heating system, wherein the mid-line connector housing has bare exterior surfaces and a sacrificial electrode.
A further aspect of the present invention is a mid-line connector for a pipe-in-pipe heating system, wherein a blank pipe of the mid-line connector has a blank pipe for connection to the flow pipe with an electrically conductive coating on an exterior surface proximate a couple location of a blank pipe electrical conductor to the blank pipe and a corrosion protective coating on an exterior surface.
While there are many aspects of the invention, one aspect is a mid-line connector for a pipe-in-pipe heated pipeline wherein an interior compartment of the mid-line connector which houses electrically conductive components is completely sealed to prevent sea water penetration.
Still another aspect of the invention is a mid-line connector equipped with dummy plugs in electric couplers or pockets to prevent deterioration of the couplers or pockets during periods of electrical inactivity.
According to another aspect of the present invention, there is provided a mid-line connector for a pipe-in-pipe heating system, wherein the connector has two wet-mateable electric coupler devices which are mounted to the mid-line connector housing in directions opposite to each other and parallel to the longitudinal axis of said connector housing. Brief Description of the Drawings
The present invention is better understood by reading the following description of non-limitative embodiments with reference to the attached drawings wherein like parts of each of the several figures are identified by the same referenced characters, and which are briefly described as follows:
Figure 1 is a cross-sectional, side view of a heating segment of a pipeline.
Figure 2 is an illustration of an offshore application of a pipe-in-pipe heated pipeline with mid-line connectors. Figure 3 is a cut-away, perspective view of a mid-line connector of the present invention with connection pockets aligned with the longitudinal axis of the pipeline, and electrical connections to the inner and outer pipes of the pipelines.
Figure 4 is a cross-sectional, side view of a mid-line connector of the present invention with connection pockets, electrical connections to the inner and outer pipes of the pipelines, coatings on the imier pipe, and seals in the annulus between the pipes.
Figure 5 is a side view of a mid-line connector of the present invention having bare external surfaces.
Figure 6 is an end view of a mid-line connector placed on a sea floor and oriented with the connection pockets toward the top of the connector. Figure 7 is an end view of a mid-line connector placed on a sea floor and oriented with the connection pockets toward the bottom of the connector.
It is to be noted, however, that the appended drawings illustrate only typical embodiments of this invention and are therefore not to be considered limiting of its scope, as the invention may admit to other equally effective embodiments. Detailed Description of the Invention
Referring to Figure 3, a perspective view of an embodiment of a mid-line connector of the present invention is illustrated. The mid-line connector 20 is inserted into a heating segment 10 of a pipeline 2 between adjacent pipe sections of the pipeline 2. Adjacent sections of the flow line 12 are connected to each other by a blank pipe section 21 which is welded to the ends of the adjacent sections of the flow pipe 12. The adjacent sections of the outer pipe 14 are connected to each other by a connector housing 22 which is welded to the sections of the outer pipe 14. As previously described, an annulus 13 is defined between the flow pipe 12 and the outer pipe 14. This annulus is similarly defined between the blank pipe section 21 and the connector housing 22. Spacer rings 23 may be positioned in the annulus 13 to ensure proper distance is maintained between the blank pipe section 21 and the connector housing 22. The spacer rings 23 may be non-conducting centralizers which maintain the inner pipe concentric to the outer pipe and to electrically insulate the pipes from each other. Some embodiments of the invention have nonconducting "shear stops" or "water stops" placed at selected intervals in the annulus. Shear stops are commonly plastic material. Water stops may be used to prevent complete water flooding of the annulus in the event of a breach in the outer pipe or other components of the pipe-in-pipe system. In the embodiment shown, the spacer rings 23 form a seal between the blank pipe section 21 and the connector housing 22 to prevent sea water penetration into the inner compartment of the mid-line connector.
The outer pipe of the pipeline may be thermally insulated to minimize heat loss and to reduce the amount of electrical current necessary to heat the contents of the pipe. Similarly, outer surfaces of the connector housing may be thermally insulated. In the pipe-in-pipe pipeline the outer surface of the flow pipe may be provided with an electrically insulating coating, for example, a fusion bonded epoxy. Such coating, when applied with an appropriate thickness, such as 20 mils (0.51 mm) or more, can withstand up to 8000 volts before failing, even after being wetted for several days. The flow pipe may also have a thermally insulating layer and perhaps even a co-extruded solid skin outer surface which protects the insulating layer. The solid skin may be a water barrier to protect the insulating layer if its is porous and provides an additional layer of electrical insulation. Similarly, the blank pipe section 21 of the mid-line connector may also have these noted layers and coatings.
Intra pipe movement between the flow pipe 12 and the outer pipe 14 may be entirely immobilized using a man made syntactic foam 34 or similar curing foam 34 that is poured in place after assembly of the mid-line connector 20. In one embodiment, the foam 34 is a two-part syntactic foam insulation (epoxy resin, s.g 0.76) containing glass microsphere filler that is a pour-in-place between the centralized blank pipe section 21 and connector housing 22. custom jigs may be employed to guarantee centralization and prevention of creep during the pouring or curing activity. Atmospheric conditions are controlled for optimal curing results and the mobilization of maximum shear capacity. The foam 34 acts as an intra pipe shear stop. Foams acceptable for this purpose have high insulating capacity for the flow pipe contents, low water absorption characteristics, a resistance to charring and short circuit due to arcing across the surface. Foam properties should be verified before a particular foam is used to guarantee the effectiveness and reliability of the selected material, as is known to those of skill in the art. In one embodiment, the foam average delivered shear stress for this application is in the range of 180 to 200 psi (1.24 - 1.38 mpa). Quality of selected materials should be useful for installation in the marine environment, variances in recipe and capable of adherence to bare gritblasted steel and coated steel surfaces with epoxy based paints or other similar protective coverings. Methods of centralizing the flow pipe 12 in the outer pipe 14 are carefully controlled to maintain concentricity and thereby continue to deliver the alignment of flow pipe 12 and the outer pipe 14 for welding.
The connector housing 22 also has a flow pipe connection pocket 24 and an outer pipe connection pocket 28. In the embodiment shown, the connection pockets 24 and 28 are wet mate receptacles. The connection pockets 24 and 28 are female electrical couplers into which male couplers are inserted to establish electrical communication between a cable 7 (see Figure 2) and the mid-line coimector 20. A dummy plug 25 is shown inserted into the flow pipe connection pocket 24. A live plug 29 is shown inserted into outer pipe connection pocket 28. Dual elastomeric seals are positioned on the inside of the connection pockets to form a seal between the connection pockets and the plugs upon insertion. Electric leads 27 are located at the distal ends of the plugs for mating with leads in the bottoms of the connection pockets.
The flow pipe connection pocket 24 is electrically coupled to the blank pipe section 21 by a braided strap 30. One end of the braided strap 30 is bolted to the flow pipe connection pocket 24, and the other end is bolted to the blank pipe section 21 by a connection block 31. The outer pipe connection pocket 28 is electrically coupled to the connector housing 22 by a connection disc 32 mounted in the connector housing 22 proximate the outer pipe connection pocket 28.
A copper coating 35 is also affixed to the exterior of the blank pipe section 21 in the vicinity of the connection with the braided strap 30. A moisture control coating 36 is also affixed to the blank pipe section 21 in the vicinity of the connection with the braided strap 30. The surface area covered by the moisture control coating 36 is greater than the surface area covered by the copper coating 35.
In an embodiment of the invention, the flow pipe connection is coated with a layer of copper spray 35 (see Figures 3 and 4). The purpose of the copper spray 35 is to reduce local heating caused by poor contact resistance. Local heating, caused by contact resistance (changes in section and shape of electrical conducting materials), is a measured and understood condition that is controlled to protect non-metallic parts in the connector cavity and the wet mateable connections from overheating. Localized overheating of non- metallic components is defined as temperatures above 250 degrees F (121 degrees C). The purity of the copper spray is monitored as part of the process. In one embodiment, a copper layer approximately 15 mis (0.381 mm) thick is adhered to the outside surface of the blank pipe section covering an area about 3 inches (7.6 cm) in all directions around the connection block 31 and over the connection block 31. The connector housing 22 is made of two sections which are welded together during the assembly process. Each of the two sections has a cylindrical pipe section the same diameter as the outer pipe of the pipe-in-pipe pipeline, a larger pipe section, and a taper or conical section which joins the different sized pipe sections. The blank pipe section 21 and the connector housing 22 are butt welded to the flow pipe 12 and outer pipe 14. Any means known to those of skill in the art for connecting pipe sections may also be used.
The mid-line connector 20 may consist of an outer body forging and an inner body forging. The inner body forging may be a carbon steel component (ASTM A694) and the flow pipe may be API 5L X70. The blank pipe section 21 is made identical to the flow pipe bore allowing routine pigging operations. The diameter of the outer body forging is selected to accommodate the two electrical connection points or connection pockets 24 and 28. The electrical connection points may be sub-assemblies that are installed with mechanical fasteners and include dual elastomeric seals 26. Redundancy in sealing arrangements is a conventional engineering practice, however in this application, the assembly procedure is simple and modular using this teclmique. The seals may be selected for field life and durable to operating conditions (40 degrees F to 250 degrees F; 4.5 degrees C to 121 degrees C) on the seafloor. The inner body forging and outer body forging are designed for simplicity in connection to the adjacent flowline pipe using butt welds or full penetration pressure containing welds. The mid-line connector is normally deployed within the pipeline 2 and affixed by annular welding and non-destructive examination of the welds on an installation vessel before deployment.
Referring to Figure 4, a side cross-sectional view of an embodiment of a mid-line connector of the present invention is shown. The flow pipe 12 extends through the inside of the connector 20, while the outer pipe 14 comprises the exterior of the connector 20. Foam 34 fills the annulus 13 between the flow pipe 12 and the outer pipe 14. Spacer rings 23 also stabilize the pipes relative to each other and seal the interior of the housing. In one illustrative embodiment of the invention, the end of the cable 7 (see Figure 2) has two electrical cables carrying an electrical supply from the electrical power supply 6. The cable 7 (see Figure 2) splits into branch cables 8 and 9 for insertion into the flow pipe connection pocket 24 and the outer pipe connection pocket 28, respectively. The flow pipe connection pocket 24 is electrically coupled to the flow pipe 12 by strap 30. The power is energized after both connections are made to the pipe-in-pipe heating segment 10 through two separate electrical leads inserted into the mid-line connector 20.
The connection between the cable 7 and the mid-line connector 20 may be made by a single remotely operated vehicle (ROV) equipped with two manipulator arms. Each connection is gripped in a manipulator using an ROV interface handle. Interface handles are commonplace to the subsea intervention industry and vary to suit the vehicle type on station. The cable may be buoyed so that it is more easily accessed by the ROV. By definition, wet-mate connectors enable underwater connection by ROV as a routine task. The wet-mate connector aligns the plug using a guiding barrel and protects a central power conduction pin. During the plug travel the power conducting surfaces are wiped clean of moisture by two seals combined with a pressure compensated oil filled chamber where a conducting shuttle pin comes to rest in the plug. The plug is held in place using two spring loaded latches riding against detents. Plug rotation is limited by a key and corresponding keyway in the wet-mate connector.
The mid-line connector is deployed such that it arrives on the seabed with the connection pockets in the top position, clear from the seafloor and accessible by the ROV, as shown in Figure 6. If for some inadvertent reason, e.g., residual pipe bending, curvature of the flowline, the mid-line connector 20 is laid down with a different orientation (see Figure 7), the connection pockets can still be successfully made by an ROV submarine. In some applications of the invention, it is a matter of random deposition on the sea floor 4, so that the ROV should be capable of connecting the cable 7 to the mid- line connector 20 regardless of its orientation. This is accomplished by excavation of the seabed material locally through dredging equipment attached to the ROV or any other method known to those of skill in the art. Dummy plugs 25 are illustrated in Figures 3 and 4. In embodiments of the invention using wet-mateable connections, connection pockets 24 and 28 may be protected from the marine environment over the life of field by long term dummy plugs 25. A typical life of field is 20 years with the electrical connection lying on the seafloor. Dummy plugs prevent calcareous type deposition on the conducting surfaces of the wet- mateable connector, particularly the silver plate on a central conducting pin. The long term dummy plugs 25 are equipped with two wiping seals 26 and encapsulate the critical electrical contact pin in an oil filled chamber, as noted above. In some applications it is advantageous to protect the pins and surfaces. This is particularly true during long dormant periods of no heating activity. While dummy plugs are illustrated, any structural feature may be used to maintain the integrity of the electrically heated pipe-in-pipe system. Different embodiments of the invention use wet-mateable and dry-mateable connections to the mid-line comiector. Dry-mateable connections to the cable are made before the pipeline is deployed to the sea floor. In the embodiments of the invention illustrated in Figures 3 and 4, the connection pockets 24 and 28 face out in a horizontal aspect in parallel with the axis of the flow pipe 12. This orientations enables a minimum pipe swelling overall diameter. The principle of maintaining electrical isolation between the pipes is respected by the details of this connection device. The also enables easier access to the connection pockets by the ROV. In some embodiments of the invention, the connection of electrical power to the flowline is made in an underwater environment at great depth, up to 6300 feet (1920 metres), or even as great as 8700 feet (2652 metres). Electrical couplings which join the cable 7 (see Figure 2) to the mid-line connector 20 (see Figures 3 and 4) may be wet- mateable devices. Any electrical couplings suitable for underwater applications may also be used. The electrical couplings may be designed for rated current and voltage and provided as sub-assemblies for insertion into the connection assembly. Depending upon the particular subsea environments, the electrical couplings may be designed for use in thousands of feet of water.
In some embodiments of the invention, the flow pipe connection pocket carries the delivered single phase alternating current and voltage to the flow pipe. This connection is subjected to voltage up to 1200 volts and single phase alternating current up to 1100 A. The flow pipe connection consists of a welded block with bolt fastenings. The bolt fastenings hold a copper braided strap in place 30, in a compliant 'U' shape. The copper braided strap 30 connects between the wet-mateable electrical connection and the flow pipe. The configuration of the strap enables some axial movement of the pipe during heating. The copper braided strap 30 may be covered in a protective jacket to prevent any inadvertent damage during welding up of the unit. In some embodiments of the invention, the blank pipe section 21 is coated with a moisture control seal 36 (see Figures 3 and 4) or other protective coating on its external surface to protect the surface from local corrosion and build-up of oxidation particles in the cavity. In some embodiments, the coating 36 is a 12-15 mils (.30 mm - .38 mm) coat of epoxy paint. The coating 36 serves to keep the blank pipe section 21 clean and dry during the assembly process and during operation. The coating 36 should maintain its integrity even though surfaces may reach temperatures of 250 °F (121 °C) during electrical heating operations. Some embodiments of the invention include non-metallic spacer rings 23 with seals to prevent moisture collection or contamination of the electrified compartment or spaces. The mid-line connector 20 is some embodiments of the invention is a robust structural assembly suitable for launching from an installation vessel, with typical loads up to and including 400 US tons (362.9 tonne) in 6000 ft (1829 meters) of water depth.
The design of the mid-line electrical connector is such that the inner and outer body can be adapted to different flow pipe diameters without changing the shape, strength, or the geometry of the electrical connections and their individual attachment to the flow and outer pipes. The use of concentric metallic reducers may be employed to adapt the diameter of the electrically heated flow pipe. Typical combinations include 6 inch pipe inside 10 inch pipe, 8 inch pipe inside 12 inch pipe, and 10 inch pipe inside 16 inch pipe (15.24 cm pipe inside 25.4 cm pipe, 20.32 cm pipe inside 30.48 cm pipe, and 25.4 cm pipe inside 40.64 cm pipe). Other combinations are also possible. Larger diameters of pipe require higher levels of current and voltage delivery to create the heating effect. Metallic reducers may be employed to achieve the adaptability of the mid-line coimector. The reducers may be substantially joined into the flow pipe using full butt welded connections and proven by non-destructive examination methods and further by externally applied proof pressure test.
Typically, the exterior surfaces of subsea pipelines are coated with an environmental barrier. Environmental barriers may comprise more than one sublayer, each of which may optionally be directed toward a particular environmental protective function, e.g., abrasion resistive material, tear resistant material, water and moisture proof material, stray current protective material, thermal protection material, or chemical protection material. Polyethylene, with an encasement standard of 800 v/mil dielectric resistance, is a good example of a stray current protective material for pipelines. In some embodiments of the invention, the outer surfaces of the mid-line connector are similarly covered with a stray current protective material. However, in real-world conditions, a defect-free bonded coating is impossible to economically obtain. Where voids or "holidays" caused by application errors or by installation damage exist, corrosion will take place. If bimetallic or stray current corrosion conditions exist, localized corrosion will be accelerated at the holidays, causing corrosion failure faster at the discrete point of holiday than if no coating had been applied to the pipeline. Accelerated corrosion results because the corrosion forces are cumulated at the discrete area of holiday, rather than being distributed along a more substantial surface area of the pipeline.
Referring to Figure 5, a side view of the outside of a mid-line connector 20 of the present invention is shown. In this embodiment, outside surfaces of mid-line connector are deliberately left exposed. The bare area of the mid-line connector, i.e., an area without any coating over the metal, is provided to serve as a discharge electrode. The area of the discharge electrode or the bare housing is selected to decrease current density from seawater to the area of the heated segment where leakage current leaves or enters the mid- line connector. The outside surfaces are bare over a distance 33 such that during electrical heating activity, the phenomena of stray current may be accommodated by the larger surface area of steel over which potential difference could exist. For a given pipe diameter of 16 inches (40.64 cm), the distance 33 of exposed surface is about 6 feet - 9 feet (1.83 m - 2.74 m). A stray current protective material 38 is adhered to the exterior of the connector housing 22 and/or outer pipe 14 in areas not deliberately left bare. While the outside surface is deliberately left bare or exposed for heating, it may be protected from normal conditions of ferrous material in seawater, using sacrificial anodes attached to the mid-line connector adjacent to the midpoint and sized for the life of field. In some cases, the sacrificial anode is sized for 20 years of flowline operation. The current density is decreased to a value that provides corrosion rates not greatly affected by the current flow through the surface of the sacrificial electrode or bare mid-line connector. The required area of the sacrificial electrode or bare mid-line connector may be estimated from calculations of current density at different values of electric field along the pipeline and calculations or measurements of electric field near the ends of the heated segment of the pipeline, along with results of measurements of corrosion rates versus current density. Measurements of electric field along the pipeline are preferably made for the pipeline to be used.
While the invention has been illustrated and described in detail in the drawings and foregoing description, the same is to be considered as illustrative and not restrictive in character, it being understood that only the preferred embodiment has been shown and described and that all changes and modifications that come within the spirit of the invention are desired to be protected.

Claims

C L A I M S
1. A connector of an electrical cable to a pipe-in-pipe pipeline, wherein the pipeline comprises an inner pipe and an outer pipe, said connector comprising: a connector housing joinable to the outer pipe of the pipeline; a blank pipe positioned within said connector housing and joinable to the inner pipe of the pipeline; at least one pocket mounted in said connector housing, wherein the cable is mateable with the at least one pocket; a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe; and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe.
2. A connector as claimed in claim 1, wherein said coimector housing comprises a bare exterior surface and a sacrificial electrode.
3. A connector as claimed in claim 1, wherein said blank pipe comprises a electrically conductive coating on an exterior surface proximate a couple location of said blank pipe conductor to the blank pipe.
4. A connector as claimed in claim 1, wherein said blank pipe comprises a corrosion protective coating on an exterior surface.
5. A connector as claimed in claim 1, wherein said at least one pocket comprises a dummy plug.
6. A connector as claimed in claim 1, wherein said at least one pocket comprises two pockets, wherein a lead of the cable is mateable with each of the two pockets.
7. A connector as claimed in claim 9, wherein said two pockets comprise wet- mateable devices.
8. A connector as claimed in claim 9, wherein said two pockets are mounted to the connector housing in directions opposite to each other and parallel to the longitudinal axis of said coimector housing.
9. A connector as claimed in claim 1, wherein said blank pipe conductor comprises a flexible strap.
10. A connector as claimed in claim 1, further comprising at least one ring in an aimulus between said blank pipe and said connector housing, wherein said at least one ring seals the interior of the connector housing from the annulus.
11. A connector as claimed in claim 1, further comprising foam in an annulus between said blank pipe and said connector housing.
12. A heated pipe-in-pipe pipeline and cable system comprising: an outer pipe; an inner pipe concentric within said outer pipe and forming an annulus between the pipes; a connector joined to said outer and inner pipes comprising: a connector housing joined to said outer pipe; a blank pipe positioned within said connector housing and joined to said inner pipe; at least one pocket mounted in said connector housing, wherein the cable is mated with the at least one pocket; a blank pipe conductor electrically coupled between the at least one pocket and the blank pipe; and an outer pipe conductor electrically coupled between the at least one pocket and the outer pipe, and a bulkhead electrically connecting said outer pipe to said inner pipe.
13. A system as claimed in claim 12, wherein said a connector housing comprising a bare exterior surface and a sacrificial electrode.
14. A system as claimed in claim 12, wherein said a blank pipe comprises an electrically conductive coating on an exterior surface proximate a couple location of said blank pipe conductor to the blank pipe and a corrosion protective coating on an exterior surface.
15. A system as claimed in claim 12, wherein said blank pipe conductor comprises a flexible strap.
16. A system as claimed in claim 12, further comprising a seal between the annulus and an interior of the connector.
17. A system as claimed in claim 12, wherein said at least one pocket comprises a dummy plug.
18. A system as claimed in claim 12, wherein said at least one pocket comprises two wet-mateable devices, wherein a lead of the cable is mateable with each of the two wet- mateable devices, wherein said wet-mateable devices are mounted to the connector housing in directions opposite to each other and parallel to the longitudinal axis of said connector housing.
19. A method for heating a pipe-in-pipe pipeline, said method comprising: placing on a sea floor a pipe-in-pipe pipeline comprising a mid-line connector and an electrically conductive bulkhead; protecting an electrical connection pocket of the mid-line connector from contact with sea water; mating a cable with the protected electrical connection pocket of the mid-line connector; and supplying electric power to the mid-line connector through the cable.
20. A method as claimed in claim 19, wherein said placing on a sea floor comprise orienting the mid-line connector so that electrical couplers on the mid-line connector are toward the top, wherein said protecting an electrical connection pocket comprises inserting a dummy plug into the electrical connection pocket, and wherein said mating a cable comprises gripping the mid-line connector with interface handles on manipulator arms of a remotely operated vehicle.
PCT/US2004/013353 2003-05-01 2004-04-30 Mid-line connector and method for pipe-in-pipe electrical heating. WO2004102059A1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013030599A1 (en) * 2011-09-02 2013-03-07 Technip France A connector arrangement for a subsea pipeline
NO20181178A1 (en) * 2018-09-11 2020-03-12 Nexans Connection device for providing an electrical connection between a subsea pipeline and an electrical conductor

Families Citing this family (350)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1509719B1 (en) * 2002-05-31 2010-04-07 Technip France SA Seal assembly
US8986456B2 (en) * 2006-10-10 2015-03-24 Asm America, Inc. Precursor delivery system
GB2474211B (en) * 2008-08-13 2012-05-02 Schlumberger Holdings Umbilical management system and method for subsea well intervention
US10378106B2 (en) 2008-11-14 2019-08-13 Asm Ip Holding B.V. Method of forming insulation film by modified PEALD
US9394608B2 (en) 2009-04-06 2016-07-19 Asm America, Inc. Semiconductor processing reactor and components thereof
US8877655B2 (en) 2010-05-07 2014-11-04 Asm America, Inc. Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species
US8883270B2 (en) * 2009-08-14 2014-11-11 Asm America, Inc. Systems and methods for thin-film deposition of metal oxides using excited nitrogen—oxygen species
US8802201B2 (en) 2009-08-14 2014-08-12 Asm America, Inc. Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species
DE102011102244B4 (en) * 2011-05-20 2014-12-31 Norma Germany Gmbh Connector for a heated fluid line and heated fluid line
DE102011102148A1 (en) * 2011-05-20 2012-11-22 Norma Germany Gmbh fluid line
DE102011102151B4 (en) * 2011-05-20 2022-05-19 Norma Germany Gmbh fluid line
US9312155B2 (en) 2011-06-06 2016-04-12 Asm Japan K.K. High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules
US9793148B2 (en) 2011-06-22 2017-10-17 Asm Japan K.K. Method for positioning wafers in multiple wafer transport
US10364496B2 (en) 2011-06-27 2019-07-30 Asm Ip Holding B.V. Dual section module having shared and unshared mass flow controllers
US10854498B2 (en) 2011-07-15 2020-12-01 Asm Ip Holding B.V. Wafer-supporting device and method for producing same
US20130023129A1 (en) 2011-07-20 2013-01-24 Asm America, Inc. Pressure transmitter for a semiconductor processing environment
US9096931B2 (en) 2011-10-27 2015-08-04 Asm America, Inc Deposition valve assembly and method of heating the same
US9341296B2 (en) * 2011-10-27 2016-05-17 Asm America, Inc. Heater jacket for a fluid line
US9017481B1 (en) 2011-10-28 2015-04-28 Asm America, Inc. Process feed management for semiconductor substrate processing
US9005539B2 (en) 2011-11-23 2015-04-14 Asm Ip Holding B.V. Chamber sealing member
US9167625B2 (en) 2011-11-23 2015-10-20 Asm Ip Holding B.V. Radiation shielding for a substrate holder
US9202727B2 (en) 2012-03-02 2015-12-01 ASM IP Holding Susceptor heater shim
US8946830B2 (en) 2012-04-04 2015-02-03 Asm Ip Holdings B.V. Metal oxide protective layer for a semiconductor device
US9029253B2 (en) 2012-05-02 2015-05-12 Asm Ip Holding B.V. Phase-stabilized thin films, structures and devices including the thin films, and methods of forming same
US8728832B2 (en) 2012-05-07 2014-05-20 Asm Ip Holdings B.V. Semiconductor device dielectric interface layer
US8933375B2 (en) 2012-06-27 2015-01-13 Asm Ip Holding B.V. Susceptor heater and method of heating a substrate
US9558931B2 (en) 2012-07-27 2017-01-31 Asm Ip Holding B.V. System and method for gas-phase sulfur passivation of a semiconductor surface
US9117866B2 (en) 2012-07-31 2015-08-25 Asm Ip Holding B.V. Apparatus and method for calculating a wafer position in a processing chamber under process conditions
US9659799B2 (en) 2012-08-28 2017-05-23 Asm Ip Holding B.V. Systems and methods for dynamic semiconductor process scheduling
US9169975B2 (en) 2012-08-28 2015-10-27 Asm Ip Holding B.V. Systems and methods for mass flow controller verification
US9021985B2 (en) 2012-09-12 2015-05-05 Asm Ip Holdings B.V. Process gas management for an inductively-coupled plasma deposition reactor
US9324811B2 (en) 2012-09-26 2016-04-26 Asm Ip Holding B.V. Structures and devices including a tensile-stressed silicon arsenic layer and methods of forming same
US10714315B2 (en) 2012-10-12 2020-07-14 Asm Ip Holdings B.V. Semiconductor reaction chamber showerhead
FR2997162B1 (en) 2012-10-22 2015-01-16 Technip France METHOD OF ASSEMBLING A RIGID CONDUIT INTENDED TO BE PLACED IN A WATER EXTEND, INSTALLATION AND DRIVING THEREFOR
US9640416B2 (en) 2012-12-26 2017-05-02 Asm Ip Holding B.V. Single-and dual-chamber module-attachable wafer-handling chamber
US20160376700A1 (en) 2013-02-01 2016-12-29 Asm Ip Holding B.V. System for treatment of deposition reactor
US8894870B2 (en) 2013-02-01 2014-11-25 Asm Ip Holding B.V. Multi-step method and apparatus for etching compounds containing a metal
US9589770B2 (en) 2013-03-08 2017-03-07 Asm Ip Holding B.V. Method and systems for in-situ formation of intermediate reactive species
US9484191B2 (en) 2013-03-08 2016-11-01 Asm Ip Holding B.V. Pulsed remote plasma method and system
CN104061399A (en) * 2013-03-19 2014-09-24 天津市普友机电设备制造有限公司 Liner type electric heating lifting pipe
US8993054B2 (en) 2013-07-12 2015-03-31 Asm Ip Holding B.V. Method and system to reduce outgassing in a reaction chamber
US9018111B2 (en) 2013-07-22 2015-04-28 Asm Ip Holding B.V. Semiconductor reaction chamber with plasma capabilities
US9793115B2 (en) 2013-08-14 2017-10-17 Asm Ip Holding B.V. Structures and devices including germanium-tin films and methods of forming same
US9396934B2 (en) 2013-08-14 2016-07-19 Asm Ip Holding B.V. Methods of forming films including germanium tin and structures and devices including the films
US9240412B2 (en) 2013-09-27 2016-01-19 Asm Ip Holding B.V. Semiconductor structure and device and methods of forming same using selective epitaxial process
US9556516B2 (en) 2013-10-09 2017-01-31 ASM IP Holding B.V Method for forming Ti-containing film by PEALD using TDMAT or TDEAT
US9605343B2 (en) 2013-11-13 2017-03-28 Asm Ip Holding B.V. Method for forming conformal carbon films, structures conformal carbon film, and system of forming same
US10179947B2 (en) 2013-11-26 2019-01-15 Asm Ip Holding B.V. Method for forming conformal nitrided, oxidized, or carbonized dielectric film by atomic layer deposition
FR3015171B1 (en) * 2013-12-12 2016-01-01 Total Sa METHOD FOR FORMING AN ELECTRICAL CONNECTION
US10683571B2 (en) 2014-02-25 2020-06-16 Asm Ip Holding B.V. Gas supply manifold and method of supplying gases to chamber using same
US10167557B2 (en) 2014-03-18 2019-01-01 Asm Ip Holding B.V. Gas distribution system, reactor including the system, and methods of using the same
US9447498B2 (en) 2014-03-18 2016-09-20 Asm Ip Holding B.V. Method for performing uniform processing in gas system-sharing multiple reaction chambers
US11015245B2 (en) 2014-03-19 2021-05-25 Asm Ip Holding B.V. Gas-phase reactor and system having exhaust plenum and components thereof
US9404587B2 (en) 2014-04-24 2016-08-02 ASM IP Holding B.V Lockout tagout for semiconductor vacuum valve
US10858737B2 (en) 2014-07-28 2020-12-08 Asm Ip Holding B.V. Showerhead assembly and components thereof
US9543180B2 (en) 2014-08-01 2017-01-10 Asm Ip Holding B.V. Apparatus and method for transporting wafers between wafer carrier and process tool under vacuum
US9890456B2 (en) 2014-08-21 2018-02-13 Asm Ip Holding B.V. Method and system for in situ formation of gas-phase compounds
US10941490B2 (en) 2014-10-07 2021-03-09 Asm Ip Holding B.V. Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same
US9657845B2 (en) 2014-10-07 2017-05-23 Asm Ip Holding B.V. Variable conductance gas distribution apparatus and method
KR102300403B1 (en) 2014-11-19 2021-09-09 에이에스엠 아이피 홀딩 비.브이. Method of depositing thin film
KR102263121B1 (en) 2014-12-22 2021-06-09 에이에스엠 아이피 홀딩 비.브이. Semiconductor device and manufacuring method thereof
US9478415B2 (en) 2015-02-13 2016-10-25 Asm Ip Holding B.V. Method for forming film having low resistance and shallow junction depth
US9810448B2 (en) * 2015-02-19 2017-11-07 Technologies Holdings Corp. System and method for heating a pipeline using heated lines
US10529542B2 (en) 2015-03-11 2020-01-07 Asm Ip Holdings B.V. Cross-flow reactor and method
US10276355B2 (en) 2015-03-12 2019-04-30 Asm Ip Holding B.V. Multi-zone reactor, system including the reactor, and method of using the same
US10458018B2 (en) 2015-06-26 2019-10-29 Asm Ip Holding B.V. Structures including metal carbide material, devices including the structures, and methods of forming same
US10600673B2 (en) 2015-07-07 2020-03-24 Asm Ip Holding B.V. Magnetic susceptor to baseplate seal
US10043661B2 (en) 2015-07-13 2018-08-07 Asm Ip Holding B.V. Method for protecting layer by forming hydrocarbon-based extremely thin film
US9899291B2 (en) 2015-07-13 2018-02-20 Asm Ip Holding B.V. Method for protecting layer by forming hydrocarbon-based extremely thin film
US10083836B2 (en) 2015-07-24 2018-09-25 Asm Ip Holding B.V. Formation of boron-doped titanium metal films with high work function
US10087525B2 (en) 2015-08-04 2018-10-02 Asm Ip Holding B.V. Variable gap hard stop design
US9647114B2 (en) 2015-08-14 2017-05-09 Asm Ip Holding B.V. Methods of forming highly p-type doped germanium tin films and structures and devices including the films
US9711345B2 (en) 2015-08-25 2017-07-18 Asm Ip Holding B.V. Method for forming aluminum nitride-based film by PEALD
US9960072B2 (en) 2015-09-29 2018-05-01 Asm Ip Holding B.V. Variable adjustment for precise matching of multiple chamber cavity housings
US9909214B2 (en) 2015-10-15 2018-03-06 Asm Ip Holding B.V. Method for depositing dielectric film in trenches by PEALD
US10211308B2 (en) 2015-10-21 2019-02-19 Asm Ip Holding B.V. NbMC layers
US10322384B2 (en) 2015-11-09 2019-06-18 Asm Ip Holding B.V. Counter flow mixer for process chamber
US9455138B1 (en) 2015-11-10 2016-09-27 Asm Ip Holding B.V. Method for forming dielectric film in trenches by PEALD using H-containing gas
US9905420B2 (en) 2015-12-01 2018-02-27 Asm Ip Holding B.V. Methods of forming silicon germanium tin films and structures and devices including the films
US9607837B1 (en) 2015-12-21 2017-03-28 Asm Ip Holding B.V. Method for forming silicon oxide cap layer for solid state diffusion process
US9627221B1 (en) 2015-12-28 2017-04-18 Asm Ip Holding B.V. Continuous process incorporating atomic layer etching
US9735024B2 (en) 2015-12-28 2017-08-15 Asm Ip Holding B.V. Method of atomic layer etching using functional group-containing fluorocarbon
US11139308B2 (en) 2015-12-29 2021-10-05 Asm Ip Holding B.V. Atomic layer deposition of III-V compounds to form V-NAND devices
US10468251B2 (en) 2016-02-19 2019-11-05 Asm Ip Holding B.V. Method for forming spacers using silicon nitride film for spacer-defined multiple patterning
US9754779B1 (en) 2016-02-19 2017-09-05 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches
US10529554B2 (en) 2016-02-19 2020-01-07 Asm Ip Holding B.V. Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches
US10501866B2 (en) 2016-03-09 2019-12-10 Asm Ip Holding B.V. Gas distribution apparatus for improved film uniformity in an epitaxial system
AU2017201583A1 (en) * 2016-03-11 2017-09-28 Chevron Australia Pty Ltd Methods for removal of components of a subsea oilfield facility
US10343920B2 (en) 2016-03-18 2019-07-09 Asm Ip Holding B.V. Aligned carbon nanotubes
US9892913B2 (en) 2016-03-24 2018-02-13 Asm Ip Holding B.V. Radial and thickness control via biased multi-port injection settings
US10865475B2 (en) 2016-04-21 2020-12-15 Asm Ip Holding B.V. Deposition of metal borides and silicides
US10190213B2 (en) 2016-04-21 2019-01-29 Asm Ip Holding B.V. Deposition of metal borides
US10087522B2 (en) 2016-04-21 2018-10-02 Asm Ip Holding B.V. Deposition of metal borides
US10032628B2 (en) 2016-05-02 2018-07-24 Asm Ip Holding B.V. Source/drain performance through conformal solid state doping
US10367080B2 (en) 2016-05-02 2019-07-30 Asm Ip Holding B.V. Method of forming a germanium oxynitride film
KR102592471B1 (en) 2016-05-17 2023-10-20 에이에스엠 아이피 홀딩 비.브이. Method of forming metal interconnection and method of fabricating semiconductor device using the same
US11453943B2 (en) 2016-05-25 2022-09-27 Asm Ip Holding B.V. Method for forming carbon-containing silicon/metal oxide or nitride film by ALD using silicon precursor and hydrocarbon precursor
US10388509B2 (en) 2016-06-28 2019-08-20 Asm Ip Holding B.V. Formation of epitaxial layers via dislocation filtering
US9859151B1 (en) 2016-07-08 2018-01-02 Asm Ip Holding B.V. Selective film deposition method to form air gaps
US10612137B2 (en) 2016-07-08 2020-04-07 Asm Ip Holdings B.V. Organic reactants for atomic layer deposition
US9793135B1 (en) 2016-07-14 2017-10-17 ASM IP Holding B.V Method of cyclic dry etching using etchant film
US10714385B2 (en) 2016-07-19 2020-07-14 Asm Ip Holding B.V. Selective deposition of tungsten
US10381226B2 (en) 2016-07-27 2019-08-13 Asm Ip Holding B.V. Method of processing substrate
US10395919B2 (en) 2016-07-28 2019-08-27 Asm Ip Holding B.V. Method and apparatus for filling a gap
US9812320B1 (en) 2016-07-28 2017-11-07 Asm Ip Holding B.V. Method and apparatus for filling a gap
US9887082B1 (en) 2016-07-28 2018-02-06 Asm Ip Holding B.V. Method and apparatus for filling a gap
US10177025B2 (en) 2016-07-28 2019-01-08 Asm Ip Holding B.V. Method and apparatus for filling a gap
KR102532607B1 (en) 2016-07-28 2023-05-15 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus and method of operating the same
US10090316B2 (en) 2016-09-01 2018-10-02 Asm Ip Holding B.V. 3D stacked multilayer semiconductor memory using doped select transistor channel
US10410943B2 (en) 2016-10-13 2019-09-10 Asm Ip Holding B.V. Method for passivating a surface of a semiconductor and related systems
US10643826B2 (en) 2016-10-26 2020-05-05 Asm Ip Holdings B.V. Methods for thermally calibrating reaction chambers
US11532757B2 (en) 2016-10-27 2022-12-20 Asm Ip Holding B.V. Deposition of charge trapping layers
US10714350B2 (en) 2016-11-01 2020-07-14 ASM IP Holdings, B.V. Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10643904B2 (en) 2016-11-01 2020-05-05 Asm Ip Holdings B.V. Methods for forming a semiconductor device and related semiconductor device structures
US10435790B2 (en) 2016-11-01 2019-10-08 Asm Ip Holding B.V. Method of subatmospheric plasma-enhanced ALD using capacitively coupled electrodes with narrow gap
US10229833B2 (en) 2016-11-01 2019-03-12 Asm Ip Holding B.V. Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures
US10134757B2 (en) 2016-11-07 2018-11-20 Asm Ip Holding B.V. Method of processing a substrate and a device manufactured by using the method
KR102546317B1 (en) 2016-11-15 2023-06-21 에이에스엠 아이피 홀딩 비.브이. Gas supply unit and substrate processing apparatus including the same
US10340135B2 (en) 2016-11-28 2019-07-02 Asm Ip Holding B.V. Method of topologically restricted plasma-enhanced cyclic deposition of silicon or metal nitride
KR20180068582A (en) 2016-12-14 2018-06-22 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus
US11447861B2 (en) 2016-12-15 2022-09-20 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure
US11581186B2 (en) 2016-12-15 2023-02-14 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus
US9916980B1 (en) 2016-12-15 2018-03-13 Asm Ip Holding B.V. Method of forming a structure on a substrate
KR20180070971A (en) 2016-12-19 2018-06-27 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus
US10269558B2 (en) 2016-12-22 2019-04-23 Asm Ip Holding B.V. Method of forming a structure on a substrate
US10867788B2 (en) 2016-12-28 2020-12-15 Asm Ip Holding B.V. Method of forming a structure on a substrate
US11390950B2 (en) 2017-01-10 2022-07-19 Asm Ip Holding B.V. Reactor system and method to reduce residue buildup during a film deposition process
US10655221B2 (en) 2017-02-09 2020-05-19 Asm Ip Holding B.V. Method for depositing oxide film by thermal ALD and PEALD
US10468261B2 (en) 2017-02-15 2019-11-05 Asm Ip Holding B.V. Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures
US10283353B2 (en) 2017-03-29 2019-05-07 Asm Ip Holding B.V. Method of reforming insulating film deposited on substrate with recess pattern
US10529563B2 (en) 2017-03-29 2020-01-07 Asm Ip Holdings B.V. Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures
US10103040B1 (en) 2017-03-31 2018-10-16 Asm Ip Holding B.V. Apparatus and method for manufacturing a semiconductor device
USD830981S1 (en) 2017-04-07 2018-10-16 Asm Ip Holding B.V. Susceptor for semiconductor substrate processing apparatus
KR102457289B1 (en) 2017-04-25 2022-10-21 에이에스엠 아이피 홀딩 비.브이. Method for depositing a thin film and manufacturing a semiconductor device
US10770286B2 (en) 2017-05-08 2020-09-08 Asm Ip Holdings B.V. Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures
US10446393B2 (en) 2017-05-08 2019-10-15 Asm Ip Holding B.V. Methods for forming silicon-containing epitaxial layers and related semiconductor device structures
US10892156B2 (en) 2017-05-08 2021-01-12 Asm Ip Holding B.V. Methods for forming a silicon nitride film on a substrate and related semiconductor device structures
US10504742B2 (en) 2017-05-31 2019-12-10 Asm Ip Holding B.V. Method of atomic layer etching using hydrogen plasma
US10886123B2 (en) 2017-06-02 2021-01-05 Asm Ip Holding B.V. Methods for forming low temperature semiconductor layers and related semiconductor device structures
US11306395B2 (en) 2017-06-28 2022-04-19 Asm Ip Holding B.V. Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus
US10685834B2 (en) 2017-07-05 2020-06-16 Asm Ip Holdings B.V. Methods for forming a silicon germanium tin layer and related semiconductor device structures
KR20190009245A (en) 2017-07-18 2019-01-28 에이에스엠 아이피 홀딩 비.브이. Methods for forming a semiconductor device structure and related semiconductor device structures
US11374112B2 (en) 2017-07-19 2022-06-28 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US11018002B2 (en) 2017-07-19 2021-05-25 Asm Ip Holding B.V. Method for selectively depositing a Group IV semiconductor and related semiconductor device structures
US10541333B2 (en) 2017-07-19 2020-01-21 Asm Ip Holding B.V. Method for depositing a group IV semiconductor and related semiconductor device structures
US10590535B2 (en) 2017-07-26 2020-03-17 Asm Ip Holdings B.V. Chemical treatment, deposition and/or infiltration apparatus and method for using the same
US10312055B2 (en) 2017-07-26 2019-06-04 Asm Ip Holding B.V. Method of depositing film by PEALD using negative bias
US10605530B2 (en) 2017-07-26 2020-03-31 Asm Ip Holding B.V. Assembly of a liner and a flange for a vertical furnace as well as the liner and the vertical furnace
US10692741B2 (en) 2017-08-08 2020-06-23 Asm Ip Holdings B.V. Radiation shield
US10770336B2 (en) 2017-08-08 2020-09-08 Asm Ip Holding B.V. Substrate lift mechanism and reactor including same
US10249524B2 (en) 2017-08-09 2019-04-02 Asm Ip Holding B.V. Cassette holder assembly for a substrate cassette and holding member for use in such assembly
US11139191B2 (en) 2017-08-09 2021-10-05 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US11769682B2 (en) 2017-08-09 2023-09-26 Asm Ip Holding B.V. Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith
US10236177B1 (en) 2017-08-22 2019-03-19 ASM IP Holding B.V.. Methods for depositing a doped germanium tin semiconductor and related semiconductor device structures
USD900036S1 (en) 2017-08-24 2020-10-27 Asm Ip Holding B.V. Heater electrical connector and adapter
US11830730B2 (en) 2017-08-29 2023-11-28 Asm Ip Holding B.V. Layer forming method and apparatus
US11056344B2 (en) 2017-08-30 2021-07-06 Asm Ip Holding B.V. Layer forming method
KR102491945B1 (en) 2017-08-30 2023-01-26 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus
US11295980B2 (en) 2017-08-30 2022-04-05 Asm Ip Holding B.V. Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures
US10607895B2 (en) 2017-09-18 2020-03-31 Asm Ip Holdings B.V. Method for forming a semiconductor device structure comprising a gate fill metal
KR102630301B1 (en) 2017-09-21 2024-01-29 에이에스엠 아이피 홀딩 비.브이. Method of sequential infiltration synthesis treatment of infiltrateable material and structures and devices formed using same
US10844484B2 (en) 2017-09-22 2020-11-24 Asm Ip Holding B.V. Apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
US10658205B2 (en) 2017-09-28 2020-05-19 Asm Ip Holdings B.V. Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber
US10403504B2 (en) 2017-10-05 2019-09-03 Asm Ip Holding B.V. Method for selectively depositing a metallic film on a substrate
US10319588B2 (en) 2017-10-10 2019-06-11 Asm Ip Holding B.V. Method for depositing a metal chalcogenide on a substrate by cyclical deposition
US10923344B2 (en) 2017-10-30 2021-02-16 Asm Ip Holding B.V. Methods for forming a semiconductor structure and related semiconductor structures
KR102443047B1 (en) 2017-11-16 2022-09-14 에이에스엠 아이피 홀딩 비.브이. Method of processing a substrate and a device manufactured by the same
US10910262B2 (en) 2017-11-16 2021-02-02 Asm Ip Holding B.V. Method of selectively depositing a capping layer structure on a semiconductor device structure
US11022879B2 (en) 2017-11-24 2021-06-01 Asm Ip Holding B.V. Method of forming an enhanced unexposed photoresist layer
CN111316417B (en) 2017-11-27 2023-12-22 阿斯莫Ip控股公司 Storage device for storing wafer cassettes for use with batch ovens
WO2019103610A1 (en) 2017-11-27 2019-05-31 Asm Ip Holding B.V. Apparatus including a clean mini environment
US10290508B1 (en) 2017-12-05 2019-05-14 Asm Ip Holding B.V. Method for forming vertical spacers for spacer-defined patterning
US10872771B2 (en) 2018-01-16 2020-12-22 Asm Ip Holding B. V. Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures
WO2019142055A2 (en) 2018-01-19 2019-07-25 Asm Ip Holding B.V. Method for depositing a gap-fill layer by plasma-assisted deposition
TW202325889A (en) 2018-01-19 2023-07-01 荷蘭商Asm 智慧財產控股公司 Deposition method
USD903477S1 (en) 2018-01-24 2020-12-01 Asm Ip Holdings B.V. Metal clamp
US11018047B2 (en) 2018-01-25 2021-05-25 Asm Ip Holding B.V. Hybrid lift pin
US10535516B2 (en) 2018-02-01 2020-01-14 Asm Ip Holdings B.V. Method for depositing a semiconductor structure on a surface of a substrate and related semiconductor structures
USD880437S1 (en) 2018-02-01 2020-04-07 Asm Ip Holding B.V. Gas supply plate for semiconductor manufacturing apparatus
US11081345B2 (en) 2018-02-06 2021-08-03 Asm Ip Holding B.V. Method of post-deposition treatment for silicon oxide film
US10896820B2 (en) 2018-02-14 2021-01-19 Asm Ip Holding B.V. Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
EP3737779A1 (en) 2018-02-14 2020-11-18 ASM IP Holding B.V. A method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process
US10731249B2 (en) 2018-02-15 2020-08-04 Asm Ip Holding B.V. Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus
KR102636427B1 (en) 2018-02-20 2024-02-13 에이에스엠 아이피 홀딩 비.브이. Substrate processing method and apparatus
US10658181B2 (en) 2018-02-20 2020-05-19 Asm Ip Holding B.V. Method of spacer-defined direct patterning in semiconductor fabrication
US10975470B2 (en) 2018-02-23 2021-04-13 Asm Ip Holding B.V. Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment
US11473195B2 (en) 2018-03-01 2022-10-18 Asm Ip Holding B.V. Semiconductor processing apparatus and a method for processing a substrate
US11629406B2 (en) 2018-03-09 2023-04-18 Asm Ip Holding B.V. Semiconductor processing apparatus comprising one or more pyrometers for measuring a temperature of a substrate during transfer of the substrate
US11114283B2 (en) 2018-03-16 2021-09-07 Asm Ip Holding B.V. Reactor, system including the reactor, and methods of manufacturing and using same
KR102646467B1 (en) 2018-03-27 2024-03-11 에이에스엠 아이피 홀딩 비.브이. Method of forming an electrode on a substrate and a semiconductor device structure including an electrode
US11088002B2 (en) 2018-03-29 2021-08-10 Asm Ip Holding B.V. Substrate rack and a substrate processing system and method
US11230766B2 (en) 2018-03-29 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
US10510536B2 (en) 2018-03-29 2019-12-17 Asm Ip Holding B.V. Method of depositing a co-doped polysilicon film on a surface of a substrate within a reaction chamber
KR102501472B1 (en) 2018-03-30 2023-02-20 에이에스엠 아이피 홀딩 비.브이. Substrate processing method
TWI811348B (en) 2018-05-08 2023-08-11 荷蘭商Asm 智慧財產控股公司 Methods for depositing an oxide film on a substrate by a cyclical deposition process and related device structures
TW202349473A (en) 2018-05-11 2023-12-16 荷蘭商Asm Ip私人控股有限公司 Methods for forming a doped metal carbide film on a substrate and related semiconductor device structures
KR102596988B1 (en) 2018-05-28 2023-10-31 에이에스엠 아이피 홀딩 비.브이. Method of processing a substrate and a device manufactured by the same
US11718913B2 (en) 2018-06-04 2023-08-08 Asm Ip Holding B.V. Gas distribution system and reactor system including same
US11270899B2 (en) 2018-06-04 2022-03-08 Asm Ip Holding B.V. Wafer handling chamber with moisture reduction
US11286562B2 (en) 2018-06-08 2022-03-29 Asm Ip Holding B.V. Gas-phase chemical reactor and method of using same
KR102568797B1 (en) 2018-06-21 2023-08-21 에이에스엠 아이피 홀딩 비.브이. Substrate processing system
US10797133B2 (en) 2018-06-21 2020-10-06 Asm Ip Holding B.V. Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures
JP2021529254A (en) 2018-06-27 2021-10-28 エーエスエム・アイピー・ホールディング・ベー・フェー Periodic deposition methods for forming metal-containing materials and films and structures containing metal-containing materials
US11499222B2 (en) 2018-06-27 2022-11-15 Asm Ip Holding B.V. Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material
US10612136B2 (en) 2018-06-29 2020-04-07 ASM IP Holding, B.V. Temperature-controlled flange and reactor system including same
KR20200002519A (en) 2018-06-29 2020-01-08 에이에스엠 아이피 홀딩 비.브이. Method for depositing a thin film and manufacturing a semiconductor device
US10388513B1 (en) 2018-07-03 2019-08-20 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10755922B2 (en) 2018-07-03 2020-08-25 Asm Ip Holding B.V. Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition
US10767789B2 (en) 2018-07-16 2020-09-08 Asm Ip Holding B.V. Diaphragm valves, valve components, and methods for forming valve components
US10483099B1 (en) 2018-07-26 2019-11-19 Asm Ip Holding B.V. Method for forming thermally stable organosilicon polymer film
US11053591B2 (en) 2018-08-06 2021-07-06 Asm Ip Holding B.V. Multi-port gas injection system and reactor system including same
US10883175B2 (en) 2018-08-09 2021-01-05 Asm Ip Holding B.V. Vertical furnace for processing substrates and a liner for use therein
US10829852B2 (en) 2018-08-16 2020-11-10 Asm Ip Holding B.V. Gas distribution device for a wafer processing apparatus
US11430674B2 (en) 2018-08-22 2022-08-30 Asm Ip Holding B.V. Sensor array, apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods
KR20200030162A (en) 2018-09-11 2020-03-20 에이에스엠 아이피 홀딩 비.브이. Method for deposition of a thin film
US11024523B2 (en) 2018-09-11 2021-06-01 Asm Ip Holding B.V. Substrate processing apparatus and method
US11049751B2 (en) 2018-09-14 2021-06-29 Asm Ip Holding B.V. Cassette supply system to store and handle cassettes and processing apparatus equipped therewith
CN110970344A (en) 2018-10-01 2020-04-07 Asm Ip控股有限公司 Substrate holding apparatus, system including the same, and method of using the same
US11232963B2 (en) 2018-10-03 2022-01-25 Asm Ip Holding B.V. Substrate processing apparatus and method
KR102592699B1 (en) 2018-10-08 2023-10-23 에이에스엠 아이피 홀딩 비.브이. Substrate support unit and apparatuses for depositing thin film and processing the substrate including the same
US10847365B2 (en) 2018-10-11 2020-11-24 Asm Ip Holding B.V. Method of forming conformal silicon carbide film by cyclic CVD
US10811256B2 (en) 2018-10-16 2020-10-20 Asm Ip Holding B.V. Method for etching a carbon-containing feature
KR102546322B1 (en) 2018-10-19 2023-06-21 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus and substrate processing method
KR102605121B1 (en) 2018-10-19 2023-11-23 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus and substrate processing method
USD948463S1 (en) 2018-10-24 2022-04-12 Asm Ip Holding B.V. Susceptor for semiconductor substrate supporting apparatus
US10381219B1 (en) 2018-10-25 2019-08-13 Asm Ip Holding B.V. Methods for forming a silicon nitride film
US11087997B2 (en) 2018-10-31 2021-08-10 Asm Ip Holding B.V. Substrate processing apparatus for processing substrates
KR20200051105A (en) 2018-11-02 2020-05-13 에이에스엠 아이피 홀딩 비.브이. Substrate support unit and substrate processing apparatus including the same
US11572620B2 (en) 2018-11-06 2023-02-07 Asm Ip Holding B.V. Methods for selectively depositing an amorphous silicon film on a substrate
US11031242B2 (en) 2018-11-07 2021-06-08 Asm Ip Holding B.V. Methods for depositing a boron doped silicon germanium film
US10818758B2 (en) 2018-11-16 2020-10-27 Asm Ip Holding B.V. Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures
US10847366B2 (en) 2018-11-16 2020-11-24 Asm Ip Holding B.V. Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process
US10559458B1 (en) 2018-11-26 2020-02-11 Asm Ip Holding B.V. Method of forming oxynitride film
US11217444B2 (en) 2018-11-30 2022-01-04 Asm Ip Holding B.V. Method for forming an ultraviolet radiation responsive metal oxide-containing film
KR102636428B1 (en) 2018-12-04 2024-02-13 에이에스엠 아이피 홀딩 비.브이. A method for cleaning a substrate processing apparatus
US11158513B2 (en) 2018-12-13 2021-10-26 Asm Ip Holding B.V. Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures
JP2020096183A (en) 2018-12-14 2020-06-18 エーエスエム・アイピー・ホールディング・ベー・フェー Method of forming device structure using selective deposition of gallium nitride, and system for the same
TWI819180B (en) 2019-01-17 2023-10-21 荷蘭商Asm 智慧財產控股公司 Methods of forming a transition metal containing film on a substrate by a cyclical deposition process
KR20200091543A (en) 2019-01-22 2020-07-31 에이에스엠 아이피 홀딩 비.브이. Semiconductor processing device
CN111524788B (en) 2019-02-01 2023-11-24 Asm Ip私人控股有限公司 Method for topologically selective film formation of silicon oxide
JP2020136678A (en) 2019-02-20 2020-08-31 エーエスエム・アイピー・ホールディング・ベー・フェー Method for filing concave part formed inside front surface of base material, and device
KR102626263B1 (en) 2019-02-20 2024-01-16 에이에스엠 아이피 홀딩 비.브이. Cyclical deposition method including treatment step and apparatus for same
TW202104632A (en) 2019-02-20 2021-02-01 荷蘭商Asm Ip私人控股有限公司 Cyclical deposition method and apparatus for filling a recess formed within a substrate surface
US11482533B2 (en) 2019-02-20 2022-10-25 Asm Ip Holding B.V. Apparatus and methods for plug fill deposition in 3-D NAND applications
TW202100794A (en) 2019-02-22 2021-01-01 荷蘭商Asm Ip私人控股有限公司 Substrate processing apparatus and method for processing substrate
KR20200108243A (en) 2019-03-08 2020-09-17 에이에스엠 아이피 홀딩 비.브이. Structure Including SiOC Layer and Method of Forming Same
KR20200108242A (en) 2019-03-08 2020-09-17 에이에스엠 아이피 홀딩 비.브이. Method for Selective Deposition of Silicon Nitride Layer and Structure Including Selectively-Deposited Silicon Nitride Layer
US11742198B2 (en) 2019-03-08 2023-08-29 Asm Ip Holding B.V. Structure including SiOCN layer and method of forming same
JP2020167398A (en) 2019-03-28 2020-10-08 エーエスエム・アイピー・ホールディング・ベー・フェー Door opener and substrate processing apparatus provided therewith
KR20200116855A (en) 2019-04-01 2020-10-13 에이에스엠 아이피 홀딩 비.브이. Method of manufacturing semiconductor device
US11447864B2 (en) 2019-04-19 2022-09-20 Asm Ip Holding B.V. Layer forming method and apparatus
KR20200125453A (en) 2019-04-24 2020-11-04 에이에스엠 아이피 홀딩 비.브이. Gas-phase reactor system and method of using same
KR20200130118A (en) 2019-05-07 2020-11-18 에이에스엠 아이피 홀딩 비.브이. Method for Reforming Amorphous Carbon Polymer Film
KR20200130121A (en) 2019-05-07 2020-11-18 에이에스엠 아이피 홀딩 비.브이. Chemical source vessel with dip tube
KR20200130652A (en) 2019-05-10 2020-11-19 에이에스엠 아이피 홀딩 비.브이. Method of depositing material onto a surface and structure formed according to the method
JP2020188255A (en) 2019-05-16 2020-11-19 エーエスエム アイピー ホールディング ビー.ブイ. Wafer boat handling device, vertical batch furnace, and method
USD975665S1 (en) 2019-05-17 2023-01-17 Asm Ip Holding B.V. Susceptor shaft
USD947913S1 (en) 2019-05-17 2022-04-05 Asm Ip Holding B.V. Susceptor shaft
USD935572S1 (en) 2019-05-24 2021-11-09 Asm Ip Holding B.V. Gas channel plate
USD922229S1 (en) 2019-06-05 2021-06-15 Asm Ip Holding B.V. Device for controlling a temperature of a gas supply unit
KR20200141002A (en) 2019-06-06 2020-12-17 에이에스엠 아이피 홀딩 비.브이. Method of using a gas-phase reactor system including analyzing exhausted gas
KR20200143254A (en) 2019-06-11 2020-12-23 에이에스엠 아이피 홀딩 비.브이. Method of forming an electronic structure using an reforming gas, system for performing the method, and structure formed using the method
USD944946S1 (en) 2019-06-14 2022-03-01 Asm Ip Holding B.V. Shower plate
USD931978S1 (en) 2019-06-27 2021-09-28 Asm Ip Holding B.V. Showerhead vacuum transport
KR20210005515A (en) 2019-07-03 2021-01-14 에이에스엠 아이피 홀딩 비.브이. Temperature control assembly for substrate processing apparatus and method of using same
JP2021015791A (en) 2019-07-09 2021-02-12 エーエスエム アイピー ホールディング ビー.ブイ. Plasma device and substrate processing method using coaxial waveguide
CN112216646A (en) 2019-07-10 2021-01-12 Asm Ip私人控股有限公司 Substrate supporting assembly and substrate processing device comprising same
KR20210010307A (en) 2019-07-16 2021-01-27 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus
KR20210010816A (en) 2019-07-17 2021-01-28 에이에스엠 아이피 홀딩 비.브이. Radical assist ignition plasma system and method
KR20210010820A (en) 2019-07-17 2021-01-28 에이에스엠 아이피 홀딩 비.브이. Methods of forming silicon germanium structures
US11643724B2 (en) 2019-07-18 2023-05-09 Asm Ip Holding B.V. Method of forming structures using a neutral beam
JP2021019198A (en) 2019-07-19 2021-02-15 エーエスエム・アイピー・ホールディング・ベー・フェー Method of forming topology-controlled amorphous carbon polymer film
CN112309843A (en) 2019-07-29 2021-02-02 Asm Ip私人控股有限公司 Selective deposition method for achieving high dopant doping
CN112309899A (en) 2019-07-30 2021-02-02 Asm Ip私人控股有限公司 Substrate processing apparatus
CN112309900A (en) 2019-07-30 2021-02-02 Asm Ip私人控股有限公司 Substrate processing apparatus
US11227782B2 (en) 2019-07-31 2022-01-18 Asm Ip Holding B.V. Vertical batch furnace assembly
US11587814B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
US11587815B2 (en) 2019-07-31 2023-02-21 Asm Ip Holding B.V. Vertical batch furnace assembly
KR20210018759A (en) 2019-08-05 2021-02-18 에이에스엠 아이피 홀딩 비.브이. Liquid level sensor for a chemical source vessel
USD965524S1 (en) 2019-08-19 2022-10-04 Asm Ip Holding B.V. Susceptor support
USD965044S1 (en) 2019-08-19 2022-09-27 Asm Ip Holding B.V. Susceptor shaft
JP2021031769A (en) 2019-08-21 2021-03-01 エーエスエム アイピー ホールディング ビー.ブイ. Production apparatus of mixed gas of film deposition raw material and film deposition apparatus
KR20210024423A (en) 2019-08-22 2021-03-05 에이에스엠 아이피 홀딩 비.브이. Method for forming a structure with a hole
USD940837S1 (en) 2019-08-22 2022-01-11 Asm Ip Holding B.V. Electrode
USD949319S1 (en) 2019-08-22 2022-04-19 Asm Ip Holding B.V. Exhaust duct
USD930782S1 (en) 2019-08-22 2021-09-14 Asm Ip Holding B.V. Gas distributor
USD979506S1 (en) 2019-08-22 2023-02-28 Asm Ip Holding B.V. Insulator
KR20210024420A (en) 2019-08-23 2021-03-05 에이에스엠 아이피 홀딩 비.브이. Method for depositing silicon oxide film having improved quality by peald using bis(diethylamino)silane
US11286558B2 (en) 2019-08-23 2022-03-29 Asm Ip Holding B.V. Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film
KR20210029090A (en) 2019-09-04 2021-03-15 에이에스엠 아이피 홀딩 비.브이. Methods for selective deposition using a sacrificial capping layer
KR20210029663A (en) 2019-09-05 2021-03-16 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus
US11562901B2 (en) 2019-09-25 2023-01-24 Asm Ip Holding B.V. Substrate processing method
CN112593212B (en) 2019-10-02 2023-12-22 Asm Ip私人控股有限公司 Method for forming topologically selective silicon oxide film by cyclic plasma enhanced deposition process
TW202129060A (en) 2019-10-08 2021-08-01 荷蘭商Asm Ip控股公司 Substrate processing device, and substrate processing method
TW202115273A (en) 2019-10-10 2021-04-16 荷蘭商Asm Ip私人控股有限公司 Method of forming a photoresist underlayer and structure including same
KR20210045930A (en) 2019-10-16 2021-04-27 에이에스엠 아이피 홀딩 비.브이. Method of Topology-Selective Film Formation of Silicon Oxide
US11637014B2 (en) 2019-10-17 2023-04-25 Asm Ip Holding B.V. Methods for selective deposition of doped semiconductor material
KR20210047808A (en) 2019-10-21 2021-04-30 에이에스엠 아이피 홀딩 비.브이. Apparatus and methods for selectively etching films
US11646205B2 (en) 2019-10-29 2023-05-09 Asm Ip Holding B.V. Methods of selectively forming n-type doped material on a surface, systems for selectively forming n-type doped material, and structures formed using same
KR20210054983A (en) 2019-11-05 2021-05-14 에이에스엠 아이피 홀딩 비.브이. Structures with doped semiconductor layers and methods and systems for forming same
US11501968B2 (en) 2019-11-15 2022-11-15 Asm Ip Holding B.V. Method for providing a semiconductor device with silicon filled gaps
KR20210062561A (en) 2019-11-20 2021-05-31 에이에스엠 아이피 홀딩 비.브이. Method of depositing carbon-containing material on a surface of a substrate, structure formed using the method, and system for forming the structure
KR20210065848A (en) 2019-11-26 2021-06-04 에이에스엠 아이피 홀딩 비.브이. Methods for selectivley forming a target film on a substrate comprising a first dielectric surface and a second metallic surface
CN112951697A (en) 2019-11-26 2021-06-11 Asm Ip私人控股有限公司 Substrate processing apparatus
CN112885692A (en) 2019-11-29 2021-06-01 Asm Ip私人控股有限公司 Substrate processing apparatus
CN112885693A (en) 2019-11-29 2021-06-01 Asm Ip私人控股有限公司 Substrate processing apparatus
JP2021090042A (en) 2019-12-02 2021-06-10 エーエスエム アイピー ホールディング ビー.ブイ. Substrate processing apparatus and substrate processing method
KR20210070898A (en) 2019-12-04 2021-06-15 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus
TW202125596A (en) 2019-12-17 2021-07-01 荷蘭商Asm Ip私人控股有限公司 Method of forming vanadium nitride layer and structure including the vanadium nitride layer
US11527403B2 (en) 2019-12-19 2022-12-13 Asm Ip Holding B.V. Methods for filling a gap feature on a substrate surface and related semiconductor structures
KR20210095050A (en) 2020-01-20 2021-07-30 에이에스엠 아이피 홀딩 비.브이. Method of forming thin film and method of modifying surface of thin film
TW202130846A (en) 2020-02-03 2021-08-16 荷蘭商Asm Ip私人控股有限公司 Method of forming structures including a vanadium or indium layer
KR20210100010A (en) 2020-02-04 2021-08-13 에이에스엠 아이피 홀딩 비.브이. Method and apparatus for transmittance measurements of large articles
US11776846B2 (en) 2020-02-07 2023-10-03 Asm Ip Holding B.V. Methods for depositing gap filling fluids and related systems and devices
US11781243B2 (en) 2020-02-17 2023-10-10 Asm Ip Holding B.V. Method for depositing low temperature phosphorous-doped silicon
US11876356B2 (en) 2020-03-11 2024-01-16 Asm Ip Holding B.V. Lockout tagout assembly and system and method of using same
KR20210116240A (en) 2020-03-11 2021-09-27 에이에스엠 아이피 홀딩 비.브이. Substrate handling device with adjustable joints
CN113394086A (en) 2020-03-12 2021-09-14 Asm Ip私人控股有限公司 Method for producing a layer structure having a target topological profile
KR20210124042A (en) 2020-04-02 2021-10-14 에이에스엠 아이피 홀딩 비.브이. Thin film forming method
TW202146689A (en) 2020-04-03 2021-12-16 荷蘭商Asm Ip控股公司 Method for forming barrier layer and method for manufacturing semiconductor device
TW202145344A (en) 2020-04-08 2021-12-01 荷蘭商Asm Ip私人控股有限公司 Apparatus and methods for selectively etching silcon oxide films
US11821078B2 (en) 2020-04-15 2023-11-21 Asm Ip Holding B.V. Method for forming precoat film and method for forming silicon-containing film
TW202140831A (en) 2020-04-24 2021-11-01 荷蘭商Asm Ip私人控股有限公司 Method of forming vanadium nitride–containing layer and structure comprising the same
KR20210132605A (en) 2020-04-24 2021-11-04 에이에스엠 아이피 홀딩 비.브이. Vertical batch furnace assembly comprising a cooling gas supply
KR20210132600A (en) 2020-04-24 2021-11-04 에이에스엠 아이피 홀딩 비.브이. Methods and systems for depositing a layer comprising vanadium, nitrogen, and a further element
KR20210134226A (en) 2020-04-29 2021-11-09 에이에스엠 아이피 홀딩 비.브이. Solid source precursor vessel
KR20210134869A (en) 2020-05-01 2021-11-11 에이에스엠 아이피 홀딩 비.브이. Fast FOUP swapping with a FOUP handler
KR20210141379A (en) 2020-05-13 2021-11-23 에이에스엠 아이피 홀딩 비.브이. Laser alignment fixture for a reactor system
KR20210143653A (en) 2020-05-19 2021-11-29 에이에스엠 아이피 홀딩 비.브이. Substrate processing apparatus
KR20210145078A (en) 2020-05-21 2021-12-01 에이에스엠 아이피 홀딩 비.브이. Structures including multiple carbon layers and methods of forming and using same
TW202201602A (en) 2020-05-29 2022-01-01 荷蘭商Asm Ip私人控股有限公司 Substrate processing device
TW202218133A (en) 2020-06-24 2022-05-01 荷蘭商Asm Ip私人控股有限公司 Method for forming a layer provided with silicon
TW202217953A (en) 2020-06-30 2022-05-01 荷蘭商Asm Ip私人控股有限公司 Substrate processing method
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Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57117000A (en) * 1981-01-13 1982-07-21 Showa Denki Kogyo Kk Feeding method of electric power to transport pipeline
SU1481553A2 (en) * 1987-04-06 1989-05-23 Государственный Научно-Исследовательский И Проектно-Конструкторский Институт "Южниигипрогаз" Pipeline having electric preheater
US6142707A (en) 1996-03-26 2000-11-07 Shell Oil Company Direct electric pipeline heating
US6161025A (en) 1998-04-01 2000-12-12 Chiu; Hung-Che External compiling device of a directory and a schedule calendar of a mobile phone
US6179523B1 (en) 1995-12-29 2001-01-30 Shell Oil Company Method for pipeline installation
US6264401B1 (en) 1995-12-29 2001-07-24 Shell Oil Company Method for enhancing the flow of heavy crudes through subsea pipelines
US6292627B1 (en) 1996-03-26 2001-09-18 Shell Oil Company Electrical heating of pipelines with pipe-in-pipe and mid-line connector
US6315497B1 (en) 1995-12-29 2001-11-13 Shell Oil Company Joint for applying current across a pipe-in-pipe system
US6371693B1 (en) 1999-08-27 2002-04-16 Shell Oil Company Making subsea pipelines ready for electrical heating
US20030017007A1 (en) 2001-07-20 2003-01-23 Bass Ronald Marshall Method of installation of electrically heated pipe-in-pipe subsea pipeline
US20030015436A1 (en) 2001-07-20 2003-01-23 Bass Ronald Marshall Corrosion protection of electrically heated pipe-in-pipe subsea pipeline
US20030020499A1 (en) 2001-07-20 2003-01-30 Bass Ronald M. Method for commissioning and operating an electrically heated pipe-in-pipe subsea pipeline

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1481533A1 (en) * 1987-10-28 1989-05-23 Г. Г Исакаев Torsion spring
US6509557B1 (en) * 1999-08-03 2003-01-21 Shell Oil Company Apparatus and method for heating single insulated flowlines
US6686745B2 (en) 2001-07-20 2004-02-03 Shell Oil Company Apparatus and method for electrical testing of electrically heated pipe-in-pipe pipeline
US6707012B2 (en) 2001-07-20 2004-03-16 Shell Oil Company Power supply for electrically heated subsea pipeline
US6688900B2 (en) * 2002-06-25 2004-02-10 Shell Oil Company Insulating joint for electrically heated pipeline

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57117000A (en) * 1981-01-13 1982-07-21 Showa Denki Kogyo Kk Feeding method of electric power to transport pipeline
SU1481553A2 (en) * 1987-04-06 1989-05-23 Государственный Научно-Исследовательский И Проектно-Конструкторский Институт "Южниигипрогаз" Pipeline having electric preheater
US6179523B1 (en) 1995-12-29 2001-01-30 Shell Oil Company Method for pipeline installation
US6264401B1 (en) 1995-12-29 2001-07-24 Shell Oil Company Method for enhancing the flow of heavy crudes through subsea pipelines
US6315497B1 (en) 1995-12-29 2001-11-13 Shell Oil Company Joint for applying current across a pipe-in-pipe system
US6142707A (en) 1996-03-26 2000-11-07 Shell Oil Company Direct electric pipeline heating
US6292627B1 (en) 1996-03-26 2001-09-18 Shell Oil Company Electrical heating of pipelines with pipe-in-pipe and mid-line connector
US6161025A (en) 1998-04-01 2000-12-12 Chiu; Hung-Che External compiling device of a directory and a schedule calendar of a mobile phone
US6371693B1 (en) 1999-08-27 2002-04-16 Shell Oil Company Making subsea pipelines ready for electrical heating
US20030017007A1 (en) 2001-07-20 2003-01-23 Bass Ronald Marshall Method of installation of electrically heated pipe-in-pipe subsea pipeline
US20030015436A1 (en) 2001-07-20 2003-01-23 Bass Ronald Marshall Corrosion protection of electrically heated pipe-in-pipe subsea pipeline
US20030020499A1 (en) 2001-07-20 2003-01-30 Bass Ronald M. Method for commissioning and operating an electrically heated pipe-in-pipe subsea pipeline

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 0062, no. 10 (M - 166) 22 October 1982 (1982-10-22) *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013030599A1 (en) * 2011-09-02 2013-03-07 Technip France A connector arrangement for a subsea pipeline
GB2494180B (en) * 2011-09-02 2013-09-04 Technip France A connector arrangement for pipe-in-pipe pipeline
US9175522B2 (en) 2011-09-02 2015-11-03 Technip France Connector arrangement for a subsea pipeline
NO20181178A1 (en) * 2018-09-11 2020-03-12 Nexans Connection device for providing an electrical connection between a subsea pipeline and an electrical conductor
NO345711B1 (en) * 2018-09-11 2021-06-28 Nexans Connection device for providing an electrical connection between a subsea pipeline and an electrical conductor

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US7033113B2 (en) 2006-04-25
US20050054228A1 (en) 2005-03-10
GB2416016A (en) 2006-01-11

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