WO2005110941A1 - Molasses treatment for the “molassperse” surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives applications - Google Patents

Molasses treatment for the “molassperse” surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives applications Download PDF

Info

Publication number
WO2005110941A1
WO2005110941A1 PCT/AU2005/000629 AU2005000629W WO2005110941A1 WO 2005110941 A1 WO2005110941 A1 WO 2005110941A1 AU 2005000629 W AU2005000629 W AU 2005000629W WO 2005110941 A1 WO2005110941 A1 WO 2005110941A1
Authority
WO
WIPO (PCT)
Prior art keywords
molasses
treatment
acid
molassperse
alkali
Prior art date
Application number
PCT/AU2005/000629
Other languages
French (fr)
Inventor
William James Gorman
Victor Vyrodov
Original Assignee
Australian Industrial Additives
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2004902556A external-priority patent/AU2004902556A0/en
Application filed by Australian Industrial Additives filed Critical Australian Industrial Additives
Priority to JP2007511765A priority Critical patent/JP2007537117A/en
Priority to NZ551941A priority patent/NZ551941A/en
Priority to AU2005244022A priority patent/AU2005244022B2/en
Publication of WO2005110941A1 publication Critical patent/WO2005110941A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B50/00—Sugar products, e.g. powdered, lump or liquid sugar; Working-up of sugar
    • C13B50/006—Molasses; Treatment of molasses
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/10—Carbohydrates or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
    • C04B2103/302—Water reducers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/52—Grinding aids; Additives added during grinding

Definitions

  • Molasses (see molasses typical analysis in Appendix 1) is traditionally used as a retarding agent in concrete admixtures [1,4]. It allows increased settings and as a result slightly reducing water consumption in concrete mixes.
  • This invented setting-retardant type high-early strength water reducing agent is prepared as follows: after molasses is diluted to 1.22-1.25 Baum'e degrees and heated to 70-80 deg.C, lime of 1-2 wt. % of that of diluted molasses is added for reaction to make a portion of sugar react with calcium oxide to form soluble calcium sugar which can produce optimum effect of water reduction.
  • the result is that the product after reaction still retains a portion of sugar component so that the said product not only possesses the effect of water reduction, but also that of setting retarding, meanwhile, the addition of anhydrous sodium sulphate in a certain proportion makes it have the effect of high-early strength.
  • “Molasses fermentation byproducts” essentially are spent waste liquor after fermentation of molasses sugars and extraction of fermentation products (mainly alcohol and yeast) from the "mother liquor”.
  • This molasses spent waste liquor in comparison with original molasses contains a relatively small quantity of the byproducts from the sugar fermentation process mainly in the form of different organic acids. These acids slightly increase the surfactant properties of molasses spent waste liquor in comparison with original molasses.
  • the main disadvantage (problem) of the "molasses fermentation byproducts” molasses spent waste liquor
  • “molasses fermentation byproducts” contain too many variables. Therefore these byproducts are seldom used in concrete admixtures application.
  • talc is a much softer material than cement clinker and gets ground significantly thinner than clinker.
  • the very fine particles of talc in the complex with molasses (as adhesive agent) hypothetically can envelope cement particles averting them from (against) aggregation.
  • the main disadvantage of this method is that molasses is not used as a surfactant- dispersant.
  • Molasses in the series is treated in acid and alkali environments at temperatures higher than ambient.
  • Inorganic and organic acids can be used for acidification of molasses up to pH 0.8
  • Inorganic and organic alkalis can be used for alkalization of molasses up to pH14.0
  • Temperature of acid and alkali treatment can be 50-200°C at ambient, positive and negative pressure
  • Catalysts of acid and alkali hydrolysis (oxidation) can be used for the treatment
  • Solids content of molasses can be 5.0-90.0%
  • Acid treatment provides: - converting of polysaccharides to monosaccharides (reducing sugars) converting of the part of monosaccharides to aldonic acids - decomposition of proteins to aminocarbonic acids with a relatively high quantity of carboxyl and amino groups
  • Alkali treatment provides: - converting of monosaccharides (reducing sugars) to saccharinic acids and their salts converting of aldonic acids to their salts decomposition of the residuary proteins to aminocarbonic acids - converting of aminocarbonic acids to their salts - converting (saponification) of wax ethers to the soluble soaps
  • the salts of saccharinic and aldonic acids are quite strong anionic surfactants with high dispersion properties.
  • the salts of aminocarbonic acids and wax soaps are effective wetting agents and detergents [7].
  • the produced complex of the surfactants provides a relatively high effectiveness of the treated molasses as concrete plasticizers (water reducing admixtures) and clinker grinding additives.
  • the modified molasses was tested as a plasicizer in cement mortars in comparison with the best general European softwood Na and Ca lignosulphonates.
  • Ratio Cement : Sand : Water was 1 : 3 : 0.55.
  • Fluidity of cement mortars was determined with Flow Table.
  • Air entrainment was determined by a volumetric method.
  • NA and CA Lignosulphonates are typical middle range water reducers and retarders.
  • Compressive strength of all cement mortars with the molasses modifications is a slightly higher in comparison with the mortars with lignosulphonates.
  • the molasses modifications are compatible with the best general European softwood Na and Ca lignosulphonates
  • the molasses modifications can be characterized as middle range water reducers with a low air entrainment.

Abstract

A method of treating molasses in which the molasses is modified to yield surfactants with plasticizer (water reducing) and dispersant properties. The essence of the treatment is that the molasses in the series is treated in acid and alkali environments at temperatures higher than ambient. This means that the ingredients of molasses are exposed to acid and alkali hydrolysis. The acid treatment provides the production of monosaccharides (reducing sugars), aldonic and aminocarbonic acids. The alkali treatment provides the forming of saccharinic acids and their salts, aldonic acid salts, aminocarbonic acids and their salts, and soluble soaps of wax ethers. The molasses modifications can be effectively used for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives application.

Description

Application for Invention
Title: Molasses treatment for the "Molassperse" surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives application
1. Background
1.1. Concrete admixtures
Molasses (see molasses typical analysis in Appendix 1) is traditionally used as a retarding agent in concrete admixtures [1,4]. It allows increased settings and as a result slightly reducing water consumption in concrete mixes.
Chinese patent titled: "PROCESS FOR PREPARING SETTING RETARDANT TYPE-HIGH- EARLY STRENGTH WATER-REDUCING AGENT AND PRODUCTS THEREOF" [2] is close to our presented invention.
This invented setting-retardant type high-early strength water reducing agent is prepared as follows: after molasses is diluted to 1.22-1.25 Baum'e degrees and heated to 70-80 deg.C, lime of 1-2 wt. % of that of diluted molasses is added for reaction to make a portion of sugar react with calcium oxide to form soluble calcium sugar which can produce optimum effect of water reduction. The result is that the product after reaction still retains a portion of sugar component so that the said product not only possesses the effect of water reduction, but also that of setting retarding, meanwhile, the addition of anhydrous sodium sulphate in a certain proportion makes it have the effect of high-early strength.
It is known that sugar (molasses sugar) added to the concrete mix immediately react with calcium oxide (which is produced in the process of cement hydration) and form "soluble calcium sugar".
The difference of this Chinese method, in comparison with traditional molasses using (direct molasses addition in concrete mix), is that a relatively small part molasses sugar is converted to "calcium sugar". The disadvantages in this method are: from a position of molasses modification: practically nothing is changed in the ingredients of concrete mix; just the process of formation of a small quantity of "calcium sugar" is slightly intensified "calcium sugar" starts to precipitate [3] at temperature lower than 20 deg. C misbalancing the hardening of concrete - sodium sulfate is used for reduction of traditionally strong molasses sugar retardation effect
The closest to the presented invention is the traditional Soviet Union's method [4] which is covered by Korean patent [5] titled: CONCRETE ADMIXTURES CONTAINING MOLASSES FERMENTATION BYPRODUCTS.
"Molasses fermentation byproducts" essentially are spent waste liquor after fermentation of molasses sugars and extraction of fermentation products (mainly alcohol and yeast) from the "mother liquor". This molasses spent waste liquor in comparison with original molasses contains a relatively small quantity of the byproducts from the sugar fermentation process mainly in the form of different organic acids. These acids slightly increase the surfactant properties of molasses spent waste liquor in comparison with original molasses. The main disadvantage (problem) of the "molasses fermentation byproducts" (molasses spent waste liquor) is their still lower surfactant properties in comparison with traditional water reducing agents such as lignosulphonates. Also "molasses fermentation byproducts" contain too many variables. Therefore these byproducts are seldom used in concrete admixtures application.
1.2. Cement clinker grinding additives
Traditionally molasses is not used as a grinding additive because of its low dispersant properties (low properties surfactant). However Chinese patent [6] titled: METHOD FOR
USING TALC & MOLASSES AS CEMENT GRINDIG AID suggests to use molasses for this application in combination with talc in approximate proportion, accordingly, 1 :10.
It seems that in this composition molasses is used as a well known adhesive agent.
In the process of grinding, talc is a much softer material than cement clinker and gets ground significantly thinner than clinker. The very fine particles of talc in the complex with molasses (as adhesive agent) hypothetically can envelope cement particles averting them from (against) aggregation.
This method is not widely used because of its low effectiveness.
The main disadvantage of this method is that molasses is not used as a surfactant- dispersant.
2. Idea of the Suggested Molasses Treatment
Deep modification of the molasses ingredients, converting them to the effective surfactants with plasticizer (water reducing) and dispersant properties.
3. Description of the Treatment (Invention)
3.1. Essence of the treatment
Molasses in the series is treated in acid and alkali environments at temperatures higher than ambient.
This means the ingredients of molasses are exposed to acid and alkali hydrolysis.
3.2. Regimes and parameters of the treatment
3.2.1. Inorganic and organic acids can be used for acidification of molasses up to pH 0.8
3.2.2. Inorganic and organic alkalis can be used for alkalization of molasses up to pH14.0
3.2.3. Temperature of acid and alkali treatment can be 50-200°C at ambient, positive and negative pressure
3.2.4. Catalysts of acid and alkali hydrolysis (oxidation) can be used for the treatment
3.2.5. Solids content of molasses can be 5.0-90.0%
3.2.6. Time of the treatment: - acid treatment 10min-24 hours alkali treatment 10min-24 hours 3.2.7. After both the acid and alkali treatment, the pH of molasses can be adjusted to the required levels.
4. Treatment effect on molasses properties
4.1. Acid treatment provides: - converting of polysaccharides to monosaccharides (reducing sugars) converting of the part of monosaccharides to aldonic acids - decomposition of proteins to aminocarbonic acids with a relatively high quantity of carboxyl and amino groups
4.2. Alkali treatment provides: - converting of monosaccharides (reducing sugars) to saccharinic acids and their salts converting of aldonic acids to their salts decomposition of the residuary proteins to aminocarbonic acids - converting of aminocarbonic acids to their salts - converting (saponification) of wax ethers to the soluble soaps
5. Properties of the new formations of the treated molasses
5.1. The salts of saccharinic and aldonic acids are quite strong anionic surfactants with high dispersion properties.
The salts of aminocarbonic acids and wax soaps are effective wetting agents and detergents [7].
5.2. Content of the produced complex of the surfactants: - domination of saccharinic and aldonic acids salts - a small part of aminocarbonic acids salts and wax soaps
5.3. The produced complex of the surfactants provides a relatively high effectiveness of the treated molasses as concrete plasticizers (water reducing admixtures) and clinker grinding additives.
6. Application tests of the treated molasses
6.1. The modified molasses was tested as a plasicizer in cement mortars in comparison with the best general European softwood Na and Ca lignosulphonates.
The test results are shown in Appendix 2.
6.2. The modified molasses was also tested as a clinker grinding additive. The test results are shown in Appendix 3.
7. Conclusion
The results of the tests show that the molasses modifications can be effectively used for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives application.
Appendix 1
Mill Molasses - Typical Analysis
Solids by Drying (%) 70-80 Total Sugar (%) 40-65 Sucrose (%) 30-40 (Jackson & Gillis method) Reducing Sugars (%) 10-20 (Lane & Eynon method) Unfermentable Sugars (%) 2-5 Crude Protein (%) 2-5 (Kjeldalh N) Ash (%) 10-15 (double sulphation)
Major Elements: Potassium 3.5-5.5 % Calcium 0.5-1.2 % Sodium 0.05-0.10 %
Trace Elements: Iron ppm Max 250 Copper ppm Max 10 Zinc ppm Max 15 Lead ppm Max 1.0 Arsenic less than ppm 1.0 Cadmium less than ppm 0.02 Appendix 2
Investigations of "Molassperse" Modified Molasses for Concrete Applications
Modifications
Three modifications of the raw molasses were done in the AIA laboratory.
The modifications were named Molassperse P-l, Molassperse P-2 and Molassperse P-3.
Testing in cement mortars
The best general European softwood Na and Ca lignosulphonates were used as control samples.
Consumption of the molasses modifications and lignosulphonates were 0.1, 0.2 and 0.3% of cement mass.
Blue Circle Southern Cement was used for making the cement mortars.
Two river sands (coarse and fine) were used in the tests (ratio 1:1).
Water/Cement ratio for all cement mortars was constant - 0.55.
Ratio Cement : Sand : Water was 1 : 3 : 0.55.
Fluidity of cement mortars was determined with Flow Table.
Air entrainment was determined by a volumetric method.
Cement mortar ISO prisms 40x40x160mm were made for compressive strength determination.
The results of the tests have shown in Table 1.
Discussion
NA and CA Lignosulphonates (control) are typical middle range water reducers and retarders.
Cement mortars with Molassperse P-l, Molassperse P-2 and Molassperse P-3 in comparison with NA Lignosulphonate and CA Lignosulphonate have a higher fluidity at low consumption 0.1 %.
At the middle consumption 0,2% and high consumption 0.3%- the mortar fluidity is similar for the molasses modifications and lignosulphonates.
Compressive strength of all cement mortars with the molasses modifications is a slightly higher in comparison with the mortars with lignosulphonates.
This can be explained by a higher air entrainment of lignosulphonates. Conclusions The molasses modifications are compatible with the best general European softwood Na and Ca lignosulphonates The molasses modifications can be characterized as middle range water reducers with a low air entrainment.
Table 1. Comparison tests of molasses modifications Molassperse P-l, Molassperse P-2 and Molassperse P-3 with NA and CA Lignosulphonates
Figure imgf000008_0001
Appendix 3
Investigations of "Molassperse" Modified Molasses for Cement Clinker Grinding Applications
Modifications Two modifications of the raw molasses were done in the AIA laboratory. The modifications were named Molassperse G-1 and Molassperse G-2. Testing in laboratory cement grinding mill Laboratory grinding mill with 2700 revolutions per hour and standard equipment were used. Cement clinker was ground with gypsum at a ratio of 95:5. The results of the tests are shown in Table 1.
Table 1. Clinker grinding tests of molasses modifications Molassperse G-1, and Molassperse G-2
Figure imgf000009_0001
Conclusion Both Molassperse G-1 and Molassperse G-2 can be used as effective cement clinker grinding additives. Reference Literature
1. B.J.Addis, D.E.Davis FULTON'S CONCRETE TECHNOLOGY Portland Cement Institute Midrand, South Africa, 1986
2. WANG RUBIN, QU ZHENBIN PROCESS FOR PREPARING SETTING RETARDANT TYPE-HIGH- EARLY STRENGTH WATER-REDUCING AGENT AND PRODUCTS THEREOF INST. OF LOW-TEMP. ARCHITECTURAL SCIENCE, HEILONGJIANG PROV. China Patent: CN 1067231 A
3. Schoenrock, Karlheinz W. R.; Ogden, UT Hsieh, Chia-Lung; Ogden, UT Rounds, Hugh G.; Ogden, UT Continuous process for the recovery of sugar from molasses Patent: US3997357
4. Admixtures for Concrete Soviet Union's State Standard: 24211-91 Moscow, 1991
5. KIM SEUNG JIN, PARK JEE WON; Republic of Korea CONCRETE ADMIXTURES CONTAINING MOLASSES FERMENTATION BYPRODUCTS Patent: KR3037597A
6. BAI XIANMING, SHAO ZHONGJUN; China METHOD FOR USING TALK & MOLASSES AS CEMENT GRINDIG AID Patent: CN1089245A
7. A.M.Schwartz, J.W.Perry SURFACE ACTIVE AGENTS THEIR CHEMISTRY AND TECHNOLOGY New York - London , 1949, 545 p

Claims

8. We claim:
A molasses treatment for the surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives application, the method comprising:
8.1. Molasses is in the series treated in acid and alkali environments at temperature higher than ambient
8.
2. Inorganic and organic acids can be used for acidification of molasses up to pH 0.8
8.
3. Inorganic and organic alkalis can be used for alkalization of molasses up to pH14.0
8.
4. Temperature of acid and alkali treatment can be 50-200°C at ambient, positive and negative pressure
8.
5. Catalysts of acid and alkali hydrolysis (oxidation) can be used for the treatment
8.
6. Solids content of molasses can be 5.0-90.0%)
8.
7. Time of the treatment: - acid treatment 10min-24 hours - alkali treatment 10min-24 hours
8.8. After the both acid and alkali treatment, the pH of molasses is adjusted up to the necessary value using inorganic and organic acids and alkalis.
PCT/AU2005/000629 2004-05-14 2005-04-28 Molasses treatment for the “molassperse” surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives applications WO2005110941A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2007511765A JP2007537117A (en) 2004-05-14 2005-04-28 Molasses treatment method for producing "Molasspers" surfactant for use in concrete fluidizer (water reducing agent) and cement clinker grinding admixture
NZ551941A NZ551941A (en) 2004-05-14 2005-04-28 Molasses treatment for the ômolassperseö surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives applications
AU2005244022A AU2005244022B2 (en) 2004-05-14 2005-04-28 Molasses treatment for the "molassperse" surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives applications

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AU2004902556 2004-05-14
AU2004902556A AU2004902556A0 (en) 2004-05-14 Molasses treatment for the "Molassperse" surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives

Publications (1)

Publication Number Publication Date
WO2005110941A1 true WO2005110941A1 (en) 2005-11-24

Family

ID=35394106

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/AU2005/000629 WO2005110941A1 (en) 2004-05-14 2005-04-28 Molasses treatment for the “molassperse” surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives applications

Country Status (4)

Country Link
JP (1) JP2007537117A (en)
CN (1) CN101006025A (en)
NZ (1) NZ551941A (en)
WO (1) WO2005110941A1 (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012155342A1 (en) 2011-05-17 2012-11-22 Construction Research & Technology Gmbh Process for preparing additive for cementitious materials, additive and mixture comprising additive
EP2559675A1 (en) 2011-08-16 2013-02-20 Sika Technology AG Enzymatically inverted saccharose as dispersing agent
US8460460B2 (en) 2011-06-24 2013-06-11 Construction Research & Technology Gmbh Cementitious composition and admixture
WO2013160158A1 (en) 2012-04-23 2013-10-31 Sika Technology Ag Enzymatically inverted sucrose as a grinding aid
US8657953B2 (en) 2011-06-24 2014-02-25 Construction Research & Technology Gmbh Cement additive
EP2862625A1 (en) * 2013-10-18 2015-04-22 Sika Technology AG Alkaline treated inverted molasses as a dispersant for mineral suspensions
CN106220024A (en) * 2016-08-26 2016-12-14 广西勤德科技股份有限公司 A kind of cane molasses produces the method for cement grinding aid
RU2770264C1 (en) * 2021-10-04 2022-04-14 Акционерное общество "СУЭК-Кузбасс" Composition for fixing dusty surfaces
CN115180868A (en) * 2022-08-16 2022-10-14 贵州石博士科技股份有限公司 Modified liquid concrete retarder and preparation method and application thereof
RU2795848C1 (en) * 2022-05-11 2023-05-12 Мехманович Тагиев Сенан Coal dust wetting agent
WO2024052077A1 (en) 2022-09-09 2024-03-14 Sika Technology Ag A novel chromium reducing agent used in a cement

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102229478B (en) * 2011-04-08 2013-07-03 江苏博特新材料有限公司 Preparation method of molasses retarding water reducer and application thereof
CN106182881B (en) * 2016-06-30 2017-10-27 潘洁萍 A kind of sugared machine squeezes roller and its manufacture method
CN110143777A (en) * 2019-03-19 2019-08-20 江西万年青工程有限公司 A kind of high-efficiency concrete grinding aid
CN110183138B (en) * 2019-06-06 2019-12-27 青岛筑建海绵城市科技有限公司 Inorganic permeable concrete modifying agent and preparation method and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB939545A (en) * 1960-10-12 1963-10-16 Ile D Etudes Et De Rech S Phar Process for the preparation of food products from sugar beet vinasses
JPS50104228A (en) * 1974-01-25 1975-08-18
JPS5229772B2 (en) * 1972-10-18 1977-08-04
US4058403A (en) * 1975-11-12 1977-11-15 Hooker Chemicals & Plastics Corporation Refractory compositions
SU983254A1 (en) * 1981-07-29 1982-12-23 Филиал Северо-Кавказского Государственного Научно-Исследовательского И Проектного Института Нефтяной Промышленности Composition for cementing high-temperature oil and gas wells
KR20030037597A (en) * 2001-11-06 2003-05-14 주식회사 지비알씨 Admixture for concrete comprising molasses fermentation by-product
WO2003078347A2 (en) * 2002-03-13 2003-09-25 W.R. Grace & Co.-Conn Beneficiated water reducing compositions

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5338731B2 (en) * 1974-06-04 1978-10-17
JPS63285138A (en) * 1987-05-15 1988-11-22 Nissan Chem Ind Ltd Grinding aid for cement clinker and blast furnace slag

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB939545A (en) * 1960-10-12 1963-10-16 Ile D Etudes Et De Rech S Phar Process for the preparation of food products from sugar beet vinasses
JPS5229772B2 (en) * 1972-10-18 1977-08-04
JPS50104228A (en) * 1974-01-25 1975-08-18
US4058403A (en) * 1975-11-12 1977-11-15 Hooker Chemicals & Plastics Corporation Refractory compositions
SU983254A1 (en) * 1981-07-29 1982-12-23 Филиал Северо-Кавказского Государственного Научно-Исследовательского И Проектного Института Нефтяной Промышленности Composition for cementing high-temperature oil and gas wells
KR20030037597A (en) * 2001-11-06 2003-05-14 주식회사 지비알씨 Admixture for concrete comprising molasses fermentation by-product
WO2003078347A2 (en) * 2002-03-13 2003-09-25 W.R. Grace & Co.-Conn Beneficiated water reducing compositions

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 197606, Derwent World Patents Index; AN 1976-10199X *
DATABASE WPI Week 197735, Derwent World Patents Index; AN 1977-62227Y *
DATABASE WPI Week 198343, Derwent World Patents Index; AN 1983-799633 *
DATABASE WPI Week 200377, Derwent World Patents Index; AN 2003-826096 *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014519466A (en) * 2011-05-17 2014-08-14 コンストラクション リサーチ アンド テクノロジー ゲーエムベーハー Method for producing additive for cementitious material, additive, and mixture containing additive
WO2012155342A1 (en) 2011-05-17 2012-11-22 Construction Research & Technology Gmbh Process for preparing additive for cementitious materials, additive and mixture comprising additive
US9133059B2 (en) 2011-06-24 2015-09-15 Construction Research & Technology Gmbh Cementitious composition and admixture
US8460460B2 (en) 2011-06-24 2013-06-11 Construction Research & Technology Gmbh Cementitious composition and admixture
US8657953B2 (en) 2011-06-24 2014-02-25 Construction Research & Technology Gmbh Cement additive
US8920556B2 (en) 2011-06-24 2014-12-30 Construction Research & Technology Gmbh Cementitious composition and admixture
EP2559675A1 (en) 2011-08-16 2013-02-20 Sika Technology AG Enzymatically inverted saccharose as dispersing agent
WO2013024138A1 (en) 2011-08-16 2013-02-21 Sika Technology Ag Enzymatically inverted saccharose as a dispersant
WO2013160158A1 (en) 2012-04-23 2013-10-31 Sika Technology Ag Enzymatically inverted sucrose as a grinding aid
EP2862625A1 (en) * 2013-10-18 2015-04-22 Sika Technology AG Alkaline treated inverted molasses as a dispersant for mineral suspensions
WO2015055725A1 (en) 2013-10-18 2015-04-23 Sika Technology Ag Alkaline-treated inverted molasses as dispersants for mineral suspensions
US9981875B2 (en) 2013-10-18 2018-05-29 Sika Technology Ag Alkaline-treated inverted molasses as dispersants for mineral suspensions
CN106220024A (en) * 2016-08-26 2016-12-14 广西勤德科技股份有限公司 A kind of cane molasses produces the method for cement grinding aid
RU2770264C1 (en) * 2021-10-04 2022-04-14 Акционерное общество "СУЭК-Кузбасс" Composition for fixing dusty surfaces
RU2795848C1 (en) * 2022-05-11 2023-05-12 Мехманович Тагиев Сенан Coal dust wetting agent
CN115180868A (en) * 2022-08-16 2022-10-14 贵州石博士科技股份有限公司 Modified liquid concrete retarder and preparation method and application thereof
CN115180868B (en) * 2022-08-16 2023-05-16 贵州石博士科技股份有限公司 Modified liquid concrete retarder and preparation method and application thereof
WO2024052077A1 (en) 2022-09-09 2024-03-14 Sika Technology Ag A novel chromium reducing agent used in a cement

Also Published As

Publication number Publication date
NZ551941A (en) 2009-10-30
JP2007537117A (en) 2007-12-20
CN101006025A (en) 2007-07-25

Similar Documents

Publication Publication Date Title
WO2005110941A1 (en) Molasses treatment for the “molassperse” surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives applications
CA2547015C (en) Gluconate broth for cement and concrete admixture
CN105272069B (en) A kind of ultra-fine portland cement base grouting material and preparation method thereof
CN108996939B (en) Prehydrated mineral powder nanocrystal core early strength agent for steam-cured concrete and preparation method thereof
KR20130062162A (en) High early strength cement comprising blast furnace slag and csa cement
WO2012155342A1 (en) Process for preparing additive for cementitious materials, additive and mixture comprising additive
CN107986648A (en) Portland slag cement and preparation method thereof
CN106673553A (en) Tile adhesive with low cost and preparation method thereof
US3960582A (en) Low porosity cement and process for producing same
CN107056110A (en) A kind of metakaolin base Portland cement mortar reinforcing agent and preparation method thereof
CN113636767A (en) Low-carbon cement and preparation method thereof
CN109503020B (en) Modifying assistant for portland cement and preparation method thereof
CN112028534B (en) Early-strength water reducing agent, production process and application thereof
CN110255943B (en) Wet-grinding barium slag admixture and preparation method and application thereof
Kim et al. Hydration kinetics of ordinary Portland cement mixed under a direct CO2 inject condition
CN114656184B (en) Sulfate erosion resistant concrete additive, preparation method thereof and concrete
EP2760805B1 (en) Method for the production of a building material
CN110668758A (en) Grouting material for connecting reinforcing steel bar sleeve
AU2005244022B2 (en) Molasses treatment for the "molassperse" surfactant production for concrete plasticizers (water reducing admixtures) and cement clinker grinding additives applications
CN102249594B (en) Alkali-activated slag cement retarder and application method thereof
CN110759660B (en) Additive for magnesium phosphate cement repair mortar and preparation method thereof
CN113683382A (en) Preparation of fiber concrete by using multi-solid-waste coupling admixture
CN110171940B (en) Coral sand admixture and preparation method and application thereof
CN102491716B (en) Titanium gypsum used in cement, and treatment method thereof by using stalk black ash
US9981875B2 (en) Alkaline-treated inverted molasses as dispersants for mineral suspensions

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2007511765

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWW Wipo information: withdrawn in national office

Ref document number: DE

WWE Wipo information: entry into national phase

Ref document number: 2005244022

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 12006502445

Country of ref document: PH

WWE Wipo information: entry into national phase

Ref document number: 551941

Country of ref document: NZ

WWE Wipo information: entry into national phase

Ref document number: 7551/DELNP/2006

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 1200602040

Country of ref document: VN

ENP Entry into the national phase

Ref document number: 2005244022

Country of ref document: AU

Date of ref document: 20050428

Kind code of ref document: A

WWP Wipo information: published in national office

Ref document number: 2005244022

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 200580023417.9

Country of ref document: CN

122 Ep: pct application non-entry in european phase