WO2005123586A3 - Silicide compositions containing alkali metals and methods of making the same - Google Patents

Silicide compositions containing alkali metals and methods of making the same Download PDF

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Publication number
WO2005123586A3
WO2005123586A3 PCT/US2005/020766 US2005020766W WO2005123586A3 WO 2005123586 A3 WO2005123586 A3 WO 2005123586A3 US 2005020766 W US2005020766 W US 2005020766W WO 2005123586 A3 WO2005123586 A3 WO 2005123586A3
Authority
WO
WIPO (PCT)
Prior art keywords
compositions
methods
alkali metal
making
relates
Prior art date
Application number
PCT/US2005/020766
Other languages
French (fr)
Other versions
WO2005123586A2 (en
Inventor
Michael Lefenfeld
James L Dye
Original Assignee
Signa Chemistry Llc
Univ Michigan State
Michael Lefenfeld
James L Dye
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=35510314&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2005123586(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Signa Chemistry Llc, Univ Michigan State, Michael Lefenfeld, James L Dye filed Critical Signa Chemistry Llc
Priority to EP05785526.4A priority Critical patent/EP1768926B1/en
Priority to CA2570295A priority patent/CA2570295C/en
Priority to CN200580027653.8A priority patent/CN101031507B/en
Priority to AU2005254551A priority patent/AU2005254551A1/en
Priority to JP2007516608A priority patent/JP5138370B2/en
Publication of WO2005123586A2 publication Critical patent/WO2005123586A2/en
Publication of WO2005123586A3 publication Critical patent/WO2005123586A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/06—Metal silicides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24V—COLLECTION, PRODUCTION OR USE OF HEAT NOT OTHERWISE PROVIDED FOR
    • F24V30/00—Apparatus or devices using heat produced by exothermal chemical reactions other than combustion
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Silicon Compounds (AREA)
  • Fuel Cell (AREA)

Abstract

The invention relates to a method of making alkali metal silicide compositions, and the compositions resulting from the method, comprising miring an alkali metal with silicon and heating the resulting mixture to a temperature below about 475 °C. The resulting compositions do not react with dry O2. Also, the invention relates to sodium silicide compositions having a powder X-ray diffraction pattern comprising at least three peaks with 2Theta angles selected from about 18.2, 28.5, 29.5, 33.7, 41.2, 47.4, and 56.2 and a solid state 23Na MAS NMR spectra peak at about 18 ppm. Moreover, the invention relates to methods of removing a volatile or flammable substance in a controlled manner. Furthermore, the alkali metal silicide compositions of the invention react with water to produce hydrogen gas.
PCT/US2005/020766 2004-06-14 2005-06-14 Silicide compositions containing alkali metals and methods of making the same WO2005123586A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP05785526.4A EP1768926B1 (en) 2004-06-14 2005-06-14 Silicide compositions containing alkali metals and methods of making the same
CA2570295A CA2570295C (en) 2004-06-14 2005-06-14 Silicide compositions containing alkali metals and methods of making the same
CN200580027653.8A CN101031507B (en) 2004-06-14 2005-06-14 Silicide compositions containing alkali metals and methods of making the same
AU2005254551A AU2005254551A1 (en) 2004-06-14 2005-06-14 Silicide compositions containing alkali metals and methods of making the same
JP2007516608A JP5138370B2 (en) 2004-06-14 2005-06-14 Silicide composition containing alkali metal and method for producing the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US57881804P 2004-06-14 2004-06-14
US60/578,818 2004-06-14
US66769305P 2005-04-04 2005-04-04
US60/667,693 2005-04-04

Publications (2)

Publication Number Publication Date
WO2005123586A2 WO2005123586A2 (en) 2005-12-29
WO2005123586A3 true WO2005123586A3 (en) 2006-07-06

Family

ID=35510314

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/020766 WO2005123586A2 (en) 2004-06-14 2005-06-14 Silicide compositions containing alkali metals and methods of making the same

Country Status (7)

Country Link
US (4) US7811541B2 (en)
EP (2) EP1768926B1 (en)
JP (2) JP5138370B2 (en)
CN (1) CN104118846B (en)
AU (1) AU2005254551A1 (en)
CA (1) CA2570295C (en)
WO (1) WO2005123586A2 (en)

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US8795926B2 (en) 2005-08-11 2014-08-05 Intelligent Energy Limited Pump assembly for a fuel cell system
US8808410B2 (en) 2009-07-23 2014-08-19 Intelligent Energy Limited Hydrogen generator and product conditioning method
US8895204B2 (en) 2010-11-08 2014-11-25 Intelligent Energy Limited Water reactive hydrogen fuel cell power system
US8940458B2 (en) 2010-10-20 2015-01-27 Intelligent Energy Limited Fuel supply for a fuel cell
US9034531B2 (en) 2008-01-29 2015-05-19 Ardica Technologies, Inc. Controller for fuel cell operation
US9102528B2 (en) 2009-03-30 2015-08-11 Intelligent Energy Limited Hydrogen generation systems and methods utilizing sodium silicide and sodium silica gel materials
US9169976B2 (en) 2011-11-21 2015-10-27 Ardica Technologies, Inc. Method of manufacture of a metal hydride fuel supply

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AU2005254551A1 (en) * 2004-06-14 2005-12-29 Michigan State University Silicide compositions containing alkali metals and methods of making the same
US9156687B2 (en) * 2005-06-14 2015-10-13 Intelligent Energy Limited Water reactive hydrogen generation system and method with separation of waste products from water reactive materials
US7670698B2 (en) * 2006-04-10 2010-03-02 Honeywell International Inc Silicide fueled power generators and methods related thereto
DE102008051670A1 (en) * 2008-10-15 2009-11-05 H2 Solar Gmbh Metallic or non-metallic silicides for photo-electrochemical decomposition of water and photovoltaic electricity generation, is illuminated, optionally in contact with water
MX2011010292A (en) 2009-03-30 2012-01-27 Signa Chemistry Inc Hydrogen generation systems and methods utilizing sodium silicide and sodium silica gel materials.
US8741004B2 (en) 2009-07-23 2014-06-03 Intelligent Energy Limited Cartridge for controlled production of hydrogen
US20110053016A1 (en) * 2009-08-25 2011-03-03 Daniel Braithwaite Method for Manufacturing and Distributing Hydrogen Storage Compositions
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BR112013027067A2 (en) 2011-04-21 2019-09-24 Eveready Battery Inc enhanced volume efficiency hydrogen generator
WO2012174251A2 (en) * 2011-06-14 2012-12-20 Signa Chemistry, Inc. Foamed cement compositions containing metal silicides usable in subterranean well operations
US9266727B2 (en) 2011-06-28 2016-02-23 Intelligent Energy Limited Hydrogen gas generator
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US9005321B2 (en) 2012-03-19 2015-04-14 Intelligent Energy Inc. Hydrogen generator system with liquid interface
CN108086953A (en) * 2012-06-25 2018-05-29 西格纳化学有限责任公司 Metal silicide in hydrocarbon production and transportation
US20130344407A1 (en) 2012-06-25 2013-12-26 Eveready Battery Company, Inc. Hydrogen Generator and Method of Controlling Reaction
CN102765723B (en) * 2012-07-23 2014-06-11 复旦大学 Method for synthesizing KSi hydrogen storage alloy
US9162201B2 (en) 2012-08-14 2015-10-20 Intelligent Energy, Inc. Hydrogen generator having liquid delivery member
US9051183B2 (en) 2012-08-24 2015-06-09 Intelligent Energy Inc. Hydrogen generator having reactant pellet with concentration gradient
JP6068907B2 (en) * 2012-10-01 2017-01-25 株式会社 東北テクノアーチ Method for producing silicon and alkali metal silicates
EP2970337A4 (en) * 2013-03-15 2016-11-16 Signa Chemistry Inc Treatment of alkali silica gel and alkali porous metal oxide compositions
US10309204B2 (en) 2013-10-17 2019-06-04 Signa Chemistry, Inc. Use of alkali metal silicides in post-chops oilfield recovery operations
PT3095758T (en) 2015-05-20 2019-03-29 Drage & Mate Int S L A system and a process for generating hydrogen
JP6535581B2 (en) * 2015-11-18 2019-06-26 信越化学工業株式会社 Negative electrode active material, mixed negative electrode active material, negative electrode for non-aqueous electrolyte secondary battery, lithium ion secondary battery
CN107188123B (en) * 2017-01-06 2019-03-08 中国计量大学 A kind of preparation method of silicon/alkali metal hydrogen manufacturing material
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CN112051302B (en) * 2020-07-27 2023-05-12 北京航天控制仪器研究所 Method for measuring alkali metal quantity in atomic gas chamber
CN111943211B (en) * 2020-08-21 2022-02-22 南方科技大学 Metal silicide preparation method and preparation auxiliary device
JP7456922B2 (en) 2020-11-25 2024-03-27 株式会社豊田自動織機 Manufacturing method of negative electrode active material raw material
JP7456921B2 (en) 2020-11-25 2024-03-27 株式会社豊田自動織機 Manufacturing method of negative electrode active material raw material

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AU2005254551A1 (en) 2005-12-29
US7811541B2 (en) 2010-10-12
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US20120201734A1 (en) 2012-08-09

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