WO2006023698A2 - Unitized fibrous constructs having functional circumferential retaining elements - Google Patents

Unitized fibrous constructs having functional circumferential retaining elements Download PDF

Info

Publication number
WO2006023698A2
WO2006023698A2 PCT/US2005/029496 US2005029496W WO2006023698A2 WO 2006023698 A2 WO2006023698 A2 WO 2006023698A2 US 2005029496 W US2005029496 W US 2005029496W WO 2006023698 A2 WO2006023698 A2 WO 2006023698A2
Authority
WO
WIPO (PCT)
Prior art keywords
construct
fibers
reinforcing
filaments
reinforcing filaments
Prior art date
Application number
PCT/US2005/029496
Other languages
French (fr)
Other versions
WO2006023698A3 (en
Inventor
Paul Schmidt
Gene Lamb
Original Assignee
Polymer Group, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polymer Group, Inc. filed Critical Polymer Group, Inc.
Priority to EP05791516A priority Critical patent/EP1789641A2/en
Publication of WO2006023698A2 publication Critical patent/WO2006023698A2/en
Publication of WO2006023698A3 publication Critical patent/WO2006023698A3/en

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C5/00Reinforcing elements, e.g. for concrete; Auxiliary elements therefor
    • E04C5/07Reinforcing elements of material other than metal, e.g. of glass, of plastics, or not exclusively made of metal
    • E04C5/073Discrete reinforcing elements, e.g. fibres
    • E04C5/076Specially adapted packagings therefor, e.g. for dosing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0077Packaging material remaining in the mixture after the mixing step, e.g. soluble bags containing active ingredients

Definitions

  • the present invention is directed to unitized fibrous constructs for reinforcing castable mixtures, such as cementitious matrices or mixtures and, more particularly a unitized fibrous construct in which the circumferential retaining element that retains a bundle of reinforcing fibers or filaments also serves as a reinforcing element upon mixture into the castable mixture.
  • Relatively large diameter fibers for example, in excess of 40 to 60 microns in diameter, can be added to a cementitious mixture such as a wet concrete blend, dispersed in the blend by mechanical agitation, followed by pouring and curing of the concrete.
  • Large diameter fibers serve to reinforce the concrete after it has been cured, by providing additional tensile strength and minimizing impact damage and crack propagation.
  • Small diameter fibers typically less than 30 to 40 microns in diameter, and having a relatively high surface area, are commonly added to concrete mixes in order to reduce the development of small elastic shrinkage cracks in the concrete during the curing period. The problem of crack development is known to occur as a result of uneven curing of the concrete.
  • the fibrous components used typically in the practice of reinforcing cementitious mixtures include specifically thermoplastic synthetic fibers of finite staple length, such as polypropylene staple fibers.
  • the corresponding performance of the binding agent is based upon application of the binding agent to the reinforcement fibrous components such that the binding agent is both uniformly applied to the majority of the fibers so as to obtain equivalency within the batch, and that no excess binding agent is introduced as such will adversely effect the ability of the reinforcement fibrous components to disengage and distribute homogeneously.
  • binding agents One other determent encountered in the use of binding agents is that air is often entrained within the micro-bundles upon application and agglomeration of the staple fibers. When such micro-bundles are subjected to mechanical mixing, the entrained air is released as a foam, which reasonably compromises the ability of the cementitious mixture to cure uniformly.
  • Cellulosic tapes have also been utilized to retain reinforcement fibers; however, such tapes can become problematic for a cementitious matrix or mixture as well. See for example United States Patent No. 5,807,458, entitled, "Reinforcing Elements for Castable Compositions", issued September 15, 1998, in the name of inventors Sanders et al.
  • the cellulose tape is prone to degradation in the alkaline environment of the mixture. Degradation of the tapes may introduce void spaces within the mixture which can negatively impact uniform curing of the cement. Further, the wet cellulose tapes can promote mold growth within the mixture that can lead to cracks in the setting mix.
  • circumferential binding elements have been utilized to provide temporary retention of fibrous constructs, as disclosed in commonly assigned U.S. Patent Publication 2004/0244653, entitled “Unitized Fibrous Concrete Reinforcement”, filed on December 9, 2004, in the name of inventors Schmidt et al, which is herein incorporated by reference as if set forth fully herein.
  • the circumferential binding element was purposeful as a retaining element, but did not contribute incremental functionality within the cementitious matrix.
  • the present invention is directed to unitized fibrous constructs for reinforcement in a castable compound, such as a cementitious matrices or mixtures.
  • the invention provides for a construct that includes a bundle of reinforcing fibers or filaments surround, at least partially, by a retaining element, which also serves the dual purpose, upon addition to the cementitious mixture, of acting as a reinforcing element.
  • the retaining element does not need to dissolve or otherwise be dispersible upon addition to the cementitious mixture. As such, degradation issues with dispersible materials are eliminated, such as issues related to void spaces in the mixture and possible mold issues leading to crack propagation.
  • a unitized fibrous construct for reinforcing a cementitious mixture includes a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface.
  • the unit will those typically form the geometry of a cylindrical bundle of filaments or fibers, although other geometries of the unit are herein contemplated and within the bounds of the present invention.
  • the construct also includes a retaining element that serves as a reinforcing element in the cementitious mixture.
  • the retaining element surrounds at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture.
  • the circumferential retaining element aids in maintaining the integrity of the unitized fibrous construct, and the fibrous component therein, for purposes of shipment, measurement, and dosing into a cementitious mixture.
  • the retaining element will be spirally wound around the plurality of fibers or filaments, such that the retaining element provides temporal retention of the bundle of fibers or filaments prior to immersion in the cementitious mixture.
  • the retaining element will be formed of a similar material, and in some embodiments the identical material, as is used to form the reinforcing fibers or filaments.
  • the circumferential retaining element may be selected from suitable materials that are considered structurally beneficial to a cementitious matrix by providing additional reinforcement, minimize impact damage, and crack propagation.
  • suitable materials that are considered structurally beneficial to a cementitious matrix by providing additional reinforcement, minimize impact damage, and crack propagation.
  • Such fibrous or filamentary material at least partially or may entirely include super absorbent polymers, splittable fiber or filaments, and fiber or filaments with three- dimensionality, such as coiled or crimped.
  • such materials may consist of thermoplastic, thermoset and partially soluble resins, which are subject to mechanical failure when a corresponding stress and/or solvency threshold is exceeded.
  • the material selected may also be mechanically modified, as exemplified by fibrillation, drawing, perforation, crimping, embossing or molding, so as to exhibit performance attributes in the cementitious matrix such as a reinforcement or elastic shrinkage crack reduction.
  • Various geometries may be employed in the application of the circumferential retaining element, including without limitation, continuous or discontinuous filaments, ribbons, or sheets, which circumscribe the combined, essentially parallel reinforcing fibrous components. It is within the purview of the present invention that the composition of the circumferential retaining elements and of one or more of the reinforcing fibrous components need not necessarily be the same.
  • the retaining element may be placed under additional tension by means of twisting the retaining element. Placing additional tension on the retaining element facilitates the mechanical removal of the retaining element upon mechanical agitation, which then enhances the fiber distribution within a cementitious mixture.
  • the present embodiment includes a single retaining element it is possible, and within the inventive concepts herein disclosed, for more than one retaining element to be used in connection with a single unitized reinforcing construct. For example, two reinforcing elements may be spirally wound around the unit of fibers or filaments in a double-helix type arrangement.
  • the reinforcing filaments are continuous filaments and in fiber embodiments the fibers are finite staple-length fibers. Additionally, the reinforcing filaments may be characterized as fibrillated reinforcing filaments. The reinforcing filaments or fibers may be imparted with tension during processing to insure that the degree of dispersion necessary occurs once the bundle of filaments or fibers are free from retention within the cementitious mixture. In alternate embodiments the reinforcing filaments or fibers may be splittable filaments or fibers or may be formed from a super absorbent polymer composition.
  • the unitized fibrous construct for reinforcing a cementitious mixture includes a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface.
  • the construct also includes a retaining element formed of one or more splittable filaments that surround at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture.
  • the splittable filaments will provide reinforcing capabilities once they have been added to the cementitious mixture
  • the reinforcing filaments or fibers may have a composition similar to or identical to the composition of the splittable filament retaining element. Additionally, the plurality of reinforcing filaments or fibers may be defined as fibrillated reinforcing filaments, which may be imparted with tension to further encourage dispersion upon release from the retaining element. The reinforcing filaments or fibers may further be defined as being formed from a super absorbent polymer composition. [0019] In yet another embodiment the unitized fibrous construct for reinforcing a cementitious mixture includes a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface.
  • the construct also includes a retaining element formed of a super absorbent polymer composition that surrounds at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture.
  • a retaining element formed of a super absorbent polymer composition that surrounds at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture.
  • the super absorbent polymer composition retaining elements will provide reinforcing capabilities once they have been added to the cementitious mixture.
  • the reinforcing filaments or fibers may have a composition similar to or identical to the composition of the super absorbent polymer composition retaining element. Additionally, the plurality of reinforcing filaments or fibers may be defined as fibrillated reinforcing filaments, which may be imparted with tension to further encourage dispersion upon release from the retaining element. The reinforcing filaments or fibers may further be defined as being formed from a super absorbent polymer composition.
  • the present invention is able to provide for a cementitious reinforcing construct that includes a retaining element that imparts reinforcing structure into the cementitious mixture.
  • a construct benefits from not having a retaining structure that disperses or otherwise dissolves in the aqueous cementitious mixture and imparts possible negative side-effects to the cementitious mixture, such as voids, strength reducing mold and the like.
  • the reinforcing aspect of the retaining element provides for a construct that is able to provide additional per unit reinforcement of the cement mixture.
  • Figure 1 is an illustrative embodiment of the unitized fibrous construct of the present invention.
  • the unitized fibrous construct 10 is defined herein as a construct including a plurality of oriented reinforcing continuous filaments or finite staple length fibers 12.
  • the filaments or fibers 12 are arranged in a general parallel relationship such that the filaments or fibers form a bundle. While the bundle will typically have a general cylindrical shape, the bundle may also have any other shape, for example oval, square, triangular, etc.
  • the plurality of filaments or fibers 12 will be bundled such that they form a circumferential exterior surface 14.
  • the construct further includes one or more retaining elements 16 that surround at least a portion of the circumferential exterior surface 14 and serve to retain the reinforcing filaments or fibers 12 prior to adding the construct 10 to a castable mixture, such as a cementitious mixture.
  • the retaining element will serve as a reinforcing element upon once added to the castable mixture, such as a cementitious mixture.
  • the retaining element 16 In order for the retaining element 16 to serve as a reinforcing element upon addition to the castable mixture the retaining element will typically be formed of a similar, and in some embodiments identical, fibrous or filamentary material, denier, and length as the reinforcing fibers or filaments 12. Further still, in alternate embodiment the retaining element 16 may be of a dissimilar fibrous or filamentary material, denier, and length as the reinforcing fibers or filaments 12. In those embodiments in which the retaining element is a dissimilar fibrous or filamentary material compared to the reinforcing fibers or filaments, the retaining element will be formed of a material that allows for the retaining element to provide reinforcing characteristics upon addition to the castable mixture.
  • the unitized fibrous construct of the present invention is formed from a plurality of reinforcing fibrous or filamentary components and one or more circumferential retaining elements.
  • the composition of such reinforcing fibers and circumferential retaining element may be formed from any suitable synthetic polymers, including, but not limited to, thermoplastic and thermoset polymers, including polyesters, polyolefins, such as polypropylene and polypropylene copolymers, polyethylene and polyethylene copolymers, polyamides, polyimides, polylactic acid, polyhydroxyalkanoate, polyvinyl alcohol, ethylene vinyl alcohol, polyacrylates, copolymers thereof, and the combinations thereof.
  • reinforcing fibers or filaments and the circumferential retaining element may be formed from any suitable natural fibers, including, but not limited to rayon, cotton, pulp, flax, and hemp and the combinations thereof.
  • a particularly preferred embodiment of the present invention is directed to reinforcing fibers or filaments including polyolefin thermoplastic resins.
  • the retaining element that surrounds a portion of the exterior surface includes splittable filaments, which may be of similar or dissimilar polymeric composition in relation to the reinforcing fibers or filaments.
  • splittable fibers are taught in United States Patent No. 6,838,402, issued on January 4, 2005, in the name of inventors Harris, et al.; United States Patent No. 6,746,766, issued on June 18, 2004, in the name of inventors Bond, et al.; United States Patent No. 6,743,506, issued on June 1 , 2004, in the name of inventors Bond et al.; and United States Patent No. 6,444,312, issued on September 9, 2002, in the name of inventor Dugan, all of which are herein incorporated by reference as if set forth fully herein.
  • the plurality of reinforcing filaments may be fibrillated, wherein the filaments may be fibrillated by any conventional fibrillation technique, such as by mechanical fibrillation described in United States Patent No. 3,302,501 , issued on February 7, 1967, in the name of inventor Greene; United States Patent No. 3,496,260, issued February 17, 1970, in the name of inventors Guenther et al.; United States Patent No. 3,550,826, issued December 29, 1970; in the name of inventor Salmela; and United States Patent No. 3,756,484, issued September 4, 1973, in the name of inventor Guenther, or by fluid and sonic fibrillation as disclosed in United States Patent No.
  • reinforcing filaments may be imparted with tension by way of twisting the filaments as well. Tension imparted in the reinforcing filaments will cause greater dispersion of the filaments once the retaining element has been removed from the construct/bundle of filaments.
  • the plurality of reinforcing fibers or filaments may be formed from a super absorbent polymer composition.
  • Exemplary super absorbent polymers are disclosed in United States Patent No. 5,145,609, issued September 8, 1992, in the name of inventor Chambers; United States Patent No. 4,820,773; issued April 11 , 1989, in the name to inventors Alexander et al.; and United States Patent No. 4,645,039, issued March 31 , 1997; in the name of inventor Brandt et al., all of which are herein incorporated by reference as if set forth fully herein.
  • the retaining element that surrounds a portion of the exterior surface may include a super absorbent polymer composition.
  • exemplary super absorbent polymers are disclosed in the previously referenced and incorporated patents.
  • the reinforcing fibers may include splittable fibers. Suitable splittable fibers are taught in the previously referenced and incorporated patents.
  • the retaining element surrounds at least a portion of the circumferential exterior surface of the construct. Once formed, the retaining element aids in maintaining the integrity of the unitized fibrous construct, and the reinforcing fibrous component therein, for the purposes of shipment, measurement, and dosing into a cementitious mixture. Upon mechanical agitation, and optionally exposure to appropriate solvents, the unitized fibrous construct in a cementitious mixture, the retaining element are disrupted, allowing for the homogenous release, distribution, and disbursement of the reinforcing fibrous component into the overall cementitious mixture.
  • the unitized fibrous construct of the present invention is believe to reduce plastic shrinkage cracking by at least 10% per ASTM 1399, Obtaining Average Residual Strength of Fiber Reinforced Concrete.
  • a preferred, though non-limiting, method is taught in part by United States Patent No. 4,228,641 , issued on October 1 , 1980, in the name of inventors O'Neil, this patent is herein incorporated by reference as if set forth fully herein.
  • the '641 O'Neil patent teaches a twine including a core bundle of synthetic monofilaments circumscribed by a synthetic material in a thin band form spirally wound about the monofilaments.
  • the dimensions of the retaining element is defined in terms of the overall circumference of the exterior surface formed by the reinforcing fibers or filaments, as based on the quantity and relative denier of the individual reinforcing fibrous components, and of length, as based on the greatest finite staple length of the cumulative combination of reinforcing fibrous components.
  • Suitable overall circumferences and lengths of the circumferential retaining elements formed in accordance with the present invention may reasonably range from 3 mm to 150 mm and from 8 mm to 100 mm, respectively.
  • circumferential retaining elements exhibit an overall diameter of between 3mm and 30mm and lengths of between 12 mm and 50 mm may be utilized.
  • the circumferential retaining elements may exhibit a width preferably about 1%-50% of the total diameter of the unitized fibrous construct, more preferably about 3%-40% of the total diameter of the unitized fibrous construct, and most preferably about 5%-30% of the total diameter of the unitized fibrous construct.
  • the circumferential retaining element is preferably about 2%-50% by weight of the unitized construct including parallelized reinforcement fibers, more preferably of about 6%-40% by weight of the unitized construct, and most preferably of about 8%-30% weight of the unitized construct.
  • the circumferential retaining element may include one or more continuous or discontinuous filaments, ribbons, or sheets of varying thicknesses that retain the reinforcing fibrous components by a plurality of wrapping techniques so as to expose more or less fiber to the external environment.
  • two thin circumferential retaining elements may be used in a double helix wrapping technique, whereby two circumferential retaining elements criss-cross back and forth about the circumference of the fibrous components.
  • the present invention is able to provide for a cementitious reinforcing construct that includes a retaining element that imparts reinforcing structure into the cementitious mixture.
  • a construct benefits from not having a retaining structure that disperses or otherwise dissolves in the aqueous cementitious mixture and imparts possible negative side-effects to the cementitious mixture, such as voids, strength reducing mold and the like.
  • the reinforcing aspect of the retaining element provides for a construct that is able to provide additional per unit reinforcement of the cement mixture.

Abstract

A unitized fibrous construct for providing reinforcement to castable structures, such as cementitious structures is claimed. The construct includes a bundle of reinforcing fibers or filaments that are held in place prior to addition to the cementitious mixture by a retaining element. The retaining element is of such a composition that upon release into the cementitious mixture it provides reinforcing capability to the cement structure. As such, the construct adds additional reinforcing capability and diminishes the likelihood of detrimental side-effects attributed to retaining elements that otherwise dissolve or disperse in the cementitious mixture.

Description

UN)TIZED FIBROUS CONSTRUCTS HAVING FUNCTIONAL CIRCUMFERENTIAL RETAINING ELEMENTS
Cross-reference to Related Application
[0001] This application claims benefit of United States provisional application No. 60/603,091 , filed on August 20, 2004.
Field Of The Invention
[0002] The present invention is directed to unitized fibrous constructs for reinforcing castable mixtures, such as cementitious matrices or mixtures and, more particularly a unitized fibrous construct in which the circumferential retaining element that retains a bundle of reinforcing fibers or filaments also serves as a reinforcing element upon mixture into the castable mixture.
Background Of The Invention
[0003] Many proposals have been made to reinforce, strengthen, and/or reduce cracking during curing or otherwise beneficially alter the properties of castable mixtures, such as cementitious mixtures, by applying and/or incorporating various types of fibrous components, including asbestos, glass, steel, as well as synthetic polymer fibers to aqueous based concrete mixes prior to the curing of the concrete. The types of polymer fibers in use or proposed for use include those composed of natural and synthetic composition. As is evident in the prior art, individual fibrous components are well known in terms of their performance modifying attributes. Relatively large diameter fibers, for example, in excess of 40 to 60 microns in diameter, can be added to a cementitious mixture such as a wet concrete blend, dispersed in the blend by mechanical agitation, followed by pouring and curing of the concrete. Large diameter fibers serve to reinforce the concrete after it has been cured, by providing additional tensile strength and minimizing impact damage and crack propagation. Small diameter fibers, typically less than 30 to 40 microns in diameter, and having a relatively high surface area, are commonly added to concrete mixes in order to reduce the development of small elastic shrinkage cracks in the concrete during the curing period. The problem of crack development is known to occur as a result of uneven curing of the concrete. The fibrous components used typically in the practice of reinforcing cementitious mixtures include specifically thermoplastic synthetic fibers of finite staple length, such as polypropylene staple fibers.
[0004] Due to the variable and unpredictable form conventional reinforcing fibrous components have heretofore been provided for end-use consumption, such as at a construction work-site, the accurate and reproducible dosing of reinforcing fibrous component into sequential batches of cementitious mixtures has been dubious at best. Further complicating the actual utilization of the reinforcing fibrous components, numerous synthetic thermoplastic polymers used in the formation of suitable staple fibers are inherently hydrophobic in nature. As a result, difficulties can arise in obtaining a uniform dispersion and blending of the reinforcing fibrous component throughout hydrous cementitious mixtures using conventional mixing equipment.
[0005] Prior attempts to address the issue described have focused on the use of binding agents. U.S. Patent No. 5,399,195, entitled, "Fibres and material comprising the same", issued on March 21 , 1995, in the name of inventors Hansen et al., discloses the addition of small amounts of fine (less than 30 microns) polymer fibers to concrete. During production, the filaments are treated with a topical wetting agent. After the filaments are chopped into staple-length fibers, the wetting agent holds or binds the staple fibers together in the form of micro-bundles. The micro- bundles remain relatively stable during handling, and when the fibers are added to the concrete mix, the wetting agent promotes dispersion of the fibers. U.S. Patent No. 6,258,159, entitled, "Product and method for incorporating synthetic polymer fibers into cement mixtures", issued on July 10, 2001 , in the name of inventor PyIe, attempts to address the forming of micro-bundles of fibers by incorporation of binding agents into the staple fibers themselves during the melt-extrusion process. [0006] The use of binding agents, whether internal or externally applied, while improving in-part issues inherent of individual staple fibers, such practices have not obviated such problems as random agglomerate size, and further, the use of binding agents has introduced additional problems. Most notably, the corresponding performance of the binding agent is based upon application of the binding agent to the reinforcement fibrous components such that the binding agent is both uniformly applied to the majority of the fibers so as to obtain equivalency within the batch, and that no excess binding agent is introduced as such will adversely effect the ability of the reinforcement fibrous components to disengage and distribute homogeneously. One other determent encountered in the use of binding agents is that air is often entrained within the micro-bundles upon application and agglomeration of the staple fibers. When such micro-bundles are subjected to mechanical mixing, the entrained air is released as a foam, which reasonably compromises the ability of the cementitious mixture to cure uniformly.
[0007] Cellulosic tapes have also been utilized to retain reinforcement fibers; however, such tapes can become problematic for a cementitious matrix or mixture as well. See for example United States Patent No. 5,807,458, entitled, "Reinforcing Elements for Castable Compositions", issued September 15, 1998, in the name of inventors Sanders et al. The cellulose tape is prone to degradation in the alkaline environment of the mixture. Degradation of the tapes may introduce void spaces within the mixture which can negatively impact uniform curing of the cement. Further, the wet cellulose tapes can promote mold growth within the mixture that can lead to cracks in the setting mix.
[0008] More recently, circumferential binding elements have been utilized to provide temporary retention of fibrous constructs, as disclosed in commonly assigned U.S. Patent Publication 2004/0244653, entitled "Unitized Fibrous Concrete Reinforcement", filed on December 9, 2004, in the name of inventors Schmidt et al, which is herein incorporated by reference as if set forth fully herein. Heretofore, the circumferential binding element was purposeful as a retaining element, but did not contribute incremental functionality within the cementitious matrix. [0009] As is evident in the industry, an unmet need exists for a means of introducing reinforcing fibrous components into a cementitious mixture such that the reinforcing fibrous components exhibit the attributes of uniform and predictable presentation for use, while the circumferential retaining elements, which temporarily bind the oriented fibrous components, further provide an advantageous and incremental performance within the cementitious matrix.
Summary Of The Invention
[0010] The present invention is directed to unitized fibrous constructs for reinforcement in a castable compound, such as a cementitious matrices or mixtures. The invention provides for a construct that includes a bundle of reinforcing fibers or filaments surround, at least partially, by a retaining element, which also serves the dual purpose, upon addition to the cementitious mixture, of acting as a reinforcing element. In this regard, the retaining element does not need to dissolve or otherwise be dispersible upon addition to the cementitious mixture. As such, degradation issues with dispersible materials are eliminated, such as issues related to void spaces in the mixture and possible mold issues leading to crack propagation. In addition, by creating a construct in which the retaining element serves as a reinforcing element further strengthening and stability of the overall cementitious mixture is imparted from a single unitized fibrous construct. [0011] In one embodiment of the invention a unitized fibrous construct for reinforcing a cementitious mixture includes a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface. The unit will those typically form the geometry of a cylindrical bundle of filaments or fibers, although other geometries of the unit are herein contemplated and within the bounds of the present invention. The construct also includes a retaining element that serves as a reinforcing element in the cementitious mixture. The retaining element surrounds at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture. Thus, once the construct is formed, the circumferential retaining element aids in maintaining the integrity of the unitized fibrous construct, and the fibrous component therein, for purposes of shipment, measurement, and dosing into a cementitious mixture. Typically the retaining element will be spirally wound around the plurality of fibers or filaments, such that the retaining element provides temporal retention of the bundle of fibers or filaments prior to immersion in the cementitious mixture. In most instances, minimal spiral winding is required, less than about 30% coverage of the surface area of the circumferential exterior surface of the unit, so as to insure that the fibers and filaments become free from containment upon agitation in the cementitious mixture. Upon mechanical agitation of the unitized fibrous construct in a cementitious mixture, the circumferential retaining element is disrupted, allowing for the homogenous release, distribution, and dispersion of the reinforcing filaments and fibers into the overall cementitious mixture and release of the circumferential retaining element itself into the mixture, which also serves as a reinforcing element.
[0012] Typically, the retaining element will be formed of a similar material, and in some embodiments the identical material, as is used to form the reinforcing fibers or filaments. The circumferential retaining element may be selected from suitable materials that are considered structurally beneficial to a cementitious matrix by providing additional reinforcement, minimize impact damage, and crack propagation. Such fibrous or filamentary material at least partially or may entirely include super absorbent polymers, splittable fiber or filaments, and fiber or filaments with three- dimensionality, such as coiled or crimped. Further, such materials may consist of thermoplastic, thermoset and partially soluble resins, which are subject to mechanical failure when a corresponding stress and/or solvency threshold is exceeded. The material selected may also be mechanically modified, as exemplified by fibrillation, drawing, perforation, crimping, embossing or molding, so as to exhibit performance attributes in the cementitious matrix such as a reinforcement or elastic shrinkage crack reduction. [0013] Various geometries may be employed in the application of the circumferential retaining element, including without limitation, continuous or discontinuous filaments, ribbons, or sheets, which circumscribe the combined, essentially parallel reinforcing fibrous components. It is within the purview of the present invention that the composition of the circumferential retaining elements and of one or more of the reinforcing fibrous components need not necessarily be the same.
[0014] It is further within the purview of the present invention that the retaining element may be placed under additional tension by means of twisting the retaining element. Placing additional tension on the retaining element facilitates the mechanical removal of the retaining element upon mechanical agitation, which then enhances the fiber distribution within a cementitious mixture. [0015] It is also noted that while the present embodiment includes a single retaining element it is possible, and within the inventive concepts herein disclosed, for more than one retaining element to be used in connection with a single unitized reinforcing construct. For example, two reinforcing elements may be spirally wound around the unit of fibers or filaments in a double-helix type arrangement. [0016] The reinforcing filaments are continuous filaments and in fiber embodiments the fibers are finite staple-length fibers. Additionally, the reinforcing filaments may be characterized as fibrillated reinforcing filaments. The reinforcing filaments or fibers may be imparted with tension during processing to insure that the degree of dispersion necessary occurs once the bundle of filaments or fibers are free from retention within the cementitious mixture. In alternate embodiments the reinforcing filaments or fibers may be splittable filaments or fibers or may be formed from a super absorbent polymer composition.
[0017] In another embodiment the unitized fibrous construct for reinforcing a cementitious mixture includes a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface. The construct also includes a retaining element formed of one or more splittable filaments that surround at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture. Typically, the splittable filaments will provide reinforcing capabilities once they have been added to the cementitious mixture
[0018] The reinforcing filaments or fibers may have a composition similar to or identical to the composition of the splittable filament retaining element. Additionally, the plurality of reinforcing filaments or fibers may be defined as fibrillated reinforcing filaments, which may be imparted with tension to further encourage dispersion upon release from the retaining element. The reinforcing filaments or fibers may further be defined as being formed from a super absorbent polymer composition. [0019] In yet another embodiment the unitized fibrous construct for reinforcing a cementitious mixture includes a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface. The construct also includes a retaining element formed of a super absorbent polymer composition that surrounds at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture. Typically, the super absorbent polymer composition retaining elements will provide reinforcing capabilities once they have been added to the cementitious mixture.
[0020] The reinforcing filaments or fibers may have a composition similar to or identical to the composition of the super absorbent polymer composition retaining element. Additionally, the plurality of reinforcing filaments or fibers may be defined as fibrillated reinforcing filaments, which may be imparted with tension to further encourage dispersion upon release from the retaining element. The reinforcing filaments or fibers may further be defined as being formed from a super absorbent polymer composition.
[0021] Thus, the present invention is able to provide for a cementitious reinforcing construct that includes a retaining element that imparts reinforcing structure into the cementitious mixture. Such a construct benefits from not having a retaining structure that disperses or otherwise dissolves in the aqueous cementitious mixture and imparts possible negative side-effects to the cementitious mixture, such as voids, strength reducing mold and the like. Additionally, the reinforcing aspect of the retaining element provides for a construct that is able to provide additional per unit reinforcement of the cement mixture.
Brief Description Of The Drawing
[0022] Figure 1 is an illustrative embodiment of the unitized fibrous construct of the present invention.
Detailed Description Of The Invention
[0023] While the present invention is susceptible of embodiments in various forms, hereinafter the present invention is described by presently preferred embodiments with the understanding that the present disclosure is to be considered as an exemplification of the invention, and is not intended to limit the invention to the specific embodiment illustrated.
[0024] Referring to Figure 1 , therein is illustrated an embodiment of a unitized fibrous construct of the present invention. The unitized fibrous construct is added to a castable mixture, such as a cementitious mixture to provide added reinforcement, resulting in greater strength, stability and crack-resistance. The unitized fibrous construct 10 is defined herein as a construct including a plurality of oriented reinforcing continuous filaments or finite staple length fibers 12. The filaments or fibers 12 are arranged in a general parallel relationship such that the filaments or fibers form a bundle. While the bundle will typically have a general cylindrical shape, the bundle may also have any other shape, for example oval, square, triangular, etc. The plurality of filaments or fibers 12 will be bundled such that they form a circumferential exterior surface 14.
[0025] The construct further includes one or more retaining elements 16 that surround at least a portion of the circumferential exterior surface 14 and serve to retain the reinforcing filaments or fibers 12 prior to adding the construct 10 to a castable mixture, such as a cementitious mixture. The retaining element will serve as a reinforcing element upon once added to the castable mixture, such as a cementitious mixture.
[0026] In order for the retaining element 16 to serve as a reinforcing element upon addition to the castable mixture the retaining element will typically be formed of a similar, and in some embodiments identical, fibrous or filamentary material, denier, and length as the reinforcing fibers or filaments 12. Further still, in alternate embodiment the retaining element 16 may be of a dissimilar fibrous or filamentary material, denier, and length as the reinforcing fibers or filaments 12. In those embodiments in which the retaining element is a dissimilar fibrous or filamentary material compared to the reinforcing fibers or filaments, the retaining element will be formed of a material that allows for the retaining element to provide reinforcing characteristics upon addition to the castable mixture.
[0027] Typically, the unitized fibrous construct of the present invention is formed from a plurality of reinforcing fibrous or filamentary components and one or more circumferential retaining elements. The composition of such reinforcing fibers and circumferential retaining element may be formed from any suitable synthetic polymers, including, but not limited to, thermoplastic and thermoset polymers, including polyesters, polyolefins, such as polypropylene and polypropylene copolymers, polyethylene and polyethylene copolymers, polyamides, polyimides, polylactic acid, polyhydroxyalkanoate, polyvinyl alcohol, ethylene vinyl alcohol, polyacrylates, copolymers thereof, and the combinations thereof. Additionally the reinforcing fibers or filaments and the circumferential retaining element may be formed from any suitable natural fibers, including, but not limited to rayon, cotton, pulp, flax, and hemp and the combinations thereof. A particularly preferred embodiment of the present invention is directed to reinforcing fibers or filaments including polyolefin thermoplastic resins.
[0028] In one embodiment of the invention the retaining element that surrounds a portion of the exterior surface includes splittable filaments, which may be of similar or dissimilar polymeric composition in relation to the reinforcing fibers or filaments. Suitable splittable fibers are taught in United States Patent No. 6,838,402, issued on January 4, 2005, in the name of inventors Harris, et al.; United States Patent No. 6,746,766, issued on June 18, 2004, in the name of inventors Bond, et al.; United States Patent No. 6,743,506, issued on June 1 , 2004, in the name of inventors Bond et al.; and United States Patent No. 6,444,312, issued on September 9, 2002, in the name of inventor Dugan, all of which are herein incorporated by reference as if set forth fully herein.
[0029] In embodiments in which the retaining element is splittable filaments, the plurality of reinforcing filaments may be fibrillated, wherein the filaments may be fibrillated by any conventional fibrillation technique, such as by mechanical fibrillation described in United States Patent No. 3,302,501 , issued on February 7, 1967, in the name of inventor Greene; United States Patent No. 3,496,260, issued February 17, 1970, in the name of inventors Guenther et al.; United States Patent No. 3,550,826, issued December 29, 1970; in the name of inventor Salmela; and United States Patent No. 3,756,484, issued September 4, 1973, in the name of inventor Guenther, or by fluid and sonic fibrillation as disclosed in United States Patent No. 3,345,242, issued October 3, 1967, in the name of inventor Rasmussen, all of which are hereby incorporated by reference as if set forth fully herein. In addition, the reinforcing filaments may be imparted with tension by way of twisting the filaments as well. Tension imparted in the reinforcing filaments will cause greater dispersion of the filaments once the retaining element has been removed from the construct/bundle of filaments.
[0030] Additionally, in embodiments in which the retaining element is splittable filaments, the plurality of reinforcing fibers or filaments may be formed from a super absorbent polymer composition. Exemplary super absorbent polymers are disclosed in United States Patent No. 5,145,609, issued September 8, 1992, in the name of inventor Chambers; United States Patent No. 4,820,773; issued April 11 , 1989, in the name to inventors Alexander et al.; and United States Patent No. 4,645,039, issued March 31 , 1997; in the name of inventor Brandt et al., all of which are herein incorporated by reference as if set forth fully herein.
[0031] In another embodiment of the invention the retaining element that surrounds a portion of the exterior surface may include a super absorbent polymer composition. Exemplary super absorbent polymers are disclosed in the previously referenced and incorporated patents.
[0032] In those embodiments in which the retaining element is formed of a super absorbent polymer composition, the reinforcing fibers may include splittable fibers. Suitable splittable fibers are taught in the previously referenced and incorporated patents.
According to the present invention, the retaining element surrounds at least a portion of the circumferential exterior surface of the construct. Once formed, the retaining element aids in maintaining the integrity of the unitized fibrous construct, and the reinforcing fibrous component therein, for the purposes of shipment, measurement, and dosing into a cementitious mixture. Upon mechanical agitation, and optionally exposure to appropriate solvents, the unitized fibrous construct in a cementitious mixture, the retaining element are disrupted, allowing for the homogenous release, distribution, and disbursement of the reinforcing fibrous component into the overall cementitious mixture. The unitized fibrous construct of the present invention is believe to reduce plastic shrinkage cracking by at least 10% per ASTM 1399, Obtaining Average Residual Strength of Fiber Reinforced Concrete. [0033] A number of suitable methodologies exist for the formation of unitized fibrous constructs in accordance with the present invention. A preferred, though non-limiting, method is taught in part by United States Patent No. 4,228,641 , issued on October 1 , 1980, in the name of inventors O'Neil, this patent is herein incorporated by reference as if set forth fully herein. The '641 O'Neil patent teaches a twine including a core bundle of synthetic monofilaments circumscribed by a synthetic material in a thin band form spirally wound about the monofilaments. It has been found by the inventors of the present invention that by practice of the method taught in the '641 O'Neil patent, with subsequent and repeated scission of the continuous twine construct at or between each iteration of the spiral winding that finite length unitized fibrous constructs are formed which are suitable for practice in light of the present invention.
[0034] The dimensions of the retaining element is defined in terms of the overall circumference of the exterior surface formed by the reinforcing fibers or filaments, as based on the quantity and relative denier of the individual reinforcing fibrous components, and of length, as based on the greatest finite staple length of the cumulative combination of reinforcing fibrous components. Suitable overall circumferences and lengths of the circumferential retaining elements formed in accordance with the present invention may reasonably range from 3 mm to 150 mm and from 8 mm to 100 mm, respectively. In a presently preferred embodiment for standard practices, circumferential retaining elements exhibit an overall diameter of between 3mm and 30mm and lengths of between 12 mm and 50 mm may be utilized. Further, the circumferential retaining elements may exhibit a width preferably about 1%-50% of the total diameter of the unitized fibrous construct, more preferably about 3%-40% of the total diameter of the unitized fibrous construct, and most preferably about 5%-30% of the total diameter of the unitized fibrous construct. Further still, the circumferential retaining element is preferably about 2%-50% by weight of the unitized construct including parallelized reinforcement fibers, more preferably of about 6%-40% by weight of the unitized construct, and most preferably of about 8%-30% weight of the unitized construct.
[0035] The circumferential retaining element may include one or more continuous or discontinuous filaments, ribbons, or sheets of varying thicknesses that retain the reinforcing fibrous components by a plurality of wrapping techniques so as to expose more or less fiber to the external environment. For instance, two thin circumferential retaining elements may be used in a double helix wrapping technique, whereby two circumferential retaining elements criss-cross back and forth about the circumference of the fibrous components.
[0036] Thus, the present invention is able to provide for a cementitious reinforcing construct that includes a retaining element that imparts reinforcing structure into the cementitious mixture. Such a construct benefits from not having a retaining structure that disperses or otherwise dissolves in the aqueous cementitious mixture and imparts possible negative side-effects to the cementitious mixture, such as voids, strength reducing mold and the like. Additionally, the reinforcing aspect of the retaining element provides for a construct that is able to provide additional per unit reinforcement of the cement mixture.
[0037] From the foregoing, it will be observed that numerous modifications and variations can be affected without departing from the true spirit and scope of the novel concept of the present invention. It is to be understood that no limitation with respect to the specific embodiments illustrated herein is intended or should be inferred. The disclosure is intended to cover, by the appended claims, all such modifications as fall within the scope of the claims.

Claims

What Is Claimed Is:
1. A unitized fibrous construct for reinforcing a cementitious mixture, the construct comprising: a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface; and a retaining element that surrounds at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture, wherein the retaining element serves as a reinforcing element in the cementitious mixture.
2. The construct of Claim 1 , wherein the plurality of reinforcing filaments and the retaining element are formed of similar materials.
3. The construct of Claim 1 , wherein the plurality of reinforcing filaments further comprise a plurality of continuous reinforcing filaments.
4. The construct of Claim 1 , wherein the plurality of reinforcing fibers further comprises a plurality of finite staple length reinforcing fibers.
5. The construct of Claim 1 , wherein the plurality of reinforcing filaments further comprises a plurality of fibrillated reinforcing filaments.
6. The construct of Claim 1 , wherein the plurality of reinforcing filaments or fibers is further defined as being imparted with tension to impart greater dispersion upon addition to the cementitious mixture.
7. The construct of Claim 1 , wherein the plurality of reinforcing filaments or fibers further comprise splittable reinforcing filaments or fibers.
8. The construct of Claim 1 , wherein the plurality of reinforcing filaments or fibers further comprise a super absorbent polymer composition.
9. The construct of Claim 1 , wherein the retaining element further comprises a splittable filament or fiber retaining element.
10. The construct of Claim 1 , wherein the retaining element further comprises a super absorbent polymer composition.
11. The construct of Claim 1 , wherein the retaining element circumscribes no more than 80% of the total surface area of the circumferential exterior surface.
12. A unitized fibrous construct for reinforcing a cementitious mixture, the construct comprising: a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface; and a retaining element formed of one or more splittable filaments that surrounds at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture.
13. The construct of Claim 12, wherein the plurality of reinforcing filaments or fibers further comprise filaments or fibers having a composition similar to the retaining element.
14. The construct of Claim 12, wherein the plurality of reinforcing filaments or fibers further comprise a plurality of fibrillated reinforcing filaments.
15. The construct of Claim 14, wherein the fibrillated filaments are further defined as being imparted with tension.
16. The construct of Claim 12, wherein the plurality of reinforcing filaments or fibers further comprise a super absorbent polymer composition.
17. The construct of Claim 12, wherein the plurality of reinforcing filaments or fibers further comprise a plurality of splittable reinforcing filaments.
18. A unitized fibrous construct for reinforcing a cementitious mixture, the construct comprising: a plurality of reinforcing filaments or fibers oriented in a generally parallel relationship such that the plurality of reinforcing filaments or fibers form a unit having a circumferential exterior surface; and a retaining element formed of a super absorbent polymer composition that surrounds at least a portion of the circumferential exterior surface and retains the plurality of reinforcing filaments or fibers prior to adding the construct to the cementitious mixture.
19. The construct of Claim 18, wherein the plurality of reinforcing filaments or fibers further comprise filaments or fibers having a composition similar to the retaining element.
20. The construct of Claim 18, wherein the plurality of reinforcing filaments or fibers further comprise a plurality of splittable reinforcing filaments or fibers.
21. The construct of Claim 18, wherein the plurality of reinforcing filaments or fibers further comprise a super absorbent polymer composition.
PCT/US2005/029496 2004-08-20 2005-08-19 Unitized fibrous constructs having functional circumferential retaining elements WO2006023698A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP05791516A EP1789641A2 (en) 2004-08-20 2005-08-19 Unitized fibrous constructs having functional circumferential retaining elements

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US60309104P 2004-08-20 2004-08-20
US60/603,091 2004-08-20

Publications (2)

Publication Number Publication Date
WO2006023698A2 true WO2006023698A2 (en) 2006-03-02
WO2006023698A3 WO2006023698A3 (en) 2007-06-14

Family

ID=35968191

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/029496 WO2006023698A2 (en) 2004-08-20 2005-08-19 Unitized fibrous constructs having functional circumferential retaining elements

Country Status (3)

Country Link
US (1) US20060070341A1 (en)
EP (1) EP1789641A2 (en)
WO (1) WO2006023698A2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2374860A1 (en) * 2010-04-12 2011-10-12 Services Pétroliers Schlumberger Methods for treating fibers
WO2021213652A1 (en) * 2020-04-22 2021-10-28 Wacker Chemie Ag Mixtures containing superabsorbers

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2514056A1 (en) * 2003-01-24 2004-08-12 Polymer Group, Inc. Unitized fibrous concrete reinforcement
EP1638900A2 (en) 2003-05-30 2006-03-29 Polymer Group Inc. Unitized filamantary concrete reinforcement having circumferential binding element
WO2010078995A1 (en) * 2009-01-09 2010-07-15 Nv Bekaert Sa Longitudinal belt with reinforcing fibres
EA025976B1 (en) * 2010-10-21 2017-02-28 Рефорстек Лтд. Reinforcement bar for concrete structures and method for manufacturing same

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4433536A (en) * 1981-09-23 1984-02-28 Exxon Research & Engineering Co. Spiral wrapped synthetic twine and method of manufacturing same
US5091255A (en) * 1990-01-23 1992-02-25 American Cyanamid Company Molding granules, their manufacture and their use in the production of molded articles
US5227227A (en) * 1990-03-05 1993-07-13 Johnson & Johnson Inc. Non-woven fabric with a thermally activated adhesive surface, resulting product and applications thereof
US5807458A (en) * 1993-05-03 1998-09-15 Minnesota Mining & Manufacturing Company Reinforcing elements for castable compositions
US5985449A (en) * 1997-10-08 1999-11-16 Specialty Filaments Crimped thermoplastic fibers for reinforcing concrete
US7147904B1 (en) * 2003-08-05 2006-12-12 Evelyn Florence, Llc Expandable tubular fabric

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE637119A (en) * 1962-09-07 1900-01-01
US3415919A (en) * 1965-07-02 1968-12-10 Delta Rope & Twine Ltd Method and apparatus for making twine
US3302501A (en) * 1965-09-24 1967-02-07 Phillips Petroleum Co Method of fibrillating plastic film by passing the film through rotating piercing means
NL134100C (en) * 1966-03-31 1900-01-01
US3523300A (en) * 1966-08-18 1970-08-04 Toray Industries Spinning method and apparatus for manufacturing yarn from textile fibers
US3756484A (en) * 1968-05-03 1973-09-04 Chevron Res Apparatus for preparing fibrous web
US3550826A (en) * 1968-07-03 1970-12-29 Chevron Res Method for preparing extremely fine fibrous webs
BE758763A (en) * 1969-11-12 1971-04-16 Nat Res Dev PERFECTED MIXING PROCESS
US3625809A (en) * 1970-02-24 1971-12-07 Owens Corning Fiberglass Corp Filament blend products
US3834916A (en) * 1972-03-23 1974-09-10 Steel Corp Fiber-reinforced cement composite
NL173433C (en) * 1973-04-16 Bekaert Sa Nv
US4228641A (en) * 1978-09-28 1980-10-21 Exxon Research & Engineering Co. Thermoplastic twines
US4477522A (en) * 1983-04-11 1984-10-16 Sherwood Research Corporation Reinforcing element and method of making the same
US4820776A (en) * 1985-04-24 1989-04-11 Texaco Inc. Hydrocarbon compositions containing polyolefin graft polymers having amine and phenothiazine grafted moieties
US4654039A (en) * 1985-06-18 1987-03-31 The Proctor & Gamble Company Hydrogel-forming polymer compositions for use in absorbent structures
USRE32649E (en) * 1985-06-18 1988-04-19 The Procter & Gamble Company Hydrogel-forming polymer compositions for use in absorbent structures
JP2506365B2 (en) * 1987-04-10 1996-06-12 株式会社クラレ Cement mortar or concrete reinforcing fiber and composition using the fiber
US5032181A (en) * 1988-04-20 1991-07-16 Chung Deborah D L Carbon fiber reinforced cement concrete composites improved by using chemical agents
DK695688D0 (en) * 1988-12-14 1988-12-14 Danaklon As FIBERS AND MATERIALS CONTAINING THE SAME
US4950692A (en) * 1988-12-19 1990-08-21 Nalco Chemical Company Method for reconstituting superabsorbent polymer fines
US4963151A (en) * 1988-12-28 1990-10-16 Trustees Of The University Of Pennsylvania Reinforced bone cement, method of production thereof and reinforcing fiber bundles therefor
US5145906A (en) * 1989-09-28 1992-09-08 Hoechst Celanese Corporation Super-absorbent polymer having improved absorbency properties
US6219991B1 (en) * 1990-08-06 2001-04-24 Hexcel Corporation Method of externally strengthening concrete columns with flexible strap of reinforcing material
US5145609A (en) * 1990-11-07 1992-09-08 Donnelly Corporation Linear polyether-containing electrochemichromic solutions and related devices
US5251640A (en) * 1992-03-31 1993-10-12 Cook, Incorporated Composite wire guide shaft
US5727357A (en) * 1996-05-22 1998-03-17 Owens-Corning Fiberglas Technology, Inc. Composite reinforcement
US6838402B2 (en) * 1999-09-21 2005-01-04 Fiber Innovation Technology, Inc. Splittable multicomponent elastomeric fibers
US6258159B1 (en) * 1999-08-30 2001-07-10 Polymer Group, Inc. Product and method for incorporating synthetic polymer fibers into cement mixtures
US6444312B1 (en) * 1999-12-08 2002-09-03 Fiber Innovation Technology, Inc. Splittable multicomponent fibers containing a polyacrylonitrile polymer component
WO2001051730A1 (en) * 2000-01-13 2001-07-19 Dow Global Technologies Inc. Reinforcing bars for concrete structures
NL1016864C2 (en) * 2000-12-13 2002-06-14 Bekaert Sa Nv Reinforcing fiber bundle and method for manufacturing such a reinforcing fiber bundle.
US6803332B2 (en) * 2001-04-10 2004-10-12 World Fibers, Inc. Composite yarn, intermediate fabric product and method of producing a metallic fabric
US6569525B2 (en) * 2001-04-25 2003-05-27 W. R. Grace & Co.-Conn. Highly dispersible reinforcing polymeric fibers
US6743506B2 (en) * 2001-05-10 2004-06-01 The Procter & Gamble Company High elongation splittable multicomponent fibers comprising starch and polymers
US20030077444A1 (en) * 2001-05-10 2003-04-24 The Procter & Gamble Company Multicomponent fibers comprising starch and polymers
US7192643B2 (en) * 2001-08-22 2007-03-20 3M Innovative Properties Company Toughened cementitious composites
DE10202039A1 (en) * 2002-01-18 2003-07-24 Basf Ag Mixtures of hydrogel-forming polymers and building materials
CA2514056A1 (en) * 2003-01-24 2004-08-12 Polymer Group, Inc. Unitized fibrous concrete reinforcement
EP1638900A2 (en) * 2003-05-30 2006-03-29 Polymer Group Inc. Unitized filamantary concrete reinforcement having circumferential binding element
US7219478B2 (en) * 2003-06-02 2007-05-22 Polymer Group, Inc. Concrete reinforcement structure
US7173086B2 (en) * 2003-10-31 2007-02-06 Stockhausen, Inc. Superabsorbent polymer with high permeability

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4433536A (en) * 1981-09-23 1984-02-28 Exxon Research & Engineering Co. Spiral wrapped synthetic twine and method of manufacturing same
US5091255A (en) * 1990-01-23 1992-02-25 American Cyanamid Company Molding granules, their manufacture and their use in the production of molded articles
US5227227A (en) * 1990-03-05 1993-07-13 Johnson & Johnson Inc. Non-woven fabric with a thermally activated adhesive surface, resulting product and applications thereof
US5807458A (en) * 1993-05-03 1998-09-15 Minnesota Mining & Manufacturing Company Reinforcing elements for castable compositions
US5985449A (en) * 1997-10-08 1999-11-16 Specialty Filaments Crimped thermoplastic fibers for reinforcing concrete
US7147904B1 (en) * 2003-08-05 2006-12-12 Evelyn Florence, Llc Expandable tubular fabric

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2374860A1 (en) * 2010-04-12 2011-10-12 Services Pétroliers Schlumberger Methods for treating fibers
WO2011128172A1 (en) * 2010-04-12 2011-10-20 Services Petroliers Schlumberger Methods for treating fibers
US8778851B2 (en) 2010-04-12 2014-07-15 Schlumberger Technology Corporation Methods for treating fibers
WO2021213652A1 (en) * 2020-04-22 2021-10-28 Wacker Chemie Ag Mixtures containing superabsorbers

Also Published As

Publication number Publication date
US20060070341A1 (en) 2006-04-06
EP1789641A2 (en) 2007-05-30
WO2006023698A3 (en) 2007-06-14

Similar Documents

Publication Publication Date Title
US7597952B2 (en) Unitized fibrous concrete reinforcement
US20060070341A1 (en) Unitized fibrous constructs having functional circumferential retaining elements
US5897928A (en) Reinforcing elements for castable composition
CA2416014C (en) Three-dimensional twisted fibers and processes for making same
CA2668683C (en) Premixing and dry fibration process
US7452418B2 (en) Unitized filamentary concrete reinforcement having circumferential binding element
US20020005263A1 (en) Uniformly dispersing fibers
KR100668619B1 (en) Textile reinforced material and method of manufacturing the same
US20110117303A1 (en) Reinforcement Composition and Method Thereof
US20050013981A1 (en) Unitized structural reinforcement construct
WO2007059467A2 (en) Composite reinforcement fiber having improved flexural properties, and castable products including same, and methods
CN112250370B (en) Lightweight concrete and production process thereof
KR101384592B1 (en) Pellet type Fiber Reinforcement Material for Concrete
KR102496080B1 (en) Complex fiber reinforcement for concrete mortar
WO2019126847A1 (en) Fibre for reinforcing fibre cement, fibre production method and fibre cement article
JP2744944B2 (en) Manufacturing method of hardened cement
JPS5913662A (en) Concrete reinforcing fiber and moldings
WO2020137466A1 (en) Bundled yarn, hydraulic composition and molded body
JP2000203906A (en) Fiber for reinforcing cement and concrete
JP2018108915A (en) Hydraulic compact and production method thereof

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2005791516

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: DE

WWP Wipo information: published in national office

Ref document number: 2005791516

Country of ref document: EP