WO2006049651A3 - Method of forming adhesives mixtures and ballistic composites utilizing the same - Google Patents

Method of forming adhesives mixtures and ballistic composites utilizing the same Download PDF

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Publication number
WO2006049651A3
WO2006049651A3 PCT/US2005/019061 US2005019061W WO2006049651A3 WO 2006049651 A3 WO2006049651 A3 WO 2006049651A3 US 2005019061 W US2005019061 W US 2005019061W WO 2006049651 A3 WO2006049651 A3 WO 2006049651A3
Authority
WO
WIPO (PCT)
Prior art keywords
olefinic
melt index
melt
same
melting point
Prior art date
Application number
PCT/US2005/019061
Other languages
French (fr)
Other versions
WO2006049651A2 (en
Inventor
Addison W Closson Jr
Original Assignee
Addison Closson Adhesive Texti
Addison W Closson Jr
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Addison Closson Adhesive Texti, Addison W Closson Jr filed Critical Addison Closson Adhesive Texti
Priority to CA002568559A priority Critical patent/CA2568559A1/en
Priority to EP05848189A priority patent/EP1773580A2/en
Priority to JP2007515484A priority patent/JP2008504142A/en
Publication of WO2006049651A2 publication Critical patent/WO2006049651A2/en
Priority to IL179638A priority patent/IL179638A0/en
Publication of WO2006049651A3 publication Critical patent/WO2006049651A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0869—Acids or derivatives thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00—Armour; Armour plates
    • F41H5/02—Plate construction
    • F41H5/04—Plate construction composed of more than one layer
    • F41H5/0471—Layered armour containing fibre- or fabric-reinforced layers
    • F41H5/0478—Fibre- or fabric-reinforced layers in combination with plastics layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/42—Alternating layers, e.g. ABAB(C), AABBAABB(C)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B32B2262/0269—Aromatic polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/56—Damping, energy absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2571/00—Protective equipment
    • B32B2571/02—Protective equipment defensive, e.g. armour plates, anti-ballistic clothing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof

Abstract

The invention relates to adhesive compositions used in composite laminar structures to improve ballistic resistance, which limits the penetration of a bullet from a gun. The composite laminar structure (125) includes a plurality of ballistic substrate layers (105, 1 10, 115, 120), e.g., polyaramid or olefinic plies, and an impact absorbing adhesive resin or adhesive composition of the invention. An adhesive composition includes an impact absorbing adhesion resin having a melt index ranging from 1 to 100; an olefinic aery late or methacrylate copolymer having a melt index between about 0.5 and about 100 or of an olefinic vinyl acetate copolymer having a melt index between about 0.5 and 350; an acid rosin having an acid number ranging from about 20 to 200; a high melt oxidized wax being having a melting point between about 80 120 °C; and a low melt wax having a melting point between about 55 to 90 °C.
PCT/US2005/019061 2004-05-28 2005-05-31 Method of forming adhesives mixtures and ballistic composites utilizing the same WO2006049651A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA002568559A CA2568559A1 (en) 2004-05-28 2005-05-31 Method of forming adhesive mixtures and ballistic composites utilizing the same
EP05848189A EP1773580A2 (en) 2004-05-28 2005-05-31 Method of forming adhesives mixtures and ballistic composites utilizing the same
JP2007515484A JP2008504142A (en) 2004-05-28 2005-05-31 Method for producing adhesive mixture and impact composite material using the mixture
IL179638A IL179638A0 (en) 2004-05-28 2006-11-27 Method of forming adhesives mixtures and ballistic composites utilizing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US57509304P 2004-05-28 2004-05-28
US60/575,093 2004-05-28

Publications (2)

Publication Number Publication Date
WO2006049651A2 WO2006049651A2 (en) 2006-05-11
WO2006049651A3 true WO2006049651A3 (en) 2007-11-29

Family

ID=36319586

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/019061 WO2006049651A2 (en) 2004-05-28 2005-05-31 Method of forming adhesives mixtures and ballistic composites utilizing the same

Country Status (6)

Country Link
EP (1) EP1773580A2 (en)
JP (1) JP2008504142A (en)
AU (1) AU2005301309A1 (en)
CA (1) CA2568559A1 (en)
IL (1) IL179638A0 (en)
WO (1) WO2006049651A2 (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2901882B1 (en) * 2006-05-30 2008-08-29 Cie Europ De Dev Ind C E D I S METHOD FOR DESIGNING PROTECTIVE CLOTHING OR EQUIPMENT FOR THE MAINTENANCE OF THE ORDER, AND METHOD FOR APPROVAL OF SUCH CLOTHING OR EQUIPMENT
WO2008105929A2 (en) * 2006-09-08 2008-09-04 Closson Addison W Method of forming adhesive mixtures and ballistic composites utilizing the same
CA2669761A1 (en) * 2006-11-15 2008-11-20 Honeywell International Inc. Microwave processing of ballistic composites
CA2681549C (en) 2007-03-26 2016-09-20 Barrday Inc. Coated multi-threat materials and methods for fabricating the same
US7994075B1 (en) * 2008-02-26 2011-08-09 Honeywell International, Inc. Low weight and high durability soft body armor composite using topical wax coatings
BR112012005764A2 (en) 2009-09-14 2016-03-08 Mitsubishi Gas Chemical Co polyamide resin composition
JP5857742B2 (en) * 2009-09-14 2016-02-10 三菱瓦斯化学株式会社 Flame retardant polyamide resin composition
WO2011040915A1 (en) * 2009-09-30 2011-04-07 Techdyne, Llc Non-metallic armor article and method of manufacture
CA2799222A1 (en) * 2010-06-11 2011-12-15 E. I. Du Pont De Nemours And Company Enhanced flexible lightweight ballistic, stab and spike resistant materials
JP4936261B2 (en) 2010-08-31 2012-05-23 美濃窯業株式会社 BORON CARBIDE-CONTAINING CERAMIC BODY AND METHOD FOR PRODUCING THE BODY
MX347739B (en) 2011-01-18 2017-05-10 Barrday Inc Ballistic resistant article comprising a self-crosslinking acrylic resin and/or a crosslinkable acrylic resin and process to manufacture said article.
EP2665985B1 (en) * 2011-01-18 2015-03-18 Teijin Aramid B.V. Ballistic resistant article comprising a styrene butadiene resin and process to manufacture said article
CN103596904B (en) * 2012-02-28 2016-08-17 美浓窑业株式会社 Impact absorbing member and manufacture method thereof
JP5342685B1 (en) * 2012-09-11 2013-11-13 美濃窯業株式会社 Shock absorbing member and manufacturing method thereof
US10458756B2 (en) 2013-03-15 2019-10-29 Scott R. Whitaker Flexible adhesive ballistic shield
US10302401B2 (en) 2013-03-15 2019-05-28 Scott R. Whitaker Ballistic shield
US20160281272A1 (en) * 2015-03-26 2016-09-29 Honeywell International Inc. Ballistic resistant composite material
JP6763146B2 (en) * 2016-01-22 2020-09-30 東洋インキＳｃホールディングス株式会社 Heat-meltable composition, lid material and food container made of the same
CN108297454B (en) * 2017-04-25 2019-11-22 航天特种材料及工艺技术研究所 A kind of polymer matrix composites, preparation method and vacuum bag used
CN112592561A (en) * 2020-12-10 2021-04-02 四川辉腾科技股份有限公司 Resin for bulletproof ceramic/aramid III composite armor and preparation method thereof
CN112793249B (en) * 2020-12-22 2024-03-15 上海仪耐新材料科技有限公司 Bulletproof plugboard and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4434261A (en) * 1982-08-06 1984-02-28 E. I. Du Pont De Nemours And Company Extrudable self-supporting hot melt adhesive sheet
US5318853A (en) * 1992-07-22 1994-06-07 Resikast Corporation Adhesive polyester prepolymer which does not etch polycarbonate sheets, and method of preparing same
US6143818A (en) * 1999-08-04 2000-11-07 Ato Findley, Inc. Hot melt adhesive based on ethylene-propylene rubber (EPR) and semicrystalline olefinic polymers
US20010053645A1 (en) * 2000-01-18 2001-12-20 Henderson William J. Multi-layered ballistic resistant article
US20020193474A1 (en) * 2001-06-14 2002-12-19 Daily Jeffrey Daniel Hot melt adhesive composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4434261A (en) * 1982-08-06 1984-02-28 E. I. Du Pont De Nemours And Company Extrudable self-supporting hot melt adhesive sheet
US5318853A (en) * 1992-07-22 1994-06-07 Resikast Corporation Adhesive polyester prepolymer which does not etch polycarbonate sheets, and method of preparing same
US6143818A (en) * 1999-08-04 2000-11-07 Ato Findley, Inc. Hot melt adhesive based on ethylene-propylene rubber (EPR) and semicrystalline olefinic polymers
US20010053645A1 (en) * 2000-01-18 2001-12-20 Henderson William J. Multi-layered ballistic resistant article
US20020193474A1 (en) * 2001-06-14 2002-12-19 Daily Jeffrey Daniel Hot melt adhesive composition

Also Published As

Publication number Publication date
CA2568559A1 (en) 2005-11-06
EP1773580A2 (en) 2007-04-18
AU2005301309A1 (en) 2006-05-11
JP2008504142A (en) 2008-02-14
WO2006049651A2 (en) 2006-05-11
IL179638A0 (en) 2007-05-15

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