WO2006065844A3 - Process for producing substituted metallocene compounds for olefin polymerization - Google Patents
Process for producing substituted metallocene compounds for olefin polymerization Download PDFInfo
- Publication number
- WO2006065844A3 WO2006065844A3 PCT/US2005/045140 US2005045140W WO2006065844A3 WO 2006065844 A3 WO2006065844 A3 WO 2006065844A3 US 2005045140 W US2005045140 W US 2005045140W WO 2006065844 A3 WO2006065844 A3 WO 2006065844A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- substituted
- metal atom
- olefin polymerization
- metallocene compounds
- compound
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT05853949T ATE458742T1 (en) | 2004-12-16 | 2005-12-14 | METHOD FOR PRODUCING SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION |
EP05853949A EP1866322B1 (en) | 2004-12-16 | 2005-12-14 | Process for producing substituted metallocene compounds for olefin polymerization |
DE602005019629T DE602005019629D1 (en) | 2004-12-16 | 2005-12-14 | METHOD FOR PRODUCING SUBSTITUTED METALOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63666204P | 2004-12-16 | 2004-12-16 | |
US60/636,662 | 2004-12-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2006065844A2 WO2006065844A2 (en) | 2006-06-22 |
WO2006065844A3 true WO2006065844A3 (en) | 2007-05-18 |
Family
ID=34982508
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/045140 WO2006065844A2 (en) | 2004-12-16 | 2005-12-14 | Process for producing substituted metallocene compounds for olefin polymerization |
PCT/US2005/045138 WO2006065843A2 (en) | 2004-12-16 | 2005-12-14 | Halogen substituted metallocene compounds for olefin polymerization |
PCT/US2005/045245 WO2006065906A2 (en) | 2004-12-16 | 2005-12-14 | Halogen substituted metallocene compounds for olefin polymerization |
PCT/US2005/045056 WO2006065809A2 (en) | 2004-12-16 | 2005-12-14 | Heteroatom bridged metallocene compounds for olefin polymerization |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/045138 WO2006065843A2 (en) | 2004-12-16 | 2005-12-14 | Halogen substituted metallocene compounds for olefin polymerization |
PCT/US2005/045245 WO2006065906A2 (en) | 2004-12-16 | 2005-12-14 | Halogen substituted metallocene compounds for olefin polymerization |
PCT/US2005/045056 WO2006065809A2 (en) | 2004-12-16 | 2005-12-14 | Heteroatom bridged metallocene compounds for olefin polymerization |
Country Status (5)
Country | Link |
---|---|
US (4) | US7709670B2 (en) |
EP (3) | EP1866322B1 (en) |
AT (1) | ATE458742T1 (en) |
DE (1) | DE602005019629D1 (en) |
WO (4) | WO2006065844A2 (en) |
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US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
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US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US8178636B2 (en) | 2004-05-04 | 2012-05-15 | Basell Polyolefine Gmbh | Process for the preparation of atactic 1-butene polymers |
WO2006065844A2 (en) * | 2004-12-16 | 2006-06-22 | Exxonmobil Chemical Patents Inc. | Process for producing substituted metallocene compounds for olefin polymerization |
EP1858934B1 (en) * | 2005-03-18 | 2013-04-24 | Basell Polyolefine GmbH | Metallocene compounds |
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DE102005055866A1 (en) * | 2005-11-23 | 2007-05-24 | Hte Ag The High Throughput Experimentation Company | Continuous reaction of two liquid, mutually immiscible phases especially in Suzuki (hetero)aryl-(hetero)aryl coupling reactions involves flowing components through packed bed reactor |
US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
US20080287619A1 (en) * | 2007-05-18 | 2008-11-20 | William Gauthier | Supported metallocene catalysts |
EP2215129A2 (en) | 2007-08-27 | 2010-08-11 | Borealis Technology OY | Catalysts |
WO2009054831A1 (en) * | 2007-10-25 | 2009-04-30 | Novolen Technology Holdings, C.V. | Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
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US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
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US8058461B2 (en) | 2010-03-01 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Mono-indenyl transition metal compounds and polymerization therewith |
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EP1866322A2 (en) | 2007-12-19 |
DE602005019629D1 (en) | 2010-04-08 |
US20060160968A1 (en) | 2006-07-20 |
US7709670B2 (en) | 2010-05-04 |
EP1833859A2 (en) | 2007-09-19 |
WO2006065906A3 (en) | 2007-02-22 |
EP1833858A2 (en) | 2007-09-19 |
WO2006065809A3 (en) | 2006-09-28 |
WO2006065809A2 (en) | 2006-06-22 |
WO2006065843A3 (en) | 2006-12-07 |
ATE458742T1 (en) | 2010-03-15 |
US20060160967A1 (en) | 2006-07-20 |
US9163046B2 (en) | 2015-10-20 |
WO2006065844A2 (en) | 2006-06-22 |
WO2006065906A2 (en) | 2006-06-22 |
US20060183874A1 (en) | 2006-08-17 |
US20100113717A1 (en) | 2010-05-06 |
EP1866322B1 (en) | 2010-02-24 |
US7557171B2 (en) | 2009-07-07 |
WO2006065843A2 (en) | 2006-06-22 |
US7446216B2 (en) | 2008-11-04 |
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