WO2006098878A1 - Sustained-release fragrance delivery system - Google Patents
Sustained-release fragrance delivery system Download PDFInfo
- Publication number
- WO2006098878A1 WO2006098878A1 PCT/US2006/007258 US2006007258W WO2006098878A1 WO 2006098878 A1 WO2006098878 A1 WO 2006098878A1 US 2006007258 W US2006007258 W US 2006007258W WO 2006098878 A1 WO2006098878 A1 WO 2006098878A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- fragrance
- particles
- carrier particles
- carrier
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
Definitions
- This invention pertains to sustained-released fragrance delivery systems, methods of producing sustained-released fragrance delivery systems, and associated products.
- compositions for sustained released fragrance delivery are known in the art.
- Conventional sustained release fragrance delivery systems typically utilize particles containing a pre-encapsulated fragrance to provide for sustained-released delivery of the fragrance.
- Conventional pre-encapsulated fragrance particles are produced by combining carrier particles (typically starch) and a fragrance in an aqueous medium and spray-drying the mixture at high temperatures (e.g., from about 132 °C to about 204 0 C).
- carrier particles typically starch
- fragrance typically starch
- fragrance typically starch
- fragrance typically a fragrance in an aqueous medium and spray-drying the mixture at high temperatures (e.g., from about 132 °C to about 204 0 C).
- the conventional spray drying technique is believed to be necessary for incorporating the fragrance into the carrier material sufficiently to promote gradual release of the fragrance over time.
- the resulting spray-dried product is then combined with a propellant and other ingredients, and stored in a pressurized container with a release valve (e.g., a spray nozzle) allowing the end user to deliver the composition as an aerosol.
- a release valve e.g., a spray nozzle
- the spray-drying process is not only expensive, but also requires the use of water and high temperatures.
- the aqueous spray drying process may degrade or reduce the effectiveness of fragrance compositions that are sensitive to such conditions, e.g., fragrances with one or more components that are volatile, thermally sensitive, or unstable in a hot aqueous environment. Fragrances derived from natural sources, e.g., plant extracts, are especially vulnerable.
- the conventional pre-encapsulation process can degrade or eliminate one or more desirable fragrance "notes" that otherwise would have been present in the underlying fragrance.
- the present invention provides a method of producing a personal care product, which includes combining a fragrance, a propellant and porous carrier particles, to produce a composition, which is substantially free of pre-encapsulated fragrance particles, and containing the composition within a pressurized container.
- the present invention also provides a personal care product comprising a pressurized container and a composition contained therein, wherein the composition includes a fragrance, a propellant and a carrier, which is substantially free of pre-encapsulated fragrance particles.
- the invention further provides a method of producing a fragrance delivery system comprising expelling from a pressurized container a composition comprising a fragrance, a propellant and a carrier, wherein the composition is substantially free of pre- encapsulated fragrance particles.
- the carrier used in accordance with the present invention consists essentially of porous carrier particles, at least about 95% of which have diameters of less than about 70 ⁇ m.
- Figure 1 depicts particle size distribution data for an exemplary carrier used in accordance with the present invention.
- the present invention provides a method of producing a personal care product, which includes combining a fragrance, a propellant and carrier particles to produce a composition, which is substantially free of pre-encapsulated fragrance particles.
- the composition is contained within a pressurized container, which preferably provides for delivery of the composition, e.g., as an aerosol.
- the present invention further provides a method of producing a fragrance delivery system, which includes expelling from a pressurized container a composition that includes a fragrance, a propellant, and carrier particles, wherein the composition is substantially free of pre-encapsulated fragrance particles.
- the propellant evaporates rapidly (e.g., within a few seconds or less at atmospheric pressure) to produce a matrix, which incorporates the fragrance into the pores of the carrier particles, to produce a sustained-release delivery system, which releases the fragrance gradually over time.
- the present invention additionally provides a personal care product comprising a pressurized container and a composition contained therein, which includes a fragrance, a propellant and carrier particles, wherein the composition is substantially free pre- encapsulated fragrance particles.
- a personal care product comprising a pressurized container and a composition contained therein, which includes a fragrance, a propellant and carrier particles, wherein the composition is substantially free pre- encapsulated fragrance particles.
- the sustained release delivery system of the present invention exhibits improvements in product performance and quality over the conventional products, which use pre-encapsulated particles.
- the present invention provides for consistent and reliable delivery of a sustained release fragrance delivery system as an aerosol, using conventional pressurized aerosol containers, without clogging associated with conventional pre-encapsulated products.
- the sustained release delivery system of the present invention has improved tactile properties, e.g., noticeably improved smoothness in texture, relative to conventional products, which use pre-encapsulated particles.
- the carrier used in the composition of the present invention preferably consists essentially of porous carrier particles, at least about 95% of which have diameters of less than about 70 ⁇ m.
- At least about 95% (e.g., 95% or greater, 96% or greater, 97% or greater, 98% or greater, or 99% or greater) of the porous carrier particles have diameters of less than about 70 ⁇ m (microns) (e.g., 70 ⁇ m or less, 68 ⁇ m or less, 65 ⁇ m or less, 63 ⁇ m or less, 60 ⁇ m or less, 58 ⁇ m or less or 55 ⁇ m or less). More preferably, at least about 97% of the porous carrier particles have diameters of less than about 70 ⁇ m. Still more preferably, at least about 99% (e.g., at least about 99.9%) of the porous carrier particles have diameters of less than about 70 ⁇ m.
- At least about 80% (e.g., 80% or greater, 85% or greater, 87% or greater, 90% or greater, 93 % or greater, 95% or greater, 97% or greater, or 99% or greater) of the porous carrier particles have diameters within about 10 ⁇ m of the median diameter of the particles (i.e., from about 10 ⁇ m greater than to about 10 ⁇ m less than the median diameter).
- the median diameter of the porous carrier particles is preferably from about 5 ⁇ m to about 60 ⁇ m.
- the median diameter of the porous carrier particles can range, e.g., from 5 ⁇ m to 60 ⁇ m, from about 5 ⁇ m to about 55 ⁇ m, from about 5 ⁇ m to about 50 ⁇ m, from about 5 ⁇ m to about 45 ⁇ m, from about 5 ⁇ m to about 40 ⁇ m, from about 5 ⁇ m to about 35 ⁇ m, from about 5 ⁇ m to about 30 ⁇ m, from about 5 ⁇ m to about 25 ⁇ m, or from about 5 ⁇ m to about 20 microns.
- the median diameter of the porous carrier particles also can range, e.g., from about 10 ⁇ m to about 50 ⁇ m, from about 10 ⁇ m to about 45 ⁇ m, from about 10 ⁇ m to about 40 ⁇ m, from about 10 ⁇ m to about 35 ⁇ m, from about 10 ⁇ m to about 30 ⁇ m, from about 10 ⁇ m to about 25 ⁇ m, or from about 10 ⁇ m to about 20 ⁇ m.
- the median diameter of the porous carrier particles also can range, e.g., from about 15 ⁇ m to about 50 ⁇ m, from about 15 ⁇ m to about 45 ⁇ m, from about 15 ⁇ m to about 40 ⁇ m, from about 15 ⁇ m to about 35 ⁇ m, from about 15 ⁇ m to about 30 ⁇ m, from about 15 ⁇ m to about 25 ⁇ m, from about 15 ⁇ m to about 20 microns, from about 20 ⁇ m to about 50 ⁇ m, from about 20 ⁇ m to about 45 ⁇ m, from about 20 ⁇ m to about 40 ⁇ m, from about 20 ⁇ m to about 35 ⁇ m, from about 20 ⁇ m to about 30 ⁇ m, or from about 20 ⁇ m to about 25 ⁇ m.
- pre-encapsulated refers to fragrance delivery systems, which utilize conventional fragrance-encapsulated particles produced by the aqueous spray drying process described above. As indicated above, the product of the present invention is substantially free of such pre-encapsulated fragrance particles.
- conventional aqueous spray drying processes may cause porous carrier particles to undergo structural changes, particularly on the exterior and, possibly, interstitial surfaces thereof, causing the particles to "ripen” and/or agglomerate.
- Suitable fragrances can include, e.g., synthetic fragrances, natural fragrances, and combinations thereof.
- Suitable fragrances can include, e.g., oils, plant extracts, and the like, and mixtures thereof.
- the fragrances can be soluble or insoluble in the propellant and can include a single fragrance compound or a blend of one or more fragrance compounds in accordance with the invention.
- the personal care product of the invention can comprise any suitable amount of fragrance.
- the fragrance can be present in the personal care product in an amount of, e.g., from about 0.01% by weight to about 10% by weight , from about 0.01% by weight to about 5% by weight, from about 0.1% by weight to about 3% by weight, from about 0.1% by weight to about 2.5% by weight, or from about 0.1% by weight to about 1% by weight (e.g., about 0.5 wt%).
- Any suitable propellant can be used in accordance with the present invention.
- Suitable propellants can include one or more liquefied compressed gases.
- Such propellants can include, for example, hydrocarbon propellants (e.g., isobutane or propane), fluorocarbon propellants (e.g., hydro fluorocarbon 152a), fluorochlorocarbon propellants, hydrochlorocarbon propellants, ether propellants (e.g., dimethyl ether), and the like, and mixtures thereof.
- the personal care product of the invention can comprise any suitable amount of propellant.
- the propellant can be present in the personal care product in an amount of, e.g., from about 80% by weight to about 98% by weight, from about 80% by weight to about 95% by weight, from about 80% by weight to about 90% by weight, from about 85% by weight to about 90% by weight, from about 85% by weight to about 95% by weight, or from about 90% by weight to about 95% by weight.
- the porous carrier particles can be manufactured from any suitable material, which is preferably capable of promoting binding of fragrance molecules to the surfaces and/or interstices of the carrier particles sufficiently to provide sustained release delivery.
- the porous carrier particles can include, for example, one or more polymers (e.g., natural polymers; synthetic polymers, such as, e.g., polymethacrylate, nylon, styrene, polystyrene, and the like, and mixtures thereof), one or more dextrins (e.g., cyclodextrin), and/or one or more inorganic materials (e.g., sodium bicarbonate, silica, fumed silica, colloidal silica, magnesium aluminum silicate, aluminum silicate, magnesium silicate, clay, and the like, and mixtures thereof).
- polymers e.g., natural polymers; synthetic polymers, such as, e.g., polymethacrylate, nylon, styrene, polystyrene, and the like, and
- the polymer includes one or more a polysaccharides, e.g., one or more polysaccharides selected from the group consisting of starches, celluloses, and the like, and combinations thereof.
- Suitable starches can include, e.g., corn starch, modified corn starch, tapioca starch, modified tapioca starch, potato starch, modified potato starch, wheat starch, modified wheat starch, and the like, and mixtures thereof.
- Suitable celluloses can include, for example, celluloses and derivatives thereof, e.g., ethyl cellulose, methyl cellulose, propylmethyl cellulose, hydroxyethyl cellulose, hydroxymethyl cellulose, hydroxypropylmethyl cellulose, and the like, and mixtures thereof.
- the porous carrier particles are made from corn starch, tapioca starch or a combination thereof.
- the personal care product of the invention can include any suitable amount of porous carrier particles.
- the porous carrier particles can be present in the personal care product of the invention in an amount of, e.g., from about 1% by weight to about 20% by weight, from about 1% by weight to about 15% by weight, from about 1% by weight to about 10% by weight, from about 1% by weight to about 8% by weight, from about 1% by weight to about 5% by weight, or from about 2% by weight to about 5% by weight (e.g., about 3 wt%).
- the pressurized container preferably includes at least one valve capable of expelling (e.g., for controllable release or delivery by an end user) at least a portion of the composition from the container.
- the valve opening can have any suitable diameter, and preferably is capable of expelling at least a portion of the composition from the pressurized container as an aerosol.
- the pressurized container includes a valve, wherein the diameter of the opening of the valve is about 210 ⁇ m.
- the particle size distribution data of the corn starch is provided in Fig. 1. Mixing and recirculating is performed for a minimum of 5 minutes.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2006223570A AU2006223570B2 (en) | 2005-03-09 | 2006-03-01 | Sustained-release fragrance delivery system |
MX2007011008A MX2007011008A (en) | 2005-03-09 | 2006-03-01 | Sustained-release fragrance delivery system. |
GB0717439A GB2438144B (en) | 2005-03-09 | 2006-03-01 | Sustained-release fragrance delivery system |
CA2600405A CA2600405C (en) | 2005-03-09 | 2006-03-01 | In situ formed aerosol sustained release fragrance system |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/076,348 US7638477B2 (en) | 2005-03-09 | 2005-03-09 | Sustained-release fragrance delivery system |
US11/076,348 | 2005-03-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006098878A1 true WO2006098878A1 (en) | 2006-09-21 |
Family
ID=36579236
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2006/007258 WO2006098878A1 (en) | 2005-03-09 | 2006-03-01 | Sustained-release fragrance delivery system |
Country Status (6)
Country | Link |
---|---|
US (1) | US7638477B2 (en) |
AU (1) | AU2006223570B2 (en) |
CA (1) | CA2600405C (en) |
GB (1) | GB2438144B (en) |
MX (1) | MX2007011008A (en) |
WO (1) | WO2006098878A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004091577A1 (en) * | 2003-04-17 | 2004-10-28 | Porten Pharmaceutical Ab | Composition, method and pharmaceutical preparation for pharmaceutical spray suspensions |
WO2019129466A1 (en) | 2017-12-29 | 2019-07-04 | Unilever N.V. | Non-spherical microcapsule |
MX2020006686A (en) | 2017-12-29 | 2021-09-14 | Unilever Ip Holdings B V | Non-spherical microcapsule. |
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- 2006-03-01 GB GB0717439A patent/GB2438144B/en not_active Expired - Fee Related
- 2006-03-01 MX MX2007011008A patent/MX2007011008A/en active IP Right Grant
- 2006-03-01 WO PCT/US2006/007258 patent/WO2006098878A1/en active Application Filing
- 2006-03-01 CA CA2600405A patent/CA2600405C/en not_active Expired - Fee Related
- 2006-03-01 AU AU2006223570A patent/AU2006223570B2/en not_active Ceased
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Also Published As
Publication number | Publication date |
---|---|
CA2600405A1 (en) | 2006-09-21 |
US7638477B2 (en) | 2009-12-29 |
GB2438144B (en) | 2009-07-15 |
AU2006223570B2 (en) | 2010-12-16 |
CA2600405C (en) | 2016-07-19 |
GB0717439D0 (en) | 2007-10-17 |
AU2006223570A1 (en) | 2006-09-21 |
GB2438144A (en) | 2007-11-14 |
MX2007011008A (en) | 2008-03-18 |
US20060205616A1 (en) | 2006-09-14 |
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