WO2007014126A3 - Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell - Google Patents

Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell Download PDF

Info

Publication number
WO2007014126A3
WO2007014126A3 PCT/US2006/028612 US2006028612W WO2007014126A3 WO 2007014126 A3 WO2007014126 A3 WO 2007014126A3 US 2006028612 W US2006028612 W US 2006028612W WO 2007014126 A3 WO2007014126 A3 WO 2007014126A3
Authority
WO
WIPO (PCT)
Prior art keywords
fuel cell
partial pressure
hydrogen
swing adsorption
pressure swing
Prior art date
Application number
PCT/US2006/028612
Other languages
French (fr)
Other versions
WO2007014126A2 (en
Inventor
James Mcelroy
John Finn
M Douglas Levan
Swaminathan Venkataraman
Fred Mitlitsky
Original Assignee
Bloom Energy Corp
James Mcelroy
John Finn
M Douglas Levan
Swaminathan Venkataraman
Fred Mitlitsky
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bloom Energy Corp, James Mcelroy, John Finn, M Douglas Levan, Swaminathan Venkataraman, Fred Mitlitsky filed Critical Bloom Energy Corp
Priority to JP2008524021A priority Critical patent/JP5113748B2/en
Priority to EP06788269A priority patent/EP1912722A4/en
Publication of WO2007014126A2 publication Critical patent/WO2007014126A2/en
Publication of WO2007014126A3 publication Critical patent/WO2007014126A3/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • B01D53/053Pressure swing adsorption with storage or buffer vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • B01D53/261Drying gases or vapours by adsorption
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04156Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying with product water removal
    • H01M8/04171Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying with product water removal using adsorbents, wicks or hydrophilic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0444Concentration; Density
    • H01M8/04447Concentration; Density of anode reactants at the inlet or inside the fuel cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04746Pressure; Flow
    • H01M8/04753Pressure; Flow of fuel cell reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668Removal of carbon monoxide or carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/16Hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/108Hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/80Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0208Other waste gases from fuel cells
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/402Further details for adsorption processes and devices using two beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/45Gas separation or purification devices adapted for specific applications
    • B01D2259/4566Gas separation or purification devices adapted for specific applications for use in transportation means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
    • C01B2203/067Integration with other chemical processes with fuel cells the reforming process taking place in the fuel cell
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0822Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/148Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry

Abstract

A method of operating a fuel cell system includes providing a fuel inlet stream into a fuel cell stack, operating the fuel cell stack to generate electricity and a hydrogen containing fuel exhaust stream, separating at least a portion of hydrogen contained in the fuel exhaust stream using partial pressure swing adsorption, and providing the hydrogen separated from the fuel exhaust stream to a hydrogen storage vessel or to a hydrogen using device.
PCT/US2006/028612 2005-07-25 2006-07-24 Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell WO2007014126A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2008524021A JP5113748B2 (en) 2005-07-25 2006-07-24 Partial pressure swing adsorption system for supplying hydrogen to vehicle fuel cells
EP06788269A EP1912722A4 (en) 2005-07-25 2006-07-24 Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/188,123 2005-07-25
US11/188,123 US7520916B2 (en) 2005-07-25 2005-07-25 Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell

Publications (2)

Publication Number Publication Date
WO2007014126A2 WO2007014126A2 (en) 2007-02-01
WO2007014126A3 true WO2007014126A3 (en) 2007-10-25

Family

ID=37677869

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/028612 WO2007014126A2 (en) 2005-07-25 2006-07-24 Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell

Country Status (4)

Country Link
US (1) US7520916B2 (en)
EP (1) EP1912722A4 (en)
JP (1) JP5113748B2 (en)
WO (1) WO2007014126A2 (en)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007014128A2 (en) * 2005-07-25 2007-02-01 Ion America Corporation Fuel cell system with electrochemical anode exhaust recycling
US9911989B2 (en) * 2005-07-25 2018-03-06 Bloom Energy Corporation Fuel cell system with partial recycling of anode exhaust
DE102005041747B4 (en) * 2005-09-02 2020-03-12 Bayerische Motoren Werke Aktiengesellschaft Process for reducing emissions by gaseous decomposition products of an electrolyte in motor vehicles and device for carrying out the process
US7883803B2 (en) * 2007-03-30 2011-02-08 Bloom Energy Corporation SOFC system producing reduced atmospheric carbon dioxide using a molten carbonated carbon dioxide pump
US7833668B2 (en) * 2007-03-30 2010-11-16 Bloom Energy Corporation Fuel cell system with greater than 95% fuel utilization
WO2008150524A2 (en) 2007-06-04 2008-12-11 Bloom Energy Corporation Structure for high temperature fuel cell system start up and shutdown
DE102007026652A1 (en) * 2007-06-08 2008-12-11 Forschungszentrum Jülich GmbH High-temperature polymer electrolyte fuel cell system and method for operating the same
WO2009059571A1 (en) * 2007-11-10 2009-05-14 Horst-Eckart Vollmar High-temperature fuel cell system having sectional circuit of the anode waste gas and outward transfer of gas components
JP2011517261A (en) * 2008-02-19 2011-05-26 ブルーム エナジー コーポレーション Fuel cell system for charging electric vehicles
US9287571B2 (en) * 2008-07-23 2016-03-15 Bloom Energy Corporation Operation of fuel cell systems with reduced carbon formation and anode leading edge damage
CN102470750B (en) * 2009-07-21 2015-11-25 丰田自动车株式会社 Fuel system and vehicle
US20110017153A1 (en) 2009-07-22 2011-01-27 Green On Demand, LLP (G.O.D.) System for on demand hydrogen production and delivery of hydrogen to an internal combustion engine
TWI553952B (en) 2009-09-02 2016-10-11 博隆能源股份有限公司 Multi-stream heat exchanger for a fuel cell system
US9856769B2 (en) * 2010-09-13 2018-01-02 Membrane Technology And Research, Inc. Gas separation process using membranes with permeate sweep to remove CO2 from combustion exhaust
JP6258037B2 (en) 2011-01-06 2018-01-10 ブルーム エナジー コーポレーション Components of SOFC hot box
US8945368B2 (en) 2012-01-23 2015-02-03 Battelle Memorial Institute Separation and/or sequestration apparatus and methods
SG11201506730WA (en) 2013-03-15 2015-09-29 Exxonmobil Res & Eng Co Integrated power generation using molten carbonate fuel cells
US9077008B2 (en) 2013-03-15 2015-07-07 Exxonmobil Research And Engineering Company Integrated power generation and chemical production using fuel cells
US20140272614A1 (en) 2013-03-15 2014-09-18 Exxonmobil Research And Engineering Company Integrated power generation and carbon capture using fuel cells
US9556753B2 (en) 2013-09-30 2017-01-31 Exxonmobil Research And Engineering Company Power generation and CO2 capture with turbines in series
US9755258B2 (en) 2013-09-30 2017-09-05 Exxonmobil Research And Engineering Company Integrated power generation and chemical production using solid oxide fuel cells
WO2015061274A1 (en) 2013-10-23 2015-04-30 Bloom Energy Corporation Pre-reformer for selective reformation of higher hydrocarbons
JP6405538B2 (en) * 2013-11-20 2018-10-17 パナソニックIpマネジメント株式会社 Fuel cell system
US9461320B2 (en) 2014-02-12 2016-10-04 Bloom Energy Corporation Structure and method for fuel cell system where multiple fuel cells and power electronics feed loads in parallel allowing for integrated electrochemical impedance spectroscopy (EIS)
US10320017B2 (en) * 2015-10-06 2019-06-11 Bloom Energy Corporation Sorbent bed assembly and fuel cell system including same
US11211625B2 (en) * 2016-04-21 2021-12-28 Fuelcell Energy, Inc. Molten carbonate fuel cell anode exhaust post-processing for carbon dioxide
CA3022534C (en) 2016-04-29 2021-01-26 Fuelcell Energy, Inc. Methanation of anode exhaust gas to enhance carbon dioxide capture.
US11398634B2 (en) 2018-03-27 2022-07-26 Bloom Energy Corporation Solid oxide fuel cell system and method of operating the same using peak shaving gas
JP7258144B2 (en) 2018-11-30 2023-04-14 フュエルセル エナジー, インコーポレイテッド Reforming catalyst pattern for fuel cells operating with enhanced CO2 utilization
WO2020112770A1 (en) 2018-11-30 2020-06-04 Exxonmobil Research And Engineering Company Regeneration of molten carbonate fuel cells for deep co 2 capture
WO2020112806A1 (en) 2018-11-30 2020-06-04 Exxonmobil Research And Engineering Company Layered cathode for molten carbonate fuel cell
WO2020112834A1 (en) 2018-11-30 2020-06-04 Exxonmobil Research And Engineering Company Fuel cell staging for molten carbonate fuel cells
US11888187B2 (en) 2018-11-30 2024-01-30 ExxonMobil Technology and Engineering Company Operation of molten carbonate fuel cells with enhanced CO2 utilization
KR20210094074A (en) 2018-11-30 2021-07-28 퓨얼 셀 에너지, 인크 Increased pressure operation of molten carbonate fuel cells with improved CO2 utilization
US11616249B2 (en) 2019-03-22 2023-03-28 Bloom Energy Corporation Solid oxide fuel cell system with hydrogen pumping cell with carbon monoxide tolerant anodes and integrated shift reactor
US11322767B2 (en) 2019-04-12 2022-05-03 Bloom Energy Corporation Solid oxide fuel cell system with hydrogen pumping cell with carbon monoxide tolerant anodes and integrated shift reactor
EP4000118A1 (en) 2019-07-19 2022-05-25 Bloom Energy Corporation Integrated power generation, carbon dioxide separation and downstream processing system and method
JP7370792B2 (en) * 2019-09-30 2023-10-30 東京瓦斯株式会社 Fuel cell system and method of operating the fuel cell system
EP4066301A1 (en) 2019-11-26 2022-10-05 ExxonMobil Technology and Engineering Company Operation of molten carbonate fuel cells with high electrolyte fill level
KR20220113681A (en) 2019-11-26 2022-08-16 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 Fuel cell module assembly and system using same
JP7298541B2 (en) * 2020-05-19 2023-06-27 トヨタ自動車株式会社 fuel cell system
WO2022167985A1 (en) * 2021-02-04 2022-08-11 Indian Institute Of Science A system for separating hydrogen from a feed gas
US11577191B1 (en) 2021-09-09 2023-02-14 ColdStream Energy IP, LLC Portable pressure swing adsorption method and system for fuel gas conditioning
WO2024013029A2 (en) * 2022-07-12 2024-01-18 Topsoe A/S Soe plant and process for performing solid oxide electrolysis

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040005492A1 (en) * 2002-03-14 2004-01-08 Questair Technologies, Inc. Hydrogen recycle for solid oxide fuel cell
US20040197612A1 (en) * 2003-02-26 2004-10-07 Questair Technologies Inc. Hydrogen recycle for high temperature fuel cells

Family Cites Families (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3488266A (en) 1967-12-12 1970-01-06 Continental Oil Co Electrochemical reduction of benzene using a carbon anode
US4041210A (en) 1976-08-30 1977-08-09 United Technologies Corporation Pressurized high temperature fuel cell power plant with bottoming cycle
US4182795A (en) 1978-07-10 1980-01-08 Energy Research Corporation Fuel cell thermal control and reforming of process gas hydrocarbons
US4532192A (en) 1984-11-06 1985-07-30 Energy Research Corporation Fuel cell system
US4792502A (en) 1986-11-14 1988-12-20 International Fuel Cells Corporation Apparatus for producing nitrogen
US4898792A (en) 1988-12-07 1990-02-06 Westinghouse Electric Corp. Electrochemical generator apparatus containing modified high temperature insulation and coated surfaces for use with hydrocarbon fuels
US4917971A (en) 1989-03-03 1990-04-17 Energy Research Corporation Internal reforming fuel cell system requiring no recirculated cooling and providing a high fuel process gas utilization
US5302470A (en) 1989-05-16 1994-04-12 Osaka Gas Co., Ltd. Fuel cell power generation system
US4983471A (en) 1989-12-28 1991-01-08 Westinghouse Electric Corp. Electrochemical cell apparatus having axially distributed entry of a fuel-spent fuel mixture transverse to the cell lengths
US5034287A (en) 1990-04-23 1991-07-23 International Fuel Cells Corporation Fuel cell cooling using heat of reaction
CA2018639A1 (en) 1990-06-08 1991-12-08 James D. Blair Method and apparatus for comparing fuel cell voltage
US5169730A (en) 1990-07-25 1992-12-08 Westinghouse Electric Corp. Electrochemical cell apparatus having an exterior fuel mixer nozzle
US5047299A (en) 1990-07-25 1991-09-10 Westinghouse Electric Corp. Electrochemical cell apparatus having an integrated reformer-mixer nozzle-mixer diffuser
US5143800A (en) 1990-07-25 1992-09-01 Westinghouse Electric Corp. Electrochemical cell apparatus having combusted exhaust gas heat exchange and valving to control the reformable feed fuel composition
US5084362A (en) 1990-08-29 1992-01-28 Energy Research Corporation Internal reforming molten carbonate fuel cell system with methane feed
JP3064167B2 (en) 1993-09-01 2000-07-12 三菱重工業株式会社 Solid electrolyte fuel cell
TW299345B (en) 1994-02-18 1997-03-01 Westinghouse Electric Corp
JPH07275631A (en) * 1994-04-11 1995-10-24 Nippon Steel Corp Substitution-reduction method for impurity in product in pressure swing adsorption method
US5498487A (en) 1994-08-11 1996-03-12 Westinghouse Electric Corporation Oxygen sensor for monitoring gas mixtures containing hydrocarbons
US5441821A (en) 1994-12-23 1995-08-15 Ballard Power Systems Inc. Electrochemical fuel cell system with a regulated vacuum ejector for recirculation of the fluid fuel stream
US5505824A (en) 1995-01-06 1996-04-09 United Technologies Corporation Propellant generator and method of generating propellants
US5601937A (en) 1995-01-25 1997-02-11 Westinghouse Electric Corporation Hydrocarbon reformer for electrochemical cells
US5733675A (en) 1995-08-23 1998-03-31 Westinghouse Electric Corporation Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer
US5573867A (en) 1996-01-31 1996-11-12 Westinghouse Electric Corporation Purge gas protected transportable pressurized fuel cell modules and their operation in a power plant
US5741605A (en) 1996-03-08 1998-04-21 Westinghouse Electric Corporation Solid oxide fuel cell generator with removable modular fuel cell stack configurations
US5686196A (en) 1996-10-09 1997-11-11 Westinghouse Electric Corporation System for operating solid oxide fuel cell generator on diesel fuel
US5955039A (en) 1996-12-19 1999-09-21 Siemens Westinghouse Power Corporation Coal gasification and hydrogen production system and method
CA2242176C (en) 1997-06-30 2009-01-27 Ballard Power Systems Inc. Solid polymer fuel cell system and method for humidifying and adjusting the temperature of a reactant stream
US6013385A (en) 1997-07-25 2000-01-11 Emprise Corporation Fuel cell gas management system
WO2000016423A2 (en) 1998-09-14 2000-03-23 Forschungszentrum Jülich GmbH Solid oxide fuel cell which operates with an excess of fuel
US6051125A (en) 1998-09-21 2000-04-18 The Regents Of The University Of California Natural gas-assisted steam electrolyzer
US6403245B1 (en) 1999-05-21 2002-06-11 Microcoating Technologies, Inc. Materials and processes for providing fuel cells and active membranes
US6329090B1 (en) 1999-09-03 2001-12-11 Plug Power Llc Enthalpy recovery fuel cell system
US6280865B1 (en) 1999-09-24 2001-08-28 Plug Power Inc. Fuel cell system with hydrogen purification subsystem
JP2001102076A (en) * 1999-09-29 2001-04-13 Daihatsu Motor Co Ltd Fuel cell apparatus
US6627338B2 (en) * 1999-12-22 2003-09-30 Ballard Power Systems Inc. Integrated fuel cell and pressure swing adsorption system
US6451466B1 (en) 2000-04-06 2002-09-17 Utc Fuel Cells, Llc Functional integration of multiple components for a fuel cell power plant
US6630264B2 (en) 2000-05-01 2003-10-07 Delphi Technologies, Inc. Solid oxide fuel cell process gas sampling for analysis
JP2001347125A (en) * 2000-06-12 2001-12-18 Mitsubishi Kakoki Kaisha Ltd Method or manufacturing high-purity gas by pressure fluctuation adsorption apparatus
US7051801B1 (en) 2000-07-28 2006-05-30 Hydrogenics Corporation Method and apparatus for humidification and temperature control of incoming fuel cell process gas
WO2002019446A2 (en) 2000-09-01 2002-03-07 Global Thermoelectric Inc. Anode oxidation protection in a high-temperature fuel cell
US6811913B2 (en) 2000-11-15 2004-11-02 Technology Management, Inc. Multipurpose reversible electrochemical system
US7294421B2 (en) 2001-02-07 2007-11-13 Delphi Technologies, Inc. Solid oxide auxiliary power unit reformate control
US6623880B1 (en) 2001-05-29 2003-09-23 The United States Of America As Represented By The Department Of Energy Fuel cell-fuel cell hybrid system
US7067208B2 (en) 2002-02-20 2006-06-27 Ion America Corporation Load matched power generation system including a solid oxide fuel cell and a heat pump and an optional turbine
US20030196893A1 (en) 2002-04-23 2003-10-23 Mcelroy James Frederick High-temperature low-hydration ion exchange membrane electrochemical cell
US6854688B2 (en) 2002-05-03 2005-02-15 Ion America Corporation Solid oxide regenerative fuel cell for airplane power generation and storage
US7179313B2 (en) 2002-08-02 2007-02-20 Catacel Corp. Regenerative autothermal catalytic steam reformer
US6821663B2 (en) 2002-10-23 2004-11-23 Ion America Corporation Solid oxide regenerative fuel cell
JP2004247290A (en) * 2003-01-21 2004-09-02 Honda Motor Co Ltd Hydrogen feeder
US6924053B2 (en) 2003-03-24 2005-08-02 Ion America Corporation Solid oxide regenerative fuel cell with selective anode tail gas circulation
US7045238B2 (en) 2003-03-24 2006-05-16 Ion America Corporation SORFC power and oxygen generation method and system
US7575822B2 (en) 2003-04-09 2009-08-18 Bloom Energy Corporation Method of optimizing operating efficiency of fuel cells
US7482078B2 (en) 2003-04-09 2009-01-27 Bloom Energy Corporation Co-production of hydrogen and electricity in a high temperature electrochemical system
US7364810B2 (en) 2003-09-03 2008-04-29 Bloom Energy Corporation Combined energy storage and fuel generation with reversible fuel cells
US7060382B2 (en) * 2003-05-15 2006-06-13 Fuelcell Energy, Inc. Fuel cell system with recycle of anode exhaust gas
US7422810B2 (en) 2004-01-22 2008-09-09 Bloom Energy Corporation High temperature fuel cell system and method of operating same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040005492A1 (en) * 2002-03-14 2004-01-08 Questair Technologies, Inc. Hydrogen recycle for solid oxide fuel cell
US20040197612A1 (en) * 2003-02-26 2004-10-07 Questair Technologies Inc. Hydrogen recycle for high temperature fuel cells

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1912722A4 *

Also Published As

Publication number Publication date
WO2007014126A2 (en) 2007-02-01
US7520916B2 (en) 2009-04-21
JP2009503788A (en) 2009-01-29
EP1912722A2 (en) 2008-04-23
JP5113748B2 (en) 2013-01-09
US20070017367A1 (en) 2007-01-25
EP1912722A4 (en) 2009-06-24

Similar Documents

Publication Publication Date Title
WO2007014126A3 (en) Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell
WO2007014127A3 (en) Fuel cell system with partial recycling of anode exhaust
WO2007014128A3 (en) Fuel cell system with electrochemical anode exhaust recycling
WO2010014774A3 (en) Modular membrane reactor and process for carbon dioxide extraction
JP2009503788A5 (en)
WO2009090429A3 (en) Improvements to gas recovery system
WO2008102509A1 (en) Hydrogen purification method, hydrogen separation membrane, and hydrogen purification apparatus
WO2006036606A8 (en) Separator plates, ion pumps, and hydrogen fuel infrastructure systems and methods for generating hydrogen
WO2006083296A8 (en) Fuel fired hydrogen generator
WO2006010012A3 (en) Fuel cell cartridge and fuel delivery system
WO2009047897A1 (en) Fuel cell system
EP1414093A3 (en) Fuel cell system
WO2012176177A8 (en) System and method for separating co2 from combustion flue gas containing sox and nox by means of molten carbonate fuel cells (mcfc)
WO2009108255A3 (en) Portable reformed fuel cell systems with water recovery
WO2004105158A3 (en) A fuel cell system with recycle of anode exhaust gas
WO2007076067A3 (en) Concentrating catalytic hydrogen production system
AU2003263796A8 (en) Pem fuel cell stack without gas diffusion media
WO2011056301A3 (en) System and method for carbon dioxide capture in an air compression and expansion system
JP6651172B2 (en) Hydrogen recovery method from biomass pyrolysis gas
WO2007030291A3 (en) Fuel cell systems and methods for passively increasing hydrogen recovery through vacuum-assisted pressure swing adsorption
WO2009067508A3 (en) Enhanced efficiency of a combined sorfc energy storage and fuel generation system
JP6659717B2 (en) Hydrogen recovery method
WO2007144764A3 (en) Compact and efficient pressure swing oxygen concentrator
EP2053316A4 (en) Separator for humidifier, humidifier, and fuel cell system comprising the humidifier
WO2009100152A3 (en) Systems and methods for on-site selective catalytic reduction

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 311/KOLNP/2008

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 2008524021

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2006788269

Country of ref document: EP