WO2007015644A1 - Method and means for purifying petrochemical products - Google Patents

Method and means for purifying petrochemical products Download PDF

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Publication number
WO2007015644A1
WO2007015644A1 PCT/NO2005/000286 NO2005000286W WO2007015644A1 WO 2007015644 A1 WO2007015644 A1 WO 2007015644A1 NO 2005000286 W NO2005000286 W NO 2005000286W WO 2007015644 A1 WO2007015644 A1 WO 2007015644A1
Authority
WO
WIPO (PCT)
Prior art keywords
product
petrochemical
products
purifying
nozzle
Prior art date
Application number
PCT/NO2005/000286
Other languages
French (fr)
Inventor
Jan Ingolf Kristiansen
Original Assignee
Jan Ingolf Kristiansen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jan Ingolf Kristiansen filed Critical Jan Ingolf Kristiansen
Priority to PCT/NO2005/000286 priority Critical patent/WO2007015644A1/en
Priority to CN200580051252.6A priority patent/CN101268174A/en
Priority to EP05771683A priority patent/EP1917334A4/en
Priority to CA002617347A priority patent/CA2617347A1/en
Priority to JP2008524924A priority patent/JP2009503228A/en
Publication of WO2007015644A1 publication Critical patent/WO2007015644A1/en
Priority to NO20081091A priority patent/NO20081091L/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M175/00Working-up used lubricants to recover useful products ; Cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/16Evaporating by spraying
    • B01D1/20Sprayers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/06Flash distillation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/06Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G33/00Dewatering or demulsification of hydrocarbon oils
    • C10G33/06Dewatering or demulsification of hydrocarbon oils with mechanical means, e.g. by filtration
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M175/00Working-up used lubricants to recover useful products ; Cleaning
    • C10M175/0091Treatment of oils in a continuous lubricating circuit (e.g. motor oil system)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1037Hydrocarbon fractions
    • C10G2300/1048Middle distillates
    • C10G2300/1055Diesel having a boiling range of about 230 - 330 °C
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/301Boiling range
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012Pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04Diesel oil

Definitions

  • the present invention is related to a method and means for removing alien liquids from petrochemical products.
  • figure 1 discloses in figure 1 a longitudinal section of a combined filter and purifier for petrochemical products according to the present invention
  • figure 2 discloses a general view of a special distillation element according to the invention
  • figure 3 discloses a longitudinal section of a nozzle in the element
  • figure 4 discloses a vertical section of the element
  • figure 5 discloses a side view of the element
  • figure 6 discloses an enlarged section through the top of the element end the top of the chamber.
  • the special distillation element 1 is placed vertically in a ventilated chamber 2 as part of a filter and purifying means comprising a filter chamber 10 and a lid or cover 3.
  • the liquid petrochemical products enter in at a flow of 20 - 35 liters per hour under a pressure of 2 — 6 bar through a tube 8.
  • the tube 8 is heated to keep it at a constant temperature of about 100 °C.
  • the liquid passes through a metering jet or nozzle 5 with an opening of 0.7 - 1.2 mm, where the velocity of the liquid is accelerated because of the sudden pressure release.
  • a metering jet or nozzle 5 with an opening of 0.7 - 1.2 mm, where the velocity of the liquid is accelerated because of the sudden pressure release.
  • a fractional separation of the components will occur and these separated materials will partly be in gas form and partly as liquid when it leaves the metering nozzle 5 like a spray or fountain hitting the cover 3 creating the ceiling of the chamber 2 that directly above the nozzle 5 is formed like the inverted inside of a dome 4.
  • the materials in the gas or in an evaporated form, the gas like steam from water and acids, possibly gasoline and other alien liquids, are vented out via a not disclosed ventilation opening due to an overpressure that will occur due to the gas formation.
  • the light and oil-diluting parts of possible diesel fuel will also be evaporated out in this process.
  • the petrochemical liquid will be reflected down from the dome 4 in the ceiling of the chamber 2 to the head 9 of the distillation element 1 and will flow down over its surface which is also heated to about 100 0 C.
  • This surface is formed like a pear or mushroom with grooves to delay the surface velocity of the liquid in order to "distillate" possible alien liquid remains.
  • the liquid flows to the bottom of the distillation chamber 2 where it is drained back to the actual equipment through a not disclosed outlet.
  • An important part of the invention is the shape of the distillation element and the ventilated chamber 2 with its inverted dome 4 in the ceiling of the chamber 2.
  • the distillation element 1 is preferably made of aluminum because of the good thermal conductivity.
  • the element 1 has a shape like a mushroom or pear.
  • An electrical heating element for heating the distillation element is inserted into a heating element bore 7 in the head of the element 1.
  • a thermostat for control of the temperature in the head of the distillation element 1 is installed in a thermostat bore 6 in the head of the distillation element 1.
  • the surface of the distillation element 1 it provided with grooves to trap or slow down the liquid flow.
  • the distillation element according to the present invention provides high performance with few parts, whereby said parts are inexpensive to manufacture. Said low price is especially remarkable when compared with the high performance. Furthermore the distillation element according to the invention is easy to install and use and need no maintenance.
  • the method and means according to the present invention is especially suitable to remove water from oil, such as hydraulic oil, oil in combustion engines, gasoline and diesel etc.
  • the distillation element 1 may be used alone in a circuit or in combination with a filter packet 11 in a filter chamber 10 of a filter or purifying box as disclosed in figure 1. Oil enters the filter box through a port 12, flows downwardly along the outside of the filter 11, penetrates through the filter 11 and enters the pipe 8 of the distillation element 1.

Abstract

A method and means for purifying petrochemical products in a circuit circulating such products at a pressure of about 2 to 6 bar, comprising heating the petrochemical product and maintaining the temperature to about 100 °C, passing the product through a nozzle of approximately 0.7 to 1.2 mm thereby to increase the velocity of the product, thereby separating different components of the product, returning separated clean petrochemical product to the circuit, and draining steam and gaseous parts.

Description

Method and means for purifying petrochemical products
The present invention is related to a method and means for removing alien liquids from petrochemical products.
The automotive industries have problems with alien liquid contaminations in petrochemical products for lubrication and different power transmissions or transformers (hydraulics, gears, valves, etc.). These contaminations mainly consist of water (from condensation, leaks, frost, etc.), not combusted fuel residues, acids and possibly other alien liquids depending on the local conditions. Acids can only form when water is present.
For the industry it is important to keep the liquid petrochemical products free from such liquid contaminations. This is achieved with the method according to the present invention as defined by the features stated in the claims.
The drawing discloses in figure 1 a longitudinal section of a combined filter and purifier for petrochemical products according to the present invention, figure 2 discloses a general view of a special distillation element according to the invention, figure 3 discloses a longitudinal section of a nozzle in the element, figure 4 discloses a vertical section of the element, figure 5 discloses a side view of the element, and figure 6 discloses an enlarged section through the top of the element end the top of the chamber.
The special distillation element 1 according to the invention is placed vertically in a ventilated chamber 2 as part of a filter and purifying means comprising a filter chamber 10 and a lid or cover 3. In the ventilated chamber 2 the liquid petrochemical products enter in at a flow of 20 - 35 liters per hour under a pressure of 2 — 6 bar through a tube 8. The tube 8 is heated to keep it at a constant temperature of about 100 °C. Immediately thereafter the liquid passes through a metering jet or nozzle 5 with an opening of 0.7 - 1.2 mm, where the velocity of the liquid is accelerated because of the sudden pressure release. Partly because of the different thermal properties of different components of the liquid mix passing through such as oil, water, fuel, etc.; these components will react differently to these sudden changes of temperature, pressure and velocity.
A fractional separation of the components will occur and these separated materials will partly be in gas form and partly as liquid when it leaves the metering nozzle 5 like a spray or fountain hitting the cover 3 creating the ceiling of the chamber 2 that directly above the nozzle 5 is formed like the inverted inside of a dome 4. The materials in the gas or in an evaporated form, the gas like steam from water and acids, possibly gasoline and other alien liquids, are vented out via a not disclosed ventilation opening due to an overpressure that will occur due to the gas formation. The light and oil-diluting parts of possible diesel fuel will also be evaporated out in this process. The petrochemical liquid will be reflected down from the dome 4 in the ceiling of the chamber 2 to the head 9 of the distillation element 1 and will flow down over its surface which is also heated to about 100 0C. This surface is formed like a pear or mushroom with grooves to delay the surface velocity of the liquid in order to "distillate" possible alien liquid remains. The liquid flows to the bottom of the distillation chamber 2 where it is drained back to the actual equipment through a not disclosed outlet.
An important part of the invention is the shape of the distillation element and the ventilated chamber 2 with its inverted dome 4 in the ceiling of the chamber 2.
The distillation element 1 is preferably made of aluminum because of the good thermal conductivity. The element 1 has a shape like a mushroom or pear.
An electrical heating element for heating the distillation element is inserted into a heating element bore 7 in the head of the element 1. A thermostat for control of the temperature in the head of the distillation element 1 is installed in a thermostat bore 6 in the head of the distillation element 1.
The surface of the distillation element 1 it provided with grooves to trap or slow down the liquid flow.
The distillation element according to the present invention provides high performance with few parts, whereby said parts are inexpensive to manufacture. Said low price is especially remarkable when compared with the high performance. Furthermore the distillation element according to the invention is easy to install and use and need no maintenance.
The method and means according to the present invention is especially suitable to remove water from oil, such as hydraulic oil, oil in combustion engines, gasoline and diesel etc. The distillation element 1 may be used alone in a circuit or in combination with a filter packet 11 in a filter chamber 10 of a filter or purifying box as disclosed in figure 1. Oil enters the filter box through a port 12, flows downwardly along the outside of the filter 11, penetrates through the filter 11 and enters the pipe 8 of the distillation element 1.

Claims

P a t e n t C l a i m s
1. A method for purifying petrochemical products in a circuit circulating such products at a pressure of about 2 to 6 bar, characterized by heating the petrochemical product and maintaining the temperature to about 100 0C, passing the product through a nozzle of approximately 0.7 to 1.2 mm thereby to increase the velocity of the product, thereby separating different components of the product, returning separated clean petrochemical product to the circuit, and draining steam and gaseous parts.
2. Method according to claim 1, characterized by entering water contaminated fuel, such as diesel, to remove substantially all water.
3. Means for purifying petrochemical products in a circuit circulating such products at a pressure of about 2 to 6 bar, comprising a cover (3) and an inlet chamber (10), characterized in that it comprises distillation element (1) having an inlet pipe (8) to be heated, a jet or nozzle (5) having an opening of about 0.7 to 1.2 mm directing the outlet flow against a dome (4) in the ceiling of the cover (3), at least one of the pipe (8) and the element (1) being provided with a heating element, the element (1) comprising a top surface or head (9) adapted to receive the liquid after liberating the gas.
PCT/NO2005/000286 2005-08-01 2005-08-01 Method and means for purifying petrochemical products WO2007015644A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
PCT/NO2005/000286 WO2007015644A1 (en) 2005-08-01 2005-08-01 Method and means for purifying petrochemical products
CN200580051252.6A CN101268174A (en) 2005-08-01 2005-08-01 Method and device for purifying petrochemical
EP05771683A EP1917334A4 (en) 2005-08-01 2005-08-01 Method and means for purifying petrochemical products
CA002617347A CA2617347A1 (en) 2005-08-01 2005-08-01 Method and means for purifying petrochemical products
JP2008524924A JP2009503228A (en) 2005-08-01 2005-08-01 Method and means for purifying petrochemical products
NO20081091A NO20081091L (en) 2005-08-01 2008-02-29 Process and apparatus for purifying oil products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/NO2005/000286 WO2007015644A1 (en) 2005-08-01 2005-08-01 Method and means for purifying petrochemical products

Publications (1)

Publication Number Publication Date
WO2007015644A1 true WO2007015644A1 (en) 2007-02-08

Family

ID=37708898

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NO2005/000286 WO2007015644A1 (en) 2005-08-01 2005-08-01 Method and means for purifying petrochemical products

Country Status (5)

Country Link
EP (1) EP1917334A4 (en)
JP (1) JP2009503228A (en)
CN (1) CN101268174A (en)
CA (1) CA2617347A1 (en)
WO (1) WO2007015644A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012164348A1 (en) 2011-05-31 2012-12-06 Ingolf Kristiansen Method and apparatus for removing alien fluids from a petrochemical product
WO2016118016A1 (en) 2015-01-23 2016-07-28 Norwegian Field Industry As Water and oil separation method using compressing tubes to vaporize water
US9823236B2 (en) 2012-12-21 2017-11-21 Colgate-Palmolive Company Method for testing oral malodor

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4146475A (en) * 1977-12-01 1979-03-27 Forsland Audre C Electrefiner
US4349438A (en) * 1981-07-08 1982-09-14 Sims Oil, Inc. Oil refiner
US4383645A (en) * 1980-12-15 1983-05-17 Allied Corporation Vapor sprayer and process for providing a volatile fluid as a vapor spray
EP0115333A2 (en) * 1983-02-01 1984-08-08 Axel Johnson Engineering Ab Method and apparatus for separating water and solid particles from oils
WO1986004830A1 (en) * 1985-02-22 1986-08-28 International Energy Corporation Oil refiner with atomizing nozzle
AT395162B (en) * 1989-10-23 1992-10-12 Splosno Gradbeno Podjetje Slov DEVICE FOR REGENERATING TECHNICAL OILS
US5314613A (en) * 1989-09-25 1994-05-24 Gaetano Russo Process and apparatus for oil decontamination
WO2003024557A1 (en) * 2001-09-17 2003-03-27 Park, Chang-Bog Apparatus for recycling and supplying lubricating oil

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4146475A (en) * 1977-12-01 1979-03-27 Forsland Audre C Electrefiner
US4383645A (en) * 1980-12-15 1983-05-17 Allied Corporation Vapor sprayer and process for providing a volatile fluid as a vapor spray
US4349438A (en) * 1981-07-08 1982-09-14 Sims Oil, Inc. Oil refiner
EP0115333A2 (en) * 1983-02-01 1984-08-08 Axel Johnson Engineering Ab Method and apparatus for separating water and solid particles from oils
WO1986004830A1 (en) * 1985-02-22 1986-08-28 International Energy Corporation Oil refiner with atomizing nozzle
US5314613A (en) * 1989-09-25 1994-05-24 Gaetano Russo Process and apparatus for oil decontamination
AT395162B (en) * 1989-10-23 1992-10-12 Splosno Gradbeno Podjetje Slov DEVICE FOR REGENERATING TECHNICAL OILS
WO2003024557A1 (en) * 2001-09-17 2003-03-27 Park, Chang-Bog Apparatus for recycling and supplying lubricating oil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1917334A4 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012164348A1 (en) 2011-05-31 2012-12-06 Ingolf Kristiansen Method and apparatus for removing alien fluids from a petrochemical product
EA026408B1 (en) * 2011-05-31 2017-04-28 Йонсен Ойл А/С Method and apparatus for removing alien fluids from a petrochemical product
US9823236B2 (en) 2012-12-21 2017-11-21 Colgate-Palmolive Company Method for testing oral malodor
WO2016118016A1 (en) 2015-01-23 2016-07-28 Norwegian Field Industry As Water and oil separation method using compressing tubes to vaporize water

Also Published As

Publication number Publication date
CA2617347A1 (en) 2007-02-08
EP1917334A4 (en) 2012-01-25
JP2009503228A (en) 2009-01-29
EP1917334A1 (en) 2008-05-07
CN101268174A (en) 2008-09-17

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