WO2007044735A3 - Amido-organoborate initiator systems - Google Patents

Amido-organoborate initiator systems Download PDF

Info

Publication number
WO2007044735A3
WO2007044735A3 PCT/US2006/039584 US2006039584W WO2007044735A3 WO 2007044735 A3 WO2007044735 A3 WO 2007044735A3 US 2006039584 W US2006039584 W US 2006039584W WO 2007044735 A3 WO2007044735 A3 WO 2007044735A3
Authority
WO
WIPO (PCT)
Prior art keywords
amido
borate
free radical
radical polymerization
nitrogen atoms
Prior art date
Application number
PCT/US2006/039584
Other languages
French (fr)
Other versions
WO2007044735A2 (en
Inventor
Shaoguang Feng
Gary L Jialanella
Peter Nickias
Toni Ristoski
Original Assignee
Dow Global Technologies Inc
Shaoguang Feng
Gary L Jialanella
Peter Nickias
Toni Ristoski
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Shaoguang Feng, Gary L Jialanella, Peter Nickias, Toni Ristoski filed Critical Dow Global Technologies Inc
Priority to JP2008534776A priority Critical patent/JP2009511502A/en
Priority to CA 2625023 priority patent/CA2625023A1/en
Priority to BRPI0617975-4A priority patent/BRPI0617975A2/en
Priority to EP20060825707 priority patent/EP1934264A2/en
Publication of WO2007044735A2 publication Critical patent/WO2007044735A2/en
Publication of WO2007044735A3 publication Critical patent/WO2007044735A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31928—Ester, halide or nitrile of addition polymer

Abstract

In one embodiment, the invention is a system for initiating free radical polymerization comprising: a) in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms, and a cationic counter ion and b) in a second part, a liberating compound which reacts with the nitrogen atom(s) bound to the boron atom upon contact with the amido-borate to form an organoborane radical. In another embodiment, the invention is a two part polymerizable composition comprising in one part, one or more amido-borate compounds and in the second part, a liberating compound which reacts with the nitrogen atoms bound to the boron atom upon contact with the amido-borate to form an organoborane radical and one or more compounds capable of free radical polymerization. The first part may further comprise one or more compounds capable of free radical polymerization. This facilitates formulating compositions that have commercially desirable volumetric ratios of the two parts.
PCT/US2006/039584 2005-10-07 2006-10-06 Amido-organoborate initiator systems WO2007044735A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2008534776A JP2009511502A (en) 2005-10-07 2006-10-06 Amide organoborate initiator system
CA 2625023 CA2625023A1 (en) 2005-10-07 2006-10-06 Amido-organoborate initiator systems
BRPI0617975-4A BRPI0617975A2 (en) 2005-10-07 2006-10-06 starch borate compound
EP20060825707 EP1934264A2 (en) 2005-10-07 2006-10-06 Amido-organoborate initiator systems

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US72494305P 2005-10-07 2005-10-07
US60/724,943 2005-10-07

Publications (2)

Publication Number Publication Date
WO2007044735A2 WO2007044735A2 (en) 2007-04-19
WO2007044735A3 true WO2007044735A3 (en) 2009-04-23

Family

ID=37686098

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2006/039575 WO2007044730A1 (en) 2005-10-07 2006-10-06 Amido-organoborate initiator systems
PCT/US2006/039584 WO2007044735A2 (en) 2005-10-07 2006-10-06 Amido-organoborate initiator systems

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US2006/039575 WO2007044730A1 (en) 2005-10-07 2006-10-06 Amido-organoborate initiator systems

Country Status (9)

Country Link
US (2) US7737241B2 (en)
EP (2) EP1934296A1 (en)
JP (2) JP2009531468A (en)
KR (2) KR20080053486A (en)
CN (2) CN101501043A (en)
BR (2) BRPI0617975A2 (en)
CA (2) CA2624322A1 (en)
RU (2) RU2008116620A (en)
WO (2) WO2007044730A1 (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090090454A1 (en) * 2003-08-13 2009-04-09 Lutz William G Method for joining piping systems and piping to equipment, fixtures, devices, structures, and appliances
JP2007515547A (en) 2003-12-22 2007-06-14 ダウ グローバル テクノロジーズ インコーポレイティド Accelerated organoborane amine complex-initiated polymerizable composition
BRPI0617975A2 (en) * 2005-10-07 2011-08-09 Dow Global Tchnologies Inc starch borate compound
US20080103274A1 (en) * 2006-10-12 2008-05-01 Jialanella Gary L Accelerated organoborane initiated polymerizable compositions
US7524907B2 (en) * 2006-10-12 2009-04-28 Dow Global Technologies, Inc. Accelerated organoborane initiated polymerizable compositions
US8377852B2 (en) 2007-10-26 2013-02-19 Dow Corning Corporation Method of preparing a substrate with a composition including an organoborane initiator
WO2010014545A1 (en) 2008-07-28 2010-02-04 Dow Corning Corporation Composite article
WO2010014537A1 (en) * 2008-07-28 2010-02-04 Dow Corning Corporation Radical polymerizable composition
US20110104508A1 (en) * 2008-08-29 2011-05-05 Dow Global Technologies Inc. Adhesive for bonding to flexible polymer surfaces
TW201026513A (en) * 2009-01-08 2010-07-16 Univ Nat Cheng Kung Imprinting process of polyimide
KR101959953B1 (en) 2009-02-04 2019-03-19 다우 실리콘즈 코포레이션 Method of forming a non-random copolymer
WO2012085169A1 (en) * 2010-12-22 2012-06-28 Haag Benjamin Metallic amidoborates for functionalizing organic compounds
KR101597888B1 (en) 2011-05-03 2016-02-25 다우 글로벌 테크놀로지스 엘엘씨 Dual cure adhesive useful for bonding to glass
EP2705064A1 (en) 2011-05-03 2014-03-12 Dow Global Technologies LLC Accelerated cure composition containing an isocyanate functional prepolymer
WO2014074140A1 (en) 2012-11-08 2014-05-15 Dow Global Technologies Llc Ultrafast dual cure adhesive useful for bonding to glass
US9382452B2 (en) * 2013-02-07 2016-07-05 Illinois Tool Works, Inc. Low surface energy bonding adhesive formulation and process for the use thereof
MX2017006766A (en) 2014-11-24 2017-09-08 Ppg Ind Ohio Inc Coreactive materials and methods for three-dimensional printing.
JP2016169297A (en) * 2015-03-12 2016-09-23 日東電工株式会社 Crosslinking agent and curable resin composition, polarizing film and method for manufacturing the same, optical film, and image display device
KR101889714B1 (en) * 2016-03-08 2018-08-20 대우조선해양 주식회사 High flame retardant coating agent with glass bubble hybridized construction
KR102258062B1 (en) * 2017-04-13 2021-05-27 주식회사 엘지화학 Acrylate based adhesive composition
AU2018279855B2 (en) 2017-06-09 2020-06-18 Prc-Desoto International, Inc. Dual cure sealants
US10434704B2 (en) 2017-08-18 2019-10-08 Ppg Industries Ohio, Inc. Additive manufacturing using polyurea materials
WO2019053645A1 (en) * 2017-09-18 2019-03-21 Aditya Birla Chemicals (Thailand) Limited An epoxy resin system for structural composites
US11015057B2 (en) 2019-04-03 2021-05-25 Prc-Desoto International, Inc. Dual-cure compositions
US11173692B2 (en) 2019-12-19 2021-11-16 Prc-Desoto International, Inc. Free radical polymerizable adhesion-promoting interlayer compositions and methods of use

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6630555B2 (en) * 2001-11-06 2003-10-07 Lord Corporation Internally blocked organoborate initiators and adhesives therefrom

Family Cites Families (98)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE599646A (en) 1960-02-02
US3275611A (en) * 1960-12-30 1966-09-27 Monsanto Co Process for polymerizing unsaturated monomers with a catalyst comprising an organoboron compound, a peroxygen compound and an amine
US3527737A (en) * 1967-09-15 1970-09-08 G C Kagaku Kogyo Kk Adhesive compositions
AT314710B (en) 1971-06-07 1974-04-25 Reichhold Albert Chemie Ag Process for bonding solid materials and hot-melt pressure-sensitive adhesives for this purpose
US3890407A (en) 1972-07-20 1975-06-17 Du Pont Novel adhesive compositions
US4106971A (en) 1975-02-21 1978-08-15 E. I. Du Pont De Nemours And Company Method of adhesive bonding
US3971751A (en) 1975-06-09 1976-07-27 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Vulcanizable silylether terminated polymer
GB1552046A (en) 1977-02-02 1979-09-05 Ciba Geigy Ag Film adhesives
CA1105035A (en) * 1977-08-24 1981-07-14 Thomas A. Whitney Alkali metal salts of complex anions containing heteroatom substituents and electrolyte compositions containing these
US4104450A (en) * 1977-08-24 1978-08-01 Exxon Research & Engineering Co. Alkali metal batteries having electrolytes including alkali metal salts of complex anions containing heteroatom substituents in organic solvent
US4117213A (en) * 1977-08-24 1978-09-26 Exxon Research & Engineering Co. Alkali metal salts of complex anions containing heteroatom substituents and electrolyte compositions containing these
US4344800A (en) 1980-06-03 1982-08-17 Dow Corning Corporation Method for producing hydrophobic reinforcing silica fillers and fillers obtained thereby
DE3041904C2 (en) * 1980-11-06 1984-11-22 Henkel KGaA, 4000 Düsseldorf Storage-stable reactive adhesives containing boron compounds
DE3207263A1 (en) * 1982-03-01 1983-09-08 Henkel KGaA, 4000 Düsseldorf SUBSTANCE MIXTURES CONTAINING ORGANO BORON COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
US4426243A (en) * 1981-12-01 1984-01-17 Illinois Tool Works Inc. Room-temperature-curable, quick-setting acrylic/epoxy adhesives and methods of bonding
DE3207264A1 (en) * 1982-03-01 1983-09-08 Henkel KGaA, 4000 Düsseldorf NEW BORALKYL COMPOUNDS, METHOD FOR THEIR PRODUCTION AND THEIR USE
US4538920A (en) * 1983-03-03 1985-09-03 Minnesota Mining And Manufacturing Company Static mixing device
US4448927A (en) * 1983-03-14 1984-05-15 Dow Corning Corporation Method of polymerizing oligomers of polydiorganosiloxane in the presence of filler
US4773957A (en) * 1983-09-22 1988-09-27 Illinois Tool Works, Inc. Bonding method employing novel methacrylate based adhesive compositions
US4536546A (en) 1983-09-22 1985-08-20 Illinois Tool Works Inc. (Meth)acrylate-based compositions
US5599856A (en) 1984-03-01 1997-02-04 Amoco Corporation Epoxy resin systems containing modifiers
EP0169536B1 (en) 1984-07-26 1994-05-18 Kanegafuchi Chemical Industry Co., Ltd. Curable polymer composition
DE3518965A1 (en) * 1985-05-25 1986-11-27 Henkel KGaA, 40589 Düsseldorf Plastic compositions which can be melted and at the same time cure aerobically, and process for their preparation
US4705838A (en) 1986-07-07 1987-11-10 Ashland Oil, Inc. Acceleration of rate of cure in boron trifluoride amine catalyzed cure of epoxy resins
KR950003688B1 (en) 1986-10-30 1995-04-17 미쓰이세끼유 가가꾸 고오교오 가부시끼가이샤 Curable coposition
US4746725A (en) 1987-02-25 1988-05-24 General Electric Company Cyclic polycarbonate-polyepoxide reaction product and method for their preparation
JPH075680B2 (en) 1987-07-03 1995-01-25 三井石油化学工業株式会社 Curable composition
US4823927A (en) 1987-08-24 1989-04-25 Ancra Corporation Retractable roller system for cargo handling
US5082147A (en) 1988-02-29 1992-01-21 Richard Jacobs Composition dispensing system
US5079098A (en) * 1988-03-16 1992-01-07 Loctite Corporation Primer for bonding low surface energy plastics with cyanoacrylate adhesives and bonding method employing same
US4985477A (en) 1988-05-13 1991-01-15 Dow Corning Corporation Method of producing treated silica filler for silicone rubber
US4942201A (en) * 1988-08-29 1990-07-17 Illinois Tool Works, Inc. Adhesive for low temperature applications
US5112691A (en) 1988-08-29 1992-05-12 Illinois Tool Works, Inc. Adhesive for low temperature applications
US5034464A (en) 1989-07-19 1991-07-23 E. I. Du Pont De Nemours And Company Amine-borane adduct curing agents for epoxy/anhydride resins
US5409995A (en) 1989-05-29 1995-04-25 Kanegafuchi Chemical Industry Co., Ltd. Curing agent, preparation thereof and curable composition comprising the same
US5132377A (en) 1989-06-05 1992-07-21 Nippon Paint Company, Limited Heat-latent, cationic polymerization initiator and resin compositions containing the same
US5126416A (en) 1990-03-26 1992-06-30 Loctite Corporation Peroxy cured (meth)acrylic ester compositions employing nitrite, borate, silicate or carbonate salt accelerators
ZA913801B (en) * 1990-05-21 1993-01-27 Dow Chemical Co Latent catalysts,cure-inhibited epoxy resin compositions and laminates prepared therefrom
US5204386A (en) 1990-11-13 1993-04-20 The Dow Chemical Company Acrylic-modified epoxy resin adhesive compositions with improved rheological control
US5506326A (en) 1991-03-06 1996-04-09 Loctite (Ireland) Limited Air-activatable polymerizable compositions containing onium salts
US5143884A (en) * 1991-04-29 1992-09-01 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US5106928A (en) 1991-04-29 1992-04-21 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
JP2995308B2 (en) * 1991-09-09 1999-12-27 鐘淵化学工業株式会社 Curable composition
US5250228A (en) 1991-11-06 1993-10-05 Raychem Corporation Conductive polymer composition
JPH05132538A (en) * 1991-11-13 1993-05-28 Nippon Paint Co Ltd New cold-setting resin composition
EP0626948B1 (en) 1992-01-24 1997-11-12 Reilly Industries, Inc. New curing agents/accelerators for epoxy resins, curable compositions and processes
US5286821A (en) 1992-03-17 1994-02-15 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US5401805A (en) 1992-04-06 1995-03-28 The Penn State Research Foundation Olefin graft copolymers prepared using borane-containing olefin backbone polymers
US5411998A (en) 1992-07-24 1995-05-02 Loctite Limited Curing anaerobic compositions through thick bondlines
JP3213424B2 (en) * 1993-02-15 2001-10-02 理想科学工業株式会社 Paper stencil sheet ejection device
KR100214288B1 (en) 1993-04-16 1999-08-02 성재갑 Compositions for antifogging coating and molding articles using the same
US5998499A (en) 1994-03-25 1999-12-07 Dentsply G.M.B.H. Liquid crystalline (meth)acrylate compounds, composition and method
US5310835A (en) * 1993-09-30 1994-05-10 National Starch And Chemical Investment Holding Corporation Transparent two-part acrylic adhesive composition and the method of use thereof
AU704705B2 (en) 1993-12-22 1999-04-29 Tremco Incorporated Moisture-curable modified acrylic polymer sealant composition
US5691065A (en) 1995-02-22 1997-11-25 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
EP0746573B1 (en) * 1994-02-22 2001-06-06 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
JPH07316525A (en) 1994-05-24 1995-12-05 Mitsui Petrochem Ind Ltd Adhesive composition for flexible printed-wiring board
JP3384168B2 (en) * 1995-02-17 2003-03-10 東洋インキ製造株式会社 Photoinitiator composition, photopolymerizable composition and photopolymerization method
US5616796A (en) 1995-04-14 1997-04-01 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive composition made therewith
US5621143A (en) 1995-04-14 1997-04-15 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5686544A (en) 1995-08-11 1997-11-11 Minnesota Mining And Manufacturing Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
WO1997007171A1 (en) 1995-08-11 1997-02-27 Minnesota Mining And Manufacturing Company Initiator system and adhesive composition made therewith
JP3084352B2 (en) 1995-08-28 2000-09-04 太陽インキ製造株式会社 Insulating resin composition for copper foil lamination type build-up and method for producing multilayer printed wiring board using the same
DE69613387T2 (en) * 1995-11-07 2002-02-14 Minnesota Mining & Mfg INITIATOR SYSTEM AND ADHESIVE COMPOSITION CONTAINING THEM
MY132867A (en) * 1995-11-24 2007-10-31 Ciba Specialty Chemicals Holding Inc Acid-stable borates for photopolymerization
US5952409A (en) * 1996-01-31 1999-09-14 3M Innovative Properties Company Compositions and methods for imparting stain resistance and stain resistant articles
US5817376A (en) 1996-03-26 1998-10-06 Minnesota Mining And Manufacturing Company Free-radically polymerizable compositions capable of being coated by electrostatic assistance
US5721281A (en) 1996-07-01 1998-02-24 Blount; David H. Flame retardant porous plastics
US5935711A (en) 1996-10-23 1999-08-10 3M Innovative Properties Company Organoborane amine complex initiator systems and polymerizable compositions made therewith
US6090904A (en) 1996-12-19 2000-07-18 Ara Werk Kramer Gmbh Silicone compositions curable in presence of moisture
US5912433A (en) * 1997-01-17 1999-06-15 Minnesota Mining And Manufacturing Company Cable closure injection sealed with low surface energy adhesive
GB9703552D0 (en) 1997-02-20 1997-04-09 Dow Corning Polymerisation of cyclosiloxanes in the presence of fillers
JP2001527565A (en) * 1997-05-23 2001-12-25 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド Polyborate coinitiator for photopolymerization
US5807910A (en) * 1997-06-23 1998-09-15 Industrial Technology Research Institute Preolymerizing epoxy resin, functionalized rubber with filler to form adhesive
US5948854A (en) * 1997-09-25 1999-09-07 Dow Corning S.A. Alkoxy-functional RTV compositions with increased green strength and increased storage stability
US6008284A (en) 1997-12-23 1999-12-28 Dow Corning Corporation Fast curing alkoxy-functional RTV compositions
JP4286345B2 (en) 1998-05-08 2009-06-24 株式会社リコー Search support system and computer-readable recording medium
US6225408B1 (en) 1998-06-12 2001-05-01 Lord Corporation Adhesive formulations
US6727320B2 (en) * 1998-11-02 2004-04-27 Henkel Loctite Corporation Polymerizable compositions in non-flowable forms
US6252023B1 (en) 1999-03-19 2001-06-26 3M Innovative Properties Company Organoborane amine complex inatator systems and polymerizable compositions made therewith
US6207781B1 (en) 1999-08-20 2001-03-27 Dow Corning Corporation Polymerization of an organofunctional cocyclic siloxane
US6054548A (en) 1999-08-26 2000-04-25 Dow Corning Limited Process for producing a silicone polymer
US6410667B1 (en) 1999-11-04 2002-06-25 3M Innovative Properties Company Initiator/amidine complexes, systems comprising the complexes, and polymerized compositions made therewith
US6806330B1 (en) * 1999-12-17 2004-10-19 Dow Global Technologies Inc. Amine organoborane complex polymerization initiators and polymerizable compositions
WO2002008303A1 (en) * 2000-07-20 2002-01-31 The Dow Chemical Company Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
EP1201722A1 (en) * 2000-10-23 2002-05-02 Loctite (R & D) Limited Polymerisation initiators, polymerisable compositions, and uses thereof
US6602958B2 (en) 2001-07-10 2003-08-05 Ips Corporation Adhesives for bonding composites
US6740716B2 (en) * 2001-10-30 2004-05-25 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
US6762260B2 (en) 2002-03-05 2004-07-13 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
WO2003089536A2 (en) * 2002-04-19 2003-10-30 Loctite (R & D) Limited Polymerisation initiators based on ammonium tetraalkyl boranes, polymerisable compositions, and uses thereof for bonding low surface energy substrates
US6867271B1 (en) 2002-06-24 2005-03-15 Henkel Corporation Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces
US6777512B1 (en) 2003-02-28 2004-08-17 Dow Global Technologies Inc. Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components
US20040242817A1 (en) 2003-05-29 2004-12-02 Lord Corporation Internally coordinated organoboranes
KR20060081656A (en) * 2003-06-09 2006-07-13 다우 글로벌 테크놀로지스 인크. Stabilized organoborane polymerization initiators and polymerizable compositions
CN1835992B (en) * 2003-08-13 2010-10-06 陶氏环球技术公司 Method for joining substrates and objects
JP2007515547A (en) 2003-12-22 2007-06-14 ダウ グローバル テクノロジーズ インコーポレイティド Accelerated organoborane amine complex-initiated polymerizable composition
CN100519567C (en) * 2004-02-23 2009-07-29 陶氏环球技术公司 Aqueous-based adhesive for bonding low surface energy substrates
BRPI0617975A2 (en) * 2005-10-07 2011-08-09 Dow Global Tchnologies Inc starch borate compound

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6630555B2 (en) * 2001-11-06 2003-10-07 Lord Corporation Internally blocked organoborate initiators and adhesives therefrom
US6841635B2 (en) * 2001-11-06 2005-01-11 Lord Corporation Internally blocked organoborate initiators and adhesives therefrom

Also Published As

Publication number Publication date
EP1934264A2 (en) 2008-06-25
BRPI0617975A2 (en) 2011-08-09
CN101278023A (en) 2008-10-01
US7816562B2 (en) 2010-10-19
US20070079931A1 (en) 2007-04-12
JP2009531468A (en) 2009-09-03
EP1934296A1 (en) 2008-06-25
CA2624322A1 (en) 2007-04-19
US20070083051A1 (en) 2007-04-12
BRPI0617591A2 (en) 2011-08-02
KR20080053486A (en) 2008-06-13
CN101501043A (en) 2009-08-05
WO2007044735A2 (en) 2007-04-19
KR20080053348A (en) 2008-06-12
RU2008118139A (en) 2009-11-20
CA2625023A1 (en) 2007-04-19
RU2008116620A (en) 2009-11-20
US7737241B2 (en) 2010-06-15
JP2009511502A (en) 2009-03-19
WO2007044730A1 (en) 2007-04-19

Similar Documents

Publication Publication Date Title
WO2007044735A3 (en) Amido-organoborate initiator systems
WO2007003956A3 (en) Eutectic mixtures based upon multivalent metal ions
MX2020000352A (en) Dual mode radiotracer and -therapeutics.
MY142423A (en) Substituted aminoacetyl pyrrolidine compounds which are dipeptidyl peptidase iv inhibitors, and pharmaceutical compositions containing them
JO3795B1 (en) Formulation comprising metformin and vildagliptin
WO2004064755A3 (en) Methods for inhibiting proteasome
TW200643097A (en) Adhesive compositions comprising mixtures of block copolymers
BR0016770B1 (en) organoborane / amine complex and polymerizable composition.
WO2008012532A3 (en) : pyridine-3-carboxamide compounds and their use for inhibiting 11-beta-hydroxysteroid dehydrogenase
WO2004072168A3 (en) Resin compositions
WO2008062437A3 (en) Process for the preparation of sevelamer hydrochloride and formulation thereof
WO2007001937A3 (en) Photocurable elastomer compositions
WO2009026179A3 (en) Antiinfective proanthocyanidin compounds and methods of use thereof
MXPA05008368A (en) Hiv inhibiting 1,2,4-triazines.
WO2008064959A3 (en) Metal compounds for use as initiators
WO2007142919A3 (en) Compositions having a high antiviral effeicacy
TW200619259A (en) Epoxy resin, epoxy resin composition and cured product thereof
TWI349008B (en) Ionic liquids having fluoroalkyltrifluoroborate anions
MY153920A (en) Aqueous coating composition
DE60220831D1 (en) Beta-Ketone Compounds Containing Initiator Systems And Compositions Produced Therewith
WO2009030604A3 (en) Flame-retardant additives
WO2008013660A3 (en) Inhibitors of advanced glycation end products
SG135166A1 (en) Polymerization inhibitor for stabilizing olefinically unsaturated monomers
WO2007068728A3 (en) N-substituted pyrrolopyridinones active as kinase inhibitors
WO2010038251A8 (en) Bifluorenylidene derivatives, their preparation and uses thereof

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200680036700.X

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2006825707

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2008534776

Country of ref document: JP

Kind code of ref document: A

Ref document number: 2625023

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: MX/a/2008/004512

Country of ref document: MX

Ref document number: 1723/CHENP/2008

Country of ref document: IN

Ref document number: 1020087008145

Country of ref document: KR

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2008116620

Country of ref document: RU

ENP Entry into the national phase

Ref document number: PI0617975

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20080403