WO2007046124A1 - Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices - Google Patents
Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices Download PDFInfo
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- WO2007046124A1 WO2007046124A1 PCT/IT2006/000742 IT2006000742W WO2007046124A1 WO 2007046124 A1 WO2007046124 A1 WO 2007046124A1 IT 2006000742 W IT2006000742 W IT 2006000742W WO 2007046124 A1 WO2007046124 A1 WO 2007046124A1
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- WIPO (PCT)
- Prior art keywords
- layer
- embossing
- protuberances
- rollers
- drying
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/006—Making patterned paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/14—Making cellulose wadding, filter or blotting paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/14—Making cellulose wadding, filter or blotting paper
- D21F11/145—Making cellulose wadding, filter or blotting paper including a through-drying process
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
- Y10T156/1039—Surface deformation only of sandwich or lamina [e.g., embossed panels]
Definitions
- the present invention relates in general to the production of so-called tissue paper, in some cases also referred to as "crepe paper", for the formation of rolls of toilet paper, paper wipes, and paper for similar uses. More in general, the invention relates to the production of a web-like fiber material, especially papermaking fibers or cellulose fibers, with a high capacity of 0 absorption and a high degree of softness. State of the art
- the fiber web remains adherent to the roller and is detached therefrom using a doctor blade, which impresses a corrugation or crinkling on the paper during detachment thereof from the roller.
- This corrugation is responsible for an increase in the volume or bulk of the paper 5 and its elasticity, which is prevalently in the working direction of the machine or machine direction, i.e., the direction parallel to the direction of feed of the web through the machine.
- a headbox which forms, on a forming fabric, a layer of a mixture of papermaking fibers and water, with a very low percentage of dry content, in the range of 0.5 wt% to 0.8 wt%.
- the percentage of water is progressively reduced until a web is formed with a dry content of fibers in the range of 48-52 wt%, according to the type of system, at the moment in which the web is transferred from a fabric or felt to the rotating surface of the Yankee roller with the aid of a press, and here the humidity of the web is further reduced, until a percentage of fiber of 95-98 wt% is obtained.
- the web is at this point considered dry and ready for the next step; consequently, it is detached by the creping blade and then wound on a reel, as mentioned above.
- some systems such as for example the one described in the U.S. patent No.
- a corrugation in the web is obtained by passing the web still having a high content of humidity from one forming fabric, which moves at a first speed of advance, to a second forming fabric, which moves at a second speed of advance, lower than the first speed of advance.
- the deceleration undergone by the web causes creping and corrugation thereof.
- a suction system set appropriately with respect to the forming fabrics withholds the paper material being formed to facilitate the generation of crinkles in the web. Examples of systems based upon this technology are described in the U.S. patents Nos. 4,072,557 and 4,440,597.
- the U.S. patent No. 4,551 ,199 describes a method and a system in which the web is transferred from a faster fabric to a slower fabric and in which the slower fabric has a particular surface mesh to bring about corrugation of the web. Similar systems and methods of this type are described in the U.S. patents No. 5,607,551 ; 5,656,132; 5,667,636; 5,672,248; 5,746,887; 5,772,845; 5,888,347; and 6,171 ,442.
- the TAD systems are also affected by drawbacks which render their use as an alternative to the drying system with the Yankee drier not always practicable or desirable.
- the costs in terms of energy consumption are higher, on account of the need to generate enormous rates of flow of hot air that traverses the web to dry it.
- the web thus formed is thicker than the one obtained with the creping blade and can present through holes, due to the use of the flow of air that traverses the web to dry it.
- the use of a Yankee roller and, downstream thereof, of a moistening section and a wet-embossing section involves numerous drawbacks.
- the main drawbacks are the following: the problems deriving from the risks of tearing of the web on account of the use of a creping blade are not solved; the production line is complex, costly and cumbersome; and the humidification of the web involves high consumption levels in terms of energy and water.
- U.S. patent No. 4,849,054 is a system in which the web of cellulose fibers with high water content is transferred along its path to a forming fabric that has a surface texture given by the mesh of the fabric that forms it, which imparts an embossing on the web.
- This is due to the fact that the web, with high water content and hence limited strength, comes to rest on the depressions formed between the threads defining the structure of the fabric. Embossing is facilitated by the use of a suction system set on the side of the fabric opposite to the side on which the web comes to rest.
- the web embossed using this technique is subsequently dried on a Yankee roller and creped with a creping blade that detaches it from the drying roller.
- the system is thus characterized by the drawbacks described above, which are linked to the use of creping blades.
- this technique involves application on the Yankee roller of a mixture of adhesive agents and of detaching agents in order to enable, on the one hand, proper adhesion of the web to the roller and, on the other, ease of detachment without any risk of tearing and without the use of mechanical members such as the creping blade.
- the use of this mixture of products involves drawbacks in terms of consumption and of operating costs and, on the other, constitutes a critical aspect of the process, in so far as the products applied must in effect perform two mutually contrasting actions, with the consequent need to select carefully the products of the mixture and to balance them in a precise and accurate way. Described in the documents No.
- US-2002/0060034, US-2002/0124978, and US-2003/0116292 are systems and methods for embossing a layer of tissue paper in conditions of high humidity content. These methods and devices envisage entraining the layer of cellulose fibers around a drying drum provided with protuberances, which impress an embossing pattern on the paper during drying. The paper is pressed against the drying drum provided with protuberances via a fabric or felt set behind which is a pressure roller, or else directly via a pressure roller made of compliant material.
- a general object of the present invention is a method and a system for the production of tissue paper, which will overcome entirely or in part one or more of the aforesaid drawbacks typical of traditional systems and methods.
- the object of an improved embodiment of the invention is a method and a system with which a tissue paper can be obtained with characteristics similar to or even better than those of the paper creped using a creping blade, but without the use of the creping blade and hence avoiding the drawbacks linked to the latter, in the first place the risk of tearing of the web during its detachment from the drying cylinder.
- a further object is to increase the productivity of the continuous machine, at the same time reducing the amount of energy required for drying the web produced and the amount of fibers required.
- the invention relates to a method for the production of a web of tissue paper, comprising the steps of: -depositing a layer of an aqueous suspension of papermaking fibers on a forming fabric;
- the drying system can comprise a Yankee cylinder or the like.
- a first value of dry content of between 20 wt% and 90 wt% and preferably between 40 wt% and
- the invention envisages creping the layer of papermaking fibers to bestow on the web the desired elasticity, in particular via an embossing process based upon a particular pattern or texture that has the capacity of creating a dense series of elastic profiles when the web being formed is still moist and of completing drying of said web in a subsequent step so as to create in the material a "memory", i.e., a tendency to return into its initial configuration if subjected to a tensile stress and then released, instead of creping the material that has reached complete drying using a blade or doctor knife that works in combination with a drying cylinder, such as, for example, a so-called Yankee drier, to detach the web when completely dry and create thereon the micro-crinkles that bestow elasticity on the web.
- a "memory” i.e., a tendency to return into its initial configuration if subjected to a tensile stress and then released
- the layer of papermaking fibers is in any case subjected to an operation of drying and of creping using a detaching blade co-operating with a Yankee cylinder.
- the corrugation on the web of fibers is imparted substantially only as a result of an embossing between at least one pair of embossing cylinders or rollers and has two purposes: the first and most important purpose is to bestow elasticity on the paper without the use of a creping blade, and the second purpose is to impart a thickness on the web itself. Drying after embossing can be achieved using a drying cylinder set downstream of the embossing rollers, or else using a set of return idlers, around which the layer of papermaking fibers is entrained.
- drying can be obtained entirely or partially by entraining the embossed web around a set of rollers inside an infrared or microwave oven or else via the use of embossing rollers, one of which is heated. All these systems can also be used in combination with a hot-air hood, which contributes to reducing the drying time, working also on the second face of the web.
- the above or other equivalent drying systems can be combined with one another.
- the reduction in the water content of the layer of papermaking fibers prior to embossing thereon is carried out until a dry content is reached, i.e., a weight percentage of fibers with respect to the total weight of the layer, which bestows, on the layer itself a consistency sufficient to withstand the mechanical operation of embossing.
- At least a first one of said embossing rollers is provided with protuberances
- at least a second one of said embossing rollers is provided with cavities, in which said protuberances of the first embossing roller penetrate.
- the two rollers have corresponding incisions, which define complementary protuberances and cavities, preferably in a number comprised between 20 and 120 per cm 2 , so that the two rollers co-operate with one another with the protuberances of one which mesh with the protuberances of the other; i.e., they penetrate into the cavities of the other.
- the two rollers can be identical to one another.
- the web or layer of papermaking fibers still moistened is passed between the protuberances of the first roller that mesh with the cavities formed by the protuberances of the second roller and vice versa, bestowing on the web or layer a deformation that generates thereon the desired elasticity and increases the total final thickness thereof.
- the embossing rollers are kept at a distance such that the protuberances of the first embossing roller and the cavities of the second embossing roller are not in mutual contact, but rather preferably are kept at a distance apart equal to or slightly greater than the thickness of the layer of papermaking fibers.
- the protuberances of the first embossing roller have a base with a first dimension in the direction of advance of the layer (referred to also as machine direction) smaller than a second dimension in the transverse direction or cross machine direction.
- the protuberances can have a pyramidal shape with a quadrangular base, in particular, preferably, rhomboidal with more or less rounded edges, with the minor diagonal oriented according to the direction of advance of the layer and the major diagonal oriented according to a transverse direction.
- the invention provides a method for the production of tissue paper, comprising the steps of: depositing a layer of an aqueous suspension of papermaking fibers on at least one forming fabric; reducing the water content in said layer, until the amount in weight of fibers in said layer is brought up to a first value; wet-embossing said layer in a nip between a pair of embossing rollers; - drying said layer to form a web of tissue paper and in which, after embossing, said layer is calendered.
- the invention relates to a system for the production of tissue paper, comprising: at least a headbox; at least a forming fabric, on which said headbox distributes a layer of an aqueous suspension of papermaking fibers; a system for removal of water from said layer to bring it to a first degree of dryness, said system comprising means for exerting a pressure, i.e., a squeezing, of the layer in order to extract at least part of the water contained therein; an embossing assembly comprising a first embossing roller and a second embossing roller, between which there passes the layer prior to total removal of water; and a drying system for drying the embossed layer of papermaking fibers.
- the invention envisages a system for the production of tissue paper, comprising: at least a headbox; at least a forming fabric, on which said headbox distributes a layer of an aqueous suspension of papermaking fibers; a system for removal of water from said layer to bring it to a first degree of dryness; an embossing assembly comprising a first embossing roller and a second embossing roller, between which there passes said layer prior to total drying; a drying system for removing water from the embossed layer; and a calender set downstream of the embossing assembly and preferably downstream of the drying system.
- Figures 1A, 1 B, and 1 C are three schematic illustrations of a system according to the invention.
- Figure 2 shows an enlargement of the nip between the two embossing rollers in a section perpendicular to the axis of the rollers themselves;
- Figure 3 is a cross-sectional view of the nip between the two embossing rollers according to a plane containing the axes of the rollers;
- Figure 4 is a plan view of a protuberance of one of the embossing rollers;
- Figure 5 is a side view of a protuberance of an embossing roller
- Figures 6 and 7 are enlarged schematic cross-sectional views of the paper obtained with the process according to the invention in a resting configuration and in a condition of elastic deformation that is assumed when the paper is subjected to a tensile force;
- Figure 8 is a schematic perspective view of a portion of paper obtained according to the invention.
- Figure 9 shows an enlarged photograph of a portion of paper obtained with a process according to the invention but with protuberances of the embossing rollers having a profile shaped like a truncated pyramid or a pyramid with a base that is square, instead of rhomboidal;
- Figure 10 shows a schematic enlargement of a section of paper obtained with a calendering step following upon embossing and, preferably, drying.
- Figure 1A is a schematic illustration of the arrangement of a possible system for production of tissue paper according to the invention.
- the reference number 1 designates as a whole a headbox that forms a layer of a suspension or a mixture of papermaking fibers and water (with possible further additives known to those skilled in the art) that is fed between two forming fabrics designated by 3 and 5.
- the direction of advance of the two forming fabrics 3 and 5 is indicated by the arrows in Figure 1.
- a suction system 6 which carries out drainage of part of the water contained in the mixture or suspension forming the layer S.
- the layer S which is formed between the fabrics 3 and 5 and from which part of the water has been drained via the suction system 6, is transferred to at least one conveying felt 7, which passes through at least one pair of pressure rollers, accompanying the layer of cellulose fibers.
- three pairs of pressure rollers 8A, 8B, 8C are provided, even though this is not binding in so far as the reduction in the water content can be obtained also with other means, such as, for example, vacuum systems or the like.
- the layer By passing in the nip of one or more pairs of rollers, the layer is squeezed and a considerable part of its own residual water content is eliminated by squeezing, i.e., by pressure. It is not excluded to pass between the pressure rollers a pair of felts or fabrics set alongside one another, set between which is the layer to be squeezed.
- a layer is obtained with a dry content for example equal to or higher than 20 wt%, preferably between 20 wt% and 90 wt%, more preferably between 40 wt% and 80 wt%, and more preferably still between 50 wt% and 70 wt%, for example around 60 wt% of dry content with respect to the total weight of the wet layer.
- This layer has a consistency that is sufficient for being fed to an embossing assembly 17 and there being subjected to a wet embossing.
- the embossing assembly 17 comprises a first embossing roller 19 and a second embossing roller 21 , which define between them an embossing nip, through which there is fed the layer S of papermaking fibers, which has been previously partially dried on the drying roller 9.
- the two embossing rollers 19, 21 are provided with protuberances 23 and cavities 25 corresponding to one another, i.e., which mesh with one another.
- Said protuberances and cavities can be obtained by etching using a machining system, by plastic deformation, chemical etching, or by any other known system.
- the surfaces of the two rollers can be complementary, with the protuberances of one corresponding to the cavities or incisions of the other.
- the two cylinders will be both obtained using a process of etching that generates protuberances having the shape of a truncated pyramid or a pyramid.
- the cavities are represented by the empty spaces present within each set of four protuberances.
- the distance between the centers of the embossing rollers 19, 21 is such that the two rollers do not touch one another even in the position corresponding to the plane of lie of the respective axes.
- the layer S is not squeezed and is not stressed mechanically by compression as occurs, instead, in dry embossing of the paper when a cylinder provided with protuberances is pressed against a roller coated with smooth rubber, the surface of which is deformed by the embossing pressure.
- the protuberances 23 can present a pyramidal shape with rhomboidal base, the minor diagonal of which is designated by i and the major diagonal by D.
- the cavities 25 may present as incisions of a corresponding shape and enable penetration therein of the pyramidal protuberances.
- the protuberances and the corresponding cavities 23, 25 are oriented in such a way that the major diagonal of the respective bases is parallel to the axes of rotation of the rollers 19, 21 , i.e., oriented in a transverse direction with respect to the direction of advance of the layer S.
- the minor diagonal is oriented in the direction of advance of the layer S, referred to also as machine direction.
- a second drying drum or roller 27 entrained around which is the embossed layer S of papermaking fibers.
- the drum or roller 27 may be a Yankee roller, a Honeycomb roller, a TAD roller or any other equivalent system.
- drying systems comprising a plurality of rollers between which the wet- embossed layer S is entrained and dried inside a microwave oven or else by heating said rollers.
- the layer S At output from of the drying roller 27 (or equivalent drying system) the layer S by now dried, which forms a web of tissue paper ready for the subsequent conversion, is wound to form a reel B.
- the drying process downstream of the embossing process stabilizes the deformation obtained in the embossing step so that the paper maintains stably in a resting condition the corrugation imparted on the paper by the protuberances 23 in combination with the cavities 25 of the embossing rollers 21 and 19.
- part of the drying operation (or even the entire drying operation) can be obtained by heating one or the other or both of the embossing rollers 19 and 21 instead of by drying means set downstream of the embossing assembly.
- Figures 6 and 7 are schematic illustrations of a longitudinal section of the paper obtained with the system and method described herein. Said section has an alternation of protuberances and cavities corresponding to the distribution of the protuberances and cavities 23, 25 of the embossing rollers 19, 21. In this way, the apparent thickness SA of the paper is much greater than the actual thickness SR of the fiber layer that forms it.
- the finished product although it is a tissue paper that has all the characteristics of softness, absorption capability, and elasticity of a paper obtained by means of a system that envisages creping using a blade, is not obtained with the use of a creping blade.
- the consequence is elimination of all the drawbacks outlined previously, which characterize the use of the creping blade. Since it is not necessary to use a creping blade co-operating with a
- Yankee cylinder for creping the paper it is possible to add to the mixture of papermaking fibers a larger amount of softening agents, which have as side effect that of facilitating detachment from the Yankee cylinder without using a blade, enabling the production of softer papers with lower risks of tearing.
- the above is possible also because, since the fibers are pressed together, there are created between them stronger bonds than with a traditional process, thus generating a web that requires a lower amount of fibers to obtain similar mechanical characteristics.
- embossing is carried out between two rollers that are not pressed against one another, but rather are kept with the respective surfaces at a certain distance apart, the fibers are not compacted, and the paper maintains its characteristics of softness and absorbency.
- the amount of pulp or aqueous suspension of papermaking fibers that the headbox can deposit on the forming fabric must take into account the fact that, in the creping step, the thickness of the paper is increased.
- the thickness (and hence the amount of pulp) that the headbox can deposit on the forming fabric is in any case smaller than the one that the paper at output from the machine must possess. This involves a reduction in the amount of material per unit time that the headbox can supply and hence, in practice, a limitation of the overall productivity of the continuous machine.
- the headbox can generate paper at a certain rate, for example 1000 m/min, this rate will be reduced to 800-900 m/min at the end of the process as a result of creping, which, by increasing the apparent thickness, reduces the dimension of the web corresponding to the direction of advance.
- the paper i.e., the partially dried layer of fibers
- the thickness of the layer S and hence the amount of material supplied by the headbox given the same final characteristics of the web on the reel must be greater than the desired final thickness, since the effect of thickening caused by traditional creping is replaced by the thickening, which is even greater, and the lengthening generated by embossing.
- the amount of aqueous suspension or mixture of papermaking fibers that can be supplied per unit time by the headbox is higher than what may be achieved in traditional continuous machines. In other words, if the headbox can generate paper at a rate of
- this rate will rise to 1050-1100 m/min at the end of the process as a result of the lengthening impressed by embossing, which increases the dimension of the web corresponding to the direction of advance.
- the productivity of the continuous machine is given by the volume of pulp that can be supplied in time given the same rate.
- a further factor which in actual fact increases the productivity of the machine is represented by the fact that embossing increases the length of the layer or web of paper, so that the speed of the layer S at output from the embossing assembly 17 and consequently the speed of winding on the reel B is greater than the speed at input to the embosser 17 and, hence, greater than the rate at which the layer S is formed by the headbox.
- the winding rate is lower than the production rate on account of the reduction in length of the layer of paper caused by the creping blade.
- a further important advantage of the invention lies in the fact that, given the final characteristics of the web obtained via embossing, it is possible to reduce the water content prior to final drying to lower levels than in traditional machines: this involves a lower requirement of energy to be used to complete total drying of the web.
- the pressure previously exerted for squeezing out the water leads to the creation of hydrogen bonds, which are much more stable, and to a merging between the fibers, which increases the strength of the web obtained given the same substance, or else enables reduction in the substance albeit preserving good mechanical characteristics, with consequent saving in papermaking fibers.
- Figure 8 is a schematic perspective view of the embossed paper web. Indicated in the figure are the bases of the pyramidal protuberances with square base on the primitive diameter of the roller and the lines of section according to the machine direction (MD), i.e., the direction of advance, and according to the cross machine direction (CMD), which is orthogonal to the machine direction.
- MD machine direction
- CMD cross machine direction
- Figure 8 is purely schematic and that, in actual fact, the protuberances of the embossed web will be less faceted and may even present a round section, an elliptical section, or a section of some other shape.
- Figure 9 illustrates, by way of example, a macro-photograph of a portion of web produced according to the invention, with an embossing profile constituted by protuberances having the shape of a truncated pyramid with a base that is square instead of having an elongated rhomboidal base as illustrated in the foregoing figures.
- FIG. 1 B A modified embodiment of the system according to the invention is shown in Figure 1 B.
- the scheme of the system of Figure 1 ' B differs from that of Figure 1A on account of the presence of a calender 10, which, in this example of embodiment, is set downstream of the drying drum 27.
- the calender 10 comprises two or more rollers pressed against one another or else kept at a limited distance from one another in order to calender the embossed layer S of tissue paper and flatten the protuberances that have been formed thereon by the embossing rollers 19, 20.
- - Figure 10 is a schematic cross section similar to that of Figure 6. It may be noted that, on account of calendering, the paper has been brought down to a smaller thickness than that obtained after embossing, with flattening of the protuberances generated by the embossing rollers.
- Calendering of the final web can be obtained even via pressure of just one cylinder, made of steel or coated with a resilient material, which cooperates directly with the Yankee drier or cylinder by flattening the web of paper before this is detached from the Yankee cylinder itself, in the case where the machine is made using this drying device.
- Calendering bestows upon the surface of the paper a better feel. Calendering can be used also in combination with a different system for partial drying of the layer S prior to wet embossing, for example using a steel Yankee cylinder as drying drum, on which the layer S is dried partially and is then wet embossed.
- Figure 1C shows a modified embodiment, in which the pressure for expelling part of the water content from the layer of aqueous mixture of papermaking fibers prior to embossing is obtained with the aid of two felts, designated by 7 and 7A, which pass through the nips defined by the pairs of pressure rollers 8A, 8B, 8C.
- the felts 7, 7A accompany the layer of fibers that is set between them through the squeezing nips.
- the felt 7A can extend as far as in the proximity of the embossing assembly 17.
- two fabrics can be used, or else a felt and a fabric instead of two felts 7, 7A.
- the remaining parts of the system of Figure 1C are the same as those of Figure 1B.
- the protuberances or projections and the cavities of the two embossing rollers can have a continuous linear shape, which extends parallel to the axis of the rollers or at an angle with respect thereto, possibly with a more or less marked corrugation.
- This provides an embossing in the form of corrugation or fluting, which is more closely similar to the creping traditionally obtained with a creping blade co-operating with a Yankee . drier.
- the density of the longitudinal protuberances can be, for example, between 20 and 100 protuberances per cm.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008536208A JP4961430B2 (en) | 2005-10-20 | 2006-10-17 | Method and apparatus for producing tissue paper, and further web of tissue paper obtained using this method and apparatus |
EP06810031A EP1937894A1 (en) | 2005-10-20 | 2006-10-17 | Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices |
BRPI0617518-0A BRPI0617518A2 (en) | 2005-10-20 | 2006-10-17 | Methods and devices for the production of sanitary paper and sanitary paper weft using such methods and devices |
US12/090,695 US8142614B2 (en) | 2005-10-20 | 2006-10-17 | Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices |
US13/371,572 US8597469B2 (en) | 2005-10-20 | 2012-02-13 | Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000218A ITFI20050218A1 (en) | 2005-10-20 | 2005-10-20 | IMPROVEMENT OF METHODS AND DEVICES FOR THE PRODUCTION OF TISSUE PAPERS AND PAPER VEIL FROM THESE DERIVATIVES |
ITFI2005A000218 | 2005-10-20 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/090,695 A-371-Of-International US8142614B2 (en) | 2005-10-20 | 2006-10-17 | Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices |
US13/371,572 Division US8597469B2 (en) | 2005-10-20 | 2012-02-13 | Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices |
Publications (1)
Publication Number | Publication Date |
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WO2007046124A1 true WO2007046124A1 (en) | 2007-04-26 |
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ID=37719220
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/IT2006/000742 WO2007046124A1 (en) | 2005-10-20 | 2006-10-17 | Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices |
Country Status (8)
Country | Link |
---|---|
US (2) | US8142614B2 (en) |
EP (1) | EP1937894A1 (en) |
JP (1) | JP4961430B2 (en) |
KR (1) | KR20080068083A (en) |
CN (1) | CN101313108A (en) |
BR (1) | BRPI0617518A2 (en) |
IT (1) | ITFI20050218A1 (en) |
WO (1) | WO2007046124A1 (en) |
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US8012309B2 (en) | 2007-01-12 | 2011-09-06 | Cascades Canada Ulc | Method of making wet embossed paperboard |
EP2425056A1 (en) | 2009-04-30 | 2012-03-07 | Delfortgroup AG | Arrangement and method for processing a paper web, in particular a cigarette paper web |
US8142613B2 (en) * | 2004-04-29 | 2012-03-27 | A. Celli Paper S.P.A. | Method and device for the production of tissue paper |
US8142614B2 (en) * | 2005-10-20 | 2012-03-27 | A. Celli Paper S.P.A. | Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices |
US10927502B2 (en) | 2016-02-08 | 2021-02-23 | Gpcp Ip Holdings Llc | Molding roll for making paper products |
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US11136719B2 (en) | 2016-02-08 | 2021-10-05 | Gpcp Ip Holdings Llc | Methods of making paper products using a molding roll |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006062237A1 (en) * | 2006-12-22 | 2008-06-26 | Voith Patent Gmbh | Machine for producing a fibrous web |
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US10280567B2 (en) | 2016-05-09 | 2019-05-07 | Kimberly-Clark Worldwide, Inc. | Texture subtractive patterning |
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Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0625610A1 (en) * | 1993-05-21 | 1994-11-23 | Kimberly-Clark Corporation | A method of making a tissue product |
US5702571A (en) * | 1994-02-18 | 1997-12-30 | Kimberly-Clark Worldwide, Inc. | Soft high bulk tissue |
WO2000020683A1 (en) * | 1998-10-01 | 2000-04-13 | Sca Hygiene Products Ab | Method of producing a paper having a three-dimensional pattern |
US20020060008A1 (en) * | 1998-10-01 | 2002-05-23 | Holger Hollmark | Method of producing a paper having a three-dimensional pattern |
US6488816B1 (en) * | 1999-06-17 | 2002-12-03 | Metso Paper Karlstad Ab | Drying section for drying a paper web in a papermaking machine |
US20030021953A1 (en) * | 2000-11-24 | 2003-01-30 | Pierre Graff | Absorbent creped paper sheet comprising a background pattern and a main decorative pattern, and embossing roll and method for making such a sheet |
US6524683B1 (en) * | 1988-01-13 | 2003-02-25 | Georgia-Pacific France | Sheet of embossed absorbent paper, and a method and device for producing same |
US20030116292A1 (en) * | 2001-12-20 | 2003-06-26 | Sca Hygiene Products Ab | Multi-layer paper web and a method of forming it |
WO2005106116A1 (en) * | 2004-04-29 | 2005-11-10 | A. Celli Paper S.P.A. | A method and device for the production of tissue paper |
Family Cites Families (67)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4072557A (en) | 1974-12-23 | 1978-02-07 | J. M. Voith Gmbh | Method and apparatus for shrinking a travelling web of fibrous material |
US4127637A (en) * | 1975-03-13 | 1978-11-28 | Scott Paper Co. | Method of manufacturing a dry-formed, embossed adhesively bonded, nonwoven fibrous sheet |
FI770610A (en) * | 1977-02-24 | 1978-08-25 | Valmet Oy | TISSUEPAPPERSMASKIN |
US4356059A (en) | 1981-11-16 | 1982-10-26 | Crown Zellerbach Corporation | High bulk papermaking system |
US4440597A (en) | 1982-03-15 | 1984-04-03 | The Procter & Gamble Company | Wet-microcontracted paper and concomitant process |
US4551199A (en) | 1982-07-01 | 1985-11-05 | Crown Zellerbach Corporation | Apparatus and process for treating web material |
CA1243233A (en) | 1982-12-20 | 1988-10-18 | Robert N. Bauernfeind | Embossing process and product |
US4849054A (en) | 1985-12-04 | 1989-07-18 | James River-Norwalk, Inc. | High bulk, embossed fiber sheet material and apparatus and method of manufacturing the same |
US5223092A (en) * | 1988-04-05 | 1993-06-29 | James River Corporation | Fibrous paper cover stock with textured surface pattern and method of manufacturing the same |
US5048589A (en) | 1988-05-18 | 1991-09-17 | Kimberly-Clark Corporation | Non-creped hand or wiper towel |
ZA893657B (en) | 1988-05-18 | 1990-01-31 | Kimberly Clark Co | Hand or wiper towel |
US5266250A (en) | 1990-05-09 | 1993-11-30 | Kroyer K K K | Method of modifying cellulosic wood fibers and using said fibers for producing fibrous products |
US5126015A (en) * | 1990-12-12 | 1992-06-30 | James River Corporation Of Virginia | Method for simultaneously drying and imprinting moist fibrous webs |
US5356364A (en) * | 1991-02-22 | 1994-10-18 | Kimberly-Clark Corporation | Method for embossing webs |
JPH06143466A (en) | 1992-11-12 | 1994-05-24 | Yuri Roll Kk | Emboss-processing device |
US5667636A (en) | 1993-03-24 | 1997-09-16 | Kimberly-Clark Worldwide, Inc. | Method for making smooth uncreped throughdried sheets |
US5607551A (en) | 1993-06-24 | 1997-03-04 | Kimberly-Clark Corporation | Soft tissue |
CA2142805C (en) | 1994-04-12 | 1999-06-01 | Greg Arthur Wendt | Method of making soft tissue products |
CA2134594A1 (en) | 1994-04-12 | 1995-10-13 | Kimberly-Clark Worldwide, Inc. | Method for making soft tissue products |
US5690788A (en) | 1994-10-11 | 1997-11-25 | James River Corporation Of Virginia | Biaxially undulatory tissue and creping process using undulatory blade |
US5609728A (en) | 1995-03-24 | 1997-03-11 | James River Corporation Of Virginia | Method and apparatus for transferring a web from a forming wire to a transferring felt in a paper making machine |
US5693403A (en) * | 1995-03-27 | 1997-12-02 | Kimberly-Clark Worldwide, Inc. | Embossing with reduced element height |
JP2959429B2 (en) * | 1995-03-29 | 1999-10-06 | 特種製紙株式会社 | Method of manufacturing embossed paper |
US6083346A (en) | 1996-05-14 | 2000-07-04 | Kimberly-Clark Worldwide, Inc. | Method of dewatering wet web using an integrally sealed air press |
US5830321A (en) | 1997-01-29 | 1998-11-03 | Kimberly-Clark Worldwide, Inc. | Method for improved rush transfer to produce high bulk without macrofolds |
US5851353A (en) * | 1997-04-14 | 1998-12-22 | Kimberly-Clark Worldwide, Inc. | Method for wet web molding and drying |
US5904812A (en) * | 1997-06-16 | 1999-05-18 | Kimberly-Clark Worldwide, Inc. | Calendered and embossed tissue products |
JP2938023B2 (en) * | 1997-07-16 | 1999-08-23 | 日清紡績株式会社 | How to make patterned paper |
US6468392B2 (en) * | 1997-09-26 | 2002-10-22 | Fort James Corporation | Soft chemi-mechanically embossed absorbent paper product and method of making same |
US6187137B1 (en) | 1997-10-31 | 2001-02-13 | Kimberly-Clark Worldwide, Inc. | Method of producing low density resilient webs |
CN1180932C (en) * | 1998-03-02 | 2004-12-22 | 法比奥·泼尼股份公司 | Method and device for producing embossed web material and product made in this way |
US6077590A (en) | 1998-04-15 | 2000-06-20 | Kimberly-Clark Worldwide, Inc. | High bulk paper towels |
TW580530B (en) | 1998-08-06 | 2004-03-21 | Kimberly Clark Co | Roll of tissue sheets having improved properties |
JP2000073299A (en) * | 1998-08-21 | 2000-03-07 | Nisshinbo Ind Inc | Production of pattern paper |
SE513917C2 (en) | 1998-10-01 | 2000-11-27 | Sca Hygiene Prod Ab | Method of making an extensible paper with a three-dimensional pattern and paper made according to the method |
SE512947C2 (en) | 1998-10-01 | 2000-06-12 | Sca Research Ab | Method of making a paper with a three-dimensional pattern |
SE512973C2 (en) * | 1998-10-01 | 2000-06-12 | Sca Research Ab | Method of producing a wet-laid thermobonded web-shaped fiber-based material and material prepared according to the method |
SE512946C2 (en) * | 1998-10-01 | 2000-06-12 | Sca Research Ab | Method of making a paper with a three-dimensional pattern and paper made with the method |
US6398909B1 (en) * | 1999-06-17 | 2002-06-04 | Valmet-Karlstad Aktiebolag | Method and apparatus for imprinting, drying, and reeling a fibrous web |
IT1307887B1 (en) * | 1999-06-18 | 2001-11-19 | Perini Fabio Spa | EMBOSSING METHOD AND DEVICE FOR THE PRODUCTION OF MULTI-LEVEL STRUCTURAL MATERIALS, AND PRODUCT SO OBTAINED. |
US6455129B1 (en) | 1999-11-12 | 2002-09-24 | Fort James Corporation | Single-ply embossed absorbent paper products |
US6348131B1 (en) | 1999-11-12 | 2002-02-19 | Fort James Corporation | Multi-ply embossed absorbent paper products |
US7037406B2 (en) * | 1999-11-12 | 2006-05-02 | Fort James Corporation | Cross-machine direction embossing of absorbent paper products having an undulatory structure including ridges extending in the machine direction |
IT1314877B1 (en) * | 2000-11-22 | 2003-01-16 | Perini Fabio Spa | METHOD AND DEVICE FOR THE PRODUCTION OF A MULTIPLE-SHEET PAPER MATERIAL AND PRODUCT SO OBTAINED |
US20020092633A1 (en) * | 2000-12-19 | 2002-07-18 | Janerik Odhe | Method for producing an extensible paper having a three-dimensional pattern |
US6585861B2 (en) * | 2000-12-19 | 2003-07-01 | Metso Paper Karlstad Ab | Device for producing an extensible paper having a three-dimensional pattern |
US20020116519A1 (en) | 2001-01-29 | 2002-08-22 | Enjoyweb, Inc. | Method, apparatus and system for transmitting compressed digital media in a secured manner |
ATE294061T1 (en) * | 2001-02-16 | 2005-05-15 | Procter & Gamble | METHOD FOR PRODUCING A THICK AND SMOOTH EMBOSSED WEB |
US20050230069A1 (en) * | 2001-02-16 | 2005-10-20 | Klaus Hilbig | Method of making a thick and smooth embossed tissue |
US7407560B2 (en) * | 2001-02-16 | 2008-08-05 | The Procter & Gamble Company | Lotioned and embossed tissue paper |
DE60130095T2 (en) * | 2001-02-16 | 2008-05-15 | The Procter & Gamble Company, Cincinnati | Embossed and lotion-treated tissue paper |
JP4768147B2 (en) | 2001-04-27 | 2011-09-07 | Nec液晶テクノロジー株式会社 | Liquid crystal display manufacturing equipment |
US6896768B2 (en) * | 2001-04-27 | 2005-05-24 | Fort James Corporation | Soft bulky multi-ply product and method of making the same |
US6733866B2 (en) * | 2001-06-15 | 2004-05-11 | Sca Hygiene Products Gmbh | Multi-ply tissue paper product and method for producing same |
ITFI20020053A1 (en) * | 2002-03-29 | 2003-09-29 | Perini Fabio Spa | METHOD AND DEVICE FOR THE PRODUCTION OF EMBOSSED AND MANUFACTURED MATERIAL OBTAINED WITH THIS METHOD |
ITFI20020061A1 (en) * | 2002-04-12 | 2003-10-13 | Perini Fabio Spa | DEVICE AND COUPLING METHOD OF VEILS FOR THE FORMATION OF SHEET ITEMS AND MANUFACTURES SO OBTAINED |
EP1365068B1 (en) * | 2002-05-10 | 2008-05-07 | The Procter & Gamble Company | Embossed tissue having loosened surface fibers and method for its production |
US6846172B2 (en) * | 2002-06-07 | 2005-01-25 | The Procter & Gamble Company | Embossing apparatus |
ITFI20020113A1 (en) * | 2002-06-26 | 2003-12-29 | Perini Fabio Spa | EMBOSSING AND LAMINATING DEVICE WITH GROUP OF INTERCHANGEABLE EMBOSSING CYLINDERS |
US20060037724A1 (en) * | 2004-08-20 | 2006-02-23 | Kao Corporation | Bulky water-disintegratable cleaning article and process of producing water-disintergratable paper |
US7799169B2 (en) * | 2004-09-01 | 2010-09-21 | Georgia-Pacific Consumer Products Lp | Multi-ply paper product with moisture strike through resistance and method of making the same |
US7435316B2 (en) * | 2005-06-08 | 2008-10-14 | The Procter & Gamble Company | Embossing process including discrete and linear embossing elements |
US7785696B2 (en) * | 2005-06-08 | 2010-08-31 | The Procter & Gamble Company | Embossed product including discrete and linear embossments |
US7799167B2 (en) * | 2005-06-09 | 2010-09-21 | Kawano Paper Co., Ltd. | Embossed crepe paper and its manufacturing method |
ITFI20050218A1 (en) * | 2005-10-20 | 2007-04-21 | Guglielmo Biagiotti | IMPROVEMENT OF METHODS AND DEVICES FOR THE PRODUCTION OF TISSUE PAPERS AND PAPER VEIL FROM THESE DERIVATIVES |
CA2617812C (en) * | 2007-01-12 | 2013-07-09 | Cascades Canada Inc. | Wet embossed paperboard and method and apparatus for manufacturing same |
US8012309B2 (en) * | 2007-01-12 | 2011-09-06 | Cascades Canada Ulc | Method of making wet embossed paperboard |
-
2005
- 2005-10-20 IT IT000218A patent/ITFI20050218A1/en unknown
-
2006
- 2006-10-17 EP EP06810031A patent/EP1937894A1/en not_active Withdrawn
- 2006-10-17 BR BRPI0617518-0A patent/BRPI0617518A2/en not_active IP Right Cessation
- 2006-10-17 WO PCT/IT2006/000742 patent/WO2007046124A1/en active Application Filing
- 2006-10-17 JP JP2008536208A patent/JP4961430B2/en not_active Expired - Fee Related
- 2006-10-17 CN CN200680043304.XA patent/CN101313108A/en active Pending
- 2006-10-17 US US12/090,695 patent/US8142614B2/en not_active Expired - Fee Related
- 2006-10-17 KR KR1020087011920A patent/KR20080068083A/en not_active Application Discontinuation
-
2012
- 2012-02-13 US US13/371,572 patent/US8597469B2/en not_active Expired - Fee Related
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6524683B1 (en) * | 1988-01-13 | 2003-02-25 | Georgia-Pacific France | Sheet of embossed absorbent paper, and a method and device for producing same |
EP0625610A1 (en) * | 1993-05-21 | 1994-11-23 | Kimberly-Clark Corporation | A method of making a tissue product |
US5702571A (en) * | 1994-02-18 | 1997-12-30 | Kimberly-Clark Worldwide, Inc. | Soft high bulk tissue |
WO2000020683A1 (en) * | 1998-10-01 | 2000-04-13 | Sca Hygiene Products Ab | Method of producing a paper having a three-dimensional pattern |
US20020060008A1 (en) * | 1998-10-01 | 2002-05-23 | Holger Hollmark | Method of producing a paper having a three-dimensional pattern |
US6488816B1 (en) * | 1999-06-17 | 2002-12-03 | Metso Paper Karlstad Ab | Drying section for drying a paper web in a papermaking machine |
US20030021953A1 (en) * | 2000-11-24 | 2003-01-30 | Pierre Graff | Absorbent creped paper sheet comprising a background pattern and a main decorative pattern, and embossing roll and method for making such a sheet |
US20030116292A1 (en) * | 2001-12-20 | 2003-06-26 | Sca Hygiene Products Ab | Multi-layer paper web and a method of forming it |
WO2005106116A1 (en) * | 2004-04-29 | 2005-11-10 | A. Celli Paper S.P.A. | A method and device for the production of tissue paper |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8425730B2 (en) * | 2004-04-29 | 2013-04-23 | A. Celli Paper S.P.A. | Method and device for the production of tissue paper |
US8142613B2 (en) * | 2004-04-29 | 2012-03-27 | A. Celli Paper S.P.A. | Method and device for the production of tissue paper |
US20120152477A1 (en) * | 2004-04-29 | 2012-06-21 | A. Celli Paper S.P.A. | Method and device for the production of tissue paper |
US8142614B2 (en) * | 2005-10-20 | 2012-03-27 | A. Celli Paper S.P.A. | Methods and devices for the production of tissue paper, and web of tissue paper obtained using said methods and devices |
US8012309B2 (en) | 2007-01-12 | 2011-09-06 | Cascades Canada Ulc | Method of making wet embossed paperboard |
US8863657B2 (en) | 2009-04-30 | 2014-10-21 | Delfortgroup Ag | Installation for processing a paper web, in particular a cigarette paper web |
EP2425056A1 (en) | 2009-04-30 | 2012-03-07 | Delfortgroup AG | Arrangement and method for processing a paper web, in particular a cigarette paper web |
EP2425056B1 (en) * | 2009-04-30 | 2015-01-28 | Delfortgroup AG | Arrangement and method for processing a paper web, in particular a cigarette paper web |
US9333530B2 (en) | 2009-04-30 | 2016-05-10 | Delfortgroup Ag | Installation for processing a paper web, in particular a cigarette paper web |
US10927502B2 (en) | 2016-02-08 | 2021-02-23 | Gpcp Ip Holdings Llc | Molding roll for making paper products |
US11035077B2 (en) | 2016-02-08 | 2021-06-15 | Gpcp Ip Holdings Llc | Methods of making paper products using a molding roll |
US11136719B2 (en) | 2016-02-08 | 2021-10-05 | Gpcp Ip Holdings Llc | Methods of making paper products using a molding roll |
US11732416B2 (en) | 2016-02-08 | 2023-08-22 | Gpcp Ip Holdings Llc | Method of making a molded paper web |
US11802375B2 (en) | 2016-02-08 | 2023-10-31 | Gpcp Ip Holdings Llc | Molding roll for making paper products |
Also Published As
Publication number | Publication date |
---|---|
BRPI0617518A2 (en) | 2011-07-26 |
CN101313108A (en) | 2008-11-26 |
ITFI20050218A1 (en) | 2007-04-21 |
US8597469B2 (en) | 2013-12-03 |
KR20080068083A (en) | 2008-07-22 |
US20120205063A1 (en) | 2012-08-16 |
JP4961430B2 (en) | 2012-06-27 |
JP2009512791A (en) | 2009-03-26 |
EP1937894A1 (en) | 2008-07-02 |
US8142614B2 (en) | 2012-03-27 |
US20090199986A1 (en) | 2009-08-13 |
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