WO2007050480A1 - Carbon filled material with reduced dusting - Google Patents
Carbon filled material with reduced dusting Download PDFInfo
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- WO2007050480A1 WO2007050480A1 PCT/US2006/041200 US2006041200W WO2007050480A1 WO 2007050480 A1 WO2007050480 A1 WO 2007050480A1 US 2006041200 W US2006041200 W US 2006041200W WO 2007050480 A1 WO2007050480 A1 WO 2007050480A1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0246—Acrylic resin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0253—Polyolefin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
Definitions
- Such sorbtion papers may be used in devices to control hydrocarbon
- paper is in combination with body waste devices such as sanitary napkins,
- particulate materials such as active carbon are used in sorbtion
- Binders such as latex binders are useful for holding particulate adsorbents within the structure of the sorption papers.
- the existing art often
- 4,748,065 discloses a flame resistant adsorbent made of a fabric substrate of
- controlling dusting is to use a secondary nonwoven material such as an outer
- carbon particles are formed within aramid fibers, rather than being enmeshed
- This invention relates to a sorbtion paper that utilizes latex binders
- thermoplastic fibers at a range of 30% to
- thermoplastic fibrous material BRIEF DESCRIPTION OF THE DRAWINGS
- FIG. 1 illustrates a cross section view of a typical fibrous web
- FIG.2 illustrates a cross section view of a fibrous web containing
- FIG.3 illustrates a cross section view of a fibrous web containing
- FIG.4 illustrates a cross section view of a fibrous web containing
- FIG. 5 illustrates a cross section view of a fibrous web containing
- FIG. 6 illustrates a cross section view of a fibrous web containing
- particulate inclusions and a binder, and containing thermoplastic fibers
- FIG. 7 illustrates a cross section view of a fibrous web containing
- FIG. 1 illustrates a microscopic cross section view of a typical fibrous
- the fibers would run in several directions, for example in the plane of
- interfiber bonding for example by hydrogen bonds that may be developed
- the fibers may typically be prepared by refining or other processes
- Additives may also be used as is well known in the art of
- FIG.2 illustrates a microscopic cross section view of a typical fibrous
- particulate web 110 containing particulate inclusions 112.
- particulate For example, the particulate
- adsorbent material such as activated carbon that may give the particulate and fibrous web composite properties useful as a sorbtion paper.
- particulates may come loose during handling or
- FIG. 3 illustrates a microscopic cross section view of a typical
- fibrous web 120 containing particulate inclusions and a binder such as a latex
- the binder may help bind the
- binder may
- binder is shown to be located as
- FIG.4 illustrates a microscopic cross section view of a typical fibrous
- particulate inclusions are bound to fibers means that little dusting will occur.
- a higher binder concentration may obstruct free fluid flow
- FIG. 5 illustrates a microscopic cross section view of a fibrous web
- Such a secondary containment layer 155 could for example be a
- porous paper, fabric, additional fiber mat, or other layer that would allow fluid permeation while containing any loose particulates.
- a secondary containment layer 155 may be costly or inconvenient.
- FIG. 6 illustrates a microscopic cross section view of a fibrous web
- the fibrous web 160 also serves as at point 162.
- thermoplastic fibers 164 Such fibers are typically formed from
- thermoplastic materials including for example polypropylene, polyethylene,
- nylon nylon, and polyimides.
- non-thermoplastic fibers 166 may optionally be non-thermoplastic fibers 166
- thermoplastic fibers 164 provide another means of
- Heat and pressure may be applied from the top side. Heat and pressure may be applied to one or both
- Heating and pressing results in a consolidated layer 175, at least near
- thermoplastic fibers undergo densification and material
- thermoplastic fibers make them more amenable to
- thermoplastic fibers are thermoplastic fibers.
- thermoplastic fibers better adhere to the
- thermoplastic fibers cohere to other thermoplastic fibers and adhere to other
- non-thermoplastic fibers forming a stronger network as a second means of
- thermoplastic containing the particulate inclusions. Furthermore the thermoplastic
- thermoplastic bonding is localized at the surface 175, the interior of the fibrous
- web 170 may be left more porous and more open to fluid flow which promotes
- thermoplastic bonding may also strengthen the fibrous web.
- a fibrous web product for use in
- sorbtion papers utilizes latex binders at a range of 5% to 14% by weight and
- thermoplastic fibers at range of 30% to 60% by weight to produce a sheet
- the structure capable of containing 5% to 65% particulate material.
- formulation utilizes an acrylonitrile binder at 8-12 % by weight, thermoplastic polypropylene fibers at 35-45% by weight, acrylic fibers at 5-15% by weight,
- non-melting fibers may optionally be any suitable material.
- the non-melting fibers may be highly fibrillated.
- the initial composite structure is formed in the papermaking
- the composite structure exhibits dusting levels comparable with other
- the material may be exposed to heat and pressure to get
- heat and pressure can also be applied in a dynamic situation such as a heated
- a heated calender nip may be used, preferably with the material at
- the calendar nip may preferably have a preset gap to limit the consolidation of the material.
- a continuous belt press may be used, the
- the amount of product consolidation may range from 20%
- a strengthening layer such as a thermoplastic layer may be applied to a product.
- Such a strengthening layer if applied may allow for the fibrous web
- a strengthening layer may make the product more durable
- inter-layer abrasion may be reduced by a strengthening layer.
- strengthening layer may also provide better adhesion of the product to other
- Such a strengthening layer may also be applied to other fibrous materials.
- thermoplastic film thermofusing, hot molding, riveting, addition of
- pressure sensitive adhesives or any combination thereof.
- the binder provide excellent chemical and physical durability in environments
Abstract
A product and method of manufacture is described for a highly filled activated carbon material (170) that retains its adsorptive characteristics with a significant reduction in carbon particulate dusting.
Description
CARBON FILLED MATERIAL WITH REDUCED DUSTING
Inventors: Stephen A. Canary, Dewey M. Wyatt, Michael F. Tschantz
CROSS REFERENCE TO RELATED APPLICATION
[0001] This Non-Provisional Application Relies on the filing date of
Provisional Application Serial #60/7137063 filed on 10/28/2005, having been filed
within 12 months thereof which is incorporated herein by reference, and the
priority thereto is claimed under 35 USC § 1.19 (e)
BACKGROUND
[0002] The use of sorbtion papers for both air and liquid filtration is well-
known and represents a well-developed art. US Patent 4,289,513 describes a
sorbtion paper containing activated carbon as a sorbent and a latex type binder
material. Such sorbtion papers may be used in devices to control hydrocarbon
evaporation losses from automobiles. Another use for such activated sorbtion
paper is in combination with body waste devices such as sanitary napkins,
disposable diapers and the like.
[0003] When particulate materials such as active carbon are used in sorbtion
papers, there exists a need to prevent 'dusting' of the particulate materials.
Binders such as latex binders are useful for holding particulate
adsorbents within the structure of the sorption papers. The existing art often
uses levels of latex binders greater than 15%, which can reduce the adsorbtive
capacity of materials such as activated carbon. For example US Patent
4,748,065 discloses a flame resistant adsorbent made of a fabric substrate of
mostly aramid fibers, with carbon particles held in place by a latex binder in
the amount of 10 to 50% by weight of the carbon particles. Another method of
controlling dusting is to use a secondary nonwoven material such as an outer
layer to encase the sorbtion material, but this adds complexity and cost. Yet
another means of reducing dusting is disclosed in US Patent 5,482,773 where
carbon particles are formed within aramid fibers, rather than being enmeshed
in a net of fibers. This also adds complexity to the process.
SUMMARY
[0004] This invention relates to a sorbtion paper that utilizes latex binders
at a range of 5% to 14% by weight and thermoplastic fibers at a range of 30% to
60% by weight to produce a sheet structure capable of containing 5% to 65%
particulate material, that greatly resists dusting and generating loose
particulate matter after passing through a secondary operation utilizing heat
and pressure to achieve limited melt and flow of the latex binder and
thermoplastic fibrous material.
BRIEF DESCRIPTION OF THE DRAWINGS
[0005] FIG. 1 illustrates a cross section view of a typical fibrous web; and
[0006] FIG.2 illustrates a cross section view of a fibrous web containing
particulate inclusions; and
[0007] FIG.3 illustrates a cross section view of a fibrous web containing
particulate inclusions and a binder at relatively low concentration; and
[0008] FIG.4 illustrates a cross section view of a fibrous web containing
particulate inclusions and a binder at higher concentration; and
[0009] FIG. 5 illustrates a cross section view of a fibrous web containing
particulate inclusions and having a secondary containment layer; and
[0010] FIG. 6 illustrates a cross section view of a fibrous web containing
particulate inclusions and a binder, and containing thermoplastic fibers; and
[0011] FIG. 7 illustrates a cross section view of a fibrous web containing
particulate inclusions and a binder and thermoplastic fibers; after having been
heated and compressed.
DETAILED DESCRIPTION
[0012] FIG. 1 illustrates a microscopic cross section view of a typical fibrous
web 100 which includes fibers 102 such as cellulose fibers. The drawing is for
illustration purposes and not necessarily to scale. Furthermore it may
represent only a portion of the fibrous web, for example one of its surfaces.
Typically the fibers would run in several directions, for example in the plane of
the cross section as represented by fibers 102, and normal to the plane or at
other directions as represented by fibers 104. At points where fibers cross each
other more or less in the same plane, as at point 106, or cross each other at
other angles such as a skewed crossing as at point 108, there may be some
interfiber bonding, for example by hydrogen bonds that may be developed
during a wet formation process such as occurs at the wet end of a paper
machine. The fibers may typically be prepared by refining or other processes
that fibrillate the fibers, so as to enhance the eventual fiber bonding and give
greater strength. Additives may also be used as is well known in the art of
papermaking.
[0013] FIG.2 illustrates a microscopic cross section view of a typical fibrous
web 110 containing particulate inclusions 112. For example, the particulate
may be an adsorbent material such as activated carbon that may give the
particulate and fibrous web composite properties useful as a sorbtion paper.
Where the particulates 112 contact fibers, such as at point 114, little bonding
would be expected, as the particulate may not be amenable to hydrogen
bonding to the fibers. Thus, particularly at the particulates near the outer
surface of the fibrous web 110, particulates may come loose during handling or
usage, causing undesirable "dusting" behavior.
[0014] FIG. 3 illustrates a microscopic cross section view of a typical
fibrous web 120 containing particulate inclusions and a binder such as a latex
binder, at relatively low concentration. The binder may help bind the
particulate inclusions to fibers, as at point 131 and 132. Further the binder may
help bind fibers to fibers, as at the in-plane crossing of fibers at point 134, or
the skew crossing of fibers at point 135. At relatively low binder
concentrations as in FIG.3, some of the particulate inclusions may still not be
bound to the fibers, and thus dusting may still occur. It should be understood
that while, for illustration purposes, the binder is shown to be located as
discrete separated positions, much of the binder may actually be more evenly
distributed such as providing a locally more uniform coverage of some fibers
as at point 137.
[0015] FIG.4 illustrates a microscopic cross section view of a typical fibrous
web 140 containing particulate inclusions and a binder at higher concentration;
so that most of the particulate inclusions are bound to fibers, as at point 142.
Although some fibers are shown for illustration clarity as having no binder
over significant portions of their length, a more realistic scenario is that much
of the fiber surfaces will be covered such as at point 145. The fact that the
particulate inclusions are bound to fibers means that little dusting will occur.
However, significant portions of the particulate surfaces may now be coated
with binder, which may reduce the effectiveness of the particulate for
achieving its active purpose (such as activated carbon acting as an adsorbent.)
Furthermore, a higher binder concentration may obstruct free fluid flow
through the fibrous web 140, also reducing the effectiveness of particulates
such as activated carbon that work best when fluids have free access to their
particle surfaces.
[0016] FIG. 5 illustrates a microscopic cross section view of a fibrous web
150 containing particulate inclusions and having a secondary containment
layer 155. Such a secondary containment layer 155 could for example be a
porous paper, fabric, additional fiber mat, or other layer that would allow
fluid permeation while containing any loose particulates. However, providing
a secondary containment layer 155 may be costly or inconvenient.
[0017] FIG. 6 illustrates a microscopic cross section view of a fibrous web
160 containing particulate inclusions and a binder that may bind the
particulate inclusions to fibers, as at point 162. The fibrous web 160 also
contains thermoplastic fibers 164. Such fibers are typically formed from
thermoplastic materials including for example polypropylene, polyethylene,
nylon, and polyimides. There may optionally be non-thermoplastic fibers 166
such as cellulosic fibers.
[0018] The presence of thermoplastic fibers 164 provides another means of
containing the particulate inclusions. In FIG. 7 the same fibrous web is
illustrated after undergoing pressing at an elevated temperature, with heating
applied from the top side. Heat and pressure may be applied to one or both
sides. Heating and pressing results in a consolidated layer 175, at least near
the surface, where the thermoplastic fibers undergo densification and material
flow. The softening of the thermoplastic fibers makes them more amenable to
binding to particulate inclusions and to other thermoplastic and non-
thermoplastic fibers. Thus the thermoplastic fibers better adhere to the
particulate inclusions as one means of containing them. Also, the
thermoplastic fibers cohere to other thermoplastic fibers and adhere to other
non-thermoplastic fibers, forming a stronger network as a second means of
containing the particulate inclusions. Furthermore the thermoplastic
deformation and bonding between fibers and particulates is localized at their
contact points, leaving the structure more porous and open for fluid flow
compared with the bonding associated with latex binders, which is not so
localized and can leave a structure less open and porous. Particularly if the
thermoplastic bonding is localized at the surface 175, the interior of the fibrous
web 170 may be left more porous and more open to fluid flow which promotes
better activity of the particulate inclusions. Besides better containing the
particulates, thermoplastic bonding may also strengthen the fibrous web.
[0019] In a preferred embodiment, a fibrous web product for use in
sorbtion papers utilizes latex binders at a range of 5% to 14% by weight and
thermoplastic fibers at range of 30% to 60% by weight to produce a sheet
structure capable of containing 5% to 65% particulate material. The structure
greatly resists dusting and generating loose particulate matter after passing
through a secondary operation utilizing heat and pressure to get limited melt
and flow of the latex binder and thermoplastic fibrous material. An example
formulation utilizes an acrylonitrile binder at 8-12 % by weight, thermoplastic
polypropylene fibers at 35-45% by weight, acrylic fibers at 5-15% by weight,
and carbon particulates at 45-55% by weight.
[0020] Along with thermoplastic fibers, non-melting fibers may optionally
be used to assist in mechanical entrapment as well as to serve as a non-melting
structural component. The non-melting fibers may be highly fibrillated.
[0021] The initial composite structure is formed in the papermaking
process that is well known and thoroughly described in prior art. It should be
noted that other sheet making techniques in wet laid and dry laid nonwoven
processes would also be suitable. Having been formed in a papermaking
process, the composite structure exhibits dusting levels comparable with other
materials that are at high particulate loading levels. To achieve the desired
low dusting levels, the material may be exposed to heat and pressure to get
densification and material flow, particularly at the outer surfaces. This process
can be applied in a static situation such as a heated flat press opening. The
heat and pressure can also be applied in a dynamic situation such as a heated
roll calender or continuous belt press, both of which are known in the art. For
example, a heated calender nip may be used, preferably with the material at
least partially wrapping one or more preheating rolls before entering the
calendar nip. The calendar nip may preferably have a preset gap to limit the
consolidation of the material. A continuous belt press may be used, the
material passing between two moving heated steel belts which press the
material, for example at about 170C and 6 bar and running at speeds of 5 to 10
meters per minute. The amount of product consolidation may range from 20%
to 60% as measured by the percent change in thickness before and after the
treatment.
[0022] To provide added strength or improved handling properties to the
product, a strengthening layer such as a thermoplastic layer may be applied to
one surface , for example by extrusion lamination, leaving the other surface
open. Such a strengthening layer if applied may allow for the fibrous web
itself to have somewhat lower strength characteristics, for example, to be more
open, less consolidated, have higher particulate content, or have a lower
binder content. A strengthening layer may make the product more durable
during handling, and may reduce or eliminate dusting from the surface to
which it is applied. If the product is stacked in sheet form, or wound into roll
form, inter-layer abrasion may be reduced by a strengthening layer. A
strengthening layer may also provide better adhesion of the product to other
surfaces, for example when incorporating the product into other manufactured
products.
[0023] Such a strengthening layer may also be applied to other fibrous
products for similar purposes.
[0024] The resulting product retains the adsorptive characteristics of the
particulate material while providing a low dusting product in a form that is
easily incorporated into other structures. Incorporation can be achieved by a
variety of methods including, but not limited to, hot melt adhesive, lamination
to a thermoplastic film, thermofusing, hot molding, riveting, addition of
pressure sensitive adhesives, or any combination thereof.
[0025] The use of polyolefin as the thermoplastic fiber and acrylonitrile as
the binder provide excellent chemical and physical durability in environments
containing significant levels of water and/or hydrocarbons in either gaseous or
liquid phases.
[0026] The consolidation conditions described provide a product that
exhibit structural rigidity and very low dusting while also preserving the
adsorptive capacity of the activated carbon particulate materials contained
within the structure.
[0027] Methods of making and using the filled structure in accordance with
the invention should be readily apparent from the mere description of the
structure and its varied appearances as provided herein. No further
discussion or illustration of such methods, therefore, is deemed necessary.
[0028] While preferred embodiments of the invention have been described
and illustrated, it should be apparent that many modifications to the
embodiments and implementations of the invention can be made without
departing from the spirit or scope of the invention. Although the preferred
embodiments illustrated herein have been described in connection with a filled
activated carbon structure, these embodiments may easily be implemented in
accordance with the invention in other structures having other functionalities.
[0029] It is to be understood therefore that the invention is not limited to
the particular embodiments disclosed (or apparent from the disclosure) herein,
but only limited by the claims appended hereto.
Claims
1. A fiber product which comprises discontinuous fibers, at least some
of which are thermoplastic, having a binder material on at least a portion of said
fibers and particulate material adhered to said fibers by said binder material.
2. A product according to claim 1 in which said particulate material is
absorbent or adsorbent.
3. A product according to claim 2 in which said particulate material is
activated carbon.
4. A product according to claim 1 in which said discontinuous
thermoplastic fibers comprise at least one of polypropylene and acrylic fibers.
5. A product according to claim 1 in which said discontinuous fibers
include cellulosic fibers.
6. A product according to claim 5 in which said discontinuous
cellulosic fibers comprise wood pulp fibers.
7. A product according to claim 6 in which said wood pulp fibers are a
majority of said discontinuous fibers.
8. A product according to claim 4 in which said discontinuous
thermoplastic fibers comprise polypropylene fibers at 30 to 60% by weight of the
total product.
9. A product according to claim 4 in which said discontinuous
thermoplastic fibers comprise acrylic fibers at up to 10% by weight of the total
product.
10. A product according to claim 4 in which said discontinuous
thermoplastic fibers are highly fibrillated.
11. A product according to any of claims 1 - 10 wherein heat and
pressure are applied to achieve densification and material flow at at least one
outer surface.
12. A product according to any of claims 1 - 10 wherein heat and
pressure are applied to achieve bonding between said thermoplastic fibers and at
least one of said thermoplastic fibers, non thermoplastic fibers, and said
particulate matter.
13. An absorbent structure comprising the fiber product of any one of
claims 1 - 12.
14. An absorbent structure according to claim 13 in which said
discontinuous fibers comprise cellulosic fibers.
15. An absorbent structure according to claim 14 in which said
discontinuous fibers comprise wood pulp fibers.
16. An absorbent structure according to claim 15 in which said wood
pulp fibers are a majority of said discontinuous fibers.
17. An absorbent structure according to claim 13 in which said
discontinuous thermoplastic fibers comprise at least one of polypropylene and
acrylic fibers.
18. An adsorbent structure according to claim 17 in which said
discontinuous thermoplastic fibers comprise 30 to 60% by weight polypropylene
fibers.
19. An adsorbent structure according to claim 17 in which said
discontinuous thermoplastic fibers comprise up to 10% acrylic fibers.
20. An adsorbent structure according to claim 13 in which said
discontinuous thermoplastic fibers are highly fibrillated.
21. A method of making an adsorbent fiber product comprising the
steps of providing discontinuous fibers, at least some of which are thermoplastic,
adding an adsorbent particulate material, adding a binder material sufficient to
cover at least a portion of said fibers, forming a sheet, and applying heat and
pressure to said sheet to bond at least portions of said thermoplastic fibers to at
least portions of at least one of said thermoplastic fibers, said non-thermoplastic
fibers, and said particulate material.
22. The method of claim 21, wherein heat and pressure are applied
using at least one of a calendar nip, a continuous belt press, a platen press, and a
wrapped roll.
23. The method of claim 21, wherein the application of heat and
pressure provides increased strength properties to said sheet.
24. The method of claim 21, wherein the application of heat and
pressure reduces the dusting tendencies of said sheet.
25. The method of claim 21, further comprising a step of laminating a
thermoplastic layer onto a surface of said sheet.
26. A method of making an adsorbent fiber product comprising the
steps of providing discontinuous fibers, adding an adsorbent particulate material,
adding a binder material sufficient to cover at least a portion of said fibers,
forming a sheet, and applying a strengthening layer to one surface of the sheet.
27. The method of claim 26, wherein the strengthening layer is an
extrusion laminated or extrusion coated layer.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US73106305P | 2005-10-28 | 2005-10-28 | |
US60/731,063 | 2005-10-28 |
Publications (1)
Publication Number | Publication Date |
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WO2007050480A1 true WO2007050480A1 (en) | 2007-05-03 |
Family
ID=37968138
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2006/041200 WO2007050480A1 (en) | 2005-10-28 | 2006-10-19 | Carbon filled material with reduced dusting |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8598073B2 (en) | 2009-04-20 | 2013-12-03 | Corning Incorporated | Methods of making and using activated carbon-containing coated substrates and the products made therefrom |
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US4160059A (en) * | 1976-05-12 | 1979-07-03 | Honshu Seishi Kabushiki Kaisha | Adsorptive nonwoven fabric comprising fused fibers, non-fused fibers and absorptive material and method of making same |
US4289513A (en) * | 1978-03-27 | 1981-09-15 | The Mead Corporation | Activated sorbtion paper and products produced thereby |
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US4904343A (en) * | 1985-04-23 | 1990-02-27 | American Cyanamid Company | Non-woven activated carbon fabric |
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US4160059A (en) * | 1976-05-12 | 1979-07-03 | Honshu Seishi Kabushiki Kaisha | Adsorptive nonwoven fabric comprising fused fibers, non-fused fibers and absorptive material and method of making same |
US4289513A (en) * | 1978-03-27 | 1981-09-15 | The Mead Corporation | Activated sorbtion paper and products produced thereby |
US4478065A (en) * | 1981-06-11 | 1984-10-23 | Innse Innocenti Santeustacchio S.P.A. | Continuous rolling mill with crossed stands for the production of seamless tubes |
US4904343A (en) * | 1985-04-23 | 1990-02-27 | American Cyanamid Company | Non-woven activated carbon fabric |
US5516585A (en) * | 1989-03-20 | 1996-05-14 | Weyerhaeuser Company | Coated fiber product with adhered super absorbent particles |
US5674339A (en) * | 1992-11-18 | 1997-10-07 | Hoechst Celanese Corporation | Process for fibrous structure containing immobilized particulate matter |
US5786065A (en) * | 1995-12-15 | 1998-07-28 | The Dexter Corporation | Abrasive nonwoven web |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8598073B2 (en) | 2009-04-20 | 2013-12-03 | Corning Incorporated | Methods of making and using activated carbon-containing coated substrates and the products made therefrom |
US8664154B2 (en) | 2009-04-20 | 2014-03-04 | Corning Incorporated | Methods of making and using activated carbon-containing coated substrates and the products made therefrom |
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