WO2007053548A3 - Polyester compositions comprising minimal amounts of cyclobutanediol - Google Patents

Polyester compositions comprising minimal amounts of cyclobutanediol Download PDF

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Publication number
WO2007053548A3
WO2007053548A3 PCT/US2006/042291 US2006042291W WO2007053548A3 WO 2007053548 A3 WO2007053548 A3 WO 2007053548A3 US 2006042291 W US2006042291 W US 2006042291W WO 2007053548 A3 WO2007053548 A3 WO 2007053548A3
Authority
WO
WIPO (PCT)
Prior art keywords
cyclobutanediol
polyester compositions
minimal amounts
residues
optionally
Prior art date
Application number
PCT/US2006/042291
Other languages
French (fr)
Other versions
WO2007053548A2 (en
Inventor
Emmett Dudley Crawford
David Scott Porter
Gary Wayne Connell
Ted Calvin Germroth
Benjamin Fredrick Barton
Damon Bryan Shackelford
Original Assignee
Eastman Chem Co
Emmett Dudley Crawford
David Scott Porter
Gary Wayne Connell
Ted Calvin Germroth
Benjamin Fredrick Barton
Damon Bryan Shackelford
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/390,812 external-priority patent/US7959836B2/en
Priority claimed from US11/390,672 external-priority patent/US20060287479A1/en
Priority claimed from US11/390,846 external-priority patent/US7955674B2/en
Priority claimed from US11/390,809 external-priority patent/US7959998B2/en
Priority claimed from US11/390,908 external-priority patent/US7462684B2/en
Priority claimed from US11/391,124 external-priority patent/US20060234073A1/en
Priority to JP2008538072A priority Critical patent/JP2009513799A/en
Priority to CA002625671A priority patent/CA2625671A1/en
Priority to EP06827056A priority patent/EP1940910A2/en
Application filed by Eastman Chem Co, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell, Ted Calvin Germroth, Benjamin Fredrick Barton, Damon Bryan Shackelford filed Critical Eastman Chem Co
Priority to US11/635,434 priority patent/US7737246B2/en
Priority to PCT/US2007/007532 priority patent/WO2007123631A1/en
Priority to PCT/US2007/007632 priority patent/WO2007126855A1/en
Priority to US12/294,690 priority patent/US20100184940A1/en
Priority to PCT/US2007/010590 priority patent/WO2007139655A1/en
Priority to PCT/US2007/010551 priority patent/WO2007139653A1/en
Priority to PCT/US2007/011150 priority patent/WO2007139663A1/en
Publication of WO2007053548A2 publication Critical patent/WO2007053548A2/en
Publication of WO2007053548A3 publication Critical patent/WO2007053548A3/en
Priority to KR1020097008484A priority patent/KR20090079212A/en
Priority to EP07836029A priority patent/EP2074158A1/en
Priority to MX2009003375A priority patent/MX2009003375A/en
Priority to PCT/US2007/015701 priority patent/WO2008051320A1/en
Priority to PCT/US2007/015704 priority patent/WO2008051321A1/en
Priority to CA002666571A priority patent/CA2666571A1/en
Priority to BRPI0717755-0A priority patent/BRPI0717755A2/en
Priority to TW096125089A priority patent/TW200819496A/en
Priority to JP2009534566A priority patent/JP2010507717A/en
Priority to EP07836026A priority patent/EP2074174A1/en
Priority to KR1020097008483A priority patent/KR20090079211A/en
Priority to MX2009003369A priority patent/MX2009003369A/en
Priority to BRPI0717761-5A priority patent/BRPI0717761A2/en
Priority to PCT/US2007/015713 priority patent/WO2008054560A2/en
Priority to CA002666585A priority patent/CA2666585A1/en
Priority to PCT/US2007/015702 priority patent/WO2008054559A1/en
Priority to JP2009534565A priority patent/JP2010507716A/en
Priority to TW096125125A priority patent/TW200819497A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66—Substances characterised by their function in the composition
    • C08L2666/78—Stabilisers against oxidation, heat, light or ozone

Abstract

Described are polyester compositions comprising (a) a dicarboxylicacidcomponent comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; minimal amounts of 2,2,4 ,4-tetramethyl-1 ,3-cyclobutanediol residues; ethylene glycol, and optionally, cyclohexanedimethanol residues.
PCT/US2006/042291 2005-03-02 2006-10-27 Polyester compositions comprising minimal amounts of cyclobutanediol WO2007053548A2 (en)

Priority Applications (28)

Application Number Priority Date Filing Date Title
JP2008538072A JP2009513799A (en) 2005-10-28 2006-10-27 Polyester composition comprising a minimum amount of cyclobutanediol
CA002625671A CA2625671A1 (en) 2005-10-28 2006-10-27 Polyester compositions comprising minimal amounts of cyclobutanediol
EP06827056A EP1940910A2 (en) 2005-10-28 2006-10-27 Polyester compositions comprising minimal amounts of cyclobutanediol
US11/635,434 US7737246B2 (en) 2005-12-15 2006-12-07 Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
US12/294,690 US20100184940A1 (en) 2005-03-02 2007-03-27 Polyester Compositions Which Comprise Cyclobutanediol and Certain Thermal Stabilizers, and/or Reaction Products Thereof
PCT/US2007/007632 WO2007126855A1 (en) 2006-03-28 2007-03-27 Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
PCT/US2007/007532 WO2007123631A1 (en) 2006-03-28 2007-03-27 Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound
PCT/US2007/010551 WO2007139653A1 (en) 2006-05-23 2007-05-02 Lcd films or sheets comprising films comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
PCT/US2007/010590 WO2007139655A1 (en) 2006-05-23 2007-05-02 Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
PCT/US2007/011150 WO2007139663A1 (en) 2006-05-23 2007-05-09 Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
TW096125125A TW200819497A (en) 2006-10-27 2007-07-10 Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
JP2009534565A JP2010507716A (en) 2006-10-27 2007-07-10 Polyester composition containing tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol and method for producing the same
PCT/US2007/015702 WO2008054559A1 (en) 2006-10-27 2007-07-10 Certain polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and high trans- cyclohexanedicarboxylic acid
CA002666585A CA2666585A1 (en) 2006-10-27 2007-07-10 Polyester compositions
PCT/US2007/015713 WO2008054560A2 (en) 2006-10-27 2007-07-10 Certain polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and high trans-cyclohexanedicarboxylic acid
BRPI0717761-5A BRPI0717761A2 (en) 2006-10-27 2007-07-10 polyester composition, polymer blend, and article of manufacture
MX2009003369A MX2009003369A (en) 2006-10-27 2007-07-10 Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor.
KR1020097008484A KR20090079212A (en) 2006-10-27 2007-07-10 Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
KR1020097008483A KR20090079211A (en) 2006-10-27 2007-07-10 Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor
EP07836029A EP2074158A1 (en) 2006-10-27 2007-07-10 Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
MX2009003375A MX2009003375A (en) 2006-10-27 2007-07-10 Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor.
PCT/US2007/015701 WO2008051320A1 (en) 2006-10-27 2007-07-10 Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor
PCT/US2007/015704 WO2008051321A1 (en) 2006-10-27 2007-07-10 Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
CA002666571A CA2666571A1 (en) 2006-10-27 2007-07-10 Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor
BRPI0717755-0A BRPI0717755A2 (en) 2006-10-27 2007-07-10 polyester composition, blend, and article of manufacture
TW096125089A TW200819496A (en) 2006-10-27 2007-07-10 Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
JP2009534566A JP2010507717A (en) 2006-10-27 2007-07-10 Polyester composition
EP07836026A EP2074174A1 (en) 2006-10-27 2007-07-10 Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor

Applications Claiming Priority (116)

Application Number Priority Date Filing Date Title
US73138905P 2005-10-28 2005-10-28
US73145405P 2005-10-28 2005-10-28
US60/731,454 2005-10-28
US60/731,389 2005-10-28
US73905805P 2005-11-22 2005-11-22
US73886905P 2005-11-22 2005-11-22
US60/739,058 2005-11-22
US60/738,869 2005-11-22
US75069305P 2005-12-15 2005-12-15
US75068205P 2005-12-15 2005-12-15
US75054705P 2005-12-15 2005-12-15
US75069205P 2005-12-15 2005-12-15
US60/750,692 2005-12-15
US60/750,693 2005-12-15
US60/750,682 2005-12-15
US60/750,547 2005-12-15
US78654706P 2006-03-28 2006-03-28
US78657206P 2006-03-28 2006-03-28
US78659806P 2006-03-28 2006-03-28
US78659606P 2006-03-28 2006-03-28
US39077306A 2006-03-28 2006-03-28
US78657106P 2006-03-28 2006-03-28
US11/390,672 US20060287479A1 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol and articles made therefrom
US11/391,495 2006-03-28
US11/390,655 US8067525B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and high glass transition temperature
US11/391,156 US7812112B2 (en) 2005-06-17 2006-03-28 Outdoor signs comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,846 US7955674B2 (en) 2005-03-02 2006-03-28 Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US11/390,908 2006-03-28
US11/390,794 US8119761B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US11/390,811 2006-03-28
US11/390,809 US7959998B2 (en) 2005-03-02 2006-03-28 Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US11/391,576 2006-03-28
US11/391,156 2006-03-28
US11/390,955 US7915376B2 (en) 2005-06-17 2006-03-28 Containers comprising polyester compositions which comprise cyclobutanediol
US11/391,576 US7803441B2 (en) 2005-06-17 2006-03-28 Intravenous components comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,955 2006-03-28
US11/390,882 US20060287486A1 (en) 2005-06-17 2006-03-28 Optical media comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,752 US8063173B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
US11/390,908 US7462684B2 (en) 2005-03-02 2006-03-28 Preparation of transparent, multilayered articles containing polyesters comprising a cyclobutanediol and homogeneous polyamide blends
US11/390,563 US7902320B2 (en) 2005-06-17 2006-03-28 Graphic art films comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,124 US20060234073A1 (en) 2005-03-02 2006-03-28 Multilayered, transparent articles containing polyesters comprising a cyclobutanediol and a process for their preparation
US11/390,630 2006-03-28
US11/390,814 2006-03-28
US11/390,751 2006-03-28
US11/390,629 US7803439B2 (en) 2005-06-17 2006-03-28 Blood therapy containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,631 2006-03-28
US11/391,137 US7985827B2 (en) 2005-06-17 2006-03-28 Polyester compositions which comprise cyclobutanediol having certain cis/trans ratios
US11/391,505 US7838620B2 (en) 2005-06-17 2006-03-28 Thermoformed sheet(s) comprising polyester compositions which comprise cyclobutanediol
US11/391,505 2006-03-28
US11/390,793 2006-03-28
US11/390,864 2006-03-28
US11/390,671 US8063172B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) made using polyester compositions containing low amounts of cyclobutanediol
US11/391,485 US7842776B2 (en) 2005-06-17 2006-03-28 Appliance parts comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,826 2006-03-28
US60/786,596 2006-03-28
US11/390,750 2006-03-28
US11/390,865 2006-03-28
US11/390,655 2006-03-28
US11/390,827 US7893188B2 (en) 2005-06-17 2006-03-28 Baby bottles comprising polyester compositions which comprise cyclobutanediol
US11/390,827 2006-03-28
US11/390,882 2006-03-28
US11/390,853 US20070270569A1 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) made from polyester compositions containing cyclobutanediol and articles made therefrom
US11/391,125 2006-03-28
US11/391,571 US20060287494A1 (en) 2005-06-17 2006-03-28 Polyester compositions containing high amounts of cyclobutanediol and articles made therefrom
US11/390,752 2006-03-28
US11/390,631 US7855267B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and moderate glass transition temperature
US11/390,722 2006-03-28
US11/390,751 US7803440B2 (en) 2005-06-17 2006-03-28 Bottles comprising polyester compositions which comprise cyclobutanediol
US11/390,654 US20060287477A1 (en) 2005-06-17 2006-03-28 Greenhouses comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4- cyclohexanedimethanol
US11/390,629 2006-03-28
US11/391,137 2006-03-28
US11/390,671 2006-03-28
US11/390,630 US7807774B2 (en) 2005-06-17 2006-03-28 Vending machines comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,722 US7893187B2 (en) 2005-06-17 2006-03-28 Glass laminates comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,485 2006-03-28
US11/390,836 2006-03-28
US60/786,571 2006-03-28
US11/390,793 US20060286389A1 (en) 2005-06-17 2006-03-28 Protein-resistant articles comprising cyclobutanediol
US11/390,826 US7906610B2 (en) 2005-06-17 2006-03-28 Food service products comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,124 2006-03-28
US11/390,750 US20060287480A1 (en) 2005-06-17 2006-03-28 Outdoor shelters comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,642 US7510768B2 (en) 2005-06-17 2006-03-28 Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US11/390,773 2006-03-28
US11/390,858 US7951900B2 (en) 2005-06-17 2006-03-28 Dialysis filter housings comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,864 US7812111B2 (en) 2005-06-17 2006-03-28 LCD films comprising polyester compositions formed from 2,2,4,4-tetramethy1-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,812 2006-03-28
US11/391,495 US7807775B2 (en) 2005-06-17 2006-03-28 Point of purchase displays comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,063 US7576171B2 (en) 2005-06-17 2006-03-28 Pacifiers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,853 2006-03-28
US11/390,836 US20060286330A1 (en) 2005-06-17 2006-03-28 Sterilization containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,563 2006-03-28
US11/390,847 US20060287484A1 (en) 2005-06-17 2006-03-28 Opththalmic devices comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,814 US20060286327A1 (en) 2005-06-17 2006-03-28 Retort containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,812 US7959836B2 (en) 2005-03-02 2006-03-28 Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol
US11/391,565 US7781562B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US11/391,565 2006-03-28
US60/786,598 2006-03-28
US11/391,063 2006-03-28
US11/391,125 US20070010650A1 (en) 2005-06-17 2006-03-28 Tough amorphous polyester compositions
US11/390,846 2006-03-28
US11/390,654 2006-03-28
US11/390,809 2006-03-28
US11/391,659 2006-03-28
US11/390,865 US20060287485A1 (en) 2005-06-17 2006-03-28 Sound barriers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,794 2006-03-28
US11/390,883 2006-03-28
US11/390,858 2006-03-28
US60/786,547 2006-03-28
US11/391,642 2006-03-28
US11/390,847 2006-03-28
US11/391,571 2006-03-28
US11/391,659 US20060287496A1 (en) 2005-06-17 2006-03-28 Polyester compositions comprising minimal amounts of cyclobutanediol
US11/390,883 US7834129B2 (en) 2005-06-17 2006-03-28 Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,811 US7868128B2 (en) 2005-06-17 2006-03-28 Skylights and windows comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
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