WO2007070114A1 - Tissue product having a transferable additive composition - Google Patents
Tissue product having a transferable additive composition Download PDFInfo
- Publication number
- WO2007070114A1 WO2007070114A1 PCT/US2006/030035 US2006030035W WO2007070114A1 WO 2007070114 A1 WO2007070114 A1 WO 2007070114A1 US 2006030035 W US2006030035 W US 2006030035W WO 2007070114 A1 WO2007070114 A1 WO 2007070114A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- tissue product
- target delivery
- additive composition
- base web
- delivery zone
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H1/00—Paper; Cardboard
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
- D21H27/008—Tissue paper; Absorbent paper characterised by inhomogeneous distribution or incomplete coverage of properties, e.g. obtained by using materials of chemical compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0253—Polyolefin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/716—Degradable
- B32B2307/7163—Biodegradable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/728—Hydrophilic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2432/00—Cleaning articles, e.g. mops, wipes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
- D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
- D21H27/005—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31975—Of cellulosic next to another carbohydrate
- Y10T428/31978—Cellulosic next to another cellulosic
- Y10T428/31982—Wood or paper
Definitions
- tissue products such as facial tissues, bath tissues, paper towels and so forth have been used to absorb fluids on the skin and leave the skin dry. Frequent use of these products may, however, tend to irritate the skin over time.
- tissue products have included additives applied to the tissue surfaces to reduce or eliminate irritated skin during heavy use periods. The additives can enhance sheet softness perceptions by reducing the stiffness of the sheet, making it more drapeable, or by providing lubricity, helping the sheet glide across the surface of the skin.
- additives may be applied to the tissue product that are intended to be transferred to the user.
- vitamins, plant extracts, medications, antimicrobial compounds, and the like may be applied to a tissue sheet in order to be transferred to a consumer upon use. Applying these compositions to a tissue or wiping product provides a certain level of convenience for the consumer.
- tissue products containing a topical composition typically have a significantly poorer efficiency than when the composition is delivered in a bottled lotion that is applied to the skin separately from the tissue product.
- Efficiency here can be defined as the ratio of amount of the substance transferred to the target surface to the amount of composition applied to the applicator. In the case of a tissue treated with an additive the treated tissue becomes the applicator.
- the applicator is the object used to transfer to the target surface and may be a finger, a hand, etc.
- manufacturing systems for topically applying the beneficial compositions are typically designed to apply the composition over the entire sheet, although only a small area of the sheet is actually used to wipe the surface.
- ' m ⁇ cK' ⁇ f t ' hefuiricfi ⁇ na ⁇ composition is wasted when the product is disposed.
- application of the composition across the entire surface of the wiping product may compromise other attributes of the tissue product, such as its ability to rapidly absorb and remove fluids, dirt, etc.
- tissue product that is capable of delivering efficacious amounts of a beneficial composition to an adjacent surface, such as the user's skin.
- tissue product containing a beneficial composition in which the composition does not compromise the inherent properties of the product, such as the wicking and absorption characteristics of the product.
- the present disclosure is generally directed to tissue products that include an additive composition designed to provide, for instance, clinical benefits to the user. More particularly, the additive composition is designed to be transferred to a user in a more efficient manner than many prior art products.
- Delivery of the additive composition from the tissue product to a user is enhanced by incorporating a target delivery zone into the product.
- the target delivery zone may contain the additive composition in relatively high amounts.
- Transfer of the additive composition is further enhanced by modifying the substrate within the target delivery zone in order to reduce the affinity of the substrate for the additive composition.
- the tissue product may be used not only to transfer the additive composition to a user, but also may be used as a wiping product.
- the present disclosure is directed to a tissue product that includes a base web containing cellulosic fibers.
- the base web may have a dry bulk density of at least about 3 cc/g and may contain, for instance, softwood fibers, hardwood fibers or mixtures thereof.
- the base web may have a bulk density of at least about 4 cc /g such as from about 5 cc / gram to about 14 cc / gram.
- a target delivery zone is located on a first side of the base web.
- the target delivery zone may comprise a portion of the total surface area of the first side.
- the additive composition is intended to be transferred to an adjacent surface when the tissue product is used.
- the additive composition may comprise a lotion that is intended to provide clinical benefits to the skin of a user.
- the first side of the base web is modified at least in the target delivery zone in a manner that causes greater amounts of the additive composition to transfer to an opposing surface when the tissue product is wiped against the opposing surface.
- the base web may be modified using various methods and techniques.
- the first side of the base web may be modified so as to render the target delivery zone hydrophobic prior to adding the additive composition to the base web.
- both the first and second sides of the base web are modified in the target delivery zone in a manner that causes greater amounts of the additive composition to transfer to an opposing surface when the tissue product is wiped against the opposing surface.
- the target delivery zone comprises less than 70% of the total surface area of either side of the sheet and preferably comprises less than 30% of the total surface area of either side of the sheet. In this manner the absorbent properties of the untreated sheet are maintained.
- the first side of the base web may be modified by adhering a polymeric film or a nonwoven web containing synthetic fibers to the base web at least in the target delivery zone.
- the polymeric film or nonwoven web may be made from a synthetic polymer, such as a polyolefin.
- suitable polyolefins include, but is not limited to, polyethylene and polypropylene.
- the film is comprised of a biodegradable film material sourced from renewable or non-renewable (petroleum) resources.
- natural resins (or biopolymers) suitable for the films include, but is not limited to, films made from starch and cellulose as well as materials such as polyhydroxyalcanoates (PHA) and.
- Polylactides formed by polymerization of lactic acid.
- biodegradable materials made from non-renewable resources include polycaprolactone and modified polyethylenes and polypropylene films.
- the nonwoven web may be a spunbond web, a meltblown web or the like.
- the nonwoven web or film may be applied to tfie same " siae"offh " d base web as the additive composition.
- the nonwoven web or film may be adhered to the opposite side of the nonwoven web.
- the base web may be perforated in between the additive composition and the nonwoven web or film.
- the first side of the base web may be modified by applying a sizing agent, a wax or a resin to the base web.
- the target delivery zone only comprises a portion of the total surface area of the sides of the base web to which the target delivery zone is present.
- the target delivery zone may comprise less than about 70% of the area of the first side of the base web, such as from about 10% to about 40% of the surface area of the side of the base web on which the target delivery zone is present.
- the target delivery zone may be visually differentiated from the remainder of the first side of the base web if desired.
- the target delivery zone may also be surrounded by a barrier to prevent migration of the additive composition in the x-y direction of the sheet.
- the additive composition may comprise any suitable composition where it is desired to transfer the composition onto an adjacent surface.
- the additive composition may comprise a skin lotion.
- the additive composition may contain a silicone.
- the additive composition may comprise a blended wax, an oil and an alcohol.
- the additive composition may be present in the target delivery zone in an amount from about 2 gsm to about 150 gsm or greater.
- the additive composition may be present in the target delivery zone in an amount from about 5 gsm to about 250 gsm such as from about 10 gsm to about 200 gsm.
- the additive composition is present in the target delivery zone in an amount of at least 25 gsm.
- the tissue product may comprise, for instance, a bath tissue, a facial tissue, a napkin, a paper towel, or the like.
- the tissue product may comprise a single ply product or a multi-ply product.
- the tissue product may include four quadrants.
- the target delivery zone may be present in one or two of the quadrants.
- the tissue product may include at least one fold line along which the base web is folded.
- the target delivery zone may be located along the fold line such that the additive composition is folded onto itself when the base web is folded.
- the target delivery zone is offset from a portion of the tissue so as not to interfere with the tissue's ability to cleanse or absorb.
- the center of the sheet will be used for cleansing and absorption such that the target delivery zones are offset from the center, located along the periphery of the sheet.
- Figure 1 A is a perspective view of one embodiment of a tissue product made in accordance with the present invention
- Figure 1 B is a cross-sectional view of the tissue product shown in Fig. 1A;
- FIG. 2 is a perspective view of another embodiment of a tissue product made in accordance with the present invention.
- FIG 3 is a perspective view of still another embodiment of a tissue product made in accordance with the present invention
- Figure 4 is a perspective view with cutaway portions of another embodiment of a tissue product made in accordance with the present invention.
- FIG. 5 is a perspective view of still another embodiment of a tissue product made in accordance with the present invention.
- FIGS. 6A and 6B are perspective views of another embodiment of a tissue product made in accordance with the present invention in which the tissue product includes two fold lines;
- FIGS 7 A and 7B are perspective views of another embodiment of a tissue product made in accordance with the present invention in which the tissue product is divided into quadrants and an additive composition is applied to two of the quadrants.
- the present disclosure is directed to tissue products containing an additive composition that is intended to be transferred to an adjacent surface during use of the product.
- the additive composition is located within a target delivery zone or target delivery zones creating treated areas and untreated areas on the product.
- the untreated areas are essentially free of the additive composition. In this manner, the additive composition does not adversely interfere with the ability of the untreated areas to absorb liquids and perform other basic functions of the tissue product.
- the base sheet where the target delivery zone is located is also modified prior to applying the additive composition in order to enhance the ability of the product to transfer the additive composition onto an adjacent surface.
- the base sheet in the target delivery zone may be modified by providing the surface with a different surface energy or porosity.
- the base sheet in the target delivery zone may be rendered hydrophobic, especially when the additive composition is hydrophilic.
- the present inventors have found that hydrophilic compositions transfer more effectively from a hydrophobic surface than from a hydrophilic surface.
- the base sheet in the target delivery zone may be modified by adhering a nonwoven web, a film, a sizing agent, a wax, a resin, and the like to the base sheet.
- the target delivery zone containing the additive composition may be clearly differentiated from the untreated areas of the base sheet.
- the differentiation may be achieved, for example, via a sensory device that makes the targefd ' ll ' ivery " zo'ne immediately detectable from visual inspection or through touch.
- a dye may be incorporated into the additive composition or otherwise into the target delivery zone so that the target delivery zone is visible upon inspection of the tissue product. Referring to Figs. 1A and 1B, one embodiment of a tissue product generally
- the tissue product 10 includes, in this embodiment, a first ply 12 and a second ply 14. It should be understood, however, that the teachings of the present invention may also be used in conjunction with single ply tissue products or tissue products containing more than two plies.
- the first ply 12 of the tissue product 10 defines a target delivery zone 16.
- the target delivery zone contains an additive composition and is configured to efficiently transfer the additive composition onto an adjacent surface when the tissue product is contacted with the surface.
- the target delivery zone 16 only occupies a portion of the total surface area of the base web 12.
- the target delivery zone 16 may comprise less than about 70% of the surface area of the side of the sheet where the target delivery zone is located, such as less than about 50% of the surface area of the sheet.
- the target delivery zone 16 may comprise less than about 30% of the total surface area of the sheet, such as less than about 20% of the surface area of the sheet.
- the tissue product 10 may include only a single target delivery zone 16 as shown in Fig.
- the target delivery zones may appear on the same side of the tissue product or on opposite sides.
- the target delivery zones may contain different additives that supply separate benefits to the user. In this way it is possible to deliver from a single sheet additives that may be incompatible with each other.
- the target delivery zone only covers a portion of the entire surface area of the tissue product, various advantages and benefits are realized. For example, by only occupying a portion of the total surface area of the base sheet, the areas of the base sheet not treated with the additive composition may remain capable of absorbing liquids unhindered by the additive composition. Thus, the 'tissue pfod ⁇ ct ' cann ⁇ f 'only effectively absorb fluids but can also apply the additive composition to an adjacent surface with a high level of efficiency.
- the base sheet 12 as shown in Figs. 1A and 1B is modified at least in the target delivery zone.
- the base web is modified in a manner that causes greater amounts of the additive composition to transfer to an opposing surface.
- the base sheet 12 may be modified over the entire surface area of the base sheet or may be modified only where the target delivery zone 16 is located. Modifying the base sheet in a manner that causes greater amounts of the additive composition to transfer to an opposing surface may in some embodiments adversely interfere with the ability of the base sheet to absorb liquids.
- the base web 12 when substantially the entire surface area of the base web 12 is modified, it may be beneficial to include further tissue plies as shown in Fig. 1 A. In this manner, the second ply 14 is available for fluid absorption and retention.
- a third ply may be contained within the first ply 12 and the second ply 14. The third or middle ply may not only further increase the water absorption characteristics of the product but may also serve as a barrier ply.
- the manner in which the base sheet 12 is modified depends on various factors and the particular application. For example, the modification may depend upon the construction of the base sheet itself or on the components contained in the additive composition.
- the base sheet 12 is modified within the target delivery zone 16 in a manner such that the additive composition has little or no adhesion to the base sheet in the target delivery zone.
- a coating may be applied to the base sheet in order to modify the base sheet in the target delivery zone.
- a sizing agent, a wax or a resin may be applied to the base sheet 12 at least within the target delivery zone 16.
- Suitable agents for creating hydrophobic areas in the sheet may be selected from agents known for imparting hydrophobicity to sheets including sizing agents such as acid rosin, alkenyl ketene dimers, alkenyl succinic anhydride, alkyl ketone dimers, and alkenol ketene dimers and are preferably applied externally to the sheet to allow for creation of treated and untreated areas. Examples of other suitable sizing agents are described in Tapermakirig TM and '' Paper Board Making", 2 nd ed., Volume III, edited by R.G. MacDonald and J.N. Franklin, incorporated herein by reference.
- an appropriate additive composition may be applied to the base sheet using any suitable technique. For instance, the additive composition may be printed on the base sheet, slot coated on the base sheet, sprayed on the base sheet, or the like.
- any suitable additive composition may be applied to a tissue product in accordance with the present disclosure.
- the specific formulation is not overly critical and can comprise any formulation known in the art.
- a non- exhaustive list of different additives that may be present in the additive composition include, for example, anti-acne actives, antimicrobial actives, antifungal actives, antiseptic actives, antioxidants, cosmetic astringents, drug astringents, deodorants, emollients, external analgesics, film formers, fragrances, humectants, natural moisturizing agents and other skin moisturizing ingredients known in the art such as lanolin, skin conditioning agents, skin exfoliating agents, skin protectants, and sunscreens.
- additives include, for instance, Vitamin E and Aloe Vera extracts. Additional additives include polysiloxanes such as dimethicone, cyclodimethicones, amidodimethicones, silicone glycols and the like. In addition to the above additives, various other ingredients may be present in the additive composition.
- the additive composition may contain preservatives, antifoamers, and surfactants.
- the basesheet may also contain one or more softeners.
- the softener may be, for instance, a polysiloxane that makes a tissue product feel softer to the skin of a user.
- Suitable polysiloxanes that may be used in the present invention include amine, aldehyde, carboxylic acid, hydroxyl, alkoxyl, polyether, polyethylene oxide, and polypropylene oxide derivatized silicones, such as aminopolydialkylsiloxanes.
- the two substituent radicals may be methyl groups, ethyl groups, and/or a straight branched or cyclic carbon chain containing from about 3 to about 8 carbon atoms.
- polysiloxanes Some commercially available examples of polysiloxanes include WETSOFT CTW, AF-21 , AF-23 and EXP-2025G of Kelmar Industries, Y-14128, Y-14344, Y-14461 and FTS-226 of the Crompton Corporation, and Dow Corning 8620, Dow Corning 2-8182, Dow Corning HMW2220 and Dow Corning 2-8194 of the Dow Corning " C ⁇ fp ⁇ raf ⁇ o ⁇ " .” " fn ' some embodiments the basesheet may comprise ingredients found in the additive composition for the purpose of modifying the physical and tactile properties of the basesheet but are not intended to be delivered to the surface being wiped by the article.
- the following is one example of an additive composition that may be used in accordance with the present disclosure.
- the following additive composition is well suited for healing irritated skin or for preventing the skin from becoming irritated.
- the following formulation for instance, is well suited for use on a facial tissue to protect one's nose.
- the amount of additive composition applied to the tissue ply 12 as shown in Fig. 1 A may also vary depending upon the particular application.
- the amount of additive composition applied to the tissue ply 12 can be sufficient so that an effective or desired amount of the composition is transferred to an adjacent surface.
- relatively high amounts on a per area basis may be applied to the base sheet. In this manner, greater amounts of the additive composition will be transferred during product use.
- the additive composition may be contained in the target delivery zone in an amount from about 2 gsm to about 150 gsm or greater.
- tfie'adfdl ⁇ live " " c ⁇ mp ⁇ s ⁇ t ⁇ bn may be present on the base sheet in an amount from about 5 gsm to about 50 gsm.
- the additive composition may be present on the base sheet in an amount of at least 25 gsm.
- the additive composition is used in a more efficient manner.
- Table 1 compares a conventional two or three ply facial tissue containing an additive composition in comparison to a similarly constructed facial tissue containing the additive composition in a target delivery zone.
- the tissue sheets have a standard size of 8.5" by 8.5" and have the additive composition applied to the tissue such that the total additive composition in the sheet is 8% by weight.
- the target delivery zone has dimensions of 2.75" by 2.75".
- tissue products typically have relatively high bulk characteristics.
- tissue products may have a dry bulk of greater than about 2 cc/g, such as greater than about 4 cc/g, such as greater than about 6 cc/g.
- the bulk of the tissue webs may be greater than about 7 cc/g, such as greater than about 9 cc/g.
- tissue sheets that are pattern densified or imprinted, such as the webs disclosed in any of the following U.S.
- Such imprinted tissue webs may have a network of densified regions that have been imprinted against a drum dryer by an imprinting fabric, and regions that are relatively less densified (e.g., "domes" in the tissue sheet) corresponding to deflection conduits in the imprinting fabric, wherein the tissue sheet superposed over the deflection conduits is deflected by an air pressure differential across the deflection conduit to form a lower-density pillow-like region or dome in the tissue sheet.
- regions that are relatively less densified e.g., "domes" in the tissue sheet
- drying operations may be useful in the manufacture of the tissue products of the present invention.
- drying methods include, but are not limited to, drum drying, through drying, steam drying such as superheated steam drying, displacement dewatering, Yankee drying, infrared drying, microwave drying, radiofrequency drying in general, and impulse drying, as disclosed in U.S. Patent No. 5,353,521 , issued on October 11 , 1994 to Orloff and U.S. Patent No. 5,598,642, issued on February 4, 1997 to Orloff et al., the disclosures of both which are herein incorporated by reference to the extent that they are non- contradictory herewith.
- Other drying technologies may be used, such as methods employing differential gas pressure include the use of air presses as disclosed U.S. Patent No.
- the tissue product may contain a variety of fiber types both natural and synthetic.
- the tissue product comprises hardwood and softwood fibers.
- the overall ratio of hardwood pulp fibers to softwood pulp fibers within the tissue product, including individual tissue sheets making up the product may vary broadly.
- the ratio of hardwood pulp fibers to softwood pulp fibers may range from about 9:1 to about 1 :9, more specifically from about 9:1 to about 1 :4, and most specifically from about 9:1 to about 1 :1.
- the hardwood pulp fibers and softwood pulp fibers may be blended prior to forming the tissue web thereby producing a homogenous distribution of hardwood pulp fibers and softwood pulp fibers in the z-direction of the tissue web.
- the hardwood pulp fibers and softwood pulp fibers may be layered (stratified fiber furnish) so as to give a heterogeneous distribution of hardwood pulp fibers and softwood pulp fibers in the z-direction of the tissue web.
- the hardwood pulp fibers may be located in at least one of the outer layers of the tissue product and'/or tissue webs wrferein at least one of the inner layers may comprise softwood pulp fibers.
- the tissue product contains secondary or recycled fibers optionally containing virgin or synthetic fibers.
- synthetic fibers may also be utilized in the present invention.
- pulp fibers is understood to include synthetic fibers.
- suitable polymers that may be used to form the synthetic fibers include, but are not limited to: polyolefins, such as, polyethylene, polypropylene, polybutylene, and the like; polyesters, such as polyethylene terephthalate, poly(glycolic acid) (PGA), poly(lactic acid) (PLA), poly( ⁇ -malic acid) (PMLA), poly( ⁇ -caprolactone) (PCL), poly(p-dioxanone) (PDS), poly(3-hydroxybutyrate) (PHB), and the like; and, polyamides, such as nylon and the like.
- polyolefins such as, polyethylene, polypropylene, polybutylene, and the like
- polyesters such as polyethylene terephthalate, poly(glycolic acid) (PGA), poly(lactic acid) (PLA), poly( ⁇ -malic acid) (PMLA), poly( ⁇
- Synthetic or natural cellulosic polymers including but not limited to: cellulosic esters; cellulosic ethers; cellulosic nitrates; cellulosic acetates; cellulosic acetate butyrates; ethyl cellulose; regenerated celluloses, such as viscose, rayon, and the like; cotton; flax; hemp; and mixtures thereof may be used in the present invention.
- the synthetic fibers may be located in one or all of the layers and sheets comprising the tissue product.
- the basis weight of tissue products treated in accordance with the present invention can also vary depending upon the ultimate use for the product.
- the basis weight can range from about 6 gsm to 200 gsm and greater.
- the tissue product can have a basis weight of from about 6 gsm to about 80 gsm.
- the tissue product retains most of its fluid handling capabilities.
- the tissue product may have a specific liquid absorbent capacity of greater than about 4 g/g, such as from about 5 g/g to about 15 g/g.
- the specific liquid absorbent capacity of a product refers to the absorbent capacity of the entire sheet including the treated region.
- the tissue product 20 in order to increase the amount of additive composition that is transferred to an opposing surface when the tissue product is wiped against the surface, the tissue product 20 includes a film 28 that is adhered to the base web 22 in the target delivery zone 26.
- the film 28 is positioned in between the base web 22 and the additive composition.
- any suitable film may be used that can be attached to the base web 22 and that causes greater amounts of the additive composition to transfer to an opposing surface.
- the film may be made from a thermoplastic polymer.
- the film may be made from a polyolefin such as polyethylene or polypropylene, from a polyester, from a polyamide, from a polyvinyl chloride, from combinations thereof, from copolymers thereof, and the like.
- the film may comprise a biodegradable polymer from a renewable or non-renewable resource.
- any suitable adhesive material or method may be used.
- the adhesive material may comprise a pressure sensitive adhesive.
- the film serves as a barrier and prevents the additive composition from being absorbed by the base web 22.
- the film may be mechanically or thermally bonded to the sheet via processes such as embossing, heat embossing and the like.
- any method known in the art for creating film laminates may be used.
- the additive may be applied to the film area prior to or after attaching to the basesheet.
- tissue product 30 As shown in Fig. 3 is similar to the tissue product 20 shown in Fig. 2.
- the tissue product 30 includes a target delivery zone 36 containing an additive composition positioned on a base web 32.
- a nonwoven web 38 is positioned in between the additive composition and the base web 32.
- the nonwoven web 38 can comprise any material that does not absorb appreciable amounts of the additive composition and allows the composition to transfer from the surface of the web.
- the nonwoven web 38 may comprise a bonded carded web, an airlaid web or a tiD ⁇ ibWd ' wiB " : 11 1 ⁇ oi ⁇ particular embodiment, the nonwoven web 38 comprises a meltblown web.
- the nonwoven web 38 can be made from various polymeric materials.
- the nonwoven web 38 may be made from a polyolefin such as polypropylene or polyethylene, from a polyamide, from a polyester, from combinations thereof, from copolymers thereof, and the like.
- the nonwoven web 38 may be adhered to the base web 32 using a suitable adhesive material.
- the nonwoven web 32 may be bonded to the base web 32 using a mechanical attachment or through thermal bonding.
- a film or nonwoven web may be positioned on the opposite side of the base web.
- a tissue product generally 40 is shown that includes a base web 42 defining a target delivery zone 46.
- An additive composition is applied on the base web in the target delivery zone 46.
- a film or nonwoven web 48 is positioned on the opposite side of the base web 42 in forming the target delivery zone 46.
- the film or nonwoven web 48 prevents the additive composition from bleeding through the base web 42.
- the base web 42 may be perforated in the target delivery zone so as to minimize the amount of additive composition that is absorbed by the base web.
- the tissue product 50 includes a base web 52 defining a target delivery zone 56.
- An additive composition is applied to the target delivery zone.
- the additive composition is located on a modified portion 58 of the base web 52.
- the modified portion 58 may comprise, for example, any of the embodiments described above such as a polymer film, nonwoven web, or a topical treatment such as a sizing agent, resin or wax.
- the modified portion 58 is larger than and surrounds the target delivery zone 56 forming a boundary 59.
- the boundary 59 separates the additive composition from the remainder of the base web 52.
- the boundary 59 may be non-absorbent and therefore may prevent the additive composition from wicking or otherwise distributing in the X-Y direction. In other words, the boundary 59 prevents the additive composition from migrating onto the untreated portions of the base web 52.
- Use of a boundary 59 may be particularly beneficial when the additive composition comprises a liquid at room temperature.
- the target delivery zone may be placed at any suitable location on the tissue product.
- the additive composition may be located along a fold line so that the additive composition folds upon itself during packaging.
- a tissue product generally 60 is shown including a base web 62 that contains a first fold line 72 and a second fold line 74.
- the target delivery zone 66 is positioned along the fold line 74 so that when the base web 62 is folded for packaging the additive composition folds upon itself. In this manner, the additive composition remains within the target delivery zone during packaging and does not become absorbed by the untreated portions of the base web.
- the tissue product may comprise a multi-ply tissue sheet.
- One of the outer plies of the tissue product has been selectively modified in order to reduce the affinity of the substrate for the additive composition.
- the additive composition is applied to the entire modified ply or a portion of the modified ply so as to create a product having enhanced transfer of the additive composition.
- a barrier ply may or may not be present between the two outer plies so as to prevent migration of the additive in the z-direction onto the unmodified ply.
- the tissue product 60 includes a single target delivery zone 66. In an alternative embodiment, however, a first target delivery ' zone ' may be pb'siti ⁇ f ⁇ ed along the fold line 74 while a second target delivery zone may be positioned along the fold line 72.
- the tissue product 80 includes a base web 82 that is folded into quadrants 90, 92, 94 and 96.
- the tissue product 80 includes a first target delivery zone 86A located on the quadrant 90 and a second target delivery zone 86B located on the quadrant 94.
- consumers are known to fold the tissue in half to contain the nasal discharge within the inside of the tissue and then perform a final dry wiping exercise with the outside surface. In this case, they are likely to fold the tissue once more into quadrants.
- this procedure causes the target delivery zones 86B and 86A to contact the nose during this final wiping step.
- the target delivery zones may be placed in quadrants or at other suitable locations so that the two target delivery zones fold upon each other when the product is folded and packaged.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008545570A JP2009523121A (en) | 2005-12-15 | 2006-08-01 | Tissue products with transferable additive composition |
BRPI0619937-2A BRPI0619937A2 (en) | 2005-12-15 | 2006-08-01 | textile product having a transferable additive composition |
EP20060789162 EP1982018B1 (en) | 2005-12-15 | 2006-08-01 | Tissue product having a transferable additive composition |
CA 2631321 CA2631321A1 (en) | 2005-12-15 | 2006-08-01 | Tissue product having a transferable additive composition |
AU2006325523A AU2006325523B2 (en) | 2005-12-15 | 2006-08-01 | Tissue product having a transferable additive composition |
CN2006800467008A CN101331275B (en) | 2005-12-15 | 2006-08-01 | Tissue product having a transferable additive composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/304,985 | 2005-12-15 | ||
US11/304,985 US7988824B2 (en) | 2005-12-15 | 2005-12-15 | Tissue product having a transferable additive composition |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007070114A1 true WO2007070114A1 (en) | 2007-06-21 |
Family
ID=37561218
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2006/030035 WO2007070114A1 (en) | 2005-12-15 | 2006-08-01 | Tissue product having a transferable additive composition |
Country Status (11)
Country | Link |
---|---|
US (1) | US7988824B2 (en) |
EP (1) | EP1982018B1 (en) |
JP (1) | JP2009523121A (en) |
KR (1) | KR20080083115A (en) |
CN (1) | CN101331275B (en) |
AU (1) | AU2006325523B2 (en) |
BR (1) | BRPI0619937A2 (en) |
CA (1) | CA2631321A1 (en) |
RU (1) | RU2412297C2 (en) |
WO (1) | WO2007070114A1 (en) |
ZA (1) | ZA200804330B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1732709A2 (en) * | 2004-04-06 | 2006-12-20 | Thi International, LLC | Apparatus and method for treating mulch |
WO2008068651A2 (en) * | 2006-12-07 | 2008-06-12 | Kimberly-Clark Worldwide, Inc. | Process for producing tissue products |
WO2008068653A1 (en) * | 2006-12-07 | 2008-06-12 | Kimberly-Clark Worldwide, Inc. | Additive compositions for treating various base sheets |
WO2008157132A1 (en) * | 2007-06-14 | 2008-12-24 | Dow Global Technologies Inc. | Additive compositions for treating various base sheets |
US8105463B2 (en) | 2009-03-20 | 2012-01-31 | Kimberly-Clark Worldwide, Inc. | Creped tissue sheets treated with an additive composition according to a pattern |
US8282776B2 (en) | 2005-12-15 | 2012-10-09 | Kimberly-Clark Worldwide, Inc. | Wiping product having enhanced oil absorbency |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080171150A1 (en) * | 2002-04-01 | 2008-07-17 | Thi International, Llc | Apparatus and Method for Treating Mulch |
US7811613B2 (en) | 2005-06-23 | 2010-10-12 | The Procter & Gamble Company | Individualized trichomes and products employing same |
AU2009267803B2 (en) * | 2008-07-11 | 2016-04-21 | Monash University | Method of fabricating microfluidic systems |
MX2012008050A (en) * | 2010-01-14 | 2012-08-01 | Procter & Gamble | Soft and strong fibrous structures and methods for making same. |
US9238348B2 (en) | 2010-10-08 | 2016-01-19 | Kimberly-Clark Worldwide, Inc. | Method of manufacture of article for delivering health-benefit agent |
US8552251B2 (en) | 2010-10-08 | 2013-10-08 | Kimberly-Clark Worldwide, Inc. | Article with health-benefit agent delivery system |
EP2720862B1 (en) | 2011-06-17 | 2016-08-24 | Fiberweb, Inc. | Vapor permeable, substantially water impermeable multilayer article |
EP2723568B1 (en) | 2011-06-23 | 2017-09-27 | Fiberweb, LLC | Vapor permeable, substantially water impermeable multilayer article |
US10369769B2 (en) | 2011-06-23 | 2019-08-06 | Fiberweb, Inc. | Vapor-permeable, substantially water-impermeable multilayer article |
WO2012178011A2 (en) | 2011-06-24 | 2012-12-27 | Fiberweb, Inc. | Vapor-permeable, substantially water-impermeable multilayer article |
WO2013110008A1 (en) | 2012-01-18 | 2013-07-25 | Worldwide Innovative Healthcare, Inc. | Modifiable occlusive skin dressing |
US10745864B2 (en) | 2016-10-25 | 2020-08-18 | The Procter & Gamble Company | Differential pillow height fibrous structures |
US10772695B2 (en) * | 2019-12-31 | 2020-09-15 | Henny Avitan | Glove with medicinal pads and differing thickness regions |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000072819A1 (en) * | 1999-05-27 | 2000-12-07 | The Procter & Gamble Company | Wipes and process of making |
WO2001049933A2 (en) | 1999-12-30 | 2001-07-12 | Sca Hygiene Products Gmbh | A method of applying treatment chemicals to a fiber-based planar product and products obtained by said method |
US20030114812A1 (en) * | 2001-12-18 | 2003-06-19 | Kimberly-Clark Worldwide, Inc. | Feminine care product with discrete areas of a skin wellness additive |
US20040118532A1 (en) * | 2002-12-20 | 2004-06-24 | Kimberly-Clark Worldwide, Inc. | Paper wiping products treated with a hydrophobic additive |
WO2004080358A1 (en) * | 2003-03-14 | 2004-09-23 | Sca Hygiene Products Ab | Carrier for additive in an absorbent article |
Family Cites Families (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1102203A (en) | 1910-07-05 | 1914-06-30 | Arthur H Scott | Paper-towel. |
US1775998A (en) | 1929-09-19 | 1930-09-16 | Greenberg Joseph | Medicated handkerchief |
US1960192A (en) | 1931-12-29 | 1934-05-22 | Standard Oil Dev Co | Composite cleaning and polishing paper |
US3814096A (en) | 1973-03-09 | 1974-06-04 | F Weiss | Facial tissue |
US4426418A (en) | 1975-06-30 | 1984-01-17 | Harry M. Weiss | Lubricated tissue |
US4601938A (en) | 1981-06-18 | 1986-07-22 | Lever Brothers Company | Article suitable for wiping surfaces |
US4440597A (en) | 1982-03-15 | 1984-04-03 | The Procter & Gamble Company | Wet-microcontracted paper and concomitant process |
US4610678A (en) * | 1983-06-24 | 1986-09-09 | Weisman Paul T | High-density absorbent structures |
US4529480A (en) | 1983-08-23 | 1985-07-16 | The Procter & Gamble Company | Tissue paper |
US4528239A (en) | 1983-08-23 | 1985-07-09 | The Procter & Gamble Company | Deflection member |
US4514345A (en) | 1983-08-23 | 1985-04-30 | The Procter & Gamble Company | Method of making a foraminous member |
US4481243A (en) | 1984-01-05 | 1984-11-06 | The Procter & Gamble Company | Pattern treated tissue paper product |
CA1252604A (en) | 1984-05-11 | 1989-04-18 | Gavin B. Rowe | Wiping article |
US5230776A (en) | 1988-10-25 | 1993-07-27 | Valmet Paper Machinery, Inc. | Paper machine for manufacturing a soft crepe paper web |
US5227242A (en) | 1989-02-24 | 1993-07-13 | Kimberly-Clark Corporation | Multifunctional facial tissue |
US4950545A (en) | 1989-02-24 | 1990-08-21 | Kimberly-Clark Corporation | Multifunctional facial tissue |
CA2026326A1 (en) * | 1989-10-04 | 1991-04-05 | James Arthur Davis | Disposable diaper having a humidity transfer region, breathable zone panel and separation layer |
US5101574A (en) | 1989-10-15 | 1992-04-07 | Institute Of Paper, Science & Technology, Inc. | Method and apparatus for drying web |
EP0536320B1 (en) | 1990-06-29 | 1994-08-31 | The Procter & Gamble Company | Papermaking belt and method of making the same using differential light transmission techniques |
US5260171A (en) | 1990-06-29 | 1993-11-09 | The Procter & Gamble Company | Papermaking belt and method of making the same using a textured casting surface |
US5275700A (en) | 1990-06-29 | 1994-01-04 | The Procter & Gamble Company | Papermaking belt and method of making the same using a deformable casting surface |
US5098522A (en) | 1990-06-29 | 1992-03-24 | The Procter & Gamble Company | Papermaking belt and method of making the same using a textured casting surface |
CA2069193C (en) | 1991-06-19 | 1996-01-09 | David M. Rasch | Tissue paper having large scale aesthetically discernible patterns and apparatus for making the same |
EP0851060B1 (en) | 1992-08-26 | 2002-10-30 | The Procter & Gamble Company | Papermaking apparatus having semicontinuous pattern |
US5667636A (en) | 1993-03-24 | 1997-09-16 | Kimberly-Clark Worldwide, Inc. | Method for making smooth uncreped throughdried sheets |
US5607551A (en) | 1993-06-24 | 1997-03-04 | Kimberly-Clark Corporation | Soft tissue |
CN1070964C (en) | 1993-12-20 | 2001-09-12 | 普罗克特和甘保尔公司 | Wet pressed paper web and method of making same |
US5695607A (en) | 1994-04-01 | 1997-12-09 | James River Corporation Of Virginia | Soft-single ply tissue having very low sidedness |
US5500277A (en) | 1994-06-02 | 1996-03-19 | The Procter & Gamble Company | Multiple layer, multiple opacity backside textured belt |
US5496624A (en) | 1994-06-02 | 1996-03-05 | The Procter & Gamble Company | Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby |
US5601871A (en) | 1995-02-06 | 1997-02-11 | Krzysik; Duane G. | Soft treated uncreped throughdried tissue |
US5665426A (en) | 1995-02-06 | 1997-09-09 | Kimberly-Clark Corporation | Soft treated tissue |
US5598642A (en) | 1995-05-12 | 1997-02-04 | Institute Of Paper Science And Technology, Inc. | Method and apparatus for drying a fiber web at elevated ambient pressures |
US5624724A (en) | 1996-04-08 | 1997-04-29 | Shimmer, Inc. | Self retainable shim |
US6143135A (en) | 1996-05-14 | 2000-11-07 | Kimberly-Clark Worldwide, Inc. | Air press for dewatering a wet web |
US6096169A (en) | 1996-05-14 | 2000-08-01 | Kimberly-Clark Worldwide, Inc. | Method for making cellulosic web with reduced energy input |
US6217707B1 (en) | 1996-12-31 | 2001-04-17 | Kimberly-Clark Worldwide, Inc. | Controlled coverage additive application |
US6498284B1 (en) * | 1997-11-14 | 2002-12-24 | The Procter & Gamble Company | Disposable absorbent article with a skin care composition on an apertured top sheet |
US20020001726A1 (en) * | 1999-12-27 | 2002-01-03 | Kimberly-Clark Worldwide, Inc. | Modified siloxane yielding transferring benefits from soft tissue products |
US6607636B2 (en) * | 2001-11-01 | 2003-08-19 | Kimberly-Clark Worldwide, Inc. | Non-rewetting multi-fiber hand towel and methods of making same |
US6989339B2 (en) * | 2002-08-15 | 2006-01-24 | National Starch And Chemical Investment Holding Corporation | Nonwoven webs treated with fixed mobile materials |
SE525872C2 (en) * | 2002-09-06 | 2005-05-17 | Stora Enso Ab | Method of producing mechanical pulp with reduced energy consumption |
US7182837B2 (en) * | 2002-11-27 | 2007-02-27 | Kimberly-Clark Worldwide, Inc. | Structural printing of absorbent webs |
US6949167B2 (en) * | 2002-12-19 | 2005-09-27 | Kimberly-Clark Worldwide, Inc. | Tissue products having uniformly deposited hydrophobic additives and controlled wettability |
US7306699B2 (en) * | 2002-12-31 | 2007-12-11 | Kimberly-Clark Worldwide, Inc. | Tissue product containing a topical composition in the form of discrete droplets |
US20040163785A1 (en) * | 2003-02-20 | 2004-08-26 | Shannon Thomas Gerard | Paper wiping products treated with a polysiloxane composition |
US7601882B2 (en) * | 2003-03-14 | 2009-10-13 | Sca Hygiene Products Ab | Carrier for additive in an absorbent article |
US7470345B2 (en) * | 2003-12-30 | 2008-12-30 | Kimberly-Clark Worldwide, Inc. | Rolled paper product having high bulk and softness |
US20050241789A1 (en) | 2004-04-30 | 2005-11-03 | Kimberly-Clark Worldwide, Inc. | Surface treated paper product |
-
2005
- 2005-12-15 US US11/304,985 patent/US7988824B2/en not_active Expired - Fee Related
-
2006
- 2006-08-01 CN CN2006800467008A patent/CN101331275B/en not_active Expired - Fee Related
- 2006-08-01 KR KR1020087014195A patent/KR20080083115A/en not_active Application Discontinuation
- 2006-08-01 EP EP20060789162 patent/EP1982018B1/en not_active Revoked
- 2006-08-01 RU RU2008128306A patent/RU2412297C2/en not_active IP Right Cessation
- 2006-08-01 WO PCT/US2006/030035 patent/WO2007070114A1/en active Application Filing
- 2006-08-01 JP JP2008545570A patent/JP2009523121A/en not_active Withdrawn
- 2006-08-01 CA CA 2631321 patent/CA2631321A1/en not_active Abandoned
- 2006-08-01 BR BRPI0619937-2A patent/BRPI0619937A2/en not_active IP Right Cessation
- 2006-08-01 AU AU2006325523A patent/AU2006325523B2/en not_active Ceased
-
2008
- 2008-05-20 ZA ZA200804330A patent/ZA200804330B/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000072819A1 (en) * | 1999-05-27 | 2000-12-07 | The Procter & Gamble Company | Wipes and process of making |
WO2001049933A2 (en) | 1999-12-30 | 2001-07-12 | Sca Hygiene Products Gmbh | A method of applying treatment chemicals to a fiber-based planar product and products obtained by said method |
US20030114812A1 (en) * | 2001-12-18 | 2003-06-19 | Kimberly-Clark Worldwide, Inc. | Feminine care product with discrete areas of a skin wellness additive |
US20040118532A1 (en) * | 2002-12-20 | 2004-06-24 | Kimberly-Clark Worldwide, Inc. | Paper wiping products treated with a hydrophobic additive |
WO2004080358A1 (en) * | 2003-03-14 | 2004-09-23 | Sca Hygiene Products Ab | Carrier for additive in an absorbent article |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1732709A2 (en) * | 2004-04-06 | 2006-12-20 | Thi International, LLC | Apparatus and method for treating mulch |
EP1732709A4 (en) * | 2004-04-06 | 2008-06-18 | Thi International Llc | Apparatus and method for treating mulch |
US8282776B2 (en) | 2005-12-15 | 2012-10-09 | Kimberly-Clark Worldwide, Inc. | Wiping product having enhanced oil absorbency |
WO2008068651A2 (en) * | 2006-12-07 | 2008-06-12 | Kimberly-Clark Worldwide, Inc. | Process for producing tissue products |
WO2008068653A1 (en) * | 2006-12-07 | 2008-06-12 | Kimberly-Clark Worldwide, Inc. | Additive compositions for treating various base sheets |
WO2008068651A3 (en) * | 2006-12-07 | 2008-10-16 | Kimberly Clark Co | Process for producing tissue products |
WO2008157132A1 (en) * | 2007-06-14 | 2008-12-24 | Dow Global Technologies Inc. | Additive compositions for treating various base sheets |
US8105463B2 (en) | 2009-03-20 | 2012-01-31 | Kimberly-Clark Worldwide, Inc. | Creped tissue sheets treated with an additive composition according to a pattern |
Also Published As
Publication number | Publication date |
---|---|
JP2009523121A (en) | 2009-06-18 |
BRPI0619937A2 (en) | 2011-10-25 |
KR20080083115A (en) | 2008-09-16 |
CA2631321A1 (en) | 2007-06-21 |
CN101331275A (en) | 2008-12-24 |
CN101331275B (en) | 2012-11-21 |
AU2006325523A1 (en) | 2007-06-21 |
RU2008128306A (en) | 2010-01-20 |
US20070137812A1 (en) | 2007-06-21 |
EP1982018B1 (en) | 2012-10-03 |
US7988824B2 (en) | 2011-08-02 |
AU2006325523B2 (en) | 2011-04-14 |
ZA200804330B (en) | 2009-09-30 |
RU2412297C2 (en) | 2011-02-20 |
EP1982018A1 (en) | 2008-10-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1982018B1 (en) | Tissue product having a transferable additive composition | |
CA2879397C (en) | Absorbent articles comprising organopolysiloxane conditioning polymers | |
CA2622804C (en) | Lotioned fibrous structures | |
JP5634393B2 (en) | A tissue product that gives a cooling sensation when in contact with the skin | |
AU2014342318B2 (en) | One-way valve nonwoven material | |
AU2005238469B2 (en) | Fibrous structures comprising a surface treating composition and a lotion composition | |
US20070196405A1 (en) | Fibrous structures comprising volatile agents | |
US20050238699A1 (en) | Fibrous structures comprising a surface treating composition and lotion composition | |
MX2008007529A (en) | Tissue product having a transferable additive composition | |
AU2015416289B2 (en) | Structures containing thermo-sensitive gels | |
US20230340730A1 (en) | Facial Tissue Comprising An Interleaved Waterproofing Plastic Film. | |
MX2008010587A (en) | Fibrous structures comprising volatile agents |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200680046700.8 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2006325523 Country of ref document: AU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2631321 Country of ref document: CA |
|
ENP | Entry into the national phase |
Ref document number: 2006325523 Country of ref document: AU Date of ref document: 20060801 Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008545570 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: MX/a/2008/007529 Country of ref document: MX Ref document number: 2006789162 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020087014195 Country of ref document: KR |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008128306 Country of ref document: RU |
|
ENP | Entry into the national phase |
Ref document number: PI0619937 Country of ref document: BR Kind code of ref document: A2 Effective date: 20080617 |