WO2007146278A3 - Sizing composition for glass fibers, sized glass products, and composites - Google Patents

Sizing composition for glass fibers, sized glass products, and composites Download PDF

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Publication number
WO2007146278A3
WO2007146278A3 PCT/US2007/013764 US2007013764W WO2007146278A3 WO 2007146278 A3 WO2007146278 A3 WO 2007146278A3 US 2007013764 W US2007013764 W US 2007013764W WO 2007146278 A3 WO2007146278 A3 WO 2007146278A3
Authority
WO
WIPO (PCT)
Prior art keywords
sizing composition
glass
composites
present
glass fibers
Prior art date
Application number
PCT/US2007/013764
Other languages
French (fr)
Other versions
WO2007146278A2 (en
Inventor
Jacob Cornelis Dijt
De Heisteeg Bartholomeus J Van
Helene A J M Bakkum
Der Woude Jacobus Hendricu Van
Original Assignee
Ppg Ind Ohio Inc
Jacob Cornelis Dijt
De Heisteeg Bartholomeus J Van
Helene A J M Bakkum
Der Woude Jacobus Hendricu Van
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ppg Ind Ohio Inc, Jacob Cornelis Dijt, De Heisteeg Bartholomeus J Van, Helene A J M Bakkum, Der Woude Jacobus Hendricu Van filed Critical Ppg Ind Ohio Inc
Publication of WO2007146278A2 publication Critical patent/WO2007146278A2/en
Publication of WO2007146278A3 publication Critical patent/WO2007146278A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/544—Silicon-containing compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209—Inorganic fibres
    • D04H1/4218—Glass fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/205—Compounds containing groups, e.g. carbamates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity

Abstract

The present invention relates to sizing compositions for glass fibers and glass fiber reinforced resins. In one embodiment, the present invention provides a sizing composition comprising at least one polyvinyl alcohol in an amount greater than about 65 weight percent of the sizing composition on a total solids basis, and at least one coupling agent in an amount greater than about 5 weight percent of the sizing composition on a total solids basis. Embodiments of the present invention also relate to fiber glass strands, glass fiber reinforced resin compositions, and methods for producing composites.
PCT/US2007/013764 2006-06-13 2007-06-12 Sizing composition for glass fibers, sized glass products, and composites WO2007146278A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/452,024 2006-06-13
US11/452,024 US20070286999A1 (en) 2006-06-13 2006-06-13 Sizing composition for glass fibers, sized fiber glass products, and composites

Publications (2)

Publication Number Publication Date
WO2007146278A2 WO2007146278A2 (en) 2007-12-21
WO2007146278A3 true WO2007146278A3 (en) 2008-03-20

Family

ID=38822344

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/013764 WO2007146278A2 (en) 2006-06-13 2007-06-12 Sizing composition for glass fibers, sized glass products, and composites

Country Status (3)

Country Link
US (1) US20070286999A1 (en)
TW (1) TW200808672A (en)
WO (1) WO2007146278A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070154697A1 (en) * 2005-12-30 2007-07-05 Cossement Marc R Two-part sizing composition for reinforcement fibers
WO2010029387A1 (en) * 2008-09-11 2010-03-18 Idris Kaynak A method for production of a nano-reinforced material
WO2010044461A1 (en) * 2008-10-17 2010-04-22 日本ゼオン株式会社 Polymerizable composition, cross-linkable molded object, crosslinked molded object, and crosslinked molded object composite body
EP2559673B1 (en) * 2011-08-19 2018-10-03 Johns Manville Sizing composition for fibers and sized fibers
US20150284289A1 (en) * 2014-04-04 2015-10-08 Ppg Industries Ohio, Inc. Sizing Compositions for Wet and Dry Filament Winding
CN107698942B (en) * 2014-06-30 2020-06-02 赛史品威奥（唐山）结构复合材料有限公司 Sheet molding composition comprising surface-modified glass filler
MX2020001514A (en) * 2017-08-07 2020-08-17 Zoltek Corp Polyvinyl alcohol-sized fillers for reinforcing plastics.
CN110685087A (en) * 2019-11-22 2020-01-14 上海曙雀贸易有限公司 Coating film-forming glass fiber yarn and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4338233A (en) * 1981-06-15 1982-07-06 Ppg Industries, Inc. Aqueous sizing composition and sized glass fibers and method
US4455343A (en) * 1980-12-29 1984-06-19 Ppg Industries, Inc. Aqueous treating composition for glass fiber strands used to produce mats for thermoplastics
EP0450638A1 (en) * 1990-04-05 1991-10-09 Ppg Industries, Inc. Chemical composition to produce water soluble curable films on fibrous surfaces and so treated glass fibers
EP0546779A1 (en) * 1991-12-13 1993-06-16 Shimadzu Corporation Oxynitride glass fiber for composite products, and glass fiber-reinforced products

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4185138A (en) * 1978-12-20 1980-01-22 Ppg Industries, Inc. Size composition and method of producing same to render glass fiber having improved dispersibility in aqueous solutions
DE3107008A1 (en) * 1981-02-25 1982-09-09 Hoechst Ag, 6000 Frankfurt SIZING AGENT FOR SYNTHESIS FIBERS
US4845140A (en) * 1986-07-07 1989-07-04 Air Products And Chemicals, Inc. Waxless polyvinyl alcohol size composition
US5024890A (en) * 1987-03-12 1991-06-18 Owens-Corning Fiberglass Corporation Size composition for impregnating filament strands and glass fibers coated therein
WO1992000837A1 (en) * 1990-07-06 1992-01-23 Ube-Nitto Kasei Co., Ltd. Fiber-reinforced polyamide resin composition and production thereof
US5300696A (en) * 1992-12-29 1994-04-05 Uop C4 rejection for etherification and isomerization process
EP0990727A1 (en) * 1998-10-02 2000-04-05 Johns Manville International Inc. Polycarboxy/polyol fiberglass binder
US6955844B2 (en) * 2002-05-24 2005-10-18 Innovative Construction And Building Materials Construction materials containing surface modified fibers
US7144600B2 (en) * 2003-02-18 2006-12-05 Milliken & Company Wax-free lubricant for use in sizing yarns, methods using same and fabrics produced therefrom
US6884838B2 (en) * 2003-02-20 2005-04-26 Johns Manville International, Inc. Water repellant fiberglass binder
US6884849B2 (en) * 2003-02-21 2005-04-26 Owens-Corning Fiberglas Technology, Inc. Poly alcohol-based binder composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4455343A (en) * 1980-12-29 1984-06-19 Ppg Industries, Inc. Aqueous treating composition for glass fiber strands used to produce mats for thermoplastics
US4338233A (en) * 1981-06-15 1982-07-06 Ppg Industries, Inc. Aqueous sizing composition and sized glass fibers and method
EP0450638A1 (en) * 1990-04-05 1991-10-09 Ppg Industries, Inc. Chemical composition to produce water soluble curable films on fibrous surfaces and so treated glass fibers
EP0546779A1 (en) * 1991-12-13 1993-06-16 Shimadzu Corporation Oxynitride glass fiber for composite products, and glass fiber-reinforced products

Also Published As

Publication number Publication date
WO2007146278A2 (en) 2007-12-21
TW200808672A (en) 2008-02-16
US20070286999A1 (en) 2007-12-13

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