WO2008014217A3 - Fluorenyl catalyst compositions and olefin polymerization process - Google Patents

Fluorenyl catalyst compositions and olefin polymerization process Download PDF

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Publication number
WO2008014217A3
WO2008014217A3 PCT/US2007/074150 US2007074150W WO2008014217A3 WO 2008014217 A3 WO2008014217 A3 WO 2008014217A3 US 2007074150 W US2007074150 W US 2007074150W WO 2008014217 A3 WO2008014217 A3 WO 2008014217A3
Authority
WO
WIPO (PCT)
Prior art keywords
group
polymerization process
olefin polymerization
catalyst compositions
fluorenyl
Prior art date
Application number
PCT/US2007/074150
Other languages
French (fr)
Other versions
WO2008014217A2 (en
Inventor
Vladimir Marin
Abbas Razavi
Original Assignee
Fina Technology
Vladimir Marin
Abbas Razavi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology, Vladimir Marin, Abbas Razavi filed Critical Fina Technology
Priority to ES07813246T priority Critical patent/ES2749498T3/en
Priority to JP2009521933A priority patent/JP2009544819A/en
Priority to EP07813246.1A priority patent/EP2044131B1/en
Publication of WO2008014217A2 publication Critical patent/WO2008014217A2/en
Publication of WO2008014217A3 publication Critical patent/WO2008014217A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

An olefin polymerization process comprising contacting one or more olefins and a catalyst component in a reaction zone under suitable reaction conditions to form a polyolefin, wherein the catalyst component is characterized by the formula: B(Cp)(Fl)MQ2 wherein M comprises a metal, Q comprises a halogen, an alkyl group or an aryl group or combinations thereof, Cp comprises a cyclopentadienyl group, Fl comprises a fluorenyl group, B is a bridging group that may be characterized by the general formula -YRH wherein Y comprises C or Si and R comprises an alkyl group, an aryl group, a poly-aryl group or combinations thereof.
PCT/US2007/074150 2006-07-25 2007-07-24 Fluorenyl catalyst compositions and olefin polymerization process WO2008014217A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
ES07813246T ES2749498T3 (en) 2006-07-25 2007-07-24 Fluorenyl catalyst compositions and olefin polymerization process
JP2009521933A JP2009544819A (en) 2006-07-25 2007-07-24 Fluorenyl catalyst composition and olefin polymerization method
EP07813246.1A EP2044131B1 (en) 2006-07-25 2007-07-24 Fluorenyl catalyst compositions and olefin polymerization process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/459,801 US7514510B2 (en) 2006-07-25 2006-07-25 Fluorenyl catalyst compositions and olefin polymerization process
US11/459,801 2006-07-25

Publications (2)

Publication Number Publication Date
WO2008014217A2 WO2008014217A2 (en) 2008-01-31
WO2008014217A3 true WO2008014217A3 (en) 2008-07-31

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PCT/US2007/074150 WO2008014217A2 (en) 2006-07-25 2007-07-24 Fluorenyl catalyst compositions and olefin polymerization process

Country Status (6)

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US (2) US7514510B2 (en)
EP (1) EP2044131B1 (en)
JP (1) JP2009544819A (en)
KR (1) KR20090035000A (en)
ES (1) ES2749498T3 (en)
WO (1) WO2008014217A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8247512B2 (en) * 2007-03-05 2012-08-21 Fina Technology, Inc. Metallocene random copolymers with cool temperature impact properties
US20080287619A1 (en) * 2007-05-18 2008-11-20 William Gauthier Supported metallocene catalysts
US8299188B2 (en) * 2007-05-18 2012-10-30 Fina Technology, Inc. Supported metallocene catalysts
EP2196481A1 (en) * 2008-12-12 2010-06-16 Total Petrochemicals Research Feluy Preparation of long-chain branched isotactic polypropylene.
EP2204375A1 (en) * 2008-12-12 2010-07-07 Total Petrochemicals Research Feluy Preparation of mono-aryl-substituted methylene-bridged substituted cyclopentadienyl-fluorenyl ligands and zirconium complexes derived thereof
US8288487B2 (en) * 2010-07-06 2012-10-16 Chevron Phillips Chemical Company Lp Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
EP2880097B1 (en) 2012-08-03 2023-10-18 ExxonMobil Chemical Patents Inc. Process to prepare a vinyl terminated polyethylene with long chain branching
US9365661B2 (en) 2012-08-03 2016-06-14 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified salan catalyst compounds
KR101394943B1 (en) * 2012-11-19 2014-05-14 대림산업 주식회사 Copolymer of ethylene and alpha-olefin and method for producing the same
BR112015028319B8 (en) * 2013-05-22 2021-07-06 Borealis Ag propylene copolymer, injection molded article, thin packaging and copolymer production process
AU2014270633B2 (en) * 2013-05-22 2016-06-02 Borealis Ag Polypropylene for film applications
US9290589B2 (en) * 2013-12-13 2016-03-22 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
KR101666170B1 (en) 2014-06-18 2016-10-13 주식회사 엘지화학 Transition metal compounds, catalyst composition comprising the same, and preparation method of poly-olefin
CN108472639B (en) * 2015-08-11 2021-06-18 格雷斯公司 Electron donor of polyolefin polymerization catalyst and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6002033A (en) * 1995-11-22 1999-12-14 Fina Research, S.A. Bridged metallocenes for use in catalyst systems
WO2004020481A1 (en) * 2002-08-29 2004-03-11 Lg Chem, Ltd. Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same

Family Cites Families (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4271060A (en) 1979-09-17 1981-06-02 Phillips Petroleum Company Solution polymerization process
DE3007725A1 (en) 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn METHOD FOR PRODUCING POLYETHYLENE, POLYPROPYLENE AND COPOLYMERS
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4767735A (en) 1987-02-02 1988-08-30 Cosden Technology, Inc. Catalyst pretreatment process
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
FR2634212B1 (en) 1988-07-15 1991-04-19 Bp Chimie Sa APPARATUS AND METHOD FOR POLYMERIZATION OF GASEOUS OLEFINS IN A FLUIDIZED BED REACTOR
US5155080A (en) 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5266607A (en) * 1989-11-30 1993-11-30 Rexene Products Company Crystallization enhancement of polyolefins
US5236998A (en) 1991-03-07 1993-08-17 Occidental Chemical Corporation Process for the manufacture of linear polyethylene containing α-alkene commonomers
US5571880A (en) * 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
US5589555A (en) 1991-10-03 1996-12-31 Novacor Chemicals (International) S.A. Control of a solution process for polymerization of ethylene
US5176872A (en) * 1992-02-19 1993-01-05 Rexene Products Company Polypropylene resins for multiple cavity stretch blow molding
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5456471A (en) 1992-08-18 1995-10-10 Macdonald; Donald K. Golf practice apparatus and fabricating process
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
KR100190268B1 (en) 1993-04-26 1999-06-01 에인혼 해롤드 Process for polymerizing monomers in fludized beds
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US6245705B1 (en) 1993-11-18 2001-06-12 Univation Technologies Cocatalysts for metallocene-based olefin polymerization catalyst systems
US6143686A (en) 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
US5643847A (en) 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US5525690A (en) * 1994-08-05 1996-06-11 Solvay (Societe Anonyme) Process for the preparation of a polyolefin and syndiotactic polypropylene
US5525678A (en) 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
US5712404A (en) * 1995-05-15 1998-01-27 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocene compounds catalyst systems, preparation and use
US5677375A (en) 1995-07-21 1997-10-14 Union Carbide Chemicals & Plastics Technology Corporation Process for producing an in situ polyethylene blend
US5665818A (en) 1996-03-05 1997-09-09 Union Carbide Chemicals & Plastics Technology Corporation High activity staged reactor process
US5627242A (en) 1996-03-28 1997-05-06 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling gas phase fluidized bed polymerization reactor
EP0881236A1 (en) * 1997-05-26 1998-12-02 Fina Research S.A. Metallocene catalyst component for use in producing isotactic polyolefins
US6228795B1 (en) 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US6207606B1 (en) 1998-05-15 2001-03-27 Univation Technologies, Llc Mixed catalysts and their use in a polymerization process
US6245868B1 (en) * 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
US7354880B2 (en) * 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
US6147173A (en) 1998-11-13 2000-11-14 Univation Technologies, Llc Nitrogen-containing group 13 anionic complexes for olefin polymerization
US6180735B1 (en) 1998-12-17 2001-01-30 Univation Technologies Catalyst composition and methods for its preparation and use in a polymerization process
US6022946A (en) * 1998-12-23 2000-02-08 Union Carbide Chemicals & Plastics Technology Corporation Process for deactivation of polyolefin compositions utilizing carbon dioxide as a deactivation agent
US6469188B1 (en) * 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
EP1031582A1 (en) * 1999-02-26 2000-08-30 Fina Research S.A. Use and production of polypropylene
EP1041180A1 (en) * 1999-03-30 2000-10-04 Fina Research S.A. Polypropylene fibres
US6339134B1 (en) * 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6346586B1 (en) * 1999-10-22 2002-02-12 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6271323B1 (en) * 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6380328B1 (en) * 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6420580B1 (en) * 1999-11-05 2002-07-16 Univation Technologies, Llc Catalyst compositions and method of polymerization therewith
US6340730B1 (en) * 1999-12-06 2002-01-22 Univation Technologies, Llc Multiple catalyst system
US6359072B1 (en) * 2000-02-16 2002-03-19 Univation Technologies, Llc Polyethylene films having improved optical properties
US6846943B2 (en) * 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
EP1195391A1 (en) * 2000-10-05 2002-04-10 ATOFINA Research Production of polypropylene
JP2004066565A (en) * 2002-08-05 2004-03-04 Japan Polychem Corp Polypropylene sheet for thermoforming and its molding
US6855783B2 (en) * 2003-04-11 2005-02-15 Fina Technology, Inc. Supported metallocene catalysts
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
US20050148460A1 (en) 2004-01-02 2005-07-07 Vladimir Marin Catalyst components and their use in the polymerization of olefins
US7094938B1 (en) * 2005-05-20 2006-08-22 Fina Technology, Inc. Process for the preparation of substituted fluorenes
EP1734059A1 (en) * 2005-06-13 2006-12-20 Total Petrochemicals Research Feluy Carbon-bridged cyclopentadienyl-fluorenyl ligands
EP1734058A1 (en) * 2005-06-13 2006-12-20 Total Petrochemicals Research Feluy Ethylene and alpha-olefins polymerisation catalyst system based on fluorenyl ligand
US7335711B2 (en) * 2005-08-17 2008-02-26 Fina Technology, Inc. Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6002033A (en) * 1995-11-22 1999-12-14 Fina Research, S.A. Bridged metallocenes for use in catalyst systems
WO2004020481A1 (en) * 2002-08-29 2004-03-11 Lg Chem, Ltd. Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
ALT H.G. ET AL., JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 518, no. 1-2, 12 July 1996 (1996-07-12), pages 7 - 15, XP004035853 *
ALT H.G. ET AL.: "Syndiospezifische Polymerization von Propylene: Synthese CH2- und CHR-verbrückte fluorenylhaltiger Ligandvorstufen für Metallocenkomplexe des Typs (C13H8-nR'nCHR-C5H4)ZrCl2 (n = 0, 2; R = H, Alkyl; R' = H, Hal)", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 526, no. 2, 27 December 1996 (1996-12-27), pages 295 - 301, XP002384399 *
KOPPL A. ET AL., JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 153, 10 March 2000 (2000-03-10), pages 109 - 119, XP001128152 *

Also Published As

Publication number Publication date
EP2044131A2 (en) 2009-04-08
US20080027189A1 (en) 2008-01-31
ES2749498T3 (en) 2020-03-20
WO2008014217A2 (en) 2008-01-31
US7514510B2 (en) 2009-04-07
JP2009544819A (en) 2009-12-17
EP2044131B1 (en) 2019-07-17
EP2044131A4 (en) 2012-03-21
US20090163688A1 (en) 2009-06-25
KR20090035000A (en) 2009-04-08

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