WO2008022804A1 - Polypropylene foam - Google Patents
Polypropylene foam Download PDFInfo
- Publication number
- WO2008022804A1 WO2008022804A1 PCT/EP2007/007470 EP2007007470W WO2008022804A1 WO 2008022804 A1 WO2008022804 A1 WO 2008022804A1 EP 2007007470 W EP2007007470 W EP 2007007470W WO 2008022804 A1 WO2008022804 A1 WO 2008022804A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polypropylene
- foam
- shi
- strain
- index
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
Definitions
- the present invention relates to a polypropylene foam having an even foam surface and small cell size. It also relates to the use of multibranched polypropylene for the preparation of foam.
- Thermoplastic foams possess a cellular structure generated by the expansion of a blowing agent.
- the cellular structure provides unique properties that enable the foamed plastics to be used for various industrial applications. Due to its outstanding functional characteristics and low material cost, polypropylene foams have been considered as a substitute for other thermoplastic foams in industrial applications. In particular, they have higher rigidity compared to other polyolefins, offer higher strength than polyethylene and better impact strength than polystyrene. Furthermore, they provide a higher service temperature range and good temperature stability.
- polypropylene is suffering from some serious drawbacks, limiting its use for the preparation of foams.
- many polypropylene materials have low melt strength and/or low melt extensibility.
- Polypropylene foams are made in a foam extrusion process wherein a gas-laden melt is suddenly expanded through pressure drop after the extrusion die. Such an expansion induces extensional flow to the polymer melt and sets certain requirements to the extensional rheology of the melt. In particular, high melt strength and/or high melt extensibility are required. If these conditions are not met, bubble film rupture is more likely to occur and the average foam cell size will decrease due to bubble coalescence. Increasing bubble size results in a decrease of impact strength of the foam.
- Linear, bimodal high molecular weight polypropylene obtained either from copolymerisation of propylene with comonomers such as ethylene or from reacting a coupling agent with polypropylene.
- EP-A-0887379 discloses the preparation of linear bimodal polypropylene in a multi-step process using at least one slurry reactor and at least one gas phase reactor.
- WO 00/78858 discloses a coupled propylene copolymer prepared by reacting a coupling agent such as polysulfonyl azide with a propylene copolymer. Due to the high molecular weight, these polymers have a high zero shear viscosity. However, they have reduced output from the extruder because a high pressure is built up in the extrusion line.
- Y/H-shaped polypropylenes from post-reactor processes such as irradiation or peroxide treatment or from copolymerisation of propylene with dienes in the presence of a metallocene catalyst.
- WO 2005/044877 discloses a foamed article comprising a propylene/ ⁇ - ⁇ diene copolymer.
- EP-A-0879830 discloses Y/H-shaped polypropylene from peroxide treatment.
- Y/H-shaped polypropylenes are inherently inhomogeneous, contain gels and show a low number of cells, thereby adversely affecting foam surface quality.
- the present invention intends to provide a polypropylene foam having improved foam surface properties such as high surface evenness, and a small cell size. Furthermore, the preparation of such a foam should be possible with high output at the foaming line without adversely affecting surface properties and cell size. Thus, the present invention intends to provide an improved balance between processibility and final foam properties.
- the object is solved by providing a foam comprising a polypropylene, wherein said polypropylene is produced in the presence of a metallocene catalyst, preferably in the presence of a metallocene catalyst as further defined below, and said foam and/or said polypropylene has (have) a. a branching index g' of less than 1.00 and b.
- the strain hardening index (SHI) is defined as the slope of the logarithm to the basis 10 of the tensile stress growth function (Ig ( ⁇ + )) as function of the logarithm to the basis 10 of the Hencky strain (Ig ( ⁇ )) in the range of Hencky strains between 1 and 3.
- the foam is free of polyethylene, even more preferred the foam comprises a polypropylene as defined above and further defined below as the only polymer component.
- the present invention is based on the finding that an improved balance between processibility and final foam properties can be achieved by using a polypropylene which has a specific branching structure.
- the foam of the present invention comprises a polypropylene which is characterized in particular by extensional melt flow properties.
- the extensional flow, or deformation that involves the stretching of a viscous material is the dominant type of deformation in converging and squeezing flows that occur in typical polymer processing operations.
- Extensional melt flow measurements are particularly useful in polymer characterization because they are very sensitive to the molecular structure of the polymeric system being tested.
- the true strain rate of extension also referred to as the Hencky strain rate
- simple extension is said to be a "strong flow” in the sense that it can generate a much higher degree of molecular orientation and stretching than flows in simple shear.
- extensional flows are very sensitive to crystallinity and macro-structural effects, such as long- chain branching, and as such can be far more descriptive with regard to polymer characterization than other types of bulk rheological measurement which apply shear flow.
- the first requirement according to the present invention is that the foam and/or the polypropylene present within said foam has/have a branching index g' of less than 1.00, more preferably less than 0.90, still more preferably less than 0.80.
- the branching index g' shall be less than 0.75.
- the branching index g' is more than 0.6, still more preferably 0.7 or more.
- the branching index g 1 of the polypropylene is in the range of 0.6 to below 1.0, more preferred in the range of more than 0.65 to 0.95, still more preferred in the range of 0.7 to 0.95.
- the branching index g' defines the degree of branching and correlates with the amount of branches of a polymer.
- a low g'-value is an indicator for a highly branched polymer.
- the branching of the polypropylene increases.
- strain hardening index (SHI@l s " ') of the foam and/or the polypropylene present within said foam shall be at least 0.30, more preferred of at least 0.40, still more preferred of at least 0.50. In a preferred embodiment the strain hardening index (SHI@l s " ') is at least 0.55.
- the strain hardening index is a measure for the strain hardening behavior of the melted foam or the polypropylene melt.
- the strain hardening index (SHI@l s " ') has been measured by a deformation rate d ⁇ /dt of 1.00 s "1 at a temperature of 180 °C for determining the strain hardening behavior, wherein the strain hardening index (SHI) is defined as the slope of the tensile stress growth function ⁇ E + as a function of the Hencky strain f on a logarithmic scale between 1.00 and 3.00 (see Figure 1).
- the Hencky strain rate ⁇ H is defined as for the Hencky strain ⁇ "F” is the tangential stretching force "R” is the radius of the equi-dimensional windup drums
- T is the measured torque signal
- A is the instantaneous cross-sectional area of a stretched molten specimen " ⁇ o " is the cross-sectional area of the specimen in the solid state (i.e. prior to melting)
- the polypropylene used for the preparation of the foam is not crosslinked.
- the foam and/or the polypropylene has/have a multi-branching index (MBI) of at least 0.15, wherein the multi-branching index (MBI) is defined as the slope of strain hardening index (SHI) as function of the logarithm to the basis 10 of the Hencky strain rate (Ig (d ⁇ /dt)).
- MBI multi-branching index
- the polypropylene used for the preparation of the foam of the present invention shows strain rate thickening which means that the strain hardening increases with extension rates. Similar to the measurement of SHI@l s " ', a strain hardening index (SHI) can be determined at different strain rates.
- a strain hardening index is defined as the slope of the logarithm to the basis 10 of the tensile stress growth function ⁇ + , ⁇ g( ⁇ + ), as function of the logarithm to the basis 10 of the Hencky strain ⁇ , ⁇ g( ⁇ ), between Hencky strains 1.00 and 3.00 at a at a temperature of 180 °C, where a SHI@0.1 s "1 is determined with a deformation rate ⁇ H of 0.10 s "1 , a SHI@0.3 s "1 is determined with a deformation rate ⁇ H of 0.30 s "1 , a SHI@3 s "1 is determined with a deformation rate ⁇ H of 3.00 s "1 , and a SHI@10 s "1 is determined with a deformation rate ⁇ H of 10.0 s '1 .
- a multi-branching index is defined as the slope of SHI as a function of Ig ( ⁇ H ), i.e.
- the strain hardening index (SHI) is defined at deformation rates ⁇ H between 0.05 s '1 and 20.00 more preferably between 0.10 s "1 and 10.0 still more preferably at the deformations rates 0.10, 0.30, 1.00, 3.00 and 10.0 s "1 . Yet more preferably the SHI-values determined by the deformations rates 0.10, 0.30, 1.00, 3.00 and 10.0 s "1 are used for the linear fit according to the least square method when establishing the multi-branching index (MBI).
- MBI multi-branching index
- the foam of the present invention and/or the polypropylene present within said foam has/have a branching index g' of less than 1.00, a strain hardening index (SHI@ls ' ') of at least 0.30 and multi- branching index (MBI) of at least 0.15. Still more preferred the foam and/or its polypropylene component has/have a branching index g' of less than 0.80, a strain hardening index (SHI@l s " ') of at least 0.40 and multi-branching index (MBI) of at least 0.15.
- the foam and/or its polypropylene component has/have a branching index g' of less than 1.00, a strain hardening index (SHI@l s " ') of at least 0.30 and multi-branching index (MBI) of at least 0.20.
- the foam and/or its polypropylene component has/have a branching index g' of less than 0.80, a strain hardening index (SHI@l s ' ') of at least 0.40 and multi-branching index (MBI) of at least 0.20.
- the foam and/or its polypropylene component has/have a branching index g' of less than 0.80, a strain hardening index (SHI@l s " ') of at least 0.50 and multi-branching index (MBI) of at least 0.30.
- the foam of the present invention comprises a polypropylene having a specific branching structure, i.e. multi-branched polypropylene.
- multi-branched polypropylene is characterized by the fact that its strain hardening index (SHI) increases with the deformation rate ⁇ H , i.e. a phenomenon which is not observed in other polypropylenes.
- strain hardening index (SHI) is not influenced by the deformation rate (see Figures 2 and 3). Accordingly, the strain hardening index (SHI) of known polymers, in particular known polypropylenes and polyethylenes, does not increase or increases only negligible with increase of the deformation rate (d ⁇ /dt).
- the multi-branching index MBI is also a parameter which is very sensitive to the branching structure of a polymeric material and can be used to characterize the foam of the present invention.
- a foam comprising a polypropylene, wherein the foam and/or the polypropylene has (have) a multi-branching index (MBI) of at least 0.15, wherein the multi-branching index (MBI) is defined as the slope of strain hardening index (SHI) as function of the logarithm to the basis 10 of the Hencky strain rate (Ig (d ⁇ /dt)), wherein d ⁇ /dt is the deformation rate, ⁇ is the Hencky strain, and the strain hardening index (SHI) is measured at 180 °C, wherein the strain hardening index (SHI) is defined as the slope of the logarithm to the basis 10 of the tensile stress growth function (Ig ( ⁇ + ))
- the multi-branching index (MBI) is at least 0.20, and still more preferred at least 0.25. In a still more preferred embodiment the multi- branching index (MBI) is at least 0.28.
- the foam is free of polyethylene, even more preferred the foam comprises a polypropylene as defined above and further defined below as the only polymer component.
- said polypropylene is produced in the presence of a metallocene catalyst, more preferably in the presence of a metallocene catalyst as further defined below.
- the foam and/or the polypropylene present within said foam has/have a branching index g' of less than 1.00, more preferably less than 0.90, still more preferably less than 0.80.
- the branching index g' shall be less than 0.75.
- the branching index g' is more than 0.6, still more preferably 0.7 or more.
- the branching index g' of the polypropylene is in the range of 0.6 to below 1.0, more preferred in the range of more than 0.65 to 0.95, still more preferred in the range of 0.7 to 0.95.
- the strain hardening index (SHI@l s " ') shall be at least 0.30, more preferred at least 0.40, still more preferred at least 0.50. In a preferred embodiment the strain hardening index (SHI@ls " ') is at least 0.55.
- the polypropylene comprised by the foam of the present invention is not crosslinked.
- the foam is further characterized in that the foam has a smooth surface, i.e. the surface does not show many defects.
- An indication, that the foam is rather defect free, is when the material used for the foam shows only few gels when converted into a film.
- the foam material converted into a film has only gels with a diameter of equal or less than 500 ⁇ m, i.e. no gels with a diameter of more than 500 ⁇ m are present in said film (converted foam), and wherein said gels are not more than 100 gels per square meter (sqm), more preferably not more than 80 gels per square meter (sqm), and yet more preferably not more than 60 gels per square meter (sqm).
- the converted foam material has only gels with a diameter of equal or less than 400 ⁇ m, i.e. no gels with a diameter of more than 500 ⁇ m are present in said film (converted foam), and wherein said gels are not more than 100 gels per square meter (sqm), more preferably not more than 80 gels per square meter (sqm), and yet more preferably not more than 60 gels per square meter (sqm).
- the converted foam material has only gels with a diameter of equal or less than 300 ⁇ m, i.e.
- the polypropylene comprised by the foam of the present invention has an amount of hot xylene insolubles of less than 0.10 wt%, more preferably less than 0.05 wt%.
- the amount of hot xylene insolubles is determined by dissolving xylene hot solubles from the polymer in a soxhlet apparatus with boiling xylene for 2 days and measuring the mass fraction of the polypropylene material insoluble in boiling xylene.
- the amount of hot xylene insolubles indicates the degree of crosslinking, i.e. the higher the degree of crosslinking the higher the amount of polymer which does not dissolve in hot xylene.
- Polymers having crosslinked areas are of lower homogeneity and contain gels, thereby reducing the number of foam cells and deteriorating the foam surface. Furthermore, crosslinking has a detrimental effect on recycling properties.
- the polypropylene component of the foam has xylene solubles (XS) of less than 2.0 wt.-%, more preferably less than 1.50 wt%, and even more preferably less than 1.00 wt%.
- Xylene solubles are the part of the polymer soluble in cold xylene determined by dissolution in boiling xylene and letting the insoluble part crystallize from the cooling solution (for the method see below in the experimental part).
- the xylene solubles fraction contains polymer chains of low stereo-regularity and is an indication for the amount of non-crystalline areas. High levels of xylene solubles are detrimental for some applications as they represent potential contamination risk.
- the foam comprises a polypropylene having a melt flow rate (MFR) given in a specific range.
- MFR melt flow rate
- the melt flow rate mainly depends on the average molecular weight. This is due to the fact that long molecules render the material a lower flow tendency than short molecules. An increase in molecular weight means a decrease in the MFR-value.
- the melt flow rate (MFR) is measured in g/10 min of the polymer discharged through a defined dye under specified temperature and pressure conditions and the measure of viscosity of the polymer which, in turn, for each type of polymer is mainly influenced by its molecular weight but also by its degree of branching.
- the melt flow rate measured under a load of 2.16 kg at 230 °C (ISO 1 133) is denoted as MFR 2 .
- the polypropylene has an MFR 2 in a range of 0.01 to 1000 g/10 min, more preferably of 0.01 to 100 g/10 min, still more preferred of 0.05 to 50 g/10 min.
- the MFR is in a range of 1.00 to 1 1.00 g/10 min.
- the MFR is in a range of 3.00 to 1 1.00 g/10 min.
- the number average molecular weight (Mn) is an average molecular weight of a polymer expressed as the first moment of a plot of the number of molecules in each molecular weight range against the molecular weight. In effect, this is the total molecular weight of all molecules divided by the number of molecules.
- the weight average molecular weight (Mw) is the first moment of a plot of the weight of polymer in each molecular weight range against molecular weight.
- the number average molecular weight (Mn) and the weight average molecular weight (Mw) as well as the molecular weight distribution are determined by size exclusion chromatography (SEC) using Waters Alliance GPCV 2000 instrument with online viscometer. The oven temperature is 140 °C. Trichlorobenzene is used as a solvent.
- the polypropylene present within the foam has a weight average molecular weight (Mw) from 10,000 to 2,000,000 g/mol, more preferably from 20,000 to 1 ,500,000 g/mol.
- the polypropylene of the instant invention is isotactic.
- the foam of the present invention comprises a polypropylene having a rather high pentad concentration, i.e. higher than 90 %, more preferably higher than 92 % and most preferably higher than 93 %.
- the pentad concentration is higher than 95 %.
- the pentad concentration is an indicator for the narrowness in the stereo-regularity distribution of the polypropylene.
- the polypropylene has a melting temperature Tm of higher than 120 °C. It is in particular preferred that the melting temperature is higher than 120 °C if the polypropylene is a polypropylene copolymer as defined below. In turn, in case the polypropylene is a polypropylene homopolymer as defined below, it is preferred, that polypropylene has a melting temperature of higher than 150 0 C, more preferred higher than 155 °C.
- the foam shall preferably comply with specific melting temperature requirements.
- the foam has a melting temperature Tm of higher than 145 °C. It is in particular preferred that the melting temperature of the foam comprising the propylene homopolymer is higher than 150 °C, more preferred higher than 155 °C.
- the foam has a melting temperature Tm of higher than 120 °C. It is in particular preferred that the melting temperature of the foam comprising the propylene copolymer is higher than 135 °C, more preferred higher than 140 0 C.
- polypropylene as defined above is preferably unimodal. In another preferred embodiment the polypropylene as defined above (and further defined below) is preferably multimodal, more preferably bimodal.
- Multimodal or “multimodal distribution” describes a frequency distribution that has several relative maxima.
- the expression “modality of a polymer” refers to the form of its molecular weight distribution (MWD) curve, i.e. the appearance of the graph of the polymer weight fraction as a function of its molecular weight. If the polymer is produced in the sequential step process, i.e. by utilizing reactors coupled in series, and using different conditions in each reactor, the different polymer fractions produced in the different reactors each have their own molecular weight distribution which may considerably differ from one another.
- the molecular weight distribution curve of the resulting final polymer can be seen at a super-imposing of the molecular weight distribution curves of the polymer fraction which will, accordingly, show a more distinct maxima, or at least be distinctively broadened compared with the curves for individual fractions.
- a polymer showing such molecular weight distribution curve is called bimodal or multimodal, respectively.
- the polypropylene of the foam is not unimodal it is preferably bimodal.
- the polypropylene used for the preparation of the foam can be a homopolymer or a copolymer. Accordingly, the homopolymer as well as the copolymer can be a multimodal polymer composition.
- the expression homopolymer used herein relates to a polypropylene that consists substantially, i.e. of at least 97 wt%, preferably of at least 99 wt%, and most preferably of at least 99.8 wt% of propylene units. In a preferred embodiment only propylene units in the polypropylene homopolymer are detectable.
- the comonomer content can be determined with FT infrared spectroscopy, as described below in the examples.
- the polypropylene used for the preparation of the foam is a propylene copolymer
- the comonomer is ethylene.
- the total amount of comonomer, more preferably ethylene, in the propylene copolymer is up to 10 mol%, more preferably up to 8 mol%, and even more preferably up to 6 mol%.
- the polypropylene is a propylene copolymer comprising a polypropylene matrix and an ethylene-propylene rubber (EPR).
- EPR ethylene-propylene rubber
- the polypropylene matrix can be a homopolymer or a copolymer, more preferably multimodal, i.e. bimodal, homopolymer or a multimodal, i.e. bimodal, copolymer.
- the polypropylene matrix is a propylene copolymer
- the comonomer is ethylene or butene.
- the preferred amount of comonomer, more preferably ethylene, in the polypropylene matrix is up to 8.00 mol%.
- the propylene copolymer matrix has ethylene as the comonomer component, it is in particular preferred that the amount of ethylene in the matrix is up to 8.00 mol%, more preferably less than 6.00 mol%. In case the propylene copolymer matrix has butene as the comonomer component, it is in particular preferred that the amount of butene in the matrix is up to 6.00 Mol%, more preferably less than 4.00 mol%.
- the ethylene-propylene rubber (EPR) in the total propylene copolymer is 50 wt% or less, more preferably 40 wt% or less. More preferably the amount of ethylene-propylene rubber (EPR) in the total propylene copolymer is in the range of 10 to 50 wt%, still more preferably in the range of 10 to 40 wt%.
- the polypropylene component of the foam as defined above is produced in the presence of a specific catalyst. Furthermore, for the production of the polypropylene of the inventive foam, the process as stated below is preferably used.
- the polypropylene component of the inventive foam is obtainable by a new catalyst system.
- This new catalyst system comprises an asymmetric catalyst, whereby the catalyst system has a porosity of less than 1.40 ml/g, more preferably less than 1.30 ml/g and most preferably less than 1.00 ml/g.
- the porosity has been measured according to DIN 66135 (N 2 ). In another preferred embodiment the porosity is not detectable when determined with the method applied according to DIN 66135 (N 2 ).
- An asymmetric catalyst according to this invention is a metallocene compound comprising at least two organic ligands which differ in their chemical structure. More preferably the asymmetric catalyst according to this invention is a metallocene compound comprising at least two organic ligands which differ in their chemical structure and the metallocene compound is free of C 2 - symmetry and/or any higher symmetry. Preferably the asymmetric metallocene compound comprises only two different organic ligands, still more preferably comprises only two organic ligands which are different and linked via a bridge.
- Said asymmetric catalyst is preferably a single site catalyst (SSC).
- SSC single site catalyst
- the catalyst system has a surface area of less than 25 m 2 /g, yet more preferred less than 20 m 2 /g, still more preferred less than 15 m 2 /g, yet still less than 10 m 2 /g and most preferred less than 5 m 2 /g.
- the surface area according to this invention is measured according to ISO 9277 (N 2 ).
- the catalytic system according to this invention comprises an asymmetric catalyst, i.e. a catalyst as defined below, and has porosity not detectable when applying the method according to
- the asymmetric catalyst compound i.e. the asymmetric metallocene, has the formula (I):
- M is Zr, Hf or Ti, more preferably Zr, and X is independently a monovalent anionic ligand, such as ⁇ -ligand, R is a bridging group linking the two Cp ligands,
- Cp is an organic ligand selected from the group consisting of unsubstituted cyclopenadienyl, unsubstituted indenyl, unsubstituted tetrahydroindenyl, unsubstituted fluorenyl, substituted cyclopenadienyl, substituted indenyl, substituted tetrahydroindenyl, and substituted fluorenyl, with the proviso that both Cp-ligands are selected from the above stated group and both Cp-ligands have a different chemical structure.
- ⁇ -ligand is understood in the whole description in a known manner, i.e. a group bonded to the metal at one or more places via a sigma bond.
- a preferred monovalent anionic ligand is halogen, in particular chlorine (Cl).
- the asymmetric catalyst is of formula (I) indicated above, wherein M is Zr and each X is Cl.
- both Cp-ligands are substituted.
- both Cp-ligands have different residues to obtain an asymmetric structure.
- both Cp-ligands are selected from the group consisting of substituted cyclopenadienyl-ring, substituted indenyl-ring, substituted tetrahydroindenyl-ring, and substituted fluorenyl-ring wherein the Cp-ligands differ in the substituents bonded to the rings.
- the optional one or more substituent(s) bonded to cyclopenadienyl, indenyl, tetrahydroindenyl, or fluorenyl may be independently selected from a group including halogen, hydrocarbyl (e.g.
- Ci-C 20 -alkyl C 2 -C 20 -alkenyl, C 2 -C 20 - alkynyl, C 3 -Ci 2 -cycloalkyl, C 6 -C 20 -aryl or C 7 -C 20 -arylalkyl), C 3 -Ci 2 -cycloalkyl which contains 1 , 2, 3 or 4 heteroatom(s) in the ring moiety, C 6 -C 2 Q- heteroaryl, Ci-C 20 -haloalkyl, -SiR" 3 , -OSiR" 3 , -SR", -PR" 2 and -NR" 2 , wherein each R" is independently a hydrogen or hydrocarbyl, e.g.
- both Cp-ligands are indenyl moieties wherein each indenyl moiety bears one or two substituents as defined above. More preferably each Cp-ligand is an indenyl moiety bearing two substituents as defined above, with the proviso that the substituents are chosen in such a manner that both Cp- ligands are of different chemical structure, i.e both Cp-ligands differ at least in one substituent bonded to the indenyl moiety, in particular differ in the substituent bonded to the five membered ring of the indenyl moiety.
- both Cp are indenyl moieties wherein the indenyl moieties comprise at least at the five membered ring of the indenyl moiety, more preferably at 2-position, a substituent selected from the group consisting of alkyl, such as Ci-C 6 alkyl, e.g. methyl, ethyl, isopropyl, and trialkyloxysiloxy, wherein each alkyl is independently selected from Cj-C 6 alkyl, such as methyl or ethyl, with proviso that the indenyl moieties of both Cp must chemically differ from each other, i.e. the indenyl moieties of both Cp comprise different substituents.
- alkyl such as Ci-C 6 alkyl, e.g. methyl, ethyl, isopropyl, and trialkyloxysiloxy
- each alkyl is independently selected from Cj-C 6 alkyl, such as methyl or ethyl, with
- both Cp are indenyl moieties wherein the indenyl moieties comprise at least at the six membered ring of the indenyl moiety, more preferably at 4-position, a substituent selected from the group consisting of a C 6 -C 2O aromatic ring moiety, such as phenyl or naphthyl, preferably phenyl, which is optionally substituted with one or more substitutents, such as Cj-C 6 alkyl, and a heteroaromatic ring moiety, with the proviso that the indenyl moieties of both Cp must chemically differ from each other, i.e. the indenyl moieties of both Cp comprise different substituents.
- a substituent selected from the group consisting of a C 6 -C 2O aromatic ring moiety such as phenyl or naphthyl, preferably phenyl, which is optionally substituted with one or more substitutents, such as Cj-C 6 alkyl,
- both Cp are indenyl moieties wherein the indenyl moieties comprise at the five membered ring of the indenyl moiety, more preferably at 2-position, a substituent and at the six membered ring of the indenyl moiety, more preferably at 4-position, a further substituent, wherein the substituent of the five membered ring is selected from the group consisting of alkyl, such as Ci-C 6 alkyl, e.g.
- each alkyl is independently selected from Ci-C 6 alkyl, such as methyl or ethyl
- the further substituent of the six membered ring is selected from the group consisting of a C 6 -C 20 aromatic ring moiety, such as phenyl or naphthyl, preferably phenyl, which is optionally substituted with one or more substituents, such as Ci-C 6 alkyl, and a heteroaromatic ring moiety, with proviso that the indenyl moieties of both Cp must chemically differ from each other, i.e. the indenyl moieties of both Cp comprise different substituents.
- both Cp are idenyl rings comprising two substituentes each and differ in the substituents bonded to the five membered ring of the idenyl rings.
- Y is C, Si or Ge
- R' is Ci to C 20 alkyl, C 6 -Cj 2 aryl, or C 7 -Ci 2 arylalkyl or trimethylsilyl.
- the bridge member R is typically placed at 1 -position.
- the bridge member R may contain one or more bridge atoms selected from e.g. C, Si and/or Ge, preferably from C and/or Si.
- One preferable bridge R is -Si(R') 2 -, wherein R' is selected independently from one or more of e.g.
- Ci-C] 0 alkyl C]-C 20 alkyl, such as C 6 -C] 2 aryl, or C 7 -C 40 , such as C 7 -C] 2 arylalkyl, wherein alkyl as such or as part of arylalkyl is preferably Ci-C 6 alkyl, such as ethyl or methyl, preferably methyl, and aryl is preferably phenyl.
- the bridge -Si(R') 2 - is preferably e.g.
- the asymmetric catalyst i.e. the asymmetric metallocene, is defined by the formula (III)
- Y is C, Si or Ge
- R' is Ci to C 20 alkyl, C 6 -Ci 2 aryl, or C 7 -Ci 2 arylalkyl.
- the asymmetric catalyst is defined by the formula (III), wherein both Cp are selected from the group consisting of substituted cyclopenadienyl, substituted indenyl, substituted tetrahydroindenyl, and substituted fluorenyl.
- the asymmetric catalyst is defined by the formula (III), wherein both Cp are selected from the group consisting of substituted cyclopenadienyl, substituted indenyl, substituted tetrahydroindenyl, and substituted fluorenyl with the proviso that both Cp-ligands differ in the substituents, i.e. the subtituents as defined above, bonded to cyclopenadienyl, indenyl, tetrahydroindenyl, or fluorenyl.
- the asymmetric catalyst is defined by the formula (III), wherein both Cp are indenyl and both indenyl differ in one substituent, i.e. in a substiuent as defined above bonded to the five member ring of indenyl.
- the asymmetric catalyst is a non-silica supported catalyst as defined above, in particular a metallocene catalyst as defined above.
- the asymmetric catalyst is dimethylsilyl [(2- methyl-(4'-tert.butyl)-4-phenyl-indenyl)(2-isopropyl-(4'-tert.butyl)-4-phenyl- indenyl)]zirconium dichloride (IUPAC: dimethylsilandiyl [(2-methyl-(4'- tert.butyl)-4-phenyl-indenyl)(2-isopropyl-(4'-tert.butyl)-4-phenyl- indenyl)]zirkonium dichloride). More preferred said asymmetric catalyst is not silica supported.
- the above described asymmetric catalyst components are prepared according to the methods described in WO 01/48034.
- the asymmetric catalyst system is obtained by the emulsion solidification technology as described in WO 03/051934.
- the asymmetric catalyst is preferably in the form of solid catalyst particles, obtainable by a process comprising the steps of a) preparing a solution of one or more asymmetric catalyst components; b) dispersing said solution in a solvent immiscible therewith to form an emulsion in which said one or more catalyst components are present in the droplets of the dispersed phase, c) solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst.
- a solvent more preferably an organic solvent, is used to form said solution.
- the organic solvent is selected from the group consisting of a linear alkane, cyclic alkane, linear alkene, cyclic alkene, aromatic hydrocarbon and halogen-containing hydrocarbon.
- the immiscible solvent forming the continuous phase is an inert solvent, more preferably the immiscible solvent comprises a fluorinated organic solvent and/or a functionalized derivative thereof, still more preferably the immiscible solvent comprises a semi-, highly- or perfluorinated hydrocarbon and/or a functionalized derivative thereof.
- said immiscible solvent comprises a perfluorohydrocarbon or a functionalized derivative thereof, preferably C 3 -C 30 perfluoroalkanes, -alkenes or - cycloalkanes, more preferred C 4 -Ci 0 perfluoro-alkanes, -alkenes or -cycloalkanes, particularly preferred perfluorohexane, perfluoroheptane, perfluorooctane or perfluoro (methylcyclohexane) or a mixture thereof.
- a perfluorohydrocarbon or a functionalized derivative thereof preferably C 3 -C 30 perfluoroalkanes, -alkenes or - cycloalkanes, more preferred C 4 -Ci 0 perfluoro-alkanes, -alkenes or -cycloalkanes, particularly preferred perfluorohexane, perfluoroheptane, perflu
- the emulsion comprising said continuous phase and said dispersed phase is a bi-or multiphasic system as known in the art.
- An emulsifier may be used for forming the emulsion. After the formation of the emulsion system, said catalyst is formed in situ from catalyst components in said solution.
- the emulsifying agent may be any suitable agent which contributes to the formation and/or stabilization of the emulsion and which does not have any adverse effect on the catalytic activity of the catalyst.
- the emulsifying agent may e.g.
- the emulsifying agent may be prepared during the emulsion preparation, e.g. by reacting a surfactant precursor with a compound of the catalyst solution.
- Said surfactant precursor may be a halogenated hydrocarbon with at least one functional group, e.g. a highly fluorinated Ci to C 30 alcohol, which reacts e.g. with a cocatalyst component, such as aluminoxane.
- any solidification method can be used for forming the solid particles from the dispersed droplets.
- the solidification is effected by a temperature change treatment.
- the emulsion subjected to gradual temperature change of up to 10 °C/min, preferably 0.5 to 6 °C/min and more preferably 1 to 5 °C/min.
- the emulsion is subjected to a temperature change of more than 40 °C, preferably more than 50 °C within less than 10 seconds, preferably less than 6 seconds.
- the recovered particles have preferably an average size range of 5 to 200 ⁇ m, more preferably 10 to 100 ⁇ m.
- the form of solidified particles have preferably a spherical shape, a predetermined particles size distribution and a surface area as mentioned above of preferably less than 25 m 2 /g, still more preferably less than 20 m 2 /g, yet more preferably less than 15 m 2 /g, yet still more preferably less than 10 m 2 /g and most preferably less than 5 mVg, wherein said particles are obtained by the process as described above.
- a spherical shape preferably a predetermined particles size distribution and a surface area as mentioned above of preferably less than 25 m 2 /g, still more preferably less than 20 m 2 /g, yet more preferably less than 15 m 2 /g, yet still more preferably less than 10 m 2 /g and most preferably less than 5 mVg, wherein said particles are obtained by the process as described above.
- the catalyst system may further comprise an activator as a cocatalyst, as described in WO 03/051934, which is enclosed herein with reference.
- cocatalysts for metallocenes and non-metallocenes are the aluminoxanes, in particular the Ci-C] 0 -alkylaluminoxanes, most particularly methylaluminoxane (MAO).
- aluminoxanes can be used as the sole cocatalyst or together with other cocatalyst(s).
- other cation complex forming catalysts activators can be used. Said activators are commercially available or can be prepared according to the prior art literature.
- aluminoxane cocatalysts are described e.g. in WO 94/28034 which is incorporated herein by reference. These are linear or cyclic oligomers of having up to 40, preferably 3 to 20, -(A1(R'")O)- repeat units (wherein R'" is hydrogen, Ci-Cio-alkyl (preferably methyl) or C 6 -Ci 8 -aryl or mixtures thereof).
- aluminoxanes such as methylaluminumoxane (MAO)
- MAO methylaluminumoxane
- the amount of Al, provided by aluminoxane can be chosen to provide a molar ratio of Ahtransition metal e.g. in the range of 1 to 10 000, suitably 5 to 8000, preferably 10 to 7000, e.g. 100 to 4000, such as 1000 to 3000.
- the ratio is preferably below 500.
- the quantity of cocatalyst to be employed in the catalyst of the invention is thus variable, and depends on the conditions and the particular transition metal compound chosen in a manner well known to a person skilled in the art.
- any additional components to be contained in the solution comprising the organotransition compound may be added to said solution before or, alternatively, after the dispersing step.
- the process temperature is higher than 60 °C.
- the process is a multi-stage process to obtain multimodal polypropylene as defined above.
- Multistage processes include also bulk/gas phase reactors known as multizone gas phase reactors for producing multimodal propylene polymer.
- a preferred multistage process is a "loop-gas phase"-process, such as developed by Borealis A/S, Denmark (known as BORSTAR® technology) described e.g. in patent literature, such as in EP 0 887 379 or in WO 92/12182.
- Multimodal polymers can be produced according to several processes which are described, e.g. in WO 92/12182, EP 0 887 379 and WO 97/22633.
- a multimodal polypropylene used for the preparation of the inventive foam is preferably produced in a multi-stage process as described in WO 92/12182. The content of this document is included herein by reference.
- the main polymerization stages are preferably carried out as a combination of a bulk polymerization/gas phase polymerization.
- the bulk polymerizations are preferably performed in a so-called loop reactor.
- the composition be produced in two main polymerization stages in combination of loop reactor/gas phase reactor.
- the process may also comprise a prepolymerization step in a manner known in the field and which may precede the polymerization step (a).
- a further elastorneric comonomer component so called ethylene- propylene rubber (EPR) component as defined in this invention, may be incorporated into the obtained propylene polymer to form a propylene copolymer as defined above.
- the ethylene-propylene rubber (EPR) component may preferably be produced after the gas phase polymerization step (b) in a subsequent second or further gas phase polymerizations using one or more gas phase reactors.
- the process is preferably a continuous process.
- the conditions for the bulk reactor of step (a) may be as follows: the temperature is within the range of 40 0 C to 1 10 °C, preferably between 60 °C and 100 °C, 70 to 90 0 C, the pressure is within the range of 20 bar to 80 bar, preferably between 30 bar to 60 bar, - hydrogen can be added for controlling the molar mass in a manner known per se.
- step a) the reaction mixture from the bulk (bulk) reactor (step a) is transferred to the gas phase reactor, i.e. to step (b), whereby the conditions in step (b) are preferably as follows:
- the temperature is within the range of 50 °C to 130 0 C, preferably between 60 0 C and 100 °C
- the pressure is within the range of 5 bar to 50 bar, preferably between 15 bar to 35 bar
- hydrogen can be added for controlling the molar mass in a manner known per se.
- the residence time can vary in both reactor zones.
- the residence time in bulk reactor, e.g. loop is in the range 0.5 to 5 hours, e.g. 0.5 to 2 hours and the residence time in gas phase reactor will generally be 1 to 8 hours.
- the polymerization may be effected in a known manner under supercritical conditions in the bulk, preferably loop reactor, and/or as a condensed mode in the gas phase reactor.
- the process of the invention or any embodiments thereof above enable highly feasible means for producing and further tailoring the propylene polymer composition within the invention, e.g. the properties of the polymer composition can be adjusted or controlled in a known manner e.g. with one or more of the following process parameters: temperature, hydrogen feed, comonomer feed, propylene feed e.g. in the gas phase reactor, catalyst, the type and amount of an external donor (if used), split between components.
- the present invention also relates to a process for the preparation of the foam as defined above, wherein a multi-branched polypropylene as defined above is subjected to foaming.
- a melt of the multi-branched polypropylene comprising a gaseous foaming agent such as butane, HFC or CO 2 is suddenly expanded through pressure drop.
- Continuous foaming processes as well as discontinuous process may be applied.
- the polymer (micro-)pellets are laden with foaming agent under pressure and heated below melting temperature before the pressure in the autoclave is suddenly relaxed.
- the dissolved foaming agent forms bubbles and creates a foam structure.
- Such preparation of discontinuously foamed beads is described for example in DE 3 539 352.
- the present invention also relates to the use of the multi-branched polypropylene as defined above for the preparation of foams.
- a Paar Physica MCR300 equipped with a TC30 temperature control unit and an oven CTT600 (convection and radiation heating) and a SERVPO 1-025 extensional device with temperature sensor and a software RHEOPLUS/32 v2.66 is used.
- the device is set to test temperature (180 0 C) for minimum 20minutes without sample in presence of the clamps
- the torque (measured in mNm) is recorded and plotted against time •
- the torque must not exceed a value of 5x 10 '3 mNm to make sure that the friction of the device is in an acceptably low range
- the device is heated for min. 20min to the test temperature (180°C measured with the thermocouple attached to the SER device) with clamps but without sample. Subsequently, the sample (0.7x1 Ox 18mm), prepared as described above, is clamped into the hot device. The sample is allowed to melt for 2 minutes +/- 20 seconds before the experiment is started.
- the device After stretching, the device is opened and the stretched film (which is winded on the drums) is inspected. Homogenous extension is required. It can be judged visually from the shape of the stretched film on the drums if the sample stretching has been homogenous or not.
- the tape must me wound up symmetrically on both drums, but also symmetrically in the upper and lower half of the specimen.
- the transient elongational viscosity calculates from the recorded torque as outlined below.
- the resulting tensile stress growth function T ⁇ E + (d ⁇ /dt, t) is plotted against the total Hencky strain ⁇ to determine the strain hardening behaviour of the melt, see Figure 1.
- the tensile stress growth function ⁇ e + can be well fitted with a function
- Ci and C 2 are fitting variables. Such derived C 2 is a measure for the strain hardening behavior of the melt and called Strain Hardening Index SHI.
- strain rate linear materials, Y- or H-structures
- strain rate short chain-, hyper- or multi-branched structures
- HDPE linear
- LLDPE short-chain branched
- LDPE hyperbranched structures
- the first polymer is a H- and Y-shaped polypropylene homopolymer made according to EP 879 830 ("A") example 1 through adjusting the MFR with the amount of butadiene. It has a MFR 230/2.16 of 2.0 g/10min, a tensile modulus of 1950 MPa and a branching index g' of 0.7.
- the second polymer is a commercial hyperbranched LDPE, Borealis "B", made in a high pressure process known in the art. It has a MFR 190/2.16 of 4.5 and a density of 923 kg/m 3 .
- the third polymer is a short chain branched LLDPE, Borealis "C", made in a low pressure process known in the art. It has a MFR 190/2.16 of 1.2 and a density of 919 kg/m 3 .
- the fourth polymer is a linear HDPE, Borealis "D", made in a low pressure process known in the art. It has a MFR 190/2.16 of 4.0 and a density of 954 kg/m 3 .
- the four materials of known chain architecture are investigated by means of measurement of the transient elongational viscosity at 180 °C at strain rates of 0.10, 0.30, 1.0, 3.0 and 10s "1 . Obtained data (transient elongational viscosity versus Hencky strain) is fitted with a function
- the parameters cl and c2 are found through plotting the logarithm of the transient elongational viscosity against the logarithm of the Hencky strain and performing a linear fit of this data applying the least square method.
- the parameter cl calculates from the intercept of the linear fit of the data lg( ⁇ + ) versus lg( ⁇ ) from
- a multi- branching index is calculated from the slope of a linear fitting curve of SHI versus Ig( ⁇ ):
- the multi-branching index MBI allows now to distinguish between Y or H- branched polymers which show a MBI smaller than 0.05 and hyper-branched polymers which show a MBI larger than 0.15. Further, it allows to distinguish between short-chain branched polymers with MBI larger than 0.10 and linear materials which have a MBI smaller than 0.10.
- strain hardening index SHI
- MBI multi-branching index
- Particle size distribution is measured via Coulter Counter LS 200 at room temperature with n-heptane as medium.
- the NMR-measurement was used for determining the mmmm pentad concentration in a manner well known in the art.
- M n Number average molecular weight
- M w weight average molecular weight
- MFD molecular weight distribution
- SEC size exclusion chromatography
- the oven temperature is 140 0 C.
- Trichlorobenzene is used as a solvent (ISO 16014).
- the number average molecular weight (M n ), the weight average molecular weight (M w ) and the molecular weight distribution (MWD) are measured by a method based on ISO 16014-1 :2003 and ISO 16014-4:2003.
- sample solution 216.5 ⁇ L were injected per analysis.
- the column set was calibrated using relative calibration with 19 narrow MWD polystyrene (PS) standards in the range of 0.5 kg/mol to 1 1 500 kg/mol and a set of well characterized broad polypropylene standards. All samples were prepared by dissolving 5 - 10 mg of polymer in 10 mL (at 160 °C) of stabilized TCB (same as mobile phase) and keeping for 3 hours with continuous shaking prior sampling in into the GPC instrument.
- PS polystyrene
- the xylene solubles (XS, wt.-%): Analysis according to the known method: 2.0 g of polymer is dissolved in 250 ml p-xylene at 135 0 C under agitation. After 30 ⁇ 2 minutes the solution is allowed to cool for 15 minutes at ambient temperature and then allowed to settle for 30 minutes at 25 ⁇ 0.5°C. The solution is filtered and evaporated in nitrogen flow and the residue dried under vacuum at 90 °C until constant weight is reached.
- Circa 2 g of the polymer (m p ) are weighted and put in a mesh of metal which is weighted (m p+m ).
- the polymer in the mesh is extracted in a soxhlet apparatus with boiling xylene for two days. Subsequently, the mesh is dried and weighted again (m ⁇ Hu+m)-
- melt- and crystallization enthalpy were measured by the DSC method according to ISO 1 1357-3.
- Stiffness Film TD transversal direction
- Stiffness Film MD machine direction
- Elongation at break TD Elongation at break MD
- Elongation at break MD Elongation at break MD
- the Rheotens apparatus is combined with an extruder/melt pump for continuous feeding of the melt strand.
- the extrusion temperature is 200 °C; a capillary die with a diameter of 2 mm and a length of 6 mm is used and the acceleration of the melt strand drawn down is 120 mm/s 2 .
- the maximum points (Fmax; v max ) at failure of the strand are characteristic for the strength and the drawability of the melt.
- Haze and transparency are determined according to ASTM D 1003-92 (haze).
- Intrinsic viscosity is measured according to DIN ISO 1628/1 , October 1999 (in Decalin at 135 0 C).
- a support-free catalyst has been prepared as described in example 5 of WO 03/051934 whilst using an asymmetric metallocene dimethylsilyl [(2- methyl-(4'-tert.butyl)-4-phenyl-indenyl)(2-isopropyl-(4'-tert.butyl)-4-phenyl- indenyl)]zirkonium dichloride.
- Such catalyst has been used to polymerise a polypropylene copolymer with 4mol% ethylene in the Borstar process, known in the art.
- a bimodal polypropylene copolymer has been prepared using a Z/N catalyst and the Borstar process.
- a Y/H shaped polymer has been prepared according to EP 0 887 379 to obtain a polypropylene copolymer of MFR 230/2 16 2.2 g/10min and a branching index g' of 0.8.
- pelletized samples have been used for foam extrusion.
- a corotating 25 mm twin screw extruder (Berstorff ZE25, L/D 39.5), following temperature settings are adjusted (Table 5):
- the pellets are melted before the foaming agent CO2 is dosed into the melt (zone 3) with a constant feed of 54g/hr through a feeder Bronkhorst F- 201 AC-FB-22-V at a pressure of 20bar.
- Such gas laden melt is homogenized and cooled before it exits the flat die attached to the extruder. Immediately after the die, the foam expands and it is collected with a standard cast-film windup equipment.
- Foamed sheets are cut from the film and investigated for its mechanical properties.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EA200970223A EA016842B1 (en) | 2006-08-25 | 2007-08-24 | Polypropylene foam and process for preparing same |
BRPI0715722-3A BRPI0715722B1 (en) | 2006-08-25 | 2007-08-24 | Polypropylene foam, its preparation process, and use of polypropylene |
KR1020087032193A KR101049703B1 (en) | 2006-08-25 | 2007-08-24 | Polypropylene foam |
CN2007800308580A CN101506261B (en) | 2006-08-25 | 2007-08-24 | Polypropylene foam |
US12/367,911 US7799841B2 (en) | 2006-08-25 | 2009-02-09 | Polypropylene foam |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06017790.4 | 2006-08-25 | ||
EP06017790A EP1900764B1 (en) | 2006-08-25 | 2006-08-25 | Polypropylene foam |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/367,911 Continuation US7799841B2 (en) | 2006-08-25 | 2009-02-09 | Polypropylene foam |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008022804A1 true WO2008022804A1 (en) | 2008-02-28 |
Family
ID=37668304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2007/007470 WO2008022804A1 (en) | 2006-08-25 | 2007-08-24 | Polypropylene foam |
Country Status (9)
Country | Link |
---|---|
US (1) | US7799841B2 (en) |
EP (1) | EP1900764B1 (en) |
KR (1) | KR101049703B1 (en) |
CN (1) | CN101506261B (en) |
AT (1) | ATE427330T1 (en) |
BR (1) | BRPI0715722B1 (en) |
DE (1) | DE602006006061D1 (en) |
EA (1) | EA016842B1 (en) |
WO (1) | WO2008022804A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015024088A1 (en) | 2013-08-23 | 2015-02-26 | Braskem S.A. | Process for producing modified poly(propene), the modified poly(propene) and the use thereof, and the polymer blend |
US10179851B2 (en) | 2013-06-05 | 2019-01-15 | Borealis Ag | One-step production of a polypropylene composition |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2645714T3 (en) * | 2011-02-28 | 2017-12-07 | Borealis Ag | Polypropylene composition suitable for extrusion coating |
ES2648254T3 (en) * | 2011-05-02 | 2017-12-29 | Borealis Ag | Polypropylene for foam and polypropylene foam |
WO2014070414A1 (en) | 2012-10-31 | 2014-05-08 | Exxonmobil Chemical Patents Inc. | Propylene copolymer compositions and processes to produce them |
US10842574B2 (en) | 2013-03-15 | 2020-11-24 | Xodus Medical, Inc. | Robotic patient protection system comprising a head mask structure, configured to protect the head of a patient, for use in robotic surgical procedures |
US10842206B2 (en) | 2013-03-15 | 2020-11-24 | Xodus Medical, Inc. | Patient protection system configured to protect the head of a patient |
CN106255720B (en) * | 2014-05-06 | 2020-04-07 | 巴塞尔聚烯烃意大利有限公司 | Multilayer film random propylene-ethylene copolymers |
EP3140329B1 (en) * | 2014-05-06 | 2019-07-24 | Basell Poliolefine Italia S.r.l. | Random propylene-ethylene copolymers |
KR102287154B1 (en) * | 2015-11-13 | 2021-08-06 | 주식회사 엘지화학 | Metallocene polypropylene and expandable polypropylene comprising the same |
WO2017090432A1 (en) * | 2015-11-26 | 2017-06-01 | 株式会社カネカ | Method for producing polypropylene-based resin foamed particles, polypropylene-based resin foamed particles, and in-mold foam molded article |
JP6963171B2 (en) * | 2017-08-30 | 2021-11-05 | キョーラク株式会社 | Foam molding resin, foam molding, manufacturing method of foam molding |
KR102550083B1 (en) * | 2018-12-13 | 2023-06-29 | 주식회사 엘지화학 | Supported hybrid catalyst and method for preparing polypropylene using the same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000073369A1 (en) * | 1999-06-01 | 2000-12-07 | Borealis Technology Oy | Process for preparing an integral polypropylene foam |
JP2003147110A (en) * | 2001-11-09 | 2003-05-21 | Mitsui Chemicals Inc | Foam of polyolefin composition and its manufacturing method |
US20050090571A1 (en) * | 2003-10-27 | 2005-04-28 | Mehta Aspy K. | Expanded bead foams from propylene-diene copolymers and their use |
Family Cites Families (86)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE203915C (en) | ||||
JPS55115416A (en) * | 1979-02-27 | 1980-09-05 | Nippon Oil Co Ltd | Manufacture of copolymer |
EP0036457B1 (en) | 1980-03-20 | 1985-02-20 | Mitsubishi Rayon Co., Ltd. | A method of producing a polypropylene film for electrical appliances |
JPS6042807B2 (en) * | 1980-04-11 | 1985-09-25 | チッソ株式会社 | Method for producing ethylene propylene α-olefin terpolymer |
JPS61115940A (en) | 1984-11-09 | 1986-06-03 | Mitsubishi Yuka Badische Kk | Polypropylene foam particle |
EP0190889B2 (en) | 1985-01-31 | 2000-07-05 | Montell North America Inc. | Polypropylene with free-end long chain branching, process for making it, and use thereof |
US4634745A (en) * | 1985-04-01 | 1987-01-06 | United States Steel Corporation | Terpolymer production |
US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
US5250631A (en) * | 1990-06-13 | 1993-10-05 | Shell Oil Company | Polymer compositions |
FI86867C (en) | 1990-12-28 | 1992-10-26 | Neste Oy | FLERSTEGSPROCESS FOR FRAMSTAELLNING AV POLYETEN |
DE59207030D1 (en) * | 1991-05-28 | 1996-10-10 | Hoechst Ag | Sealable, opaque, biaxially oriented polypropylene multilayer film, process for its production and its use |
DE69408989T2 (en) | 1993-05-25 | 1998-11-05 | Exxon Chemical Patents Inc | METALOCENATE CATALYST SYSTEM ON A SUPPORT FOR THE OLEFIN POLYMERIZATION, THEIR PRODUCTION AND USE |
IT1269914B (en) | 1994-03-24 | 1997-04-16 | Himonty Inc | PAINTABLE COMPOSITIONS OF PROPYLENE CRYSTALLINE COPOLYMERS HAVING LOW WELDABILITY TEMPERATURE |
NO314475B1 (en) | 1994-03-24 | 2003-03-24 | Nippon Petrochemicals Co Ltd | Electrically insulating polymeric material and its use |
US5468440B1 (en) | 1994-05-06 | 1997-04-08 | Exxon Chemical Patents Inc | Process of making oriented film or structure |
EP0690458A3 (en) | 1994-06-27 | 1997-01-29 | Mitsubishi Cable Ind Ltd | Insulating composition and formed article thereof |
JP3388896B2 (en) | 1994-08-08 | 2003-03-24 | 株式会社日立ユニシアオートモティブ | Inhalation type dispenser |
EP0745637A1 (en) | 1995-05-31 | 1996-12-04 | Hoechst Aktiengesellschaft | Biaxially oriented film of polypropylene with high area modules |
EP0747212A1 (en) | 1995-05-31 | 1996-12-11 | Hoechst Aktiengesellschaft | Biaxially oriented polypropylene film with improved barrier properties against water-vapour and oxygen |
ATE195286T1 (en) * | 1995-05-31 | 2000-08-15 | Hoechst Ag | BIAXIAL ORIENTED POLYPROPYLENE FILM WITH INCREASED DIMENSIONAL STABILITY |
SE9504539D0 (en) | 1995-12-19 | 1995-12-19 | Borealis As | Procatalyst and process for the preparation of a multimodal ethylene homopolymer and / or ethylene / 1-olefin copolymer by gas-phase polymerization |
BE1009963A3 (en) * | 1995-12-22 | 1997-11-04 | Solvay | COMPOSITIONS STATISTICS PROPYLENE COPOLYMERS, METHOD OF MAKING, AND CONTAINING SHEETS MULTI-sealable. |
US6037546A (en) * | 1996-04-30 | 2000-03-14 | Belden Communications Company | Single-jacketed plenum cable |
CN1081652C (en) | 1996-08-09 | 2002-03-27 | 东丽株式会社 | Polypropylene film and capacitor made by using the same as the dielectric |
JP4195095B2 (en) | 1996-09-04 | 2008-12-10 | エクソンモービル・ケミカル・パテンツ・インク | Improved propylene polymer for drawn films. |
US6218023B1 (en) | 1997-04-21 | 2001-04-17 | Montell North America, Inc. | Co-extruded laminate comprising at least one propylene graft copolymer layer |
US6204348B1 (en) | 1997-05-20 | 2001-03-20 | Borealis Gmbh | Modified polypropylenes of improved processability |
CN1116315C (en) | 1997-05-30 | 2003-07-30 | 株式会社宏大化纤 | Polypropylene resin composition and injection-molded article |
FI111848B (en) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Process and equipment for the preparation of homopolymers and copolymers of propylene |
FI104824B (en) | 1997-06-24 | 2000-04-14 | Borealis As | Process for producing propylene polymers |
IT1293757B1 (en) | 1997-07-23 | 1999-03-10 | Pirelli Cavi S P A Ora Pirelli | CABLES WITH RECYCLABLE COVERING WITH HOMOGENEOUS DISTRIBUTION |
CN1105120C (en) | 1997-08-05 | 2003-04-09 | 株式会社宏大化纤 | Polypropylene resin composition and use thereof |
KR100556319B1 (en) | 1997-08-15 | 2006-03-03 | 다우 글로벌 테크놀로지스 인크. | Films produced from substantially linear homogeneous olefin polymer compositions |
FI974175A (en) | 1997-11-07 | 1999-05-08 | Borealis As | Process for producing polypropylene |
US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
DE19813399A1 (en) * | 1998-03-26 | 1999-09-30 | Basf Ag | Statistical propylene copolymers |
DE19827327A1 (en) | 1998-06-19 | 1999-12-30 | Targor Gmbh | Sealable multilayer film with a low sealing temperature and a low content of xylene-soluble material, useful in packaging applications |
KR100611849B1 (en) * | 1998-08-26 | 2006-08-11 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Branched polypropylene compositions |
DE19949235A1 (en) | 1998-10-16 | 2000-05-11 | Chisso Corp | Propylene-ethylene-alpha-olefin terpolymer, useful for the production of molded articles and film, contains 85-99.99 mol per cent propylene and has specific elution characteristics in o-dichlorobenzene |
WO2000034385A1 (en) * | 1998-12-08 | 2000-06-15 | The Dow Chemical Company | Mel-bondable polypropylene/ethylene polymer fiber and composition for making the same |
FI991057A0 (en) | 1999-05-07 | 1999-05-07 | Borealis As | High stiffness propylene polymers and process for their preparation |
DE60017468T2 (en) | 1999-06-24 | 2005-06-02 | The Dow Chemical Co., Midland | Polyolefin composition with improved impact properties |
EP1218423B1 (en) | 1999-10-02 | 2005-03-16 | Borealis Technology Oy | Modified supported catalysts for the polymerization of olefins |
JP2001168431A (en) | 1999-12-13 | 2001-06-22 | Matsushita Electric Ind Co Ltd | Laser and microwave generator |
CN1249096C (en) | 1999-12-23 | 2006-04-05 | 巴塞尔聚烯烃有限公司 | Transition metal compound, ligand system, catalyst system and the use of the latter for the polymerisation and copolymerisation of olefins |
EP1142684A3 (en) * | 2000-04-03 | 2002-06-26 | Sumitomo Chemical Company, Limited | Thermoplastic resin sheet and container |
JP2001354814A (en) | 2000-06-16 | 2001-12-25 | Chisso Corp | Propylene-based resin sheet |
US7125933B2 (en) | 2000-06-22 | 2006-10-24 | Univation Technologies, Llc | Very low density polyethylene blends |
JP2004501259A (en) | 2000-06-22 | 2004-01-15 | エクソンモービル・ケミカル・パテンツ・インク | Blend composed of ultra low density polyethylene and high density polyethylene |
EP1313782A1 (en) | 2000-08-22 | 2003-05-28 | Exxonmobil Chemical Patents Inc. | Polypropylene polymers |
WO2002044251A1 (en) | 2000-11-28 | 2002-06-06 | Borealis Gmbh | Use of propylene terpolymers for the production of films |
JP2002294010A (en) | 2001-03-30 | 2002-10-09 | Sumitomo Chem Co Ltd | Polypropylene-based resin composition for oriented film and the resultant oriented film |
GB0111020D0 (en) | 2001-05-04 | 2001-06-27 | Borealis Tech Oy | Process |
JP2002363356A (en) | 2001-06-04 | 2002-12-18 | Grand Polymer Co Ltd | Polypropylene resin composition for extrusion coating |
ATE328912T1 (en) | 2001-06-20 | 2006-06-15 | Borealis Tech Oy | PRODUCTION OF A CATALYST COMPONENT FOR OLEFIN POLYMERIZATION |
EP1295910A1 (en) | 2001-09-25 | 2003-03-26 | Borealis GmbH | Insulating foam composition |
EP1302310A1 (en) | 2001-10-15 | 2003-04-16 | Atofina Research S.A. | Adhesion of polyethylene on polypropylene |
WO2003040233A2 (en) | 2001-11-06 | 2003-05-15 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
EP1323747A1 (en) | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
SG113461A1 (en) * | 2002-05-09 | 2005-08-29 | Sumitomo Chemical Co | Polypropylene resin composition and heat-shrinkable film obtained from the same |
US6756463B2 (en) | 2002-05-16 | 2004-06-29 | Japan Polychem Corporation | Propylene polymer |
RU2325404C2 (en) | 2002-08-01 | 2008-05-27 | Базелль Полиолефин Италия С.П.А. | Highstereoregular polypropylene with improved properties |
JP2006500470A (en) | 2002-09-20 | 2006-01-05 | エクソンモービル・ケミカル・パテンツ・インク | Supercritical polymerization method and polymer produced thereby |
EP1408077A1 (en) | 2002-10-09 | 2004-04-14 | Borealis Technology Oy | Polymer composition comprising nanofillers |
AU2003284027A1 (en) | 2002-10-24 | 2004-05-13 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
EP1422250A1 (en) | 2002-11-20 | 2004-05-26 | ATOFINA Research | Branched polypropylene |
US7326756B2 (en) | 2002-12-05 | 2008-02-05 | Exxonmobil Chemical Patents Inc. | High temperature bulk polymerization of branched crystalline polypropylene |
ATE426902T1 (en) | 2002-12-12 | 2009-04-15 | Borealis Tech Oy | COAXIAL CABLE CONTAINING A DIELECTRIC MATERIAL |
EP1484345A1 (en) | 2003-06-06 | 2004-12-08 | Borealis Technology Oy | Process for the production of polypropylene using a Ziegler-Natta catalyst |
EP1495861A1 (en) | 2003-07-10 | 2005-01-12 | Total Petrochemicals Research Feluy | High transparency, high impact resistance containers |
JP2006022276A (en) | 2004-07-09 | 2006-01-26 | Fujikura Ltd | Composition for insulator and high-foaming insulator and coaxial cable for high frequency using the composition |
EP1634699A1 (en) | 2004-09-10 | 2006-03-15 | Syrom 90 S.P.A. | Multilayer metallized film and production method |
KR20070083746A (en) * | 2004-10-22 | 2007-08-24 | 다우 글로벌 테크놀로지스 인크. | Inherently open-celled polypropylene foam with large cell size |
CN100389150C (en) * | 2004-10-29 | 2008-05-21 | 中国石油化工股份有限公司 | Polypropylene foaming premix and its preparation method |
US7138474B1 (en) | 2005-05-03 | 2006-11-21 | Fina Technology, Inc. | End use articles derived from polypropylene homopolymers and random copolymers |
DE602005015196D1 (en) | 2005-05-20 | 2009-08-13 | Borealis Tech Oy | Polymer with high melt flow and improved resistance for tube applications |
EP1726602A1 (en) | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
EP1726603A1 (en) | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
EP1847551A1 (en) | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Process for the preparation of polypropylene |
EP1847555A1 (en) | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Multi-branched Polypropylene |
EP1847552A1 (en) | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Catalytic system |
DE602006002512D1 (en) * | 2006-07-10 | 2008-10-09 | Borealis Tech Oy | Short-chain branched polypropylene |
DE602006011873D1 (en) * | 2006-07-10 | 2010-03-11 | Borealis Tech Oy | Polypropylene-based cable layer with high electrical breakdown voltage resistance |
EP1892264A1 (en) | 2006-08-25 | 2008-02-27 | Borealis Technology Oy | Extrusion coated substrate |
-
2006
- 2006-08-25 EP EP06017790A patent/EP1900764B1/en active Active
- 2006-08-25 AT AT06017790T patent/ATE427330T1/en not_active IP Right Cessation
- 2006-08-25 DE DE602006006061T patent/DE602006006061D1/en active Active
-
2007
- 2007-08-24 KR KR1020087032193A patent/KR101049703B1/en active IP Right Grant
- 2007-08-24 CN CN2007800308580A patent/CN101506261B/en active Active
- 2007-08-24 EA EA200970223A patent/EA016842B1/en not_active IP Right Cessation
- 2007-08-24 BR BRPI0715722-3A patent/BRPI0715722B1/en not_active IP Right Cessation
- 2007-08-24 WO PCT/EP2007/007470 patent/WO2008022804A1/en active Application Filing
-
2009
- 2009-02-09 US US12/367,911 patent/US7799841B2/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000073369A1 (en) * | 1999-06-01 | 2000-12-07 | Borealis Technology Oy | Process for preparing an integral polypropylene foam |
JP2003147110A (en) * | 2001-11-09 | 2003-05-21 | Mitsui Chemicals Inc | Foam of polyolefin composition and its manufacturing method |
US20050090571A1 (en) * | 2003-10-27 | 2005-04-28 | Mehta Aspy K. | Expanded bead foams from propylene-diene copolymers and their use |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10179851B2 (en) | 2013-06-05 | 2019-01-15 | Borealis Ag | One-step production of a polypropylene composition |
WO2015024088A1 (en) | 2013-08-23 | 2015-02-26 | Braskem S.A. | Process for producing modified poly(propene), the modified poly(propene) and the use thereof, and the polymer blend |
US9815951B2 (en) | 2013-08-23 | 2017-11-14 | Braskem S.A. | Process for producing modified poly(propene), the modified poly(propene) and the use thereof, and the polymer blend |
Also Published As
Publication number | Publication date |
---|---|
DE602006006061D1 (en) | 2009-05-14 |
EP1900764B1 (en) | 2009-04-01 |
KR20090029236A (en) | 2009-03-20 |
ATE427330T1 (en) | 2009-04-15 |
CN101506261B (en) | 2011-04-27 |
BRPI0715722B1 (en) | 2018-06-26 |
US20090176902A1 (en) | 2009-07-09 |
EA016842B1 (en) | 2012-07-30 |
US7799841B2 (en) | 2010-09-21 |
KR101049703B1 (en) | 2011-07-15 |
EA200970223A1 (en) | 2009-12-30 |
BRPI0715722A2 (en) | 2013-09-17 |
EP1900764A1 (en) | 2008-03-19 |
CN101506261A (en) | 2009-08-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1900764B1 (en) | Polypropylene foam | |
EP2007823B1 (en) | Multiple -branched polypropylene | |
US8142902B2 (en) | Extrusion coated substrate | |
EP2054464B1 (en) | Blown film of polypropylene | |
US7956148B2 (en) | Process for the preparation of polypropylene | |
EP1882703B1 (en) | Short-chain branched polypropylene | |
US8378047B2 (en) | Biaxially oriented polypropylene film | |
US8247052B2 (en) | Coaxial cable | |
US20090312178A1 (en) | Catalytic system | |
EP2097461B1 (en) | Process for the manufacture of branched polypropylene |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200780030858.0 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 07801895 Country of ref document: EP Kind code of ref document: A1 |
|
DPE1 | Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1020087032193 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1030/CHENP/2009 Country of ref document: IN |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 200970223 Country of ref document: EA |
|
NENP | Non-entry into the national phase |
Ref country code: RU |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 07801895 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: PI0715722 Country of ref document: BR Kind code of ref document: A2 Effective date: 20090225 |