WO2008033622A3 - Metallized polymeric films - Google Patents

Metallized polymeric films Download PDF

Info

Publication number
WO2008033622A3
WO2008033622A3 PCT/US2007/075062 US2007075062W WO2008033622A3 WO 2008033622 A3 WO2008033622 A3 WO 2008033622A3 US 2007075062 W US2007075062 W US 2007075062W WO 2008033622 A3 WO2008033622 A3 WO 2008033622A3
Authority
WO
WIPO (PCT)
Prior art keywords
butylene
skin layer
polymeric skin
films
layer
Prior art date
Application number
PCT/US2007/075062
Other languages
French (fr)
Other versions
WO2008033622A2 (en
Inventor
Laurence Dominique Urbain
George Forman Cretekos
Christophe J Maertens
Original Assignee
Exxonmobil Oil Corp
Laurence Dominique Urbain
George Forman Cretekos
Christophe J Maertens
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Oil Corp, Laurence Dominique Urbain, George Forman Cretekos, Christophe J Maertens filed Critical Exxonmobil Oil Corp
Priority to CA2663507A priority Critical patent/CA2663507C/en
Priority to EP20070813693 priority patent/EP2077945A2/en
Priority to CN2007800339786A priority patent/CN101535049B/en
Publication of WO2008033622A2 publication Critical patent/WO2008033622A2/en
Publication of WO2008033622A3 publication Critical patent/WO2008033622A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/242—All polymers belonging to those covered by group B32B27/32
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B32B2255/205—Metallic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/28—Multiple coating on one surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7244—Oxygen barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B32B2307/734—Dimensional stability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/75—Printability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers

Abstract

Disclosed herein is an improved, metallized polymer film and method for preparing the same. Such films comprise a) at least one treated polymeric skin layer comprising butylene, and b) a metal layer deposited onto at least one surface of this polymeric skin layer. The polymeric skin layer can comprise a propylene-butylene copolymer or an ethylene-propylene-butylene terpolymer, with this copolymer or terpolymer containing from about 4 wt% to about 12 wt% of butylene. The polymeric skin layer is preferably preconditioned by subjecting an outermost surface thereof to plasma treatment which facilitates the deposition thereon of a strongly adhering metal layer which is preferably aluminum. The resulting multi-layer films exhibit metal adhesion bond strength of at least about 100 grams/25mm. These films will preferably also exhibit a Water Vapor Transmission Rate of from about 0.05 to about 0.2 g/m2/24hour, and an Oxygen Transmission Rate of from about 5.0 to about 20 cm3/m2/24hour.
PCT/US2007/075062 2006-09-15 2007-08-02 Metallized polymeric films WO2008033622A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CA2663507A CA2663507C (en) 2006-09-15 2007-08-02 Metallized polymeric films
EP20070813693 EP2077945A2 (en) 2006-09-15 2007-08-02 Metallized polymeric films
CN2007800339786A CN101535049B (en) 2006-09-15 2007-08-02 Metallized polymeric films

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/521,656 US8048532B2 (en) 2006-09-15 2006-09-15 Metallized polymeric films
US11/521,656 2006-09-15

Publications (2)

Publication Number Publication Date
WO2008033622A2 WO2008033622A2 (en) 2008-03-20
WO2008033622A3 true WO2008033622A3 (en) 2009-06-04

Family

ID=37734811

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/075062 WO2008033622A2 (en) 2006-09-15 2007-08-02 Metallized polymeric films

Country Status (5)

Country Link
US (2) US8048532B2 (en)
EP (1) EP2077945A2 (en)
CN (1) CN101535049B (en)
CA (1) CA2663507C (en)
WO (1) WO2008033622A2 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102395467A (en) 2009-04-15 2012-03-28 埃克森美孚石油公司 Film composition and method of making the same
US20110293848A1 (en) * 2010-05-28 2011-12-01 Christian Kohlweyer Method and System for Treating Flexible Films
CN102939326A (en) 2010-06-09 2013-02-20 埃克森美孚石油公司 Film composition and method of making the same
CN103180140A (en) * 2010-09-20 2013-06-26 埃克森美孚石油公司 Multi-layer films having improved sealing properties
US20130180213A1 (en) * 2012-01-12 2013-07-18 Exxonmobil Oil Corporation Scanner-Sensitive Metallized Films
JP6431050B2 (en) * 2013-06-04 2018-11-28 トレオファン・ジャーマニー・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング・ウント・コンパニー・コマンデイトゲゼルシャフト Sealable polypropylene film
CA2917643A1 (en) * 2013-07-09 2015-01-15 United Technologies Corporation Industrial products formed from plated polymers
CN103724845A (en) * 2013-12-18 2014-04-16 芜湖万润机械有限责任公司 Composite polyolefin capacitor metallized film with small size and high compression strength and preparation method thereof
EP2960054B1 (en) * 2014-06-26 2022-10-12 Taghleef Industries SPA Surface-treated films with polypropylene base
US10357940B2 (en) 2014-08-07 2019-07-23 Dow Global Technologies Llc Multilayer metallized cast film and packaging made therefrom
ES2952453T3 (en) * 2014-10-27 2023-10-31 Taghleef Ind Inc Ultra High Barrier Metallized Film
US10040613B2 (en) 2015-03-11 2018-08-07 M & Q Ip Leasing, Llc Liners for cooking vessels
US20180017200A1 (en) 2016-07-15 2018-01-18 Nordson Corporation Adhesive transfer hose having a barrier layer and method of use
US20180029317A1 (en) * 2016-07-26 2018-02-01 The Boeing Company Metal-modified, plasma-treated thermoplastics for improved electrical performance
EP3500429B1 (en) * 2016-12-22 2023-12-06 Jindal Innovation Center SRL Coated, metallized films
DE102017129352A1 (en) * 2017-12-08 2019-06-13 Ensinger Gmbh Polymer-based substrate and process for its preparation
CN108556424A (en) * 2018-04-03 2018-09-21 鹤山市正达复合包装有限公司 A kind of composite membrane and preparation method thereof
WO2020023474A1 (en) * 2018-07-25 2020-01-30 Jindal Films Americas Llc Coated, metallized, conformable films
DE102018118225A1 (en) 2018-07-27 2020-01-30 Schott Ag Optical-electrical conductor arrangement with optical waveguide and electrical conductive layer
WO2022157120A1 (en) 2021-01-22 2022-07-28 Tetra Laval Holdings & Finance S.A. Irradiation sterilisable packaging material and stabilized polyolefin film for use therein
EP4052903A1 (en) * 2021-03-01 2022-09-07 Borealis AG High-barrier blown film polyolefin solutions for barrier coating
EP4335639A1 (en) 2022-09-06 2024-03-13 Tetra Laval Holdings & Finance S.A. Laminated packaging material comprising a barrier layer and packaging container made therefrom

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001053077A1 (en) * 2000-01-24 2001-07-26 Mobil Oil Corporation Multilayer metallized polyolefin film
WO2002098656A2 (en) * 2001-05-30 2002-12-12 Exxonmobil Oil Corporation Monoweb metallized film suitable for direct surface printing
WO2003072357A2 (en) * 2002-02-28 2003-09-04 Ucb, S.A. Metallisable, oriented, multilayer polyolefin film

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4304377A1 (en) * 1993-02-13 1994-08-18 Hoechst Ag Low-boiling, biaxially oriented polyolefin multilayer film, process for its preparation and its use
US5725962A (en) * 1993-12-01 1998-03-10 Mobil Oil Corporation Oriented HDPE films with metallized skin layer
EP0669348B1 (en) 1994-02-25 1998-06-10 Sumitomo Chemical Company Limited Propylene random copolymer and film laminate thereof
TW394731B (en) * 1995-03-29 2000-06-21 Toray Industries Polyolefin-based laminate film
US6033786A (en) * 1995-09-27 2000-03-07 Applied Extrusion Technologies, Inc. Metallized films
IT1282371B1 (en) 1996-01-26 1998-03-20 Bimo Italia S P A METALLIC PLASTIC FILMS
US5922471A (en) * 1996-03-04 1999-07-13 Union Carbide Chemicals & Plastics Technology Corporation Metallizable polypropylene random copolymer compositions
DE19720313A1 (en) 1997-05-15 1998-11-19 Wolff Walsrode Ag Multi-layer, stretched, heat-sealable polypropylene film vacuum-coated
US6149985A (en) * 1999-07-07 2000-11-21 Eastman Kodak Company High-efficiency plasma treatment of imaging supports
US6420041B1 (en) * 1999-12-20 2002-07-16 Exxonmobil Oil Corporation Film with metallizable skin layer
DE10022306A1 (en) * 2000-05-09 2001-11-29 Trespaphan Gmbh Transparent biaxially oriented polyolefin film with improved adhesive properties
US6773818B2 (en) * 2002-09-06 2004-08-10 Exxonmobil Oil Corporation Metallized, metallocene-catalyzed, polypropylene films
US6863964B2 (en) * 2002-10-09 2005-03-08 Exxonmobil Oil Corporation Metallized multilayer film
DE10307133B4 (en) 2003-02-20 2007-05-16 Treofan Germany Gmbh & Co Kg Metallized opaque foil
CA2518507A1 (en) 2003-04-10 2004-10-28 Exxonmobil Oil Corporation Process for the production of improved metallized films
EP1634699A1 (en) 2004-09-10 2006-03-15 Syrom 90 S.P.A. Multilayer metallized film and production method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001053077A1 (en) * 2000-01-24 2001-07-26 Mobil Oil Corporation Multilayer metallized polyolefin film
WO2002098656A2 (en) * 2001-05-30 2002-12-12 Exxonmobil Oil Corporation Monoweb metallized film suitable for direct surface printing
WO2003072357A2 (en) * 2002-02-28 2003-09-04 Ucb, S.A. Metallisable, oriented, multilayer polyolefin film

Also Published As

Publication number Publication date
US20110308719A1 (en) 2011-12-22
WO2008033622A2 (en) 2008-03-20
CA2663507A1 (en) 2008-03-20
CN101535049B (en) 2013-04-17
EP2077945A2 (en) 2009-07-15
CA2663507C (en) 2012-07-10
US8404072B2 (en) 2013-03-26
US8048532B2 (en) 2011-11-01
CN101535049A (en) 2009-09-16
US20080070050A1 (en) 2008-03-20

Similar Documents

Publication Publication Date Title
WO2008033622A3 (en) Metallized polymeric films
CA1223228B (en) Oriented polypropylene film substrate and method of manufacture
EP1780313A3 (en) Treated Aluminum Article And Method For Making Same
US5525421A (en) Metallized composite film structure and method
WO2008079549A3 (en) Polymer coating for medical devices
WO2007045805A3 (en) Antifouling material and production method thereof
CA2391261A1 (en) Films with improved blocking resistance and surface properties
WO2008029733A1 (en) Multilayer body
EP1011299A3 (en) Coatings for improved resin dust resistance
WO2008076535A3 (en) Multi-layer films comprising propylene-based polymers
WO2006107545A3 (en) Method for forming a barrier/seed layer for copper metallization
JPH05212826A (en) Combination product of metallized stretching film
WO2010147703A3 (en) Metallized polypropylene film and a process of making the same
AU3181501A (en) Microporous multilayer film and method for making same
WO2009051993A3 (en) Process for plasma coating a polypropylene object
EP0828609B1 (en) Protective coating for metal surfaces
WO2007087269A3 (en) Antimicrobial coating methods
PL1809792T3 (en) Common rack for electroplating and pvd coating operations
EP2896502B1 (en) Composite sheet and method of manufacturing
TW200700224A (en) Substrates coated with coating systems that include a treatment layer
JP5351204B2 (en) Method for producing gas barrier film having hot water resistance and gas barrier film having hot water resistance
EP0282094A2 (en) Plasma treatment with organic vapos to promote a metal adhesion of polypropylene film
JP4772165B1 (en) Gas barrier film manufacturing method and gas barrier film
WO2006111400A3 (en) Method and device for producing electronic components
JP4799699B1 (en) Gas barrier film manufacturing method and gas barrier film

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200780033978.6

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2007813693

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2663507

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE