WO2008054560A3 - Certain polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and high trans-cyclohexanedicarboxylic acid - Google Patents
Certain polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and high trans-cyclohexanedicarboxylic acid Download PDFInfo
- Publication number
- WO2008054560A3 WO2008054560A3 PCT/US2007/015713 US2007015713W WO2008054560A3 WO 2008054560 A3 WO2008054560 A3 WO 2008054560A3 US 2007015713 W US2007015713 W US 2007015713W WO 2008054560 A3 WO2008054560 A3 WO 2008054560A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mole
- cyclohexanedicarboxylic acid
- acid residues
- residues
- cyclohexanedimethanol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
Abstract
Described as one aspect of the invention are polyester compositions comprising at least one polyester which comprises: (A) a dicarboxylic acid component comprising: i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising: (a) 70 to 98 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and (b) 2 to 30 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof; ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues,; and iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (B) a glycol component comprising: i) 1 to 99 mole % of 2, 2, 4, 4-tetramethyl-1, 3-cyclobutanediol residues; and ii) 1 to 99 mole % of 1, 4-cyclohexanedimethanol residues, 1, 3-cyclohexariedimethanol residues, 1, 2-cyclohexanedimethanol residues or esters thereof or mixtures thereof, wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %; the total mole % of said glycol component is equal to 100 mole %; wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.5 g/100 ml at 25°C; and wherein said polyester has a Tg of from 60 to 155°C. The polyesters may be manufactured into articles.
Applications Claiming Priority (46)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2006/042293 WO2007053550A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having high glass transition temperature and articles made therefrom |
PCT/US2006/042069 WO2007053460A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
US11/588,883 US20070105993A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
USPCT/US06/41917 | 2006-10-27 | ||
PCT/US2006/042292 WO2007053549A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
US11/588,527 US20100087574A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
PCT/US2006/041917 WO2007053434A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
USPCT/US06/42291 | 2006-10-27 | ||
US11/588,527 | 2006-10-27 | ||
US11/588,906 | 2006-10-27 | ||
US11/588,554 | 2006-10-27 | ||
US11/588,907 US20070106054A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom |
US11/588,883 | 2006-10-27 | ||
US11/588,907 | 2006-10-27 | ||
USPCT/US06/42292 | 2006-10-27 | ||
US11/588,524 US20100096589A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom |
PCT/US2006/042291 WO2007053548A2 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions comprising minimal amounts of cyclobutanediol |
US11/588,524 | 2006-10-27 | ||
US11/588,458 | 2006-10-27 | ||
USPCT/US06/42069 | 2006-10-27 | ||
USPCT/US06/42293 | 2006-10-27 | ||
US11/588,458 US20070100122A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol and articles made therefrom |
US11/588,906 US8193302B2 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
US11/588,554 US20070100125A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions comprising minimal amounts of cyclobutanediol |
US11/635,434 | 2006-12-07 | ||
US11/635,434 US7737246B2 (en) | 2005-12-15 | 2006-12-07 | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
US11/635,433 | 2006-12-07 | ||
US11/635,433 US20070142511A1 (en) | 2005-12-15 | 2006-12-07 | Polyester compositions which comprise cyclobutanediol ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
US11/706,791 US20070232779A1 (en) | 2006-03-28 | 2007-02-14 | Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid |
US11/706,476 US20070232778A1 (en) | 2006-03-28 | 2007-02-14 | Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid |
US11/706,791 | 2007-02-14 | ||
US11/706,476 | 2007-02-14 | ||
PCT/US2007/007532 WO2007123631A1 (en) | 2006-03-28 | 2007-03-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
USPCT/US07/07532 | 2007-03-27 | ||
PCT/US2007/007632 WO2007126855A1 (en) | 2006-03-28 | 2007-03-27 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
USPCT/US07/07632 | 2007-03-27 | ||
PCT/US2007/010590 WO2007139655A1 (en) | 2006-05-23 | 2007-05-02 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
PCT/US2007/010551 WO2007139653A1 (en) | 2006-05-23 | 2007-05-02 | Lcd films or sheets comprising films comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
USPCT/US07/10551 | 2007-05-02 | ||
USPCT/US07/10590 | 2007-05-02 | ||
USPCT/US07/11150 | 2007-05-09 | ||
PCT/US2007/011150 WO2007139663A1 (en) | 2006-05-23 | 2007-05-09 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
US91731607P | 2007-05-10 | 2007-05-10 | |
US60/917,316 | 2007-05-10 | ||
US11/773,275 | 2007-07-03 | ||
US11/773,275 US8586701B2 (en) | 2005-10-28 | 2007-07-03 | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008054560A2 WO2008054560A2 (en) | 2008-05-08 |
WO2008054560A3 true WO2008054560A3 (en) | 2008-07-24 |
Family
ID=47831243
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2007/015704 WO2008051321A1 (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
PCT/US2007/015701 WO2008051320A1 (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor |
PCT/US2007/015702 WO2008054559A1 (en) | 2006-10-27 | 2007-07-10 | Certain polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and high trans- cyclohexanedicarboxylic acid |
PCT/US2007/015713 WO2008054560A2 (en) | 2006-10-27 | 2007-07-10 | Certain polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and high trans-cyclohexanedicarboxylic acid |
Family Applications Before (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2007/015704 WO2008051321A1 (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
PCT/US2007/015701 WO2008051320A1 (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and ethylene glycol, and manufacturing processes therefor |
PCT/US2007/015702 WO2008054559A1 (en) | 2006-10-27 | 2007-07-10 | Certain polyester compositions which comprise tetramethylcyclobutanediol, cyclohexanedimethanol and high trans- cyclohexanedicarboxylic acid |
Country Status (8)
Country | Link |
---|---|
EP (2) | EP2074174A1 (en) |
JP (2) | JP2010507716A (en) |
KR (2) | KR20090079212A (en) |
BR (2) | BRPI0717761A2 (en) |
CA (2) | CA2666585A1 (en) |
MX (2) | MX2009003369A (en) |
TW (2) | TW200819496A (en) |
WO (4) | WO2008051321A1 (en) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9029460B2 (en) * | 2009-02-06 | 2015-05-12 | Stacey James Marsh | Coating compositions containing acrylic and aliphatic polyester blends |
US8163850B2 (en) * | 2009-02-06 | 2012-04-24 | Eastman Chemical Company | Thermosetting polyester coating compositions containing tetramethyl cyclobutanediol |
US8168721B2 (en) * | 2009-02-06 | 2012-05-01 | Eastman Chemical Company | Coating compositions containing tetramethyl cyclobutanediol |
US7915374B2 (en) * | 2009-04-27 | 2011-03-29 | Eastman Chemical Company | Copolyesters having improved thermal stability and methods for making them |
US9156941B2 (en) * | 2010-12-20 | 2015-10-13 | Eastman Chemical Company | Color in titanium catalyzed polyesters |
US20120184668A1 (en) * | 2011-01-17 | 2012-07-19 | Eastman Chemical Company | Clear Ternary Blends of Polycarbonate with an Aliphatic Polyester and an Aromatic-Aliphatic Polyester |
US8580872B2 (en) * | 2011-07-21 | 2013-11-12 | Eastman Chemical Company | Sulfopolyester polymer compositions with improved water dispersibility |
EP2774950B1 (en) | 2011-11-01 | 2019-03-27 | Midori Anzen Co., Ltd. | Resin composition and molded body |
US8623483B1 (en) * | 2012-10-23 | 2014-01-07 | Eastman Chemical Company | Copolyesters containing neopentyl glycol and 2,2,4,4-tetraalkyl 1,3-cyclobutanediol |
WO2015125644A1 (en) * | 2014-02-24 | 2015-08-27 | 東レ株式会社 | Polyester film |
WO2015129500A1 (en) * | 2014-02-27 | 2015-09-03 | 東レ株式会社 | Laminate film |
JP6323872B2 (en) * | 2014-07-31 | 2018-05-16 | 花王株式会社 | Toner for electrophotography |
JP6323871B2 (en) * | 2014-07-31 | 2018-05-16 | 花王株式会社 | Toner for electrophotography |
JP2015028177A (en) * | 2014-09-22 | 2015-02-12 | イーストマン ケミカル カンパニー | Improved method for producing polyester |
US11072684B2 (en) | 2016-08-18 | 2021-07-27 | Eastman Chemical Company | Polyester compositions which comprise tetramethylcyclobutandiol and ethylene glycol, with improved catalyst system |
US11091586B2 (en) | 2016-08-18 | 2021-08-17 | Eastman Chemical Company | Polyester compositions which comprise tetramethyl cyclobutanediol and ethylene glycol, with improved catalyst system |
EP3500614A1 (en) * | 2016-08-18 | 2019-06-26 | Eastman Chemical Company | Polyester compositions which comprise tetramethylcyclobutanediol and ethylene glycol for calendering |
KR102589382B1 (en) * | 2018-08-08 | 2023-10-12 | 에스케이케미칼 주식회사 | Polyester resin and preparation method of the same |
CN114206615A (en) * | 2019-08-02 | 2022-03-18 | 伊士曼化工公司 | Multilayer sheet |
EP4041796A1 (en) * | 2019-10-08 | 2022-08-17 | Eastman Chemical Company | Catalyst systems for crystallizable reactor grade resins |
US11788317B2 (en) * | 2020-09-28 | 2023-10-17 | Kathryn Corcoran | Cell phone canopy |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4525504A (en) * | 1983-10-24 | 1985-06-25 | Eastman Kodak Company | Stabilized polyester compositions suitable for outdoor applications |
US5498668A (en) * | 1994-10-31 | 1996-03-12 | Eastman Chemical Company | Blends of certain polyesters with acrylics |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6495656B1 (en) * | 1990-11-30 | 2002-12-17 | Eastman Chemical Company | Copolyesters and fibrous materials formed therefrom |
US6037424A (en) * | 1996-12-28 | 2000-03-14 | Eastman Chemical Company | Clear blends of polycarbonates and polyesters |
US6043322A (en) * | 1996-12-28 | 2000-03-28 | Eastman Chemical Company | Clear polycarbonate and polyester blends |
US5989663A (en) * | 1996-12-30 | 1999-11-23 | Eastman Chemical Company | Blow-molding polyesters from terephthalic acid, 2, 2, 4, 4-tetramethyl-1,3-cyclobutanediol, and ethylene glycol |
US6120889A (en) * | 1999-06-03 | 2000-09-19 | Eastman Chemical Company | Low melt viscosity amorphous copolyesters with enhanced glass transition temperatures |
US20050010017A1 (en) * | 2003-07-11 | 2005-01-13 | Blakely Dale Milton | Addition of UV inhibitors to pet process for maximum yield |
CA2530484A1 (en) * | 2003-07-11 | 2005-01-27 | Eastman Chemical Company | Addition of uv absorbers to pet process for maximum yield |
US20060094858A1 (en) * | 2004-10-28 | 2006-05-04 | Turner Sam R | Novel copolyester compositions with improved impact strength at low temperatures |
WO2007053548A2 (en) * | 2005-10-28 | 2007-05-10 | Eastman Chemical Company | Polyester compositions comprising minimal amounts of cyclobutanediol |
WO2007053549A1 (en) * | 2005-10-28 | 2007-05-10 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
-
2007
- 2007-07-10 KR KR1020097008484A patent/KR20090079212A/en not_active Application Discontinuation
- 2007-07-10 JP JP2009534565A patent/JP2010507716A/en not_active Withdrawn
- 2007-07-10 WO PCT/US2007/015704 patent/WO2008051321A1/en active Application Filing
- 2007-07-10 MX MX2009003369A patent/MX2009003369A/en unknown
- 2007-07-10 CA CA002666585A patent/CA2666585A1/en not_active Abandoned
- 2007-07-10 TW TW096125089A patent/TW200819496A/en unknown
- 2007-07-10 BR BRPI0717761-5A patent/BRPI0717761A2/en not_active Application Discontinuation
- 2007-07-10 TW TW096125125A patent/TW200819497A/en unknown
- 2007-07-10 EP EP07836026A patent/EP2074174A1/en not_active Withdrawn
- 2007-07-10 WO PCT/US2007/015701 patent/WO2008051320A1/en active Application Filing
- 2007-07-10 JP JP2009534566A patent/JP2010507717A/en not_active Withdrawn
- 2007-07-10 MX MX2009003375A patent/MX2009003375A/en unknown
- 2007-07-10 BR BRPI0717755-0A patent/BRPI0717755A2/en not_active Application Discontinuation
- 2007-07-10 EP EP07836029A patent/EP2074158A1/en not_active Withdrawn
- 2007-07-10 WO PCT/US2007/015702 patent/WO2008054559A1/en active Application Filing
- 2007-07-10 WO PCT/US2007/015713 patent/WO2008054560A2/en active Application Filing
- 2007-07-10 KR KR1020097008483A patent/KR20090079211A/en not_active Application Discontinuation
- 2007-07-10 CA CA002666571A patent/CA2666571A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4525504A (en) * | 1983-10-24 | 1985-06-25 | Eastman Kodak Company | Stabilized polyester compositions suitable for outdoor applications |
US5498668A (en) * | 1994-10-31 | 1996-03-12 | Eastman Chemical Company | Blends of certain polyesters with acrylics |
Also Published As
Publication number | Publication date |
---|---|
MX2009003369A (en) | 2009-04-14 |
KR20090079212A (en) | 2009-07-21 |
KR20090079211A (en) | 2009-07-21 |
EP2074174A1 (en) | 2009-07-01 |
TW200819496A (en) | 2008-05-01 |
JP2010507717A (en) | 2010-03-11 |
EP2074158A1 (en) | 2009-07-01 |
JP2010507716A (en) | 2010-03-11 |
WO2008051321A8 (en) | 2008-07-10 |
BRPI0717761A2 (en) | 2013-03-12 |
CA2666585A1 (en) | 2008-05-02 |
CA2666571A1 (en) | 2008-05-02 |
WO2008051321A1 (en) | 2008-05-02 |
MX2009003375A (en) | 2009-04-14 |
WO2008054559A1 (en) | 2008-05-08 |
WO2008054560A2 (en) | 2008-05-08 |
BRPI0717755A2 (en) | 2013-03-12 |
TW200819497A (en) | 2008-05-01 |
WO2008051320A1 (en) | 2008-05-02 |
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