WO2008069880A3 - Composition and process for the removal of sulfur from middle distillage fuels - Google Patents

Composition and process for the removal of sulfur from middle distillage fuels Download PDF

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Publication number
WO2008069880A3
WO2008069880A3 PCT/US2007/023158 US2007023158W WO2008069880A3 WO 2008069880 A3 WO2008069880 A3 WO 2008069880A3 US 2007023158 W US2007023158 W US 2007023158W WO 2008069880 A3 WO2008069880 A3 WO 2008069880A3
Authority
WO
WIPO (PCT)
Prior art keywords
composition
sulfur
component
fuels
distillage
Prior art date
Application number
PCT/US2007/023158
Other languages
French (fr)
Other versions
WO2008069880A2 (en
Inventor
Ki-Hyouk Choi
Original Assignee
Saudi Arabian Oil Co
Aramco Services Co
Ki-Hyouk Choi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Arabian Oil Co, Aramco Services Co, Ki-Hyouk Choi filed Critical Saudi Arabian Oil Co
Priority to EP07839918A priority Critical patent/EP2102313A2/en
Priority to CN2007800509039A priority patent/CN101657527B/en
Priority to BRPI0720143A priority patent/BRPI0720143B1/en
Publication of WO2008069880A2 publication Critical patent/WO2008069880A2/en
Publication of WO2008069880A3 publication Critical patent/WO2008069880A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • C10G25/05—Removal of non-hydrocarbon compounds, e.g. sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Abstract

A composition and process for removing sulfur from middle distillate petroleum hydrocarbon fuels. The composition includes an alumina component and a carbon component. The composition is present in an amount effective to adsorb sulfur compounds from the fuel. The alumina component and the carbon component preferably collectively comprise a composite material. The composition can further include a sulfur component, preferably a metal sulfide or sulfur oxide. The composition can also further include at least one compound having a Group VI or Group VIII metal from the periodic table.
PCT/US2007/023158 2006-12-06 2007-11-02 Composition and process for the removal of sulfur from middle distillage fuels WO2008069880A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07839918A EP2102313A2 (en) 2006-12-06 2007-11-02 Composition and process for the removal of sulfur from middle distillage fuels
CN2007800509039A CN101657527B (en) 2006-12-06 2007-11-02 Composition and process for the removal of sulfur from middle distillage fuels
BRPI0720143A BRPI0720143B1 (en) 2006-12-06 2007-11-02 composition and process for the removal of sulfur from medium distillate fuels

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/634,466 US7842181B2 (en) 2006-12-06 2006-12-06 Composition and process for the removal of sulfur from middle distillate fuels
US11/634,466 2006-12-06

Publications (2)

Publication Number Publication Date
WO2008069880A2 WO2008069880A2 (en) 2008-06-12
WO2008069880A3 true WO2008069880A3 (en) 2009-06-25

Family

ID=39492785

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/023158 WO2008069880A2 (en) 2006-12-06 2007-11-02 Composition and process for the removal of sulfur from middle distillage fuels

Country Status (6)

Country Link
US (3) US7842181B2 (en)
EP (1) EP2102313A2 (en)
KR (1) KR20100014300A (en)
CN (1) CN101657527B (en)
BR (1) BRPI0720143B1 (en)
WO (1) WO2008069880A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7842181B2 (en) * 2006-12-06 2010-11-30 Saudi Arabian Oil Company Composition and process for the removal of sulfur from middle distillate fuels
US8142646B2 (en) 2007-11-30 2012-03-27 Saudi Arabian Oil Company Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds
US20090145808A1 (en) * 2007-11-30 2009-06-11 Saudi Arabian Oil Company Catalyst to attain low sulfur diesel
US9636662B2 (en) 2008-02-21 2017-05-02 Saudi Arabian Oil Company Catalyst to attain low sulfur gasoline
US9005432B2 (en) 2010-06-29 2015-04-14 Saudi Arabian Oil Company Removal of sulfur compounds from petroleum stream
US8535518B2 (en) 2011-01-19 2013-09-17 Saudi Arabian Oil Company Petroleum upgrading and desulfurizing process
US9878925B2 (en) * 2011-12-22 2018-01-30 3M Innovative Properties Company Filtration medium comprising a thermolysis product of a carbon oxychalcogenide and a metal salt, method of removing chloramine with this filtration medium and method of making this filtration medium
US9708196B2 (en) 2013-02-22 2017-07-18 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
CA2843041C (en) 2013-02-22 2017-06-13 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US9364773B2 (en) 2013-02-22 2016-06-14 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US11440815B2 (en) 2013-02-22 2022-09-13 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US9926497B2 (en) 2015-10-16 2018-03-27 Saudi Arabian Oil Company Method to remove metals from petroleum
US9708546B2 (en) * 2015-10-29 2017-07-18 King Fahd University Of Petroleum And Minerals Method for removing sulfur compounds from a hydrocarbon fluid using an adsorbent
US10106748B2 (en) 2017-01-03 2018-10-23 Saudi Arabian Oil Company Method to remove sulfur and metals from petroleum
US10752847B2 (en) 2017-03-08 2020-08-25 Saudi Arabian Oil Company Integrated hydrothermal process to upgrade heavy oil
US10703999B2 (en) 2017-03-14 2020-07-07 Saudi Arabian Oil Company Integrated supercritical water and steam cracking process
US10526552B1 (en) 2018-10-12 2020-01-07 Saudi Arabian Oil Company Upgrading of heavy oil for steam cracking process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2018282A (en) * 1978-04-10 1979-10-17 Continental Oil Co Process for treating coker gasoline
US4464252A (en) * 1982-08-23 1984-08-07 Exxon Research & Engineering Co. Adsorbents for sulfur removal
WO1996000269A1 (en) * 1994-06-23 1996-01-04 Chevron Chemical Company Process for reforming hydrocarbon feedstocks over a sulfur sensitive catalyst
EP1454976A1 (en) * 2003-03-07 2004-09-08 Institut Francais Du Petrole Desulfurization, deazotation or dearomatization process of a hydrocarbon feedstock by adsorption over a solid spent sorbent

Family Cites Families (130)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB796175A (en) 1954-10-04 1958-06-04 California Research Corp Improvements in or relating to catalysts and the production thereof
US2944012A (en) 1957-03-15 1960-07-05 Exxon Research Engineering Co Process for stabilizing jet fuels
US2967204A (en) 1958-08-04 1961-01-03 Gulf Research Development Co Hydrogenation of aromatics with a tungsten and nickel sulfide, supported on alumina, catalyst composite
US3116234A (en) 1959-12-08 1963-12-31 Shell Oil Co Process for the catalytic desulfurization of hydrocarbon oils
GB1098698A (en) 1965-10-04 1968-01-10 British Petroleum Co Improvements relating to the desulphurisation of petroleum fractions
GB1232594A (en) 1967-07-11 1971-05-19
US3545915A (en) 1967-07-14 1970-12-08 Calgon C0Rp Method of removing carbon monoxide from gases
US3586621A (en) 1968-09-03 1971-06-22 Phillips Petroleum Co Hydrocarbon steam reforming,conversion and refining
US3830752A (en) 1968-09-20 1974-08-20 Union Oil Co Hydrocarbon conversion catalysts
US3501396A (en) 1969-04-14 1970-03-17 Universal Oil Prod Co Hydrodesulfurization of asphaltene-containing black oil
GB1366674A (en) * 1971-09-28 1974-09-11 British Petroleum Co Graphite pellets
US3733259A (en) 1971-11-10 1973-05-15 Texaco Inc Treatment of heavy petroleum oils
US4210628A (en) 1973-07-12 1980-07-01 Takeda Chemical Industries, Ltd. Removal of nitrogen oxides
US3864451A (en) 1973-08-16 1975-02-04 Environics Inc Method for Removing Nitric Oxide from Combustion Gases
US4005005A (en) 1974-05-31 1977-01-25 Standard Oil Company (Indiana) Process for recovering and upgrading hydrocarbons from tar sands
US3948755A (en) 1974-05-31 1976-04-06 Standard Oil Company Process for recovering and upgrading hydrocarbons from oil shale and tar sands
US3960708A (en) 1974-05-31 1976-06-01 Standard Oil Company Process for upgrading a hydrocarbon fraction
US3988238A (en) 1974-07-01 1976-10-26 Standard Oil Company (Indiana) Process for recovering upgraded products from coal
ZA753184B (en) 1974-05-31 1976-04-28 Standard Oil Co Process for recovering upgraded hydrocarbon products
US3960706A (en) 1974-05-31 1976-06-01 Standard Oil Company Process for upgrading a hydrocarbon fraction
US3948754A (en) 1974-05-31 1976-04-06 Standard Oil Company Process for recovering and upgrading hydrocarbons from oil shale and tar sands
US3989618A (en) 1974-05-31 1976-11-02 Standard Oil Company (Indiana) Process for upgrading a hydrocarbon fraction
US4082695A (en) 1975-01-20 1978-04-04 Mobil Oil Corporation Catalyst for residua demetalation and desulfurization
JPS54809A (en) * 1977-06-03 1979-01-06 Pioneer Electronic Corp Electronic tuning receiver
US4325926A (en) * 1977-12-16 1982-04-20 Chevron Research Company Process for removing sulfur dioxide from a gas
US4203829A (en) 1978-09-28 1980-05-20 Standard Oil Company (Indiana) Catalyst, method of preparation and use thereof in hydrodesulfurizing cracked naphtha
US4485007A (en) 1982-06-15 1984-11-27 Environmental Research And Technology Inc. Process for purifying hydrocarbonaceous oils
US4544481A (en) 1982-07-20 1985-10-01 Exxon Research And Engineering Co. Supported carbon-containing molybdenum and tungsten sulfide catalysts their preparation and use
US4879265A (en) 1982-08-19 1989-11-07 Union Oil Company Of California Hydroprocessing catalyst and phosphorous and citric acid containing impregnating solution
US4483761A (en) 1983-07-05 1984-11-20 The Standard Oil Company Upgrading heavy hydrocarbons with supercritical water and light olefins
US4530755A (en) 1983-10-31 1985-07-23 Exxon Research And Engineering Co. Coking with solvent separation of recycle oil using coker naphtha
US4743357A (en) 1983-12-27 1988-05-10 Allied Corporation Catalytic process for production of light hydrocarbons by treatment of heavy hydrocarbons with water
US4719000A (en) 1984-04-02 1988-01-12 Atlantic Richfield Company Upgrading petroleum asphaltenes
US4594141A (en) 1984-12-18 1986-06-10 The Standard Oil Company Conversion of high boiling organic materials to low boiling materials
US4818370A (en) 1986-07-23 1989-04-04 Cities Service Oil And Gas Corporation Process for converting heavy crudes, tars, and bitumens to lighter products in the presence of brine at supercritical conditions
US4762814A (en) 1986-11-14 1988-08-09 Phillips Petroleum Company Hydrotreating catalyst and process for its preparation
US4840725A (en) 1987-06-19 1989-06-20 The Standard Oil Company Conversion of high boiling liquid organic materials to lower boiling materials
US4813370A (en) 1988-04-21 1989-03-21 Capamaggio Scott A Bookmarker
US4908122A (en) 1989-05-08 1990-03-13 Uop Process for sweetening a sour hydrocarbon fraction
US5096567A (en) 1989-10-16 1992-03-17 The Standard Oil Company Heavy oil upgrading under dense fluid phase conditions utilizing emulsified feed stocks
US5278138A (en) 1990-04-16 1994-01-11 Ott Kevin C Aerosol chemical vapor deposition of metal oxide films
US5087350A (en) 1990-05-08 1992-02-11 Laboratorios Paris, C.A. Process for recovering metals and for removing sulfur from materials containing them by means of an oxidative extraction
US5851381A (en) 1990-12-07 1998-12-22 Idemitsu Kosan Co., Ltd. Method of refining crude oil
US5167797A (en) 1990-12-07 1992-12-01 Exxon Chemical Company Inc. Removal of sulfur contaminants from hydrocarbons using n-halogeno compounds
US5411658A (en) 1991-08-15 1995-05-02 Mobil Oil Corporation Gasoline upgrading process
US5435907A (en) 1992-04-20 1995-07-25 Texaco Inc. Hydrodearomatization of middle distillate hydrocarbons
DE69315636D1 (en) 1992-07-27 1998-01-22 Texaco Development Corp Hydra treatment of crack naphta
TW261554B (en) 1992-10-05 1995-11-01 Du Pont
TW256798B (en) 1992-10-05 1995-09-11 Du Pont
US5384051A (en) 1993-02-05 1995-01-24 Mcginness; Thomas G. Supercritical oxidation reactor
US5316659A (en) 1993-04-02 1994-05-31 Exxon Research & Engineering Co. Upgrading of bitumen asphaltenes by hot water treatment
US5462651A (en) 1994-08-09 1995-10-31 Texaco Inc. Hydrodearomatization of hydrocarbon oils using novel "phosphorus treated carbon" supported metal sulfide catalysts
DE69424398T2 (en) 1993-12-30 2000-10-19 Cosmo Oil Co Ltd Process for the preparation of a hydrodesulfurization catalyst
US5466363A (en) 1994-02-10 1995-11-14 Mobil Oil Corporation Integrated process for hydrotreating heavy oil, then manufacturing an alloy or steel using a carbon-based catalyst
CA2143404C (en) 1994-03-09 1999-05-04 Michael Siskin Process for removal of heteroatoms under reducing conditions in supercritical water
US5861136A (en) 1995-01-10 1999-01-19 E. I. Du Pont De Nemours And Company Method for making copper I oxide powders by aerosol decomposition
US5676822A (en) 1995-03-09 1997-10-14 Texaco Inc. Process for hydrodearomatization of hydrocarbon oils using carbon supported metal sulfide catalysts promoted by zinc
US5695632A (en) 1995-05-02 1997-12-09 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
JP3387700B2 (en) 1995-07-26 2003-03-17 新日本石油株式会社 Desulfurization method of catalytic cracking gasoline
US5616165A (en) 1995-08-25 1997-04-01 E. I. Du Pont De Nemours And Company Method for making gold powders by aerosol decomposition
US5597476A (en) 1995-08-28 1997-01-28 Chemical Research & Licensing Company Gasoline desulfurization process
US6699304B1 (en) 1997-02-24 2004-03-02 Superior Micropowders, Llc Palladium-containing particles, method and apparatus of manufacture, palladium-containing devices made therefrom
EP1007308B1 (en) 1997-02-24 2003-11-12 Superior Micropowders LLC Aerosol method and apparatus, particulate products, and electronic devices made therefrom
JP2001513828A (en) 1997-02-24 2001-09-04 スーペリア マイクロパウダーズ リミテッド ライアビリティ カンパニー Oxygen-containing fluorescent powder, method for producing the fluorescent powder, and apparatus using the fluorescent powder
US6159267A (en) 1997-02-24 2000-12-12 Superior Micropowders Llc Palladium-containing particles, method and apparatus of manufacture, palladium-containing devices made therefrom
US6103393A (en) 1998-02-24 2000-08-15 Superior Micropowders Llc Metal-carbon composite powders, methods for producing powders and devices fabricated from same
US6780350B1 (en) 1997-02-24 2004-08-24 Superior Micropowders Llc Metal-carbon composite powders, methods for producing powders and devices fabricated from same
US5928497A (en) * 1997-08-22 1999-07-27 Exxon Chemical Pateuts Inc Heteroatom removal through countercurrent sorption
JP3729621B2 (en) 1997-09-24 2005-12-21 新日本石油株式会社 Hydrocracking method for catalytic cracking gasoline and gasoline
US6248230B1 (en) * 1998-06-25 2001-06-19 Sk Corporation Method for manufacturing cleaner fuels
US6277271B1 (en) 1998-07-15 2001-08-21 Uop Llc Process for the desulfurization of a hydrocarbonaceoous oil
DE19835479B4 (en) 1998-08-06 2007-06-06 Kjeld Andersen Process for the catalytic removal of metal compounds from heavy oils
US5958224A (en) 1998-08-14 1999-09-28 Exxon Research And Engineering Co Process for deep desulfurization using combined hydrotreating-oxidation
US6685762B1 (en) 1998-08-26 2004-02-03 Superior Micropowders Llc Aerosol method and apparatus for making particulate products
FR2785908B1 (en) 1998-11-18 2005-12-16 Inst Francais Du Petrole PROCESS FOR PRODUCING LOW SULFUR CONTENT
US6197718B1 (en) 1999-03-03 2001-03-06 Exxon Research And Engineering Company Catalyst activation method for selective cat naphtha hydrodesulfurization
JP3489478B2 (en) 1999-03-31 2004-01-19 三菱マテリアル株式会社 Conversion method of hydrocarbon resources using supercritical water
EP1057879A3 (en) * 1999-06-02 2001-07-04 Haldor Topsoe A/S A combined process for improved hydrotreating of diesel fuels
US6228254B1 (en) 1999-06-11 2001-05-08 Chevron U.S.A., Inc. Mild hydrotreating/extraction process for low sulfur gasoline
JP2001019984A (en) 1999-07-07 2001-01-23 Tokyo Gas Co Ltd Activated carbon fiber adsorbent for removing odorant in fuel gas
US6303020B1 (en) 2000-01-07 2001-10-16 Catalytic Distillation Technologies Process for the desulfurization of petroleum feeds
JP2001192676A (en) 2000-01-11 2001-07-17 Mitsubishi Materials Corp Method for conversion of hydrocarbon resource, etc., in high efficiency
US6596157B2 (en) 2000-04-04 2003-07-22 Exxonmobil Research And Engineering Company Staged hydrotreating method for naphtha desulfurization
US6488840B1 (en) 2000-04-18 2002-12-03 Exxonmobil Research And Engineering Company Mercaptan removal from petroleum streams (Law950)
WO2002022763A1 (en) 2000-09-11 2002-03-21 Research Triangle Institute Process for desulfurizing hydrocarbon fuels and fuel components
US6610197B2 (en) 2000-11-02 2003-08-26 Exxonmobil Research And Engineering Company Low-sulfur fuel and process of making
US6579444B2 (en) 2000-12-28 2003-06-17 Exxonmobil Research And Engineering Company Removal of sulfur compounds from hydrocarbon feedstreams using cobalt containing adsorbents in the substantial absence of hydrogen
US6827845B2 (en) 2001-02-08 2004-12-07 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
US6881325B2 (en) 2001-02-08 2005-04-19 Bp Corporation North America Inc. Preparation of components for transportation fuels
US6500219B1 (en) 2001-03-19 2002-12-31 Sulphco, Inc. Continuous process for oxidative desulfurization of fossil fuels with ultrasound and products thereof
US20040188327A1 (en) 2001-06-20 2004-09-30 Catalytic Distillation Technologies Process for sulfur reduction in naphtha streams
US6623627B1 (en) 2001-07-09 2003-09-23 Uop Llc Production of low sulfur gasoline
JP3791363B2 (en) 2001-08-07 2006-06-28 株式会社日立製作所 Lightening of heavy oil
AU2002326926A1 (en) 2001-09-17 2003-04-01 Southwest Research Institute Pretreatment processes for heavy oil and carbonaceous materials
AU2003215213A1 (en) 2002-02-12 2003-09-04 The Penn State Research Foundation Deep desulfurization of hydrocarbon fuels
JP3724438B2 (en) 2002-03-08 2005-12-07 株式会社日立製作所 Method and apparatus for treating heavy oil with supercritical water, and power generation system equipped with heavy oil treatment apparatus
US6893554B2 (en) 2002-03-13 2005-05-17 Exxonmobil Research And Engineering Company Naphtha desulfurization with selectively suppressed hydrogenation
JP3669340B2 (en) 2002-03-27 2005-07-06 株式会社日立製作所 Oil refining method and refiner, and power plant
JP4336308B2 (en) * 2002-05-22 2009-09-30 株式会社ジャパンエナジー Adsorption desulfurization agent for desulfurizing petroleum fraction, desulfurization method using the same, and method for producing light oil including the desulfurization method
JP4395570B2 (en) 2002-07-30 2010-01-13 独立行政法人産業技術総合研究所 Method for producing hydrogen by thermochemical decomposition of water
EP1403358A1 (en) 2002-09-27 2004-03-31 ENI S.p.A. Process and catalysts for deep desulphurization of fuels
EP1577007B1 (en) 2002-12-18 2013-03-20 Cosmo Oil Co., Ltd. Hydrotreating catalyst for gas oil, process for producing the same, and method of hydrotreating gas oil
US7087156B2 (en) 2002-12-19 2006-08-08 W.R. Grace & Co. - Conn. Process for removal of nitrogen containing contaminants from gas oil feedstreams
US20040178123A1 (en) 2003-03-13 2004-09-16 Catalytic Distillation Technologies Process for the hydrodesulfurization of naphtha
JP4594602B2 (en) 2003-06-24 2010-12-08 三井造船株式会社 Method for oxidative desulfurization of liquid petroleum products
TW200521219A (en) 2003-07-08 2005-07-01 Shell Int Research Process to prepare a base oil
JP4098181B2 (en) 2003-08-05 2008-06-11 株式会社日立製作所 Heavy oil treatment method and heavy oil treatment system
US20050040078A1 (en) * 2003-08-20 2005-02-24 Zinnen Herman A. Process for the desulfurization of hydrocarbonacecus oil
US7267761B2 (en) 2003-09-26 2007-09-11 W.R. Grace & Co.-Conn. Method of reducing sulfur in hydrocarbon feedstock using a membrane separation zone
US7435330B2 (en) 2003-10-07 2008-10-14 Hitachi, Ltd. Heavy oil reforming method, an apparatus therefor, and gas turbine power generation system
FR2863265B1 (en) 2003-12-04 2006-12-08 Centre Nat Rech Scient PROCESS FOR THE SYNTHESIS OF CHALCOGENIDE NANOPARTICLES HAVING A LAMELLAR STRUCTURE
CN1253536C (en) * 2004-03-24 2006-04-26 华东理工大学 Catalysis, oxidation sweetening method for distillate oil of petroleum
US7799210B2 (en) 2004-05-14 2010-09-21 Exxonmobil Research And Engineering Company Process for removing sulfur from naphtha
US20050284794A1 (en) 2004-06-23 2005-12-29 Davis Timothy J Naphtha hydroprocessing with mercaptan removal
US7909985B2 (en) 2004-12-23 2011-03-22 University Of Utah Research Foundation Fragmentation of heavy hydrocarbons using an ozone-containing fragmentation fluid
CN101253256B (en) 2005-08-01 2011-11-16 日本能源株式会社 Method for desulfurization of hydrocarbon oil
JP2009533304A (en) 2006-04-07 2009-09-17 チャート・インダストリーズ・インコーポレーテッド Supercritical processes, reactors, and equipment for hydrogen production
US20080099375A1 (en) * 2006-10-30 2008-05-01 Exxonmobil Research And Engineering Company Process for adsorption of sulfur compounds from hydrocarbon streams
US20080099374A1 (en) 2006-10-31 2008-05-01 Chevron U.S.A. Inc. Reactor and process for upgrading heavy hydrocarbon oils
US20080099377A1 (en) 2006-10-31 2008-05-01 Chevron U.S.A. Inc. Process for upgrading heavy hydrocarbon oils
US20080099376A1 (en) 2006-10-31 2008-05-01 Chevron U.S.A. Inc. Upgrading heavy hydrocarbon oils
US20080099378A1 (en) 2006-10-31 2008-05-01 Chevron U.S.A. Inc. Process and reactor for upgrading heavy hydrocarbon oils
FR2908781B1 (en) 2006-11-16 2012-10-19 Inst Francais Du Petrole PROCESS FOR DEEP DEFLAVING CRACKING SPECIES WITH LOW LOSS OF OCTANE INDEX
US7842181B2 (en) * 2006-12-06 2010-11-30 Saudi Arabian Oil Company Composition and process for the removal of sulfur from middle distillate fuels
FR2913235B1 (en) 2007-03-02 2011-02-25 Inst Francais Du Petrole IMPROVED METHOD FOR DESULFURIZING AND DEAZATING A GASOLINE TYPE HYDROCARBON CUT CONTAINING NITROGEN COMPOUNDS
US7780847B2 (en) 2007-10-01 2010-08-24 Saudi Arabian Oil Company Method of producing low sulfur, high octane gasoline
US8142646B2 (en) 2007-11-30 2012-03-27 Saudi Arabian Oil Company Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds
US8088711B2 (en) 2007-11-30 2012-01-03 Saudi Arabian Oil Company Process and catalyst for desulfurization of hydrocarbonaceous oil stream
US20090145808A1 (en) 2007-11-30 2009-06-11 Saudi Arabian Oil Company Catalyst to attain low sulfur diesel
US9636662B2 (en) 2008-02-21 2017-05-02 Saudi Arabian Oil Company Catalyst to attain low sulfur gasoline

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2018282A (en) * 1978-04-10 1979-10-17 Continental Oil Co Process for treating coker gasoline
US4464252A (en) * 1982-08-23 1984-08-07 Exxon Research & Engineering Co. Adsorbents for sulfur removal
WO1996000269A1 (en) * 1994-06-23 1996-01-04 Chevron Chemical Company Process for reforming hydrocarbon feedstocks over a sulfur sensitive catalyst
EP1454976A1 (en) * 2003-03-07 2004-09-08 Institut Francais Du Petrole Desulfurization, deazotation or dearomatization process of a hydrocarbon feedstock by adsorption over a solid spent sorbent

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