WO2008147013A3 - Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts - Google Patents

Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts Download PDF

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Publication number
WO2008147013A3
WO2008147013A3 PCT/KR2008/000547 KR2008000547W WO2008147013A3 WO 2008147013 A3 WO2008147013 A3 WO 2008147013A3 KR 2008000547 W KR2008000547 W KR 2008000547W WO 2008147013 A3 WO2008147013 A3 WO 2008147013A3
Authority
WO
WIPO (PCT)
Prior art keywords
zirconia
syngas
liquid hydrocarbons
aluminum oxide
preparation methods
Prior art date
Application number
PCT/KR2008/000547
Other languages
French (fr)
Other versions
WO2008147013A2 (en
Inventor
Ki-Won Jun
Jong-Wook Bae
Seung-Moon Kim
Jong-Hyeok Oh
Original Assignee
Korea Res Inst Chem Tech
Daelim Ind Co Ltd
Doosan Mecatec Co Ltd
Korea Internat Corp
Hyundai Engineering Co Ltd
Sk Energy Co Ltd
Ki-Won Jun
Jong-Wook Bae
Seung-Moon Kim
Jong-Hyeok Oh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Res Inst Chem Tech, Daelim Ind Co Ltd, Doosan Mecatec Co Ltd, Korea Internat Corp, Hyundai Engineering Co Ltd, Sk Energy Co Ltd, Ki-Won Jun, Jong-Wook Bae, Seung-Moon Kim, Jong-Hyeok Oh filed Critical Korea Res Inst Chem Tech
Priority to EP08705003A priority Critical patent/EP2152413A2/en
Publication of WO2008147013A2 publication Critical patent/WO2008147013A2/en
Publication of WO2008147013A3 publication Critical patent/WO2008147013A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B01J35/615—
    • B01J35/66—
    • B01J35/69—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
    • B01J2523/48—Zirconium
    • B01J35/633—
    • B01J35/635—

Abstract

The present invention relates to a cobalt/zirconia-alumina catalyst, in which cobalt is supported as an active ingredient on zirconia-alumina prepared by co-precipitation, having a bimodal pore structure with different pore sizes and maintaining a specific pore volume ratio and a method for preparing liquid hydrocarbons with high yield from the Fischer- Tropsch of a syngas (CO/H2/CO2 ) in the presence of the cobalt/zirconia-alumina catalyst.
PCT/KR2008/000547 2007-05-29 2008-01-30 Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts WO2008147013A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08705003A EP2152413A2 (en) 2007-05-29 2008-01-30 Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020070052243A KR100837377B1 (en) 2007-05-29 2007-05-29 Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts
KR10-2007-0052243 2007-05-29

Publications (2)

Publication Number Publication Date
WO2008147013A2 WO2008147013A2 (en) 2008-12-04
WO2008147013A3 true WO2008147013A3 (en) 2009-03-26

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2008/000547 WO2008147013A2 (en) 2007-05-29 2008-01-30 Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts

Country Status (3)

Country Link
EP (1) EP2152413A2 (en)
KR (1) KR100837377B1 (en)
WO (1) WO2008147013A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102489312B (en) * 2011-11-24 2013-06-19 武汉凯迪工程技术研究总院有限公司 Fischer-Tropsch synthesis cobalt-based nano-catalyst based on porous material confinement, and preparation method thereof
KR101469183B1 (en) * 2013-08-23 2014-12-10 한국화학연구원 method of prepering supported catalyst
KR20150108437A (en) * 2014-03-17 2015-09-30 씨큐브 주식회사 Flaky aluminum oxide and method of producing thereof
CN104226315B (en) * 2014-09-30 2017-01-11 厦门大学 Co-based catalyst used for preparing hydrocarbon mixture through CO hydrogenation and preparation method thereof
WO2017193696A1 (en) 2016-05-12 2017-11-16 中国科学院福建物质结构研究所 Catalyst, preparation method therefor and application thereof in preparation of syngas
CN113117683A (en) * 2021-04-16 2021-07-16 郑州大学 Supported catalyst and preparation method thereof
CN116943662B (en) * 2023-06-13 2024-02-20 北京海望氢能科技有限公司 Heterogeneous catalyst and preparation method and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619910A (en) * 1985-06-05 1986-10-28 Air Products And Chemicals, Inc. Catalyst for selective conversion of synthesis gas and method of making the catalyst

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Publication number Priority date Publication date Assignee Title
JP2859270B2 (en) * 1987-06-11 1999-02-17 旭光学工業株式会社 Camera gaze direction detection device
US4799077A (en) * 1987-11-23 1989-01-17 Polaroid Corporation Common drive for shutter blades and objective lens assembly
US7541310B2 (en) 2003-10-16 2009-06-02 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619910A (en) * 1985-06-05 1986-10-28 Air Products And Chemicals, Inc. Catalyst for selective conversion of synthesis gas and method of making the catalyst

Also Published As

Publication number Publication date
EP2152413A2 (en) 2010-02-17
WO2008147013A2 (en) 2008-12-04
KR100837377B1 (en) 2008-06-12

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