WO2009013529A2 - Uv barrier film - Google Patents
Uv barrier film Download PDFInfo
- Publication number
- WO2009013529A2 WO2009013529A2 PCT/GB2008/050596 GB2008050596W WO2009013529A2 WO 2009013529 A2 WO2009013529 A2 WO 2009013529A2 GB 2008050596 W GB2008050596 W GB 2008050596W WO 2009013529 A2 WO2009013529 A2 WO 2009013529A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- film
- additive
- film according
- present
- benzophenone
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/014—Stabilisers against oxidation, heat, light or ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
Definitions
- the present invention concerns UV barrier films, in particular polymeric films comprising a mixture of both inorganic and organic UV blocking compounds.
- WO-A-04/87795 discloses a biaxially oriented polypropylene (BOPP) film which has dispersed therein rigid rod like UV absorbers compatible with the polymer such as (E 1 E)-1 ,4- diphenylbuta-1 ,3-diene (DPBD); (E,E)-1 ,6-diphenylhexa-1 ,3,5-triene (DPHT); and beta, beta-carotene (carotene) at typical concentrations of about 0.01% w/w.
- BOPP biaxially oriented polypropylene
- absorbers preferentially align along one of the two orientation axes of the film and allow anisotropy in the film to be covertly detected by the difference in the UV fluorescence spectra of the film in along each axis. This provides a covert means to authenticate the film, which is useful as a substrate for security applications.
- EP-B-1004626 discloses a thin packaging film made out of a thermoplastic material with anti-UV properties, characterized in that its composition further comprises a combination of at least one organic compound with at least one inorganic UV-absorbent compound, for improved barrier against UV rays, and improved transparency.
- the organic compound is a benzotriazole
- the inorganic compound is micronized zinc oxide.
- the material for the film further comprises a binder compound, for example a benzophenone, in order to improve the compatibility between the organic component and the base-resin.
- US Patent No. 6,916,867 discloses polyolefin compositions which comprise as UV absorber a synergistic mixture of a) at least one hydroxybenzophenone and at least one 2-hydroxyphenylbenzotriazole with the proviso that the polyolefin is a high density polyethylene of the "Phillips" type or a polyethylene of the metallocene type; b) at least one hydroxybenzophenone and at least one 2-hydroxyphenyltriazine, with the proviso that if the polyolefin is polypropylene, no polyvinylpyridin is present c) at least one hydroxybenzophenone and at least one oxanilide; d) at least one 2- hydroxyphenylbenzotriazole and at least one oxanilide; e) at least one 2- hydroxyphenyltriazine and at least one oxanilide; f) at least one hydroxybenzophenone, at least one 2-hydroxyphenylbenz
- the film of the invention realises a significant advantage in optical properties, and by careful selection of the relative quantities of the respective additives, it has been found possible to formulate the film composition without the aid of a binder to solubilise the organic component.
- organic UV absorbers One problem with organic UV absorbers is their tendency to bloom or migrate to the film surface over time, causing a deterioration in the optical properties of the film.
- organic additives such as triazines, hindered amines, oxanilides, cyanoacrylates, benzotriazoles and/or benzophenones can largely be avoided by limiting the quantity of such additive in the film to below 2.0%, preferably below 1.5%, more preferably below 1.0% and most preferably below 0.75% by weight of the film composition.
- inorganic and organic UV blocking additives provides a polypropylene film which exhibits excellent optical properties and yet is substantially UV blocking, to the extent that at the point of maximum transmittance of UV light between 220 and 350nm the film transmits no more that 30%, preferably no more than 25%, more preferably no more than 20% and most preferably no more than 15% of the UV light incident upon the film at the wavelength of the said maximum transmittance.
- the film of the invention preferably exhibits wide angle haze (WAH) of less than 10%, more preferably less than 8% and most preferably less than 6%.
- WAH wide angle haze
- the film may be a multilayer structure formed by any suitable method (such as co-extrusion and/or lamination) with one or more core or surface layers being formed as described herein.
- the film comprises biaxially oriented polypropylene (BOPP).
- BOPP films may be prepared with substantially balanced physical properties, for example as can be produced using substantially equal machine direction and transverse direction stretch ratios, or can be unbalanced where the film is significantly more oriented in one direction (MD or TD).
- Sequential stretching can be used, in which heated rollers effect stretching of the film in the machine direction and a stenter over is thereafter used to effect stretching in the transverse direction, or simultaneous stretching, for example using the so-called bubble process.
- the machine direction and transverse direction stretch ratios are preferably in the range of from 4:1 to 10:1 , and more preferably from 6:1 to 8:1.
- benzotriazoles may be contemplated for use in the present invention, of which 2-(2'-hydroxy-3', 5'-di-t-amylphenyl) benzotriazole available under the trade name Cyasorb UV-2337 from Cytec Industries Inc.
- Commercially available materials may also comprise a blend of one or more organic UV absorbers, together with one or more inorganic UV absorbers, of which Shelfplus UV 1400 is also an example.
- UV absorbers include a polypropylene masterbatch containing 10% mineral oxide available under the designation UVBLOCK10 from Ampacet.
- the skin layers preferably have a thickness of from about 0.05 microns to about 2 microns, preferably from about 0.1 microns to about 1.5 microns, more preferably from about 0.2 microns to about 1.25 microns, most preferably from about 0.3 microns to about 0.9 microns.
- Figure 1 depicts the UV spectra of Examples 1 to 4.
- Figure 2 depicts the UV spectra of Examples 5 to 10;
- Figure 3 depicts the UV spectra of Examples 11 to 15;
- Figure 6 depicts the UV spectra of Examples 27 to 32;
- Figure 8 depicts the UV spectra of Examples 39 to 44;
- Figure 10 depicts the UV spectra of Examples 51 to 56;
- Figure 11 depicts the UV spectra of Examples 57 to 62;
- Figure 12 depicts the UV spectra of Examples 63 to 68;
- UV blocking additives which were used were as follows:
- Tinuvin 234 (member of the benzotriazole family, namely 2-(2H-benzotriazol-
- UVBLOCK10 an inorganic, non-migratory additive
- active ZnO inorganic, non-migratory additive
- active TiO 2 inorganic Additives
- Masterbatches were prepared by compounding UV barrier additives in the powder state with polypropylene pellets using a PRISM twin screw extruder.
- Plaques of polypropylene were produced with a Rondol multilayer extruder by mixing polypropylene granules and various UV barrier additives masterbatch. These plaques were then stretched using a TA long stretcher.
- Accelerated ageing was also carried out by exposing samples to a 50 0 C oven for 30 days in order to assess the stability of the final product.
- a three layer polymeric tube was formed by co-extruding a core layer of polypropylene homopolymer with two skin layers of polyethylene/polypropylene/polybutylene terpolymer (a random copolymer) on opposite sides of the core layer.
- UV additive masterbatch containing the selected UV additive was blended prior to extrusion with the polypropylene homopolymer in the core.
- the tube was cooled and subsequently reheated before being blown to produce a three layer biaxially oriented film tube.
- the blown film tube was spliced and cut to provide a three layer film of 23 ⁇ m thickness.
- the optical and UV transmittance properties of the films were measured and the results shown in Table 11 and in Figure 11. All UV graphs have been normalised to 25 ⁇ m. Table 11
- the UV spectra shown in Figure 12 show the transmission profiles of one film in accordance with the invention (0.5% Tinuvin 234 + 0.5% Active Ti ⁇ 2 + 1.5% Active ZnO in PP) compared with five comparative Examples (three being the same respectively as comparative Examples 52, 54 and 57 above, and two being different film types, namely commercially available cellulose and cellulose acetate films respectively).
Abstract
Description
Claims
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/670,356 US8088848B2 (en) | 2007-07-24 | 2008-07-08 | UV barrier film |
CN2008801003156A CN101765628B (en) | 2007-07-24 | 2008-07-18 | UV barrier film |
JP2010517488A JP2010534265A (en) | 2007-07-24 | 2008-07-18 | UV blocking film |
ES08788574.5T ES2559861T3 (en) | 2007-07-24 | 2008-07-18 | UV barrier film |
PL08788574T PL2167573T3 (en) | 2007-07-24 | 2008-07-18 | Uv barrier film |
KR1020167032454A KR20160137662A (en) | 2007-07-24 | 2008-07-18 | Uv barrier film |
EP08788574.5A EP2167573B1 (en) | 2007-07-24 | 2008-07-18 | Uv barrier film |
KR1020157011259A KR20150055092A (en) | 2007-07-24 | 2008-07-18 | Uv barrier film |
HK10110581.2A HK1143986A1 (en) | 2007-07-24 | 2010-11-12 | Uv barrier film uv |
US13/308,339 US8664307B2 (en) | 2007-07-24 | 2011-11-30 | UV barrier film |
US14/159,115 US8906987B2 (en) | 2007-07-24 | 2014-01-20 | UV barrier film |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0714418.1 | 2007-07-24 | ||
GBGB0714418.1A GB0714418D0 (en) | 2007-07-24 | 2007-07-24 | UV barrier film |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/670,356 A-371-Of-International US8088848B2 (en) | 2007-07-24 | 2008-07-08 | UV barrier film |
US13/308,339 Continuation US8664307B2 (en) | 2007-07-24 | 2011-11-30 | UV barrier film |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009013529A2 true WO2009013529A2 (en) | 2009-01-29 |
WO2009013529A3 WO2009013529A3 (en) | 2009-04-02 |
Family
ID=38512778
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2008/050596 WO2009013529A2 (en) | 2007-07-24 | 2008-07-18 | Uv barrier film |
Country Status (10)
Country | Link |
---|---|
US (3) | US8088848B2 (en) |
EP (1) | EP2167573B1 (en) |
JP (2) | JP2010534265A (en) |
KR (3) | KR20100057824A (en) |
CN (1) | CN101765628B (en) |
ES (1) | ES2559861T3 (en) |
GB (1) | GB0714418D0 (en) |
HK (1) | HK1143986A1 (en) |
PL (1) | PL2167573T3 (en) |
WO (1) | WO2009013529A2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2514539A (en) * | 2013-04-09 | 2014-12-03 | Innovia Films Ltd | UV protected films |
US9916777B2 (en) | 2012-12-19 | 2018-03-13 | Innovia Films Limited | Label |
WO2020127227A1 (en) | 2018-12-17 | 2020-06-25 | Polycine Gmbh | Flexible multi-layered film having uv and visible light barrier layer for medical packaging |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0708692D0 (en) | 2007-05-04 | 2007-06-13 | Innovia Films Ltd | Seelable, pealable film |
PT2147044E (en) * | 2007-05-24 | 2013-11-15 | Innovia Films Ltd | Low emissivity film |
GB0714419D0 (en) * | 2007-07-24 | 2007-09-05 | Innovia Films Ltd | Indicia means |
GB0714418D0 (en) | 2007-07-24 | 2007-09-05 | Innovia Films Ltd | UV barrier film |
EP2393030A3 (en) | 2010-06-07 | 2012-02-29 | Samsung SDS Co. Ltd. | Anti-malware system and operating method thereof |
EP2400424B8 (en) | 2010-06-18 | 2016-05-18 | Samsung SDS Co., Ltd. | Anti-malware system and operating method thereof |
AU2014206508B2 (en) * | 2013-01-17 | 2017-09-14 | Nirotek A.C.S. Ltd. | Transfer tape comprising adhesive for a protective wrap |
KR102443361B1 (en) | 2015-09-03 | 2022-09-19 | 삼성디스플레이 주식회사 | Display device |
EP3272524A1 (en) | 2016-07-21 | 2018-01-24 | Omya International AG | Calcium carbonate as cavitation agent for biaxially oriented polypropylene films |
CN106449658A (en) | 2016-11-08 | 2017-02-22 | 武汉华星光电技术有限公司 | A TFT substrate and a manufacturing method thereof |
JP6418301B1 (en) * | 2017-09-27 | 2018-11-07 | 大日本印刷株式会社 | Encapsulant sheet for solar cell module and solar cell module using the same |
JP6797095B2 (en) * | 2017-10-10 | 2020-12-09 | 共同印刷株式会社 | Transparent laminate |
CN114195796B (en) * | 2021-12-20 | 2023-05-23 | 常州大学 | Deep blue thermoexciton luminescent material, and preparation method and application thereof |
Family Cites Families (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US395243A (en) * | 1888-12-25 | Julius maggi | ||
US751047A (en) | 1904-02-02 | biechee | ||
US2605897A (en) | 1949-10-21 | 1952-08-05 | John B Rundle | Package |
US4157784A (en) * | 1974-07-26 | 1979-06-12 | G.A.O. Gesellschaft Fur Automation Und Organisation Mbh | Safeguard against falsification of securities and the like which is suitable for automatic machines |
US4011190A (en) * | 1975-11-24 | 1977-03-08 | Ses, Incorporated | Selective black for absorption of solar energy |
USD266224S (en) * | 1979-06-04 | 1982-09-21 | Bronander Jr Wilhelm B | Multi-pack cigarette package |
JPS57137366A (en) * | 1981-02-19 | 1982-08-24 | Matsushita Electric Ind Co Ltd | Coating composition for selective absorption of solar heat |
USD276566S (en) * | 1982-04-19 | 1984-11-27 | Tdk Corporation | Wrapping sheet for a cassette |
USD276567S (en) * | 1982-04-19 | 1984-11-27 | Tdk Corporation | Wrapping sheet for a cassette |
DE3362079D1 (en) | 1982-07-10 | 1986-03-20 | Ciba Geigy Ag | A method of providing a protected layer |
GB8315001D0 (en) * | 1983-06-01 | 1983-07-06 | Ici Plc | Multiple-layer polyolefin films |
GB8620430D0 (en) * | 1986-08-22 | 1986-10-01 | Plessey Co Plc | Marking of articles |
US4720423A (en) * | 1986-08-25 | 1988-01-19 | Minnesota Mining And Manufacturing Company | Package opening system |
DE3871854D1 (en) | 1987-05-05 | 1992-07-16 | Ciba Geigy Ag | STABILIZATION OF ORGANIC POLYMERS AGAINST LIGHT DEGRADATION. |
US5807625A (en) * | 1988-01-12 | 1998-09-15 | Sicpa Holding S.A. | Security document with reversibly photochromic printing inks |
US5174492A (en) * | 1988-10-05 | 1992-12-29 | Gabriel Gero | Multiple purpose dispensing package and blank |
US4836438A (en) | 1988-10-11 | 1989-06-06 | Westvaco Corporation | Ovenable carton with handles |
GB8828091D0 (en) | 1988-12-01 | 1989-01-05 | Traqson Ltd | Security marking |
GB2236466A (en) | 1989-09-11 | 1991-04-03 | Specialist Printers Ltd | Ultra-violet light detector |
GB2243578A (en) | 1990-04-02 | 1991-11-06 | Federal Printers Limited | Security label |
IT1246170B (en) | 1990-07-24 | 1994-11-16 | Ciba Geigy Spa | POLYPROPYLENE STABILIZING COMPOSITION INCLUDING TRIAZINIC COMPOUNDS CONTAINING PIPERIDINIC GROUPS AND METALLIC COMPOUNDS |
MX9200724A (en) * | 1991-02-22 | 1993-05-01 | Exxon Chemical Patents Inc | HEAT SEALABLE MIX OF POLYETHYLENE OR PLASTOMER OF VERY LOW DENSITY WITH POLYMERS BASED ON POLYPROPYLENE AND THERMAL SEALABLE FILM AS WELL AS ARTICLES MADE WITH THOSE. |
US5249676A (en) * | 1991-05-07 | 1993-10-05 | R. J. Reynolds Tobacco Company | Flavor burst structure and method of making the same |
US5154284A (en) * | 1991-11-07 | 1992-10-13 | Starkey Merrily J | Compact disc packaging |
GB2280129A (en) * | 1993-07-21 | 1995-01-25 | Mobil Plastics Europ Inc | Peelable film |
JPH06297630A (en) | 1993-04-20 | 1994-10-25 | Oike Ind Co Ltd | Transparent ultraviolet absorbing protective film |
JP3057671B2 (en) | 1993-06-14 | 2000-07-04 | キヤノン株式会社 | Solar cell module |
US5425996A (en) * | 1994-04-05 | 1995-06-20 | Borden, Inc. | Biaxially oriented polypropylene metallized white film |
US5489473A (en) * | 1994-04-07 | 1996-02-06 | Borden, Inc. | Biaxially and monoaxially oriented polypropylene cold seal release film |
WO1995033012A1 (en) * | 1994-05-30 | 1995-12-07 | Hitachi Chemical Company, Ltd. | Coating-protective film |
EP0692373B1 (en) * | 1994-07-13 | 1999-11-24 | Hoechst Trespaphan GmbH | Peelable, sealable polyolefin laminate |
GB9415397D0 (en) | 1994-07-29 | 1994-09-21 | Mobil Plastics Europ Inc | Peelable film structure |
GB2296466B (en) | 1994-12-23 | 1998-02-04 | Courtaulds Films | Polymeric films |
IT1273607B (en) * | 1995-04-26 | 1997-07-08 | Ciba Geigy Spa | COMBINATION OF STABILIZERS FOR ORGANIC SYNTHETIC POLYMERS |
US5730354A (en) * | 1996-07-12 | 1998-03-24 | Kt Industries Inc. | Printed tear tape |
GB2354245B (en) * | 1996-08-22 | 2001-04-25 | Ciba Sc Holding Ag | Stabilizer mixtures for polyolefins |
TW467931B (en) * | 1996-08-22 | 2001-12-11 | Ciba Sc Holding Ag | Stabilizer mixtures |
GB2349151B (en) * | 1996-08-22 | 2001-02-21 | Ciba Sc Holding Ag | Stabilizer mixtures for polyolefins |
AU5249798A (en) | 1996-11-05 | 1998-06-10 | Eastman Chemical Company | Security document and method using invisible coded markings |
DE29622554U1 (en) | 1996-12-30 | 1997-05-22 | Tabac Fab Reunies Sa | Divisible packaging, especially a cigarette cartridge |
US6231975B1 (en) * | 1997-01-24 | 2001-05-15 | Mobil Oil Corporation | Sealable film |
US5924571A (en) * | 1997-02-15 | 1999-07-20 | Agfa-Gevaert | Reclosable film package |
DE19743120A1 (en) | 1997-09-30 | 1999-04-01 | Focke & Co | Container pack for cigarettes and method and device for producing the same |
US6117438A (en) * | 1997-12-31 | 2000-09-12 | Kimberly-Clark Worldwide, Inc. | Water degradable microlayer polymer film and articles including same |
US20030226978A1 (en) * | 1998-01-30 | 2003-12-11 | Segan Industries | Integrating ultraviolet exposure detection devices |
CA87599S (en) * | 1998-09-03 | 1999-09-24 | Rothmans Benson & Hedges | Two-pack cigarette package |
US6815482B1 (en) * | 1998-11-10 | 2004-11-09 | The Procter & Gamble Company | Film with UV-barrier properties |
CA2253134C (en) * | 1998-11-10 | 2001-10-02 | Rothmans, Benson & Hedges Inc. | Two-pack kit for packaging make-your-own cigarettes |
DE69814096T2 (en) | 1998-11-10 | 2004-03-04 | The Procter & Gamble Company, Cincinnati | Film with UV barrier properties |
US6773797B1 (en) * | 1998-12-29 | 2004-08-10 | Kimberly-Clark Worldwide, Inc. | Extruded poly (ethylene oxide) and filler composites and films having enhanced ductility and breathability |
US6248442B1 (en) * | 1998-12-31 | 2001-06-19 | Mobil Oil Corporation | Easy opening hermetically sealed film |
US6491161B1 (en) * | 1999-03-12 | 2002-12-10 | Focke & Co. (Gmbh & Co.) | Package, especially for a group of cigarette packs, plus method and device for manufacturing same |
US6511728B1 (en) * | 1999-03-23 | 2003-01-28 | Flexplay Technologies, Inc. | Pseudo-transmissive read inhibitor for optical storage media |
US6168075B1 (en) * | 1999-04-12 | 2001-01-02 | Recot, Inc. | Breakaway container with thumb slit |
AU5976100A (en) | 1999-06-21 | 2001-01-09 | Cryovac, Inc. | Easy-openable pouch and oriented multi-layer thermoplastic film suitably employed in the manufacture thereof |
US20050014431A1 (en) | 1999-07-21 | 2005-01-20 | Carmody Debra J. | Polymer coated web with good water vapor permeability |
IT1320874B1 (en) * | 2000-01-18 | 2003-12-10 | Gd Spa | CIGARETTE PACKAGE AND RELATED PACKAGING METHOD. |
USD453681S1 (en) * | 2000-02-15 | 2002-02-19 | Jean-Luc Kursner | Condom package |
GB2361005B (en) * | 2000-04-04 | 2002-08-14 | Ciba Sc Holding Ag | Synergistic mixtures of uv-absorbers in polyolefins |
US6824878B2 (en) | 2001-06-12 | 2004-11-30 | Exxonmobil Oil Corporation | Method for preparing sealable films with siloxane additives |
EP1316419A3 (en) | 2001-11-30 | 2004-01-28 | General Electric Company | Weatherable multilayer articles and method for their preparation |
US8057903B2 (en) | 2001-11-30 | 2011-11-15 | Sabic Innovative Plastics Ip B.V. | Multilayer articles comprising resorcinol arylate polyester and method for making thereof |
US6706377B2 (en) * | 2002-01-11 | 2004-03-16 | Exxonmobil Oil Corporation | Sealable film |
ITBO20020210A1 (en) | 2002-04-19 | 2003-10-20 | Gd Spa | WRAPPING METHOD OF CIGARETTE PACKAGES AND WRAPPING SHEET FOR THE REALIZATION OF THIS METHOD |
US20030203231A1 (en) * | 2002-04-30 | 2003-10-30 | Kimberly-Clark Worldwide, Inc. | UV stabilization of synthetic paper |
US6997981B1 (en) * | 2002-05-20 | 2006-02-14 | Jds Uniphase Corporation | Thermal control interface coatings and pigments |
US20060166023A1 (en) * | 2002-09-06 | 2006-07-27 | Dai Nippon Printing Co., Ltd. | Backside protective sheet for solar battery module and solar battery module using the same |
CO5410180A1 (en) | 2002-10-22 | 2004-06-30 | Ciba Sc Holding Ag | COMPOSITION AND PROCESS TO POWER THE PRODUCTION OF BIO-MASS IN GREENHOUSES |
US6896956B2 (en) * | 2002-12-13 | 2005-05-24 | Exxonmobil Oil Corporation | Sealable and peelable film structure |
US6770361B2 (en) * | 2002-12-13 | 2004-08-03 | Exxonmobil Oil Corporation | Sealable and peelable film structure |
US7270882B2 (en) * | 2003-02-21 | 2007-09-18 | General Electric Company | Weatherable multilayer articles and method for their preparation |
GB0307615D0 (en) | 2003-04-02 | 2003-05-07 | Ucb Sa | Authentication means |
USD491313S1 (en) * | 2003-04-08 | 2004-06-08 | Michael Schrott | Dental floss holder in credit card form |
USD541471S1 (en) * | 2003-12-31 | 2007-04-24 | Philip Morris Usa, Inc. | Cigarette mini-pack with hinged lid |
US20050150786A1 (en) * | 2003-07-16 | 2005-07-14 | Mitten Robert T. | Cigarette pack comprising twin cigarette packets |
US7377384B2 (en) * | 2003-07-16 | 2008-05-27 | Philip Morris Usa Inc. | Cigarette pack comprising twin cigarette packets |
USD594596S1 (en) * | 2003-12-31 | 2009-06-16 | Philip Morris Usa Inc. | Cigarette mini-pack with hinged lid |
US7153576B2 (en) | 2004-01-20 | 2006-12-26 | General Electric Company | Weatherable multilayer article assemblies and method for their preparation |
WO2005075193A1 (en) | 2004-02-03 | 2005-08-18 | Tokuyama Corporation | Laminate and process for producing the same |
US20050197480A1 (en) | 2004-03-05 | 2005-09-08 | Temple Rodger G. | Barrier coating comprising a polyurethane dispersion and elastomeric material |
US20050230960A1 (en) | 2004-03-29 | 2005-10-20 | Bilodeau Wayne L | Security label, secured article and method for making the label and article |
US20060040091A1 (en) | 2004-08-23 | 2006-02-23 | Bletsos Ioannis V | Breathable low-emissivity metalized sheets |
US7798320B2 (en) * | 2005-06-10 | 2010-09-21 | Philip Morris Usa Inc. | Aromatic pocket tear tape for cigarette pack |
US20070031690A1 (en) | 2005-08-05 | 2007-02-08 | Curwood, Inc. | Multilayer coextruded films including frangible intralaminar bonding forces |
US8025985B2 (en) | 2005-08-11 | 2011-09-27 | E. I. Du Pont De Nemours And Company | Porous metallized sheets coated with an inorganic layer having low emissivity and high moisture vapor permeability |
EP1770438B1 (en) * | 2005-09-27 | 2009-07-15 | FUJIFILM Corporation | Packing box for photosensitive recording material |
USD594742S1 (en) * | 2006-02-08 | 2009-06-23 | Philip Morris Usa Inc. | Package |
ITBO20060214A1 (en) * | 2006-03-29 | 2006-06-28 | Gd Spa | METHOD FOR THE PRODUCTION OF OVERHEAD MATERIAL AND PACKAGE EQUIPPED WITH MATERIALS SO PRODUCED. |
TWI283377B (en) * | 2006-04-18 | 2007-07-01 | Ind Tech Res Inst | Flexible display |
GB0708692D0 (en) * | 2007-05-04 | 2007-06-13 | Innovia Films Ltd | Seelable, pealable film |
PT2147044E (en) * | 2007-05-24 | 2013-11-15 | Innovia Films Ltd | Low emissivity film |
GB0714419D0 (en) * | 2007-07-24 | 2007-09-05 | Innovia Films Ltd | Indicia means |
GB0714418D0 (en) | 2007-07-24 | 2007-09-05 | Innovia Films Ltd | UV barrier film |
USD592525S1 (en) * | 2007-09-14 | 2009-05-19 | Innovia Films Limited | Cigarette package wrapper |
USD592526S1 (en) * | 2007-09-14 | 2009-05-19 | Innovia Films Limited | Cigarette package wrapper |
AU325005S (en) * | 2008-10-03 | 2009-03-04 | Innovia Films Ltd | Foils and film for packaging (cigarette packet) |
USD619477S1 (en) * | 2008-10-03 | 2010-07-13 | Innovia Films Limited | Outer wrapper for packaging of CDs/DVDs |
USD613182S1 (en) | 2008-12-18 | 2010-04-06 | Innovia Films Limited | Packaging for cigarette packs, boxed articles or playing cards |
GB0823072D0 (en) | 2008-12-18 | 2009-01-28 | Innovia Films Ltd | Naked collation package |
-
2007
- 2007-07-24 GB GBGB0714418.1A patent/GB0714418D0/en not_active Ceased
-
2008
- 2008-07-08 US US12/670,356 patent/US8088848B2/en not_active Expired - Fee Related
- 2008-07-18 EP EP08788574.5A patent/EP2167573B1/en active Active
- 2008-07-18 KR KR1020107004102A patent/KR20100057824A/en active Search and Examination
- 2008-07-18 KR KR1020157011259A patent/KR20150055092A/en active Search and Examination
- 2008-07-18 WO PCT/GB2008/050596 patent/WO2009013529A2/en active Application Filing
- 2008-07-18 CN CN2008801003156A patent/CN101765628B/en not_active Expired - Fee Related
- 2008-07-18 JP JP2010517488A patent/JP2010534265A/en active Pending
- 2008-07-18 ES ES08788574.5T patent/ES2559861T3/en active Active
- 2008-07-18 KR KR1020167032454A patent/KR20160137662A/en not_active Application Discontinuation
- 2008-07-18 PL PL08788574T patent/PL2167573T3/en unknown
-
2010
- 2010-11-12 HK HK10110581.2A patent/HK1143986A1/en not_active IP Right Cessation
-
2011
- 2011-11-30 US US13/308,339 patent/US8664307B2/en not_active Expired - Fee Related
-
2013
- 2013-10-03 JP JP2013207921A patent/JP5833075B2/en not_active Expired - Fee Related
-
2014
- 2014-01-20 US US14/159,115 patent/US8906987B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
None |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9916777B2 (en) | 2012-12-19 | 2018-03-13 | Innovia Films Limited | Label |
GB2514539A (en) * | 2013-04-09 | 2014-12-03 | Innovia Films Ltd | UV protected films |
WO2020127227A1 (en) | 2018-12-17 | 2020-06-25 | Polycine Gmbh | Flexible multi-layered film having uv and visible light barrier layer for medical packaging |
Also Published As
Publication number | Publication date |
---|---|
ES2559861T3 (en) | 2016-02-16 |
EP2167573A2 (en) | 2010-03-31 |
US8664307B2 (en) | 2014-03-04 |
US20120126186A1 (en) | 2012-05-24 |
GB0714418D0 (en) | 2007-09-05 |
JP2014028969A (en) | 2014-02-13 |
KR20100057824A (en) | 2010-06-01 |
KR20160137662A (en) | 2016-11-30 |
PL2167573T3 (en) | 2016-05-31 |
CN101765628A (en) | 2010-06-30 |
CN101765628B (en) | 2013-06-05 |
JP2010534265A (en) | 2010-11-04 |
US8088848B2 (en) | 2012-01-03 |
HK1143986A1 (en) | 2011-01-21 |
EP2167573B1 (en) | 2016-01-06 |
WO2009013529A3 (en) | 2009-04-02 |
US20140155517A1 (en) | 2014-06-05 |
JP5833075B2 (en) | 2015-12-16 |
US8906987B2 (en) | 2014-12-09 |
US20100247898A1 (en) | 2010-09-30 |
KR20150055092A (en) | 2015-05-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8906987B2 (en) | UV barrier film | |
RU2510333C2 (en) | Nanosized absorbers of ir-radiation in moulded articles | |
DE60023353T2 (en) | LIGHT-RELATED OBJECTS | |
KR101720357B1 (en) | Fluoropolymeric multilayer optical film and methods of making and using the same | |
US20170226312A1 (en) | Fluoropolymer composition | |
EP1969186A2 (en) | Calcium carbonate barrier films and uses thereof | |
EP3251841B1 (en) | Biaxially oriented, uv-stabilized, single or multi-layer polyester film with at least one-sided antireflection coating (antiglare) and a transparency of at least 93.5% | |
US20080146703A1 (en) | Mono- or Multilayer Stabilized Polyester Film | |
EP2275255A1 (en) | Single layer or multilayer, stabilised polyester film | |
JP2000191918A5 (en) | ||
WO2003099911A1 (en) | Transparent polyolefin film having a uv barrier | |
WO2014167313A1 (en) | Uv protected films | |
JP6901029B2 (en) | Laminated film | |
CN114096408B (en) | Resin composition for optical film | |
JP2809687B2 (en) | Propylene resin film | |
JP2005323599A (en) | Polyolefin agricultural film | |
CN114096408A (en) | Resin composition for optical film | |
EP1849597B1 (en) | A polyolefin film having antifog and anti-UV properties | |
KR20200036400A (en) | Protective film | |
JP2011148920A (en) | Polypropylene resin composition and film made of polypropylene resin |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200880100315.6 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 08788574 Country of ref document: EP Kind code of ref document: A2 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008788574 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2010517488 Country of ref document: JP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 20107004102 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12670356 Country of ref document: US |