WO2009094336A3 - Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them - Google Patents

Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them Download PDF

Info

Publication number
WO2009094336A3
WO2009094336A3 PCT/US2009/031455 US2009031455W WO2009094336A3 WO 2009094336 A3 WO2009094336 A3 WO 2009094336A3 US 2009031455 W US2009031455 W US 2009031455W WO 2009094336 A3 WO2009094336 A3 WO 2009094336A3
Authority
WO
WIPO (PCT)
Prior art keywords
methods
compositions
making
disclosed
estolides
Prior art date
Application number
PCT/US2009/031455
Other languages
French (fr)
Other versions
WO2009094336A4 (en
WO2009094336A2 (en
Inventor
Randal J. Bernhardt
Greg P. Dado
Dennis S. Murphy
Lourdes R. Alonso
Christopher A. Gariepy
Eddie I. Filipovic
Original Assignee
Stepan Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP09703929.1A priority Critical patent/EP2247574B1/en
Priority to MX2010007991A priority patent/MX2010007991A/en
Priority to CA2712955A priority patent/CA2712955C/en
Priority to BRPI0907444-9A priority patent/BRPI0907444A2/en
Priority to CN200980110511.6A priority patent/CN101981002B/en
Priority to AU2009206542A priority patent/AU2009206542B2/en
Application filed by Stepan Company filed Critical Stepan Company
Priority to US12/507,011 priority patent/US8129328B2/en
Publication of WO2009094336A2 publication Critical patent/WO2009094336A2/en
Publication of WO2009094336A3 publication Critical patent/WO2009094336A3/en
Publication of WO2009094336A4 publication Critical patent/WO2009094336A4/en
Priority to ZA2010/05575A priority patent/ZA201005575B/en
Priority to US13/359,266 priority patent/US8338358B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/04Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
    • C07C303/06Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/22Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0026Low foaming or foam regulating compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3788Graft polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)

Abstract

Sulfo-estolides and methods of making them are described. Useful methods include acid side bleaching, partial hydrogenation of the fatty acid, pretreatment of the fatty acid to provide color inhibition, acid side hydrolysis of the sulfo-estolides, or conversion of SHP to an essentially fully hydrolyzed product (HSHP) or a partially hydrolyzed product (PHSHP). Detergent formulations, such as laundry detergents, softeners, and other materials, containing any of these materials are disclosed. Laundry methods employing these formulations are also disclosed. These formulations are useful as laundry detergents and can be biodegradable, heavy duty liquids, 2X or 3X and up to 6X concentrates, low foaming, and/or effective in a high efficiency washing machine. Methods for laundering fabrics with the compositions are also disclosed.
PCT/US2009/031455 2008-01-22 2009-01-20 Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them WO2009094336A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
MX2010007991A MX2010007991A (en) 2008-01-22 2009-01-20 Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them.
CA2712955A CA2712955C (en) 2008-01-22 2009-01-20 Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
BRPI0907444-9A BRPI0907444A2 (en) 2008-01-22 2009-01-20 Sulfonated solids and other fatty acid derivatives, methods of making them, and compositions and processes employ them
CN200980110511.6A CN101981002B (en) 2008-01-22 2009-01-20 Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
AU2009206542A AU2009206542B2 (en) 2008-01-22 2009-01-20 Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
EP09703929.1A EP2247574B1 (en) 2008-01-22 2009-01-20 Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
US12/507,011 US8129328B2 (en) 2008-01-22 2009-07-21 Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them
ZA2010/05575A ZA201005575B (en) 2008-01-22 2010-08-04 Sulfonated estolides and other derivatives of fatty acids,methods of making them,and compositions and processes employing them
US13/359,266 US8338358B2 (en) 2008-01-22 2012-01-26 Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2266208P 2008-01-22 2008-01-22
US61/022,662 2008-01-22

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/507,011 Continuation-In-Part US8129328B2 (en) 2008-01-22 2009-07-21 Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them

Publications (3)

Publication Number Publication Date
WO2009094336A2 WO2009094336A2 (en) 2009-07-30
WO2009094336A3 true WO2009094336A3 (en) 2009-10-15
WO2009094336A4 WO2009094336A4 (en) 2009-12-03

Family

ID=40639767

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/031455 WO2009094336A2 (en) 2008-01-22 2009-01-20 Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them

Country Status (9)

Country Link
US (3) US7666828B2 (en)
EP (4) EP2247574B1 (en)
CN (1) CN101981002B (en)
AU (1) AU2009206542B2 (en)
BR (1) BRPI0907444A2 (en)
CA (1) CA2712955C (en)
MX (1) MX2010007991A (en)
WO (1) WO2009094336A2 (en)
ZA (1) ZA201005575B (en)

Families Citing this family (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7998920B2 (en) * 2008-01-22 2011-08-16 Stepan Company Sulfonated estolide compositions containing magnesium sulfate and processes employing them
US7666828B2 (en) * 2008-01-22 2010-02-23 Stepan Company Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
US7879790B2 (en) * 2008-01-22 2011-02-01 Stepan Company Mixed salts of sulfonated estolides and other derivatives of fatty acids, and methods of making them
US8809392B2 (en) 2008-03-28 2014-08-19 Ecolab Usa Inc. Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
MX2010010236A (en) 2008-03-28 2010-10-20 Ecolab Inc Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents.
US8871807B2 (en) 2008-03-28 2014-10-28 Ecolab Usa Inc. Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids
BRPI0917805A2 (en) * 2008-08-14 2016-03-01 Melaleuca Inc ultra-concentrated liquid laundry detergent
US8058223B2 (en) * 2009-01-21 2011-11-15 Stepan Company Automatic or machine dishwashing compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8119588B2 (en) * 2009-01-21 2012-02-21 Stepan Company Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US7884064B2 (en) * 2009-01-21 2011-02-08 Stepan Company Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids
US8124577B2 (en) * 2009-01-21 2012-02-28 Stepan Company Personal care compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
WO2011010997A1 (en) * 2009-07-21 2011-01-27 Stepan Company Mixed salts of sulfonated estolides and other derivatives of fatty acids, and methods of making them
WO2011010998A1 (en) * 2009-07-21 2011-01-27 Stepan Company Sulfonated estolide compositions containing magnesium sulfate and processes employing them
EP2277860B1 (en) * 2009-07-22 2015-08-19 Stepan Company Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them
US8278260B2 (en) * 2009-08-21 2012-10-02 S.C. Johnson & Son, Inc. Water-activated “green” cleaning wipe
AU2010292056B9 (en) * 2009-09-11 2014-07-10 Stepan Company Liquid cleaning compositions containing sulfonated estolides and alkyl ester sulfonates
CN102712563B (en) * 2009-11-03 2015-11-25 斯特潘公司 Sulphur methylsuccinic acid (or its salt), its preparation method and comprise its composition
WO2011072232A1 (en) * 2009-12-11 2011-06-16 Stepan Company Liquid cleaning compositions containing sulfonated estolides and polymeric foam builders
JP5510123B2 (en) * 2010-06-30 2014-06-04 三浦工業株式会社 Operation method of steam boiler
ES2532537T3 (en) 2010-07-22 2015-03-27 Unilever N.V. Detergent compositions comprising a biotensive and lipase
WO2012010405A1 (en) 2010-07-22 2012-01-26 Unilever Plc Detergent compositions comprising biosurfactant and enzyme
JP2013536838A (en) 2010-08-31 2013-09-26 バイオシンセティック テクノロジーズ,リミティド ライアビリティ カンパニー Catalytic process for preparing estolide base oil
EA024706B1 (en) 2010-10-25 2016-10-31 Стипэн Компани Laundry detergents based on compositions derived from natural oil metathesis
CN103228615B (en) * 2010-10-25 2016-06-22 斯特潘公司 It is derived from the metathetic quaternized fatty amine of natural oil, amido amine and their derivant
EP2633018B1 (en) * 2010-10-25 2021-07-28 Stepan Company Sulfonates from natural oil metathesis
EP2652107B1 (en) * 2010-12-13 2019-03-27 Colgate-Palmolive Company Dilutable concentrated cleaning composition
MY191912A (en) 2011-06-17 2022-07-18 Biosynthetic Technologies Llc Estolide compositions exhibiting high oxidative stability
US8236194B1 (en) 2011-06-17 2012-08-07 Lubrigreen Biosynthetics, Llc Refrigerating fluid compositions comprising estolide compounds
WO2012173666A1 (en) 2011-06-17 2012-12-20 Lubrigreen Biosynthetics, Llc Epoxidized estolides, sulfurized estolides, and methods of making the same
USD781942S1 (en) * 2011-11-18 2017-03-21 Toyo Tanso Co., Ltd. Graphite sheet for protecting crucible
US9321664B2 (en) 2011-12-20 2016-04-26 Ecolab Usa Inc. Stable percarboxylic acid compositions and uses thereof
CN106396037B (en) 2012-03-30 2019-10-15 艺康美国股份有限公司 Peracetic acid/hydrogen peroxide and peroxide reducing agent are used to handle drilling fluid, fracturing fluid, recirculation water and the purposes for discharging water
WO2013162924A1 (en) 2012-04-24 2013-10-31 Stepan Company Synergistic surfactant blends
DE102012208286A1 (en) * 2012-05-16 2013-11-21 Henkel Ag & Co. Kgaa Low-water, liquid detergent with surfactants derived from renewable raw materials
US8586771B1 (en) 2012-06-18 2013-11-19 Biosynthetic Technologies, Llc Processes of preparing estolide compounds that include removing sulfonate residues
WO2014056743A1 (en) * 2012-10-12 2014-04-17 Henkel Ag & Co. Kgaa Liquid detergent compositions with soap, sulfo-estolide surfactant and cellulase
GB201218835D0 (en) * 2012-10-19 2012-12-05 Reckitt Benckiser Nv Dishwashing detergent composition comprising soapwort extract
US20140256811A1 (en) 2013-03-05 2014-09-11 Ecolab Usa Inc. Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids
US8822719B1 (en) 2013-03-05 2014-09-02 Ecolab Usa Inc. Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring
US10165774B2 (en) 2013-03-05 2019-01-01 Ecolab Usa Inc. Defoamer useful in a peracid composition with anionic surfactants
US9222058B2 (en) * 2013-03-12 2015-12-29 Ecolab Usa Inc. Cleaning composition and method for removal of sunscreen stains
US9702074B2 (en) 2013-03-15 2017-07-11 Whirlpool Corporation Methods and compositions for treating laundry items
US9624615B2 (en) 2013-03-15 2017-04-18 Whirlpool Corporation Methods and compositions for treating laundry items
CN103320238B (en) * 2013-07-02 2015-02-04 武汉理工大学 Water-based cleaning agent with weak acidity for removing thick oil dirt, and preparation method thereof
US9994497B2 (en) * 2014-02-25 2018-06-12 The Procter & Gamble Company Process for making renewable surfactant intermediates and surfactants from fats and oils and products thereof
US10752562B2 (en) 2014-02-25 2020-08-25 The Procter & Gamble Company Process for making renewable surfactant intermediates and surfactants from fats and oils and products thereof
US10058542B1 (en) 2014-09-12 2018-08-28 Thioredoxin Systems Ab Composition comprising selenazol or thiazolone derivatives and silver and method of treatment therewith
US9943816B2 (en) 2014-10-20 2018-04-17 Eastman Chemical Company Amphoteric ester sulfonates
US9381147B2 (en) 2014-10-20 2016-07-05 Johnson & Johnson Consumer Inc. Compositions comprising zwitterionic ester ammonioalkanoates
US9533951B2 (en) 2014-10-20 2017-01-03 Eastman Chemical Company Heterocyclic amphoteric compounds
WO2016160407A1 (en) 2015-03-31 2016-10-06 Stepan Company Detergents based on alpha-sulfonated fatty ester surfactants
US9993408B2 (en) * 2015-09-17 2018-06-12 Johnson & Johnson Consumer Inc. Compositions comprising zwitterionic alkyl-alkanoylamides and/or alkyl alkanoates
US11414380B2 (en) 2015-09-17 2022-08-16 Eastman Chemical Company Amphoteric compounds
KR102333351B1 (en) * 2016-07-11 2021-12-02 주식회사 플라즈맵 Sterilization Apparatus Utilizing Sealing Pouch and Vacuum Container
DE102016216539A1 (en) * 2016-09-01 2018-03-01 Henkel Ag & Co. Kgaa Detergent with saponin
US11324697B2 (en) * 2017-08-10 2022-05-10 The Children's Medical Center Corporation Methods and compositions relating to emulsions comprising fish oil and/or omega-3 fatty acids
US20190216697A1 (en) 2018-01-18 2019-07-18 Nohbo,LLC Hygiene product pod and methods of using same
KR20200085891A (en) 2018-01-26 2020-07-15 더 프록터 앤드 갬블 캄파니 Water soluble unit dose article containing fragrance
WO2019147532A1 (en) 2018-01-26 2019-08-01 The Procter & Gamble Company Water-soluble unit dose articles comprising perfume
KR20200086739A (en) 2018-01-26 2020-07-17 더 프록터 앤드 갬블 캄파니 Water soluble unit dose article containing enzyme
KR102433420B1 (en) 2018-01-26 2022-08-18 더 프록터 앤드 갬블 캄파니 Water-Soluble Articles and Related Methods
US20210009926A1 (en) * 2018-02-13 2021-01-14 Eastman Chemical Company Enzymatic process for producing intermediates useful as esterquat precursors
WO2019168829A1 (en) 2018-02-27 2019-09-06 The Procter & Gamble Company A consumer product comprising a flat package containing unit dose articles
US10982176B2 (en) * 2018-07-27 2021-04-20 The Procter & Gamble Company Process of laundering fabrics using a water-soluble unit dose article
US11859338B2 (en) 2019-01-28 2024-01-02 The Procter & Gamble Company Recyclable, renewable, or biodegradable package
EP3712237A1 (en) 2019-03-19 2020-09-23 The Procter & Gamble Company Fibrous water-soluble unit dose articles comprising water-soluble fibrous structures
US11045397B2 (en) * 2019-11-06 2021-06-29 Nohbo, LLC Hygiene product pod and methods of using same
WO2021092311A1 (en) * 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content glycol ether and glycol ether ester compositons
WO2023056576A1 (en) * 2021-10-06 2023-04-13 Dow Global Technologies Llc Reduced volatile organic compound surfactant compositions
WO2023056577A1 (en) * 2021-10-06 2023-04-13 Dow Global Technologies Llc Hydroxyl amine surfactant compositions
WO2023168301A2 (en) * 2022-03-01 2023-09-07 C16 Biosciences, Inc. Home care compositions comprising microbially produced oil and derivatives thereof
WO2024006701A1 (en) * 2022-06-28 2024-01-04 Stepan Company Method for making dialkyl amino acid ester sulfonates
WO2024073331A1 (en) * 2022-09-26 2024-04-04 Stepan Company Hard surface cleaning compositions comprising rhamnolipids and sulfonated alkyl esters co-surfactant
WO2024073326A1 (en) * 2022-09-26 2024-04-04 Stepan Company Hard surface cleaning compositions comprising rhamnolipids and alkyl sulfate co-surfactant

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1380390A (en) * 1970-12-16 1975-01-15 Unilever Ltd Detergent compositions
WO2000018363A1 (en) * 1998-09-25 2000-04-06 The United States Of America, As Represented By The Secretary Of Agriculture Improved shampoos and conditioners containing estolides
WO2001053247A1 (en) * 2000-01-24 2001-07-26 The United States Of America, As Represented By The Secretary Of Agriculture Biodegradable oleic estolide ester having saturated fatty acid end group useful as lubricant base stock

Family Cites Families (91)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2581375A (en) 1948-12-10 1952-01-08 Petrolite Corp Esters of sulfo high fatty acids with oxyalkylated phenol aldehyde resins
US2743288A (en) 1953-06-24 1956-04-24 Tennessee Corp Production of monosulfonated carboxylic acids and their esters
US2995524A (en) 1958-01-22 1961-08-08 Tennessee Corp Detergent compositions
BE631335A (en) 1962-04-24
DE1218646B (en) 1963-07-13 1966-06-08 Henkel & Cie Gmbh Liquid or paste-like washing active substance concentrates
US3332880A (en) 1965-01-04 1967-07-25 Procter & Gamble Detergent composition
GB1082179A (en) 1965-07-19 1967-09-06 Citrique Belge Nv Unsaturated carboxylic salt materials and derivatives thereof
CA817377A (en) 1967-03-20 1969-07-08 W.R. Grace And Co. Foamed detergent composition
GB1278421A (en) 1969-06-27 1972-06-21 Lankro Chem Ltd The sulphonation of unsaturated carboxylic acids
US3664961A (en) 1970-03-31 1972-05-23 Procter & Gamble Enzyme detergent composition containing coagglomerated perborate bleaching agent
GB1372034A (en) 1970-12-31 1974-10-30 Unilever Ltd Detergent compositions
JPS5028515B2 (en) 1971-09-30 1975-09-16
US3898187A (en) 1972-12-26 1975-08-05 Procter & Gamble Liquid detergent compositions
US3929678A (en) 1974-08-01 1975-12-30 Procter & Gamble Detergent composition having enhanced particulate soil removal performance
US4228044A (en) 1978-06-26 1980-10-14 The Procter & Gamble Company Laundry detergent compositions having enhanced particulate soil removal and antiredeposition performance
DK187280A (en) 1980-04-30 1981-10-31 Novo Industri As RUIT REDUCING AGENT FOR A COMPLETE LAUNDRY
GB2095275B (en) 1981-03-05 1985-08-07 Kao Corp Enzyme detergent composition
DE3275200D1 (en) 1981-07-13 1987-02-26 Procter & Gamble Foaming surfactant compositions
GR76287B (en) 1981-09-28 1984-08-04 Procter & Gamble
JPS58117292A (en) * 1981-12-30 1983-07-12 ライオン株式会社 Detergent composition
ATE21926T1 (en) 1982-05-10 1986-09-15 Procter & Gamble LOW-PHOSPHATE LAUNDRY DETERGENT COMPOSITIONS.
US4561998A (en) 1982-05-24 1985-12-31 The Procter & Gamble Company Near-neutral pH detergents containing anionic surfactant, cosurfactant and fatty acid
DE3380443D1 (en) 1982-12-23 1989-09-28 Procter & Gamble Zwitterionic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4597898A (en) 1982-12-23 1986-07-01 The Proctor & Gamble Company Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties
EP0111965B1 (en) 1982-12-23 1989-07-26 THE PROCTER & GAMBLE COMPANY Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
DE3380307D1 (en) 1982-12-23 1989-09-07 Procter & Gamble Ethoxylated amine polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4548744A (en) 1983-07-22 1985-10-22 Connor Daniel S Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions
US4507219A (en) 1983-08-12 1985-03-26 The Proctor & Gamble Company Stable liquid detergent compositions
JPS61100556A (en) 1984-10-20 1986-05-19 Lion Corp Preparation of saturated/unsaturated-mixed-fatty acid ester sulfonate
US4663071A (en) 1986-01-30 1987-05-05 The Procter & Gamble Company Ether carboxylate detergent builders and process for their preparation
EP0322429B1 (en) 1987-05-29 1994-10-19 Genencor International, Inc. Cutinase cleaning composition
DE3720000A1 (en) 1987-06-15 1988-12-29 Henkel Kgaa FATTY ACID POLYOXYALKYLESTER SULFONATES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS A SURFACTANT
DK212388D0 (en) 1988-04-15 1988-04-15 Novo Industri As DETERGENT ADDITIVE
DE3828226A1 (en) 1988-08-19 1990-02-22 Henkel Kgaa USE OF MIXTURES CONTAINING (A) ALKALI, AMMONIUM AND / OR AMINE SALT OF SULFURATED, UNSATURATED FATS, AND (B) ALKOXYLATED ALKYL AND / OR ALKENYL ALCOHOLS AND / OR SULFONATE ACID SEEDS AS NETWORKS
DE3828892A1 (en) 1988-08-25 1990-03-29 Henkel Kgaa OELSAEURE LOW-ALKYLESTERSULFONATE, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
DE3926345A1 (en) 1989-08-09 1991-02-14 Henkel Kgaa AQUEOUS ANCIENT SIDE CONCENTRATES WITH A CONTENT OF OIL ACID SULPHONATES AND THE USE OF OIL ACID SULPHONATES AS A VISCOSITY CONTROLLER FOR AQUEOUS ANION ANTENSIDE CONCENTRATES
DE3926344A1 (en) 1989-08-09 1991-02-28 Henkel Kgaa METHOD FOR THE PRODUCTION OF LIGHT-COLORED OELSAEURESULFONATES
US5075501A (en) 1989-10-02 1991-12-24 Ethyl Corporation Mixed tert-amine oxide dihydrates
US5071594A (en) 1989-10-02 1991-12-10 Ethyl Corporation Free flowing granular laundry detergent comprising tert-amine oxide dihydrate
DE4007755A1 (en) 1990-03-12 1991-09-19 Henkel Kgaa FOAMING SURFACE PREPARATIONS
GB2247832B (en) 1990-09-11 1994-03-30 Haison Yuen A clothes drying rack
KR930702514A (en) 1990-09-13 1993-09-09 안네 제케르 Lipase variant
DE4035935A1 (en) 1990-11-12 1992-05-14 Henkel Kgaa Prodn. of alpha-sulpho fatty acid salt dispersions - with high concn. using surfactant to reduce viscosity
DE4039348A1 (en) 1990-12-10 1992-06-11 Henkel Kgaa CARPET CLEANER
DE4107414A1 (en) 1991-03-08 1992-09-10 Henkel Kgaa LIQUID CLEANING AGENT CONTAINING SULFOLOIC ACIDS
US5254290A (en) 1991-04-25 1993-10-19 Genevieve Blandiaux Hard surface cleaner
DE4117671A1 (en) 1991-05-29 1992-12-03 Henkel Kgaa METHOD FOR OBTAINING MINERALS FROM NON-SULFIDIC ORES BY FLOTATION
US5776872A (en) 1992-03-25 1998-07-07 The Procter & Gamble Company Cleansing compositions technical field
US5883062A (en) 1993-09-14 1999-03-16 The Procter & Gamble Company Manual dishwashing compositions
BR9407834A (en) 1993-10-14 1997-05-13 Procter & Gamble Cleaning compositions containing protease
MX9605097A (en) 1994-04-25 1997-08-30 Procter & Gamble Stable, aqueous laundry detergent composition having improved softening properties.
US5466394A (en) 1994-04-25 1995-11-14 The Procter & Gamble Co. Stable, aqueous laundry detergent composition having improved softening properties
DE19504192A1 (en) 1995-02-09 1996-08-14 Henkel Ecolab Gmbh & Co Ohg Thickening aqueous cleaning agents for hard surfaces
US5576282A (en) 1995-09-11 1996-11-19 The Procter & Gamble Company Color-safe bleach boosters, compositions and laundry methods employing same
MA24137A1 (en) 1996-04-16 1997-12-31 Procter & Gamble MANUFACTURE OF BRANCHED SURFACES.
ATE235826T1 (en) 1996-07-16 2003-04-15 Procter & Gamble USE OF A MIXTURE CONTAINING EMULSIFIERS, COMPLEX IMAGERS AND ESSENTIAL OILS AS A DISINFECTANT
US5929022A (en) 1996-08-01 1999-07-27 The Procter & Gamble Company Detergent compositions containing amine and specially selected perfumes
EP0973855B1 (en) 1997-03-07 2003-08-06 The Procter & Gamble Company Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids
TR200000883T2 (en) 1997-07-21 2000-07-21 The Procter & Gamble Company Improved alkylbenzenesulfonate surfactants
BR9813250B1 (en) 1997-10-10 2008-11-18 process for the preparation of detergent agglomerates.
US6242406B1 (en) 1997-10-10 2001-06-05 The Procter & Gamble Company Mid-chain branched surfactants with cellulose derivatives
US5965508A (en) 1997-10-21 1999-10-12 Stepan Company Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids
US6018063A (en) 1998-11-13 2000-01-25 The United States Of America As Represented By The Secretary Of Agriculture Biodegradable oleic estolide ester base stocks and lubricants
DE19857687A1 (en) 1998-12-15 2000-06-21 Henkel Ecolab Gmbh & Co Ohg Pasty detergent
US6034046A (en) 1999-03-26 2000-03-07 Colgate Palmolive Company All purpose liquid bathroom cleaning compositions
US6903064B1 (en) 1999-05-26 2005-06-07 Procter & Gamble Company Detergent composition comprising polymeric suds volume and suds duration enhancers
US6649580B2 (en) 2000-04-20 2003-11-18 Colgate-Palmolive Company Cleaning compositions
AU2001259725A1 (en) 2000-05-15 2001-11-26 The Procter And Gamble Company Compositions comprising cyclodextrin derivatives
AU2001290913A1 (en) 2000-09-14 2002-03-26 Stepan Company Antimicrobial ternary surfactant blend comprising cationic, anionic, and bridging surfactants, and methods of preparing same
GB0104979D0 (en) 2001-02-28 2001-04-18 Unilever Plc Unit dose cleaning product
US6953849B2 (en) 2001-03-28 2005-10-11 Council Of Scientific And Industrial Research Process for the isolation of glycolipids
US6605579B1 (en) 2001-05-11 2003-08-12 Colgate- Palmolive Company Antibacterial liquid dish cleaning compositions
US20030105352A1 (en) 2001-08-03 2003-06-05 Dado Gregory P. Arylalkylsulfonic acids and methods for producing same
US20050153853A1 (en) * 2002-01-31 2005-07-14 Stepan Company Soap bar compositions comprising alpha sulfonated alkyl ester or sulfonated fatty acid and synthetic surfactant and processes for producing same
WO2003082811A1 (en) * 2002-03-29 2003-10-09 Lg Household & Health Care Ltd. Manufacturing method of monoglyceride sulfonate, toilet soap composition using the same, and manufacturing method of toilet soap composition comprising salt
US6797011B2 (en) 2002-12-05 2004-09-28 Anna Carner Blangiforti Leather therapy treatment
US20040152616A1 (en) 2003-02-03 2004-08-05 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Laundry cleansing and conditioning compositions
US20080139443A1 (en) 2004-04-21 2008-06-12 Stepan Company Acidic Hard Surface Cleaner with Alkoxylated Quaternary Compound
DE102004029475A1 (en) 2004-06-18 2006-01-26 Henkel Kgaa New enzymatic bleaching system
WO2006066059A1 (en) 2004-12-17 2006-06-22 The Procter & Gamble Company Hydrophobically modified polyols for improved hydrophobic soil cleaning
KR101446925B1 (en) 2006-02-24 2014-10-07 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 Polymers containing silicone copolyol macromers and personal care compositions containing same
US20080015135A1 (en) 2006-05-05 2008-01-17 De Buzzaccarini Francesco Compact fluid laundry detergent composition
WO2008137802A2 (en) 2007-05-04 2008-11-13 Ecolab Inc. Compositions including hardness ions and gluconate and methods employing them to reduce corrosion and etch
US7709436B2 (en) 2007-05-09 2010-05-04 The Dial Corporation Low carbon footprint compositions for use in laundry applications
US7879790B2 (en) * 2008-01-22 2011-02-01 Stepan Company Mixed salts of sulfonated estolides and other derivatives of fatty acids, and methods of making them
US7666828B2 (en) 2008-01-22 2010-02-23 Stepan Company Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
US7998920B2 (en) * 2008-01-22 2011-08-16 Stepan Company Sulfonated estolide compositions containing magnesium sulfate and processes employing them
US8119588B2 (en) * 2009-01-21 2012-02-21 Stepan Company Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US7884064B2 (en) * 2009-01-21 2011-02-08 Stepan Company Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids
US8124577B2 (en) * 2009-01-21 2012-02-28 Stepan Company Personal care compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8058223B2 (en) * 2009-01-21 2011-11-15 Stepan Company Automatic or machine dishwashing compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1380390A (en) * 1970-12-16 1975-01-15 Unilever Ltd Detergent compositions
WO2000018363A1 (en) * 1998-09-25 2000-04-06 The United States Of America, As Represented By The Secretary Of Agriculture Improved shampoos and conditioners containing estolides
WO2001053247A1 (en) * 2000-01-24 2001-07-26 The United States Of America, As Represented By The Secretary Of Agriculture Biodegradable oleic estolide ester having saturated fatty acid end group useful as lubricant base stock

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A.J. STIRTON, ET AL.: "Surface-active properties of salts fo alpha-sulphonated acids and esters", JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, vol. 13, no. 1, January 1954 (1954-01-01), SPRINGER, BERLIN, DE, pages 13 - 16, XP002537683, ISSN: 0003-021X, DOI: 10.1007/BF02544763 *

Also Published As

Publication number Publication date
EP2258679A2 (en) 2010-12-08
EP2247574A2 (en) 2010-11-10
US8338358B2 (en) 2012-12-25
AU2009206542A1 (en) 2009-07-30
EP2270122A2 (en) 2011-01-05
CN101981002A (en) 2011-02-23
EP2270122A3 (en) 2011-01-26
US7666828B2 (en) 2010-02-23
US8129328B2 (en) 2012-03-06
CA2712955A1 (en) 2009-07-30
EP2258817A2 (en) 2010-12-08
EP2258679A3 (en) 2011-01-26
CA2712955C (en) 2014-04-22
US20120129955A1 (en) 2012-05-24
EP2258679B1 (en) 2015-01-07
WO2009094336A4 (en) 2009-12-03
US20090188055A1 (en) 2009-07-30
MX2010007991A (en) 2010-12-21
EP2247574B1 (en) 2015-01-07
BRPI0907444A2 (en) 2015-07-14
US20100016198A1 (en) 2010-01-21
EP2258817B1 (en) 2015-01-07
WO2009094336A2 (en) 2009-07-30
CN101981002B (en) 2015-06-24
EP2258817A3 (en) 2011-01-26
AU2009206542B2 (en) 2014-01-16
ZA201005575B (en) 2011-04-28
EP2270122B1 (en) 2015-01-07

Similar Documents

Publication Publication Date Title
WO2009094336A3 (en) Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
WO2011025615A3 (en) Method of laundering fabrics at low temperature
ZA200705665B (en) Low-foaming liquid laundry detergent
MX2012003191A (en) Detergent composition comprising surfactant boosting polymers.
MY158366A (en) Compositions comprising sulfonated estolides and alkyl ester sulfonates,methods of making them,and compositions and processes employing them
MX337039B (en) Method for hand washing dishes having long lasting suds.
WO2011156297A3 (en) Compacted liquid laundry detergent composition comprising lipase of bacterial origin
PL2121887T3 (en) Non-rinse fabric softener
CN102250697A (en) Liquid laundry detergent
MX2011007716A (en) Automatic or machine dishwashing compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof.
CN103897871A (en) Clothing washing agent
CN103146504A (en) Environment-friendly energy-saving concentrated washing powder and preparation method thereof
MY163259A (en) A detergent composition having shading dyes and lipase
DE602007010773D1 (en) It methylestersulfonat
CN102703254A (en) Fading lotion
CN103013721A (en) High efficiency phosphorus-free degerming laundry detergent
CN104830561A (en) Super-concentrated low-foam high-efficient laundry detergent
CN102690728A (en) Liquid detergent for softening fabric
CN102911074B (en) Method for producing alkanolamide by taking crude oil as raw material
CN106883946A (en) Except mite liquid detergent
WO2009112974A3 (en) Low sudsing hand washing liquid laundry detergent
CN101597545A (en) Fabric stubborn stain detergent
CN104232339A (en) Low foam liquid detergent
CN103897842A (en) Household textile washing agent
CN105018246B (en) A kind of mold-proof oxidation-resistant liquid detergent

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200980110511.6

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09703929

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2712955

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: MX/A/2010/007991

Country of ref document: MX

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2009206542

Country of ref document: AU

ENP Entry into the national phase

Ref document number: 2009206542

Country of ref document: AU

Date of ref document: 20090120

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2009703929

Country of ref document: EP

ENP Entry into the national phase

Ref document number: PI0907444

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20100722