WO2009148733A3 - Crosslinked organic-inorganic hybrid membranes and their use in gas separation - Google Patents

Crosslinked organic-inorganic hybrid membranes and their use in gas separation Download PDF

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Publication number
WO2009148733A3
WO2009148733A3 PCT/US2009/042458 US2009042458W WO2009148733A3 WO 2009148733 A3 WO2009148733 A3 WO 2009148733A3 US 2009042458 W US2009042458 W US 2009042458W WO 2009148733 A3 WO2009148733 A3 WO 2009148733A3
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WO
WIPO (PCT)
Prior art keywords
membranes
peo
organotrialkoxysilane
crosslinked
inorganic hybrid
Prior art date
Application number
PCT/US2009/042458
Other languages
French (fr)
Other versions
WO2009148733A2 (en
Inventor
Chunqing Liu
Stephen T. Wilson
Santi Kulprathipanja
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc filed Critical Uop Llc
Priority to BRPI0913103A priority Critical patent/BRPI0913103A2/en
Priority to AU2009255458A priority patent/AU2009255458B2/en
Publication of WO2009148733A2 publication Critical patent/WO2009148733A2/en
Publication of WO2009148733A3 publication Critical patent/WO2009148733A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C08L1/20—Esters of both organic acids and inorganic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0079—Manufacture of membranes comprising organic and inorganic components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0079—Manufacture of membranes comprising organic and inorganic components
    • B01D67/00793—Dispersing a component, e.g. as particles or powder, in another component
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/08—Polysaccharides
    • B01D71/12—Cellulose derivatives
    • B01D71/14—Esters of organic acids
    • B01D71/16—Cellulose acetate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/521—Aliphatic polyethers
    • B01D71/5211—Polyethylene glycol or polyethyleneoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/70—Polymers having silicon in the main chain, with or without sulfur, nitrogen, oxygen or carbon only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/70—Polymers having silicon in the main chain, with or without sulfur, nitrogen, oxygen or carbon only
    • B01D71/702—Polysilsesquioxanes or combination of silica with bridging organosilane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B7/00—Preparation of cellulose esters of both organic and inorganic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33303—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group
    • C08G65/33306—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33348—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group
    • C08G65/33351—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
    • C08G2650/58—Ethylene oxide or propylene oxide copolymers, e.g. pluronics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

The present invention is for crosslinked membranes and in particular for crosslinked poly(ethylene oxide)-cellulose acetate-silsesquioxane (PEO-CA-Si) organic-inorganic hybrid membranes and their use in gas separation. These crosslinked PEO-CA-Si membranes were prepared by in-situ sol-gel co-condensation of crosslinkable PEO-organotrialkoxysilane and CA-organotrialkoxysilane polymers in the presence of acetic acid catalyst during the formation of membranes. The crosslinkable PEO- and CA-organotrialkoxysilane polymers were synthesized via the reaction between the hydroxyl groups on PEO (or on CA) and the isocyanate on organotrialkoxysilane to form urethane linkages under mild conditions. The crosslinked PEO-CA-Si membranes exhibited both increased selectivity of CO2/N2 and CO2 permeability as compared to a CA membrane, suggesting that these membranes are very promising for gas separations such as CO2/N2 separation.
PCT/US2009/042458 2008-06-02 2009-05-01 Crosslinked organic-inorganic hybrid membranes and their use in gas separation WO2009148733A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
BRPI0913103A BRPI0913103A2 (en) 2008-06-02 2009-05-01 cross-linked organic-inorganic hybrid polymer, and production process thereof
AU2009255458A AU2009255458B2 (en) 2008-06-02 2009-05-01 Crosslinked organic-inorganic hybrid membranes and their use in gas separation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/131,392 2008-06-02
US12/131,392 US7790803B2 (en) 2008-06-02 2008-06-02 Crosslinked organic-inorganic hybrid membranes and their use in gas separation

Publications (2)

Publication Number Publication Date
WO2009148733A2 WO2009148733A2 (en) 2009-12-10
WO2009148733A3 true WO2009148733A3 (en) 2010-02-18

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PCT/US2009/042458 WO2009148733A2 (en) 2008-06-02 2009-05-01 Crosslinked organic-inorganic hybrid membranes and their use in gas separation

Country Status (5)

Country Link
US (2) US7790803B2 (en)
AU (1) AU2009255458B2 (en)
BR (1) BRPI0913103A2 (en)
MY (1) MY152072A (en)
WO (1) WO2009148733A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100326273A1 (en) * 2006-09-29 2010-12-30 Uop Llc Plasticization resistant membranes
US8177891B2 (en) * 2007-05-24 2012-05-15 Fujifilm Manufacturing Europe B.V. Membrane comprising oxyethylene groups
JP5175342B2 (en) * 2007-05-24 2013-04-03 フジフィルム・マニュファクチュアリング・ヨーロッパ・ベスローテン・フエンノートシャップ Membrane, its manufacturing method and use
CN101754798B (en) * 2007-05-24 2013-01-02 富士胶片制造欧洲有限公司 Membrane comprising oxyethylene groups
SG186909A1 (en) * 2010-07-09 2013-02-28 Univ Singapore Ultra-permeable membranes for gas separation
CN102029115B (en) * 2010-10-27 2012-12-19 合肥学院 Preparation method of ethanol pervaporation hybrid film used for removing methyl alcohol in wastewater
CN102029116A (en) * 2010-10-27 2011-04-27 合肥学院 Preparation method of polyvinyl alcohol pervaporation hybrid membrane
EP2654926A2 (en) * 2010-12-20 2013-10-30 Dow Global Technologies LLC Crosslinked silane-modified molecularly self-assembling material
US8765824B2 (en) 2011-04-19 2014-07-01 Exxonmobil Research And Engineering Company Ethanol stable polyether epoxy based membrane for ethanol and aromatics separation
KR101936924B1 (en) 2012-12-06 2019-01-09 삼성전자주식회사 Separation membrane, and water treatment device using said separation membrane
KR101695793B1 (en) 2014-10-21 2017-01-23 한국과학기술연구원 Gas separation membrane with ladder-like polysilsesquioxane and method for fabricating the same
WO2017030811A1 (en) * 2015-08-19 2017-02-23 Drexel University Hybrid electrolytes with controlled network structures for lithium metal batteries
US9901880B2 (en) * 2015-10-29 2018-02-27 Korea Institute Of Science And Technology Carbon molecular sieve membranes based on fluorine-containing polymer/polysilsesquioxane blending precursors and method for fabricating the same
EP3618944A1 (en) 2017-05-04 2020-03-11 Saudi Arabian Oil Company Crosslinked polymer membranes and methods of their production
CN109575153B (en) * 2018-11-22 2021-04-02 福建工程学院 Polysaccharide derivative polymer and preparation method thereof
CN109847592A (en) * 2019-01-04 2019-06-07 广州汉至蓝能源与环境技术有限公司 A kind of organic-inorganic hybrid films preparation method
CN114432910B (en) * 2022-01-29 2023-04-14 中国科学院过程工程研究所 Separation membrane and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040104615A (en) * 2002-04-25 2004-12-10 알테코 메디칼 아베 Improved separation
US20050113547A1 (en) * 2003-09-11 2005-05-26 Siwen Li Phosphonic-acid grafted hybrid inorganic-organic proton electrolyte membranes (PEMs)
US20070072978A1 (en) * 2005-09-27 2007-03-29 Boston Scientific Scimed, Inc. Organic-inorganic hybrid particle material and polymer compositions containing same
US20070100078A1 (en) * 2003-05-28 2007-05-03 Siwen Li Hybrid inorganic-organic polymer electrolyte membranes (pems) based on ankyloxysilane grafted thermoplastic polymers

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3567632A (en) 1968-09-04 1971-03-02 Du Pont Permselective,aromatic,nitrogen-containing polymeric membranes
US4230463A (en) 1977-09-13 1980-10-28 Monsanto Company Multicomponent membranes for gas separations
US5127925A (en) 1982-12-13 1992-07-07 Allied-Signal Inc. Separation of gases by means of mixed matrix membranes
US4728345A (en) 1983-12-28 1988-03-01 Monsanto Company Multicomponent gas separation membranes having polyphosphazene coatings
US4551156A (en) * 1984-01-16 1985-11-05 Standard Oil Company Permselective membrane compositions for gas separations and process for the separation of gases therewith
US4740219A (en) 1985-02-04 1988-04-26 Allied-Signal Inc. Separation of fluids by means of mixed matrix membranes
FR2625690B1 (en) 1988-01-11 1993-04-23 Inst Francais Du Petrole PROCESS FOR SEPARATING THE CONSTITUENTS OF A GAS PHASE MIXTURE USING A COMPOSITE MEMBRANE
DE3824359A1 (en) 1988-04-07 1989-10-19 Bayer Ag COMPOSITE MEMBRANES, METHOD FOR THEIR PRODUCTION AND THEIR USE
US5104532A (en) 1989-09-15 1992-04-14 Exxon Research And Engineering Company Flat stack permeator
US5354547A (en) 1989-11-14 1994-10-11 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
US5507860A (en) 1989-11-14 1996-04-16 Air Products And Chemicals, Inc. Composite porous carbonaceous membranes
US5507856A (en) 1989-11-14 1996-04-16 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
US5288304A (en) 1993-03-30 1994-02-22 The University Of Texas System Composite carbon fluid separation membranes
FR2724327B1 (en) 1994-09-12 1996-10-25 Air Liquide METHOD FOR CASCADE MEMBRANE SEPARATION OF MEMBRANES OF DIFFERENT SELECTIVITY
US5650479A (en) * 1995-06-06 1997-07-22 The Cynara Co. Interfacially polymerized polyester films
DE19853971B4 (en) 1998-11-23 2011-06-16 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Inorganic / organic polysiloxane hybrid polymers and their use
KR20030015287A (en) 2000-06-22 2003-02-20 이 아이 듀폰 디 네모아 앤드 캄파니 Mixed matrix nanoporous carbon membranes
US6605140B2 (en) 2000-08-09 2003-08-12 National Research Council Of Canada Composite gas separation membranes
EP1188477A1 (en) 2000-09-13 2002-03-20 Thomas Maschmeyer Method for absorbing compounds using zeolites
US6503295B1 (en) 2000-09-20 2003-01-07 Chevron U.S.A. Inc. Gas separations using mixed matrix membranes
US6500233B1 (en) 2000-10-26 2002-12-31 Chevron U.S.A. Inc. Purification of p-xylene using composite mixed matrix membranes
US6626980B2 (en) 2001-09-21 2003-09-30 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Mixed matrix membranes incorporating chabazite type molecular sieves
US6508860B1 (en) 2001-09-21 2003-01-21 L'air Liquide - Societe Anonyme A'directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Gas separation membrane with organosilicon-treated molecular sieve
US6726744B2 (en) 2001-11-05 2004-04-27 Uop Llc Mixed matrix membrane for separation of gases
US20030126990A1 (en) 2001-12-20 2003-07-10 Koros William J. Crosslinked and crosslinkable hollow fiber membrane and method of making same
US20030131731A1 (en) 2001-12-20 2003-07-17 Koros William J. Crosslinked and crosslinkable hollow fiber mixed matrix membrane and method of making same
US20070022877A1 (en) 2002-04-10 2007-02-01 Eva Marand Ordered mesopore silica mixed matrix membranes, and production methods for making ordered mesopore silica mixed matric membranes
US7109140B2 (en) 2002-04-10 2006-09-19 Virginia Tech Intellectual Properties, Inc. Mixed matrix membranes
US6863983B2 (en) 2002-06-25 2005-03-08 University Of Massachusetts Layered silicate material and applications of layered materials with porous layers
US7025804B2 (en) 2002-12-02 2006-04-11 L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for separating hydrocarbon-containing gas mixtures using hydrocarbon-resistant membranes
US6946015B2 (en) 2003-06-26 2005-09-20 The Regents Of The University Of California Cross-linked polybenzimidazole membrane for gas separation
US7268094B2 (en) 2003-08-18 2007-09-11 Chevron U.S.A. Inc. Mixed matrix membrane with super water washed silica containing molecular sieves and methods for making and using the same
US7138006B2 (en) 2003-12-24 2006-11-21 Chevron U.S.A. Inc. Mixed matrix membranes with low silica-to-alumina ratio molecular sieves and methods for making and using the membranes
US7166146B2 (en) 2003-12-24 2007-01-23 Chevron U.S.A. Inc. Mixed matrix membranes with small pore molecular sieves and methods for making and using the membranes
US20050230305A1 (en) 2004-03-26 2005-10-20 Kulkarni Sudhir S Novel method for forming a mixed matrix composite membrane using washed molecular sieve particles
US20050268782A1 (en) 2004-03-26 2005-12-08 Kulkarni Sudhir S Novel polyimide based mixed matrix membranes
US6997971B1 (en) 2004-07-28 2006-02-14 The Regents Of The University Of California Cross-linked polybenzimidazole membrane for gas separation
US7306647B2 (en) 2004-11-19 2007-12-11 Chevron U.S.A. Inc. Mixed matrix membrane with mesoporous particles and methods for making and using the same
US7476636B2 (en) 2004-12-03 2009-01-13 L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploration Des Procedes Georges Claude Method of making mixed matrix membranes using electrostatically stabilized suspensions
ATE513071T1 (en) 2005-07-08 2011-07-15 Univ Bath INORGANIC POROUS HOLLOW FIBERS

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040104615A (en) * 2002-04-25 2004-12-10 알테코 메디칼 아베 Improved separation
US20070100078A1 (en) * 2003-05-28 2007-05-03 Siwen Li Hybrid inorganic-organic polymer electrolyte membranes (pems) based on ankyloxysilane grafted thermoplastic polymers
US20050113547A1 (en) * 2003-09-11 2005-05-26 Siwen Li Phosphonic-acid grafted hybrid inorganic-organic proton electrolyte membranes (PEMs)
US20070072978A1 (en) * 2005-09-27 2007-03-29 Boston Scientific Scimed, Inc. Organic-inorganic hybrid particle material and polymer compositions containing same

Also Published As

Publication number Publication date
US7790803B2 (en) 2010-09-07
BRPI0913103A2 (en) 2016-01-05
US20100288122A1 (en) 2010-11-18
WO2009148733A2 (en) 2009-12-10
MY152072A (en) 2014-08-15
AU2009255458A1 (en) 2009-12-10
US20090299015A1 (en) 2009-12-03
US8030399B2 (en) 2011-10-04
AU2009255458B2 (en) 2013-09-12

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