WO2010002575A2 - Exposure indicating device - Google Patents
Exposure indicating device Download PDFInfo
- Publication number
- WO2010002575A2 WO2010002575A2 PCT/US2009/047360 US2009047360W WO2010002575A2 WO 2010002575 A2 WO2010002575 A2 WO 2010002575A2 US 2009047360 W US2009047360 W US 2009047360W WO 2010002575 A2 WO2010002575 A2 WO 2010002575A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- exposure
- indicating device
- nano
- index
- refraction
- Prior art date
Links
Classifications
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B18/00—Breathing masks or helmets, e.g. affording protection against chemical agents or for use at high altitudes or incorporating a pump or compressor for reducing the inhalation effort
- A62B18/08—Component parts for gas-masks or gas-helmets, e.g. windows, straps, speech transmitters, signal-devices
- A62B18/088—Devices for indicating filter saturation
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B18/00—Breathing masks or helmets, e.g. affording protection against chemical agents or for use at high altitudes or incorporating a pump or compressor for reducing the inhalation effort
- A62B18/08—Component parts for gas-masks or gas-helmets, e.g. windows, straps, speech transmitters, signal-devices
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B23/00—Filters for breathing-protection purposes
- A62B23/02—Filters for breathing-protection purposes for respirators
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B7/00—Respiratory apparatus
- A62B7/10—Respiratory apparatus with filter elements
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/41—Refractivity; Phase-affecting properties, e.g. optical path length
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/47—Scattering, i.e. diffuse reflection
- G01N21/4788—Diffraction
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
- G01N21/783—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour for analysing gases
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
Definitions
- the present invention is directed to an exposure indicating device.
- respirator systems exist to protect users from exposure to dangerous chemicals. Examples of these systems include negative pressure or powered air respirators which use a cartridge containing a sorbent material for removing harmful substances from the ambient air, and supplied air respirators.
- a number of protocols have been developed to evaluate the air being delivered to the user. These protocols may also be used to determine whether the sorbent material is near depletion. The protocols include sensory warning, administrative control, passive indicators, and active indicators.
- an end-of-life sensor (“EOLS”) or end-of-service-life indicator (“ESLI”) can warn that a filter element in such a device may be approaching saturation or may be ineffective against a particular material.
- EOLS end-of-life sensor
- ESLI end-of-service-life indicator
- an exposure indicating device is disposed in a respirator system.
- the exposure indicating device comprises a diffractive optical element.
- the exposure indicating device comprises a material having an index of refraction that changes as a function of exposure to a chemical vapor.
- the exposure indicating device provides an optical signal that changes in optical property as a function of exposure to the vapor.
- the diffractive optical element comprises a diffraction grating.
- the material comprises a nano-porous material having an index of refraction that changes as a function of exposure to the chemical vapor.
- the nano-porous material comprises an amorphous random covalent network that includes silicon, carbon, hydrogen and oxygen with a mean pore size in a range from about 0.5 to about 10 nanometers.
- the diffractive optical element is formed from the nano-porous material.
- the diffractive optical element is substantially embedded in the nano-porous material.
- the diffractive optical element comprises a diffraction grating having an index of refraction that is substantially equal to an index of refraction of the surrounding nano-porous material prior to exposure to the chemical vapor.
- the diffraction grating has an index of refraction that is different from an index of refraction of the surrounding nano-porous material prior to after sufficient exposure to the chemical vapor.
- the device is a passive device. In another aspect, the device is an active device.
- the diffractive optical element comprises a patterned microporous amorphous carbon material.
- an exposure indicating device disposed in a respirator system includes a face mask having mounted thereon at least one replaceable air purifying respirator cartridge comprising a sorbent material.
- the exposure indicating device includes a diffractive optical element formed on a substrate, the substrate mounted to an inner sidewall of the at least one respirator cartridge.
- the mounting location on the sidewall of the at least one respirator cartridge is substantially transparent.
- the exposure indicating device comprises a nano-porous material having an index of refraction that changes as a function of exposure to a chemical vapor, where the exposure indicating device provides an optical signal that changes in optical property as a function of exposure to the chemical vapor.
- the diffractive optical element is formed from the nano-porous material having an index of refraction that changes as a function of exposure to the chemical vapor. In another aspect, the diffractive optical element is substantially embedded in the nano-porous material, where the nano-porous material is substantially surrounded by the sorbent material.
- the diffractive optical element comprises a diffraction grating having an index of refraction that is substantially equal to an index of refraction of the surrounding nano-porous material prior to exposure to the chemical vapor and that is different from an index of refraction of the surrounding nano-porous material after sufficient exposure to the vapor.
- the exposure indicating device is a passive device.
- FIG. 1 is a schematic view of a respirator having an exposure indicating device according to an aspect of the invention.
- Fig. 2 is a section view of a respirator cartridge having an exposure indicating device according to an aspect of the invention.
- Fig. 3 A is a schematic view of an exposure indicating according to an aspect of the invention.
- Fig. 3B is a schematic view of an exposure indicating device according to another aspect of the invention.
- Fig. 4A is a schematic view of an exemplary grating.
- Figs. 4B and 4C are schematic views of exposure indicating device before and after exposure according to an aspect of the invention.
- Figs. 5A-5C are schematic views of a process for making a grating for an exposure indicating device according to another aspect of the invention.
- Fig. 6 is a graph showing the optical response of an example diffraction grating to changing exposure.
- the present invention is directed to an exposure indicating device.
- the exposure indicating device is utilized with a personal respirator to indicate to the wearer that the purifying cartridges used with the respirator need to be replaced.
- the exposure indicating device is an optically-based, passive device that changes its index of refraction as a function of exposure to a deleterious vapor or other airborne substance.
- the exposure indicating device utilizes a diffractive optical element, such as a diffraction grating, to provide a visual indication that the purifying cartridge is near depletion.
- the diffractive element can be a nano-porous material. In another aspect, the diffractive element can be embedded in a nano-porous material.
- an exemplary personal respirator 1 includes a face mask 2 on which is mounted a pair of replaceable air purifying respirator cartridges 3.
- the cartridges 3 each serve as enclosures for a sorbent material (e.g., activated carbon and/or others described below) not shown in Fig. 1.
- the front cover 4 of each cartridge 3 includes a plurality of openings 5 that serve as gas inlets, permitting ambient air from the external environment to flow into cartridge 3, through the sorbent material and then through a passage (not labeled in Fig. 1) that serves as a gas outlet from cartridge 3 and an inlet to face mask 2.
- the sidewall 6 in each cartridge 3 is transparent or at least includes a transparent portion 7 through which a wearer of face mask 2 can see the exposure indicating device 8 (also referred to herein as an indicator 8 or an indicator 8').
- the exposure indicating device 8 also referred to herein as an indicator 8 or an indicator 8'.
- at least a substantial portion of sidewall 6 is transparent.
- the exposure indicating device 8 can be located near an upper surface of the sidewall 6 for more straightforward viewing by the wearer.
- exposure indicating device 8 is optically responsive, undergoing a visibly discernible colorimetric change when the sorbent material becomes equilibrated with a particular vapor or target species (referred to herein simply as the vapor) at the conditions of exposure, thus aiding the wearer in recognizing that it is time to replace the cartridge or cartridges 3.
- Exhaled air exits respirator 1 through exhalation valve 9.
- the indicator may be used in a variety of respiratory protective devices.
- the indicator may also be deployed in a single cartridge respirator or a powered air-purifying respirator.
- Fig. 2 is a side view, partially in section, of respirator cartridge 3. If desired, the openings 5 could be sealed until use using for example a removable cover (not shown in Fig. 1 and Fig. 2) that would be removed before use.
- a bed of sorbent material 21 disposed within the cartridge absorbs or adsorbs vapors of interest passing from the openings 5 to outlet 23.
- a one-way inhalation valve can also be utilized.
- the one-way inhalation valve can be mounted on the main face piece of the respirator, or optionally, a one-way inhalation valve 25 can be mounted on a post 27 to prevent exhaled air from entering cartridge 3.
- a threaded or preferably bayoneted connector or connectors 29 can be used to removably couple cartridge 3 to mask 2.
- Sidewall 6 is either entirely transparent or it at least includes a substantially transparent portion 7. The transparent sidewall permits ambient light to pass into exposure indicating device 8.
- the cartridges 3 would be removed and replaced with fresh cartridges 3 when a visibly discernible change in the appearance of exposure indicating device 8 indicates that the sorbent material 21 underneath exposure indicating device 8 has become equilibrated with the vapor at the conditions of exposure.
- the exposure indicating device 8 can provide a bright rainbow-type, multicolor appearance upon vapor equilibrium.
- such a change in appearance may include a change in color such as from green to red or other color.
- an appearance change e.g., a color change
- the advancing appearance change would indicate the remaining service life for cartridge 3 (like a bar gauge or fuel gauge) rather than just the end of service life, especially where appropriate care is taken to design cartridge 3 so that its remaining lifetime is linearly proportional to the spatial vapor front penetration past exposure indicating device 8.
- exposure indicating device 8 could be placed toward the end of the flow path only so as to give warning only at the desired remaining service life percentage.
- Exposure indicating device 8 may if desired include a pattern or reference color to assist in visual discernment of changes in the appearance of exposure indicating device 8.
- appearance changes in exposure indicating device 8 could be visibly monitored under ambient lighting, thereby providing EOLS or ESLI as a passive device.
- indicator 8 could be illuminated using an external light source such as a light emitting diode (LED) and evaluated using a photodetector mounted on the periphery of cartridge 3 to provide an optoelectronic signal.
- light could be delivered to the exposure indicating device 8 via one or more optical fibers. Whether viewed under ambient light or by using an external light source and photodetector, the breadth of chemical detection could if desired be increased in a variety of ways. For example, a small array of indicators traversing the vapor flow path could be employed. Figs.
- indicator 8 includes a diffractive element.
- the diffractive element comprises a diffraction grating 52 disposed on a substrate 53. The formation of the grating 52 on substrate 53 is described in further detail below. Alternatively, the grating 52 can be etched into substrate 53.
- the diffractive element here diffraction grating 52, is embedded in a nano-porous material 54, which substantially surrounds the diffraction grating (i.e., not on all sides).
- the embedding may be accomplished by a conventional spray coat process, dip coat process, or similar method, where the nano-porous material could embed the solid grating and/or fill the "grooves" formed on the diffractive element.
- the substrate 53 is disposed on an inner surface of sidewall 6 and may be adhered to a surface of sidewall 6 by using a conventional adhesive, such as an epoxy .
- the sorbent material 21 envelops the embedded indicator 8 and substantially surrounds it.
- the exposure indicating device experiences a change in refractive index as a function of exposure.
- the grating 52 has a constant index of refraction (n g ) while the nano-porous material 54 has a variable index of refraction, where the index of refraction changes as a function of the material's exposure to a particular vapor.
- the appearance of the grating depends on the exposure level of the nano-porous material 54 to the vapor.
- the diffractive element comprises a diffraction grating.
- diffraction grating 52 can be formed having a conventional structure of alternating peaks and valleys.
- the grating 52 may be formed as a blazed grating, a chirped grating, or other diffractive element, as would be apparent to one of ordinary skill in the art given the present description.
- the material used to form diffraction grating 52 has an initial index of refraction (n g ).
- the diffraction grating 52 is substantially surrounded by the nano-porous material 54.
- light 80 passing into the nano-porous material 54 is unaffected by the presence of the embedded diffraction grating 52.
- the nano-porous material 54 As the nano-porous material 54 is exposed to the vapor, its index of refraction changes from (n pi ) to (n pe ), such that n pe ⁇ n g .
- a portion of the light 80 passing into the exposed nano-porous material 54 is diffracted by the embedded diffraction grating 52 (diffracted light 82) that is visible to a user as a diffraction pattern (e.g., a rainbow-type pattern). This diffraction pattern indicates to the user that the sorbent cartridge should be replaced.
- the diffractive element can be replaced with a refractive element such as a lens.
- the lens and the nano-porous material that surrounds it can have the same initial index of refraction.
- the nano-porous material As the nano-porous material is exposed to the vapor, its index of refraction changes.
- the lens can bring into view a symbol or other structure that was not in view prior to the index change of the nano-porous material.
- the nano-porous material 54 may comprise a homogeneous or heterogeneous material, and may, for example, be made from a mixture of inorganic components, a mixture of organic components, or a mixture of inorganic and organic components.
- the nano-porous material desirably has a range of pore sizes or a surface area selected to provide vapor sorption characteristics like those of the sorbent media. Suitable porosity can be obtained by using porous materials such as foams made from high internal phase emulsions, such as those described in U.S. Patent No. 6,573,305 Bl (Thunhorst et al.).
- Porosity may also be obtained via carbon dioxide foaming to create a microporous material (see “Macromolecules", 2001, vol. 34, pp. 8792-8801), or by nanophase separation of polymer blends (see “Science”, 1999, vol. 283, p. 520).
- the pore diameters preferably are smaller than the peak wavelength of the desired indicator coloration.
- Nano-sized pores are preferred, e.g., with average pore sizes of about 0.5 to about 20 nm, 0.5 to about 10 nm, or 0.5 to about 5 nm.
- Representative inorganic nano-porous materials include porous silica, metal oxides, metal nitrides, metal oxynitrides and other inorganic materials that experience a change in index of refraction through exposure to a particular vapor.
- the inorganic nano-porous materials may be silicon oxides, silicon nitrides, silicon oxynitrides, aluminum oxides, titanium oxides, titanium nitride, titanium oxynitride, tin oxides, zirconium oxides, zeolites or combinations thereof.
- Porous silica is an exemplary nano-porous material.
- Porous silicas may be prepared, for example, using a sol-gel processing route and made with or without an organic template.
- organic templates include surfactants, e.g., anionic or nonionic surfactants such as alkyltrimethylammonium salts, poly(ethyleneoxide-co-propylene oxide) block copolymers and other surfactants or polymers that will be apparent to persons having ordinary skill in the art.
- the sol-gel mixture may be converted to a silicate and the organic template may be removed to leave a network o f micropores within the silica .
- porous silica materials are described in Ogawa et al., Chem. Commun. Pp. 1149-1150 (1996), in Kresge et al., Nature, Vol. 359, pp. 710-712 (1992), in Jia et al., Chemistry Letters, Vol. 33(2), pp. 202-203 (2004) and in U.S. Patent No. 5,858,457 (Brinker et al.).
- a variety of organic molecules may also be employed as organic templates.
- sugars such as glucose and mannose may be used as organic templates to generate porous silicates, see Wei et al, Adv. Mater.199%, Vol. 10, p. 313 (1998).
- Organo-substituted siloxanes or organo- ⁇ -siloxanes may be included in the sol-gel composition to render the micropores more hydrophobic and limit sorption of water vapor.
- Plasma chemical vapor deposition may also be employed to generate porous inorganic materials. Examples of such materials are described in U.S. Patent No. 6,312,793 (Grill et al.) and U.S. Publication No. 20070141580.
- U.S. Publication No. 20070141580 describes an amorphous random covalent network that includes silicon, carbon, hydrogen and oxygen with a mean pore size in a range from 0.5 to 10 nanometers.
- Another example material comprises a silicon/carbon/oxygen plasma deposited film (SiCO) described in U.S. Patent Application Serial No. 11/618,010.
- Representative organic nano-porous materials include polymers, copolymers (including block copolymers) and mixtures thereof prepared or preparable from classes of monomers including hydrophobic acrylates and methacrylates, difunctional monomers, vinyl monomers, hydrocarbon monomers (olefins), silane monomers, fluorinated monomers, hydroxylated monomers, acrylamides, anhydrides, aldehyde-functionalized monomers, amine- or amine salt-functionalized monomers, acid-functionalized monomers, epoxide-functionalized monomers and mixtures or combinations thereof.
- U.S. Patent Application Publication No. US 2004/0184948 Al contains an extensive list of such monomers and reference is made thereto for further details.
- PIMs intrinsic microporosity
- Suitable PIMs include, but are not limited to, polymers disclosed in "Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic microporous materials," Budd et al., Chem. Commun., 2004, pp. 230-231. Additional PIMs are disclosed in Budd et al., J. Mater. Chem., 2005, 15, pp. 1977-1986, in McKeown et al., Chem. Eur. J. 2005, 11, No. 9, 2610- 2620 and in Published PCT application No. WO 2005/012397 A2 (McKeown et al.).
- One or more polymers within an organic layer may be at least partially crosslinked.
- Crosslinking may be desirable in some embodiments because it can increase mechanical stability and sensitivity to certain analytes.
- Crosslinking can be achieved by incorporating one or more multifunctional monomers into the layer, by subjecting the layer to, e.g., electron beam or gamma ray treatment, by adding or forming coordination compounds or ionic compounds in the layer, or by forming hydrogen bonds in the layer.
- crosslinking is carried out in the presence of a porogen which may be subsequently extracted from the crosslinked system to yield a porous material.
- Suitable porogens include, but are not limited to, inert organic molecules, such as normal alkanes (e.g., decane) or aromatics (e.g., benzene or toluene).
- Other crosslinked polymers include the above-mentioned highly crosslinked styrenic polymers.
- the nano-porous material may be treated to modify its surface properties or adsorption characteristics.
- a variety of such treatments may be employed, e.g., by exposing the micropores of an inorganic nano-porous material to a suitable organosilane compound.
- Fig. 3B shows a schematic view of an alternative exemplary indicator 8'.
- indicator 8' includes a diffractive element, such as diffraction grating 52', disposed on a substrate 53. The formation of the grating 52' is described in further detail below. Alternatively, the grating 52' can be etched into substrate 53.
- the diffractive element here diffraction grating 52', comprises a nano-porous material whose refractive index changes as a function of exposure to a vapor, such that its index of refraction changes from an initial value (n gl ) to an exposed value (n ge ), such that n ge ⁇ n gl .
- the substrate 53 is disposed on an inner surface of sidewall 6 and may be adhered to a surface of sidewall 6 by using a conventional adhesive, such as an epoxy.
- the sorbent material 21 envelops the embedded indicator 8.
- the diffractive element can be a diffraction grating 52 formed on a silica or otherwise transparent substrate.
- the index of refraction of the diffraction grating 52 remains constant while the index of refraction of the surrounding nano-porous material changes as a function of exposure.
- diffraction grating 52' comprises a nano-porous material whose index of refraction changes as a function of exposure.
- the diffraction grating 52' may be manufactured as follows.
- the diffraction grating 52 is formed as a thin film stack of diamond-like carbon (DLC) and diamond- like glass (DLG). The deposition of DLC and DLG materials is described in U.S. Patent Application Serial No. 11/618,010.
- Fig. 5 A shows a schematic view of an in-process grating 101a that is used to form final grating 52'.
- the initial stack comprises a substrate 102, a DLC layer 104 formed on the substrate, a DLG layer 106 formed on the DLC layer, and a photoresist layer 108 formed on the DLG layer.
- substrate 102 is a silica material. Colored glasses or other transparent substrate materials can also be utilized. Other gratings can formed on silicon based substrates, which are best utilized in an active system, incorporating a separate light source and/or optical fibers, such as is described above.
- Deposition can be performed in a batch reactor, such as is available from Plasmatherm (e.g., model no. 3032).
- the substrate 102 can be primed before deposition of the DLC and DLG, e.g., using an oxygen plasma and a tetramethylsilane plasma.
- the thickness of the DLC 104 can be formed from about 500 nm to about 1000 nm (preferably about 800 nm) and the thickness of the DLG 106 can be formed from about 20 nm to about 100 nm (preferably about 50 nm).
- a conventional photoresist material such as a positive photoresist material, having a thickness of about 500 nm, can be utilized (e.g., MICROPOSIT S 1805, available from Rohm and Hass Electronic materials, Marlborough, MA).
- the photoresist 108 can have a standard alternating pattern.
- the photoresist 108 can have a suitable pattern for a blazed grating, a chirped grating, or other diffractive element. The patterning and development can be accomplished using conventional photolithographic techniques.
- the photoresist pattern is then transferred to the DLG, as shown in the in-process structure 101b of Fig. 5B.
- a reactive ion etching (RIE) technique can be employed to transfer the pattern.
- the DLG 106 can be etched using a C3F8/O2 etch. Of course, other etchants can also be utilized.
- This pattern is then further transferred to the DLC layer 104.
- a conventional RIE technique such as an 02 etch, can be utilized.
- the resultant in-process structure 101c is shown in Fig. 5C. After etching, the grating is annealed to result in a patterned microporous amorphous carbon material that changes index as a function of exposure to certain vapors.
- a grating was tested against a range of toluene challenged concentrations.
- a sample grating was placed in a test chamber.
- An evaporator was utilized to create toluene vapor that was injected into an air stream that was pumped (using an adjustable pump) into the test chamber.
- the sample grating was laid at an angle of about 45 degrees and illuminated with a conventional microscope lamp.
- a large core optical fiber was used to collect a portion of the reflected light signal. The reflected light comprised a rainbow type pattern.
- Fig. 6 provides a graph of the sample diffraction grating response to Toluene exposure for pre-exposure and 50 ppm exposure levels.
- the optical spectrum data of the sample was monitored with a tungsten halogen light source (R-LS-I, available from Ocean Optics), a reflection probe, and a USB-2000 spectrometer.
- a nano-porous material in conjunction with a diffractive element as part of an exposure indicating device for a respirator system, can be utilized for EOLS or ESLI applications.
- Various modifications, equivalent processes, as well as numerous structures to which the present invention may be applicable will be readily apparent to those of skill in the art to which the present invention is directed upon review of the present specification.
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- Chemical Kinetics & Catalysis (AREA)
- Plasma & Fusion (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Diffracting Gratings Or Hologram Optical Elements (AREA)
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRPI0910150A BRPI0910150B1 (en) | 2008-06-30 | 2009-06-15 | exposure indicating devices |
CN200980121024XA CN102056649B (en) | 2008-06-30 | 2009-06-15 | Exposure indicating device |
JP2011516437A JP5943605B2 (en) | 2008-06-30 | 2009-06-15 | Exposure indicator device |
US12/997,650 US8459200B2 (en) | 2008-06-30 | 2009-06-15 | Exposure indicating device |
EP09774027.8A EP2307103B1 (en) | 2008-06-30 | 2009-06-15 | Respirator system comprising an exposure indicating device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US7683908P | 2008-06-30 | 2008-06-30 | |
US61/076,839 | 2008-06-30 |
Publications (2)
Publication Number | Publication Date |
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WO2010002575A2 true WO2010002575A2 (en) | 2010-01-07 |
WO2010002575A3 WO2010002575A3 (en) | 2010-05-06 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2009/047360 WO2010002575A2 (en) | 2008-06-30 | 2009-06-15 | Exposure indicating device |
Country Status (7)
Country | Link |
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US (1) | US8459200B2 (en) |
EP (1) | EP2307103B1 (en) |
JP (1) | JP5943605B2 (en) |
KR (1) | KR101544633B1 (en) |
CN (1) | CN102056649B (en) |
BR (1) | BRPI0910150B1 (en) |
WO (1) | WO2010002575A2 (en) |
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KR101224009B1 (en) * | 2010-12-06 | 2013-01-24 | 대한민국 | Alarming apparatus for exchanging filter box |
JP2013537978A (en) * | 2010-09-23 | 2013-10-07 | スリーエム イノベイティブ プロパティズ カンパニー | Porous chemical indicators for gaseous media |
WO2022055994A1 (en) * | 2020-09-09 | 2022-03-17 | One Science LLC | Face mask |
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Also Published As
Publication number | Publication date |
---|---|
CN102056649A (en) | 2011-05-11 |
EP2307103B1 (en) | 2018-12-19 |
CN102056649B (en) | 2012-11-28 |
JP5943605B2 (en) | 2016-07-05 |
KR20110039289A (en) | 2011-04-15 |
BRPI0910150B1 (en) | 2019-01-22 |
JP2011527008A (en) | 2011-10-20 |
EP2307103A4 (en) | 2014-12-24 |
EP2307103A2 (en) | 2011-04-13 |
WO2010002575A3 (en) | 2010-05-06 |
US8459200B2 (en) | 2013-06-11 |
BRPI0910150A2 (en) | 2016-01-19 |
US20110088611A1 (en) | 2011-04-21 |
KR101544633B1 (en) | 2015-08-17 |
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