WO2010048091A3 - Boron crosslinkers for fracturing fluids with appreciably lower polymer loading and related methods and compositions - Google Patents

Boron crosslinkers for fracturing fluids with appreciably lower polymer loading and related methods and compositions Download PDF

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Publication number
WO2010048091A3
WO2010048091A3 PCT/US2009/061174 US2009061174W WO2010048091A3 WO 2010048091 A3 WO2010048091 A3 WO 2010048091A3 US 2009061174 W US2009061174 W US 2009061174W WO 2010048091 A3 WO2010048091 A3 WO 2010048091A3
Authority
WO
WIPO (PCT)
Prior art keywords
compositions
lower polymer
related methods
methods
fracturing fluids
Prior art date
Application number
PCT/US2009/061174
Other languages
French (fr)
Other versions
WO2010048091A2 (en
Inventor
Hong Sun
Frances De Benedictis
Qi Qu
Jerry Edwin Pardue
Original Assignee
Bj Services Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/255,125 external-priority patent/US8173580B2/en
Priority claimed from US12/580,352 external-priority patent/US8389763B2/en
Priority claimed from US12/580,322 external-priority patent/US8420577B2/en
Application filed by Bj Services Company filed Critical Bj Services Company
Priority to AU2009307821A priority Critical patent/AU2009307821A1/en
Priority to BRPI0919899A priority patent/BRPI0919899A2/en
Priority to CA2741273A priority patent/CA2741273C/en
Publication of WO2010048091A2 publication Critical patent/WO2010048091A2/en
Publication of WO2010048091A3 publication Critical patent/WO2010048091A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60—Compositions for stimulating production by acting on the underground formation
    • C09K8/62—Compositions for forming crevices or fractures
    • C09K8/66—Compositions based on water or polar solvents
    • C09K8/68—Compositions based on water or polar solvents containing organic compounds
    • C09K8/685—Compositions based on water or polar solvents containing organic compounds containing cross-linking agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/025—Boronic and borinic acid compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60—Compositions for stimulating production by acting on the underground formation
    • C09K8/84—Compositions based on water or polar solvents
    • C09K8/86—Compositions based on water or polar solvents containing organic compounds
    • C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
    • C09K8/887—Compositions based on water or polar solvents containing organic compounds macromolecular compounds containing cross-linking agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60—Compositions for stimulating production by acting on the underground formation
    • C09K8/84—Compositions based on water or polar solvents
    • C09K8/86—Compositions based on water or polar solvents containing organic compounds
    • C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
    • C09K8/90—Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose

Abstract

Fracturing fluid compositions and methods of fracturing subterranean formations using polyboronic compounds as crosslinking agents. Polyboronic compounds and methods of making them. The polyboronic compounds are produced by contacting a polymeric amine with a trialkylborates in the presence of a solvent so that the resulting molecule has more than one B-N bond. The compositions and methods of the present invention allow for lower polymer loadings because achieving higher fracturing fluid viscosities can be achieved using less polymer than in traditional crosslinked systems.
PCT/US2009/061174 2008-10-21 2009-10-19 Boron crosslinkers for fracturing fluids with appreciably lower polymer loading and related methods and compositions WO2010048091A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU2009307821A AU2009307821A1 (en) 2008-10-21 2009-10-19 Boron crosslinkers for fracturing fluids with appreciably lower polymer loading and related methods and compositions
BRPI0919899A BRPI0919899A2 (en) 2008-10-21 2009-10-19 boron crosslinkers for appreciably lower polymerically charged fracture fluids and related methods and compositions
CA2741273A CA2741273C (en) 2008-10-21 2009-10-19 Boron crosslinkers for fracturing fluids with appreciably lower polymer loading and related methods and compositions

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US12/255,125 US8173580B2 (en) 2008-10-21 2008-10-21 Boron crosslinkers for fracturing fluids with appreciably lower polymer loading
US12/255,125 2008-10-21
US12/580,352 US8389763B2 (en) 2008-10-21 2009-10-16 Methods of making polyboronic compounds and compositions related thereto
US12/580,322 2009-10-16
US12/580,352 2009-10-16
US12/580,322 US8420577B2 (en) 2008-10-21 2009-10-16 Methods of making polyboronic compounds and compositions related thereto

Publications (2)

Publication Number Publication Date
WO2010048091A2 WO2010048091A2 (en) 2010-04-29
WO2010048091A3 true WO2010048091A3 (en) 2010-06-24

Family

ID=41510788

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/061174 WO2010048091A2 (en) 2008-10-21 2009-10-19 Boron crosslinkers for fracturing fluids with appreciably lower polymer loading and related methods and compositions

Country Status (4)

Country Link
AU (1) AU2009307821A1 (en)
BR (1) BRPI0919899A2 (en)
CA (1) CA2741273C (en)
WO (1) WO2010048091A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130157926A1 (en) * 2010-06-18 2013-06-20 Johannes Franciscus Joseph Engbersen Boronated polymers
US8708045B2 (en) * 2010-06-30 2014-04-29 Halliburton Energy Services, Inc. Multifunctional boronic acid crosslinking agents and associated methods
US8424603B2 (en) * 2010-06-30 2013-04-23 Halliburton Energy Services, Inc. Multifunctional boronic crosslinkers and associated methods
CN102775979B (en) * 2012-07-19 2014-08-06 中国石油天然气股份有限公司 Efficient cross-linking agent for reducing working concentration of guar gum and preparation method of efficient cross-linking agent
US20170247606A1 (en) * 2014-11-19 2017-08-31 Halliburton Energy Services, Inc. Silica crosslinker including boronic acid functionalities or esters thereof for treatment of subterranean formations
WO2017048249A1 (en) * 2015-09-16 2017-03-23 Halliburton Energy Services, Inc. Low-polymer loading treatment fluid for use in subterranean formation operations
CN112111263B (en) * 2020-09-23 2023-03-28 中国石油大学(华东) Preparation method of high-temperature-resistant clean fracturing fluid

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3284410A (en) * 1965-06-22 1966-11-08 Lubrizol Corp Substituted succinic acid-boron-alkylene amine-cyanamido derived additive and lubricating oil containing same
GB1545629A (en) * 1977-07-27 1979-05-10 Ici Ltd Process for preparing diaminodikto-,diaminodihydroxy-aminohydroxydiketo-,dihydroxyketimino-and diketo dihydroxy-hydronaphthacene derivatives
US4328113A (en) * 1980-01-14 1982-05-04 Mobil Oil Corporation Friction reducing additives and compositions thereof
US4474671A (en) * 1983-02-04 1984-10-02 Mobil Oil Corporation Products of reaction of organic diamines, boron compounds and acyl sarcosines and lubricants containing same
FR2855180A1 (en) * 2003-05-23 2004-11-26 Rhodia Chimie Sa Aqueous fluid for oil and gas field applications, e.g. as drilling fluid, contains a polymer with boronate groups, a ligand polymer with groups which react with boronate, and a water-soluble salt
US20060003900A1 (en) * 2004-07-02 2006-01-05 Hanes Robert E Jr Methods and compositions for crosslinking polymers with boronic acids
US20060089265A1 (en) * 2004-10-25 2006-04-27 Halliburton Energy Services, Inc. Boronic acid networking agents and associated methods

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3284410A (en) * 1965-06-22 1966-11-08 Lubrizol Corp Substituted succinic acid-boron-alkylene amine-cyanamido derived additive and lubricating oil containing same
GB1545629A (en) * 1977-07-27 1979-05-10 Ici Ltd Process for preparing diaminodikto-,diaminodihydroxy-aminohydroxydiketo-,dihydroxyketimino-and diketo dihydroxy-hydronaphthacene derivatives
US4328113A (en) * 1980-01-14 1982-05-04 Mobil Oil Corporation Friction reducing additives and compositions thereof
US4474671A (en) * 1983-02-04 1984-10-02 Mobil Oil Corporation Products of reaction of organic diamines, boron compounds and acyl sarcosines and lubricants containing same
FR2855180A1 (en) * 2003-05-23 2004-11-26 Rhodia Chimie Sa Aqueous fluid for oil and gas field applications, e.g. as drilling fluid, contains a polymer with boronate groups, a ligand polymer with groups which react with boronate, and a water-soluble salt
US20060003900A1 (en) * 2004-07-02 2006-01-05 Hanes Robert E Jr Methods and compositions for crosslinking polymers with boronic acids
US20060089265A1 (en) * 2004-10-25 2006-04-27 Halliburton Energy Services, Inc. Boronic acid networking agents and associated methods

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
J. GOUBEAU, E. EKHOFF: "Über die Reaktion von Borsäuremethylester mit Ammoniak und Aminen II", Z. ANORG. ALLG. CHEMIE, vol. 268, 1 February 1952 (1952-02-01), pages 145 - 158, XP002579239 *
S.L. WISKUR ET AL: "pKa values and geometries of secondary and tertiary amines complexed to boronic acids - implications for sensor design", ORGANIC LETTERS, vol. 3, no. 9, 2001, pages 1311 - 1314, XP002564462 *

Also Published As

Publication number Publication date
WO2010048091A2 (en) 2010-04-29
CA2741273A1 (en) 2010-04-29
AU2009307821A1 (en) 2010-04-29
BRPI0919899A2 (en) 2016-02-16
CA2741273C (en) 2017-03-14

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