WO2010054055A3 - Copper catalyst for dehydrogenation application - Google Patents

Copper catalyst for dehydrogenation application Download PDF

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Publication number
WO2010054055A3
WO2010054055A3 PCT/US2009/063364 US2009063364W WO2010054055A3 WO 2010054055 A3 WO2010054055 A3 WO 2010054055A3 US 2009063364 W US2009063364 W US 2009063364W WO 2010054055 A3 WO2010054055 A3 WO 2010054055A3
Authority
WO
WIPO (PCT)
Prior art keywords
copper catalyst
weight
catalytic compositions
compositions
dehydrogenation
Prior art date
Application number
PCT/US2009/063364
Other languages
French (fr)
Other versions
WO2010054055A2 (en
Inventor
Jianping Chen
Original Assignee
Basf Catalysts Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Catalysts Llc filed Critical Basf Catalysts Llc
Priority to JP2011535664A priority Critical patent/JP5639070B2/en
Priority to CN200980154092.6A priority patent/CN102271808B/en
Priority to EP09825398A priority patent/EP2364209A4/en
Priority to KR1020117013153A priority patent/KR101660552B1/en
Publication of WO2010054055A2 publication Critical patent/WO2010054055A2/en
Publication of WO2010054055A3 publication Critical patent/WO2010054055A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J35/66—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

Disclosed are catalytic compositions having from about 35% to about 75% of Cu by weight, from about 15% to about 35% of Al by weight, and about 5% to about 20% of Mn by weight. The catalytic compositions are bulk homogeneous compositions formed from extruding and calcinating a powder formed from a precipitation reaction of Cu(NO3)2, Mn(NO3)2, Na2AI2O3. The catalytic compositions have one or more crystalline phases of one or more of CuO and CuxMn(3-X)O4 where x is from about 1 to about 1.5, or both. The catalytic compositions are useful for the conversion of 1,4-butane-di-ol to γ-butyrolactone by a dehydrogenation reaction.
PCT/US2009/063364 2008-11-10 2009-11-05 Copper catalyst for dehydrogenation application WO2010054055A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2011535664A JP5639070B2 (en) 2008-11-10 2009-11-05 Copper catalysts for dehydrogenation applications
CN200980154092.6A CN102271808B (en) 2008-11-10 2009-11-05 Copper catalyst for dehydrogenation application
EP09825398A EP2364209A4 (en) 2008-11-10 2009-11-05 Copper catalyst for dehydrogenation application
KR1020117013153A KR101660552B1 (en) 2008-11-10 2009-11-05 Copper catalyst for dehydrogenation application

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US11312508P 2008-11-10 2008-11-10
US61/113,125 2008-11-10
US12/424,014 2009-04-15
US12/424,014 US8828903B2 (en) 2008-11-10 2009-04-15 Copper catalyst for dehydrogenation application

Publications (2)

Publication Number Publication Date
WO2010054055A2 WO2010054055A2 (en) 2010-05-14
WO2010054055A3 true WO2010054055A3 (en) 2010-08-12

Family

ID=42153539

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/063364 WO2010054055A2 (en) 2008-11-10 2009-11-05 Copper catalyst for dehydrogenation application

Country Status (8)

Country Link
US (1) US8828903B2 (en)
EP (2) EP3243566A1 (en)
JP (1) JP5639070B2 (en)
KR (1) KR101660552B1 (en)
CN (1) CN102271808B (en)
MY (1) MY159972A (en)
TW (1) TWI490038B (en)
WO (1) WO2010054055A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103360206B (en) * 2012-04-01 2016-03-02 中国石油化工股份有限公司 Produce the method for BDO, tetrahydrofuran (THF), gamma-butyrolactone and butanols
CN103360209B (en) * 2012-04-01 2015-02-11 中国石油化工股份有限公司 Method for co-producing 1,4-butanediol, gamma-butyrolactone and butanol
CN103360210B (en) * 2012-04-01 2016-02-24 中国石油化工股份有限公司 Purifying BDO also increases production the method for gamma-butyrolactone
CN103360208B (en) * 2012-04-01 2016-02-24 中国石油化工股份有限公司 Be separated the method for acetal in BDO
TWI476051B (en) * 2012-11-21 2015-03-11 Ind Tech Res Inst Catalyst, method for preparing the catalyst, and method for decomposing gas
DE102014013530A1 (en) * 2014-09-12 2016-03-17 Clariant International Ltd. Extruded Cu-Al-Mn hydrogenation catalyst
WO2016170450A1 (en) * 2015-04-20 2016-10-27 Sabic Global Technologies B.V. Method of improving dehydrogenation of hydrocarbons
CN109999827B (en) * 2019-04-19 2020-09-08 苏州大学 Manganese molybdate coated copper mesh and application thereof in separation of oil-water emulsion and degradation of organic pollutants in water
CN115996794A (en) * 2020-06-30 2023-04-21 巴斯夫公司 Chromium-free copper catalyst for hydrogenolysis/hydrogenation of fatty esters

Citations (4)

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US5981769A (en) * 1996-03-01 1999-11-09 Basf Aktiengesellschaft Process for preparing 1,6- hexanediol and caprolactone
US6093677A (en) * 1996-09-05 2000-07-25 Basf Aktiengesellschaft Catalyst for dehydrogenating 1,4-butanediol to γ-butyrolactone
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US5210229A (en) * 1991-07-17 1993-05-11 Tonen Chemical Corporation Process for the preparation of gamma-butyrolactone
US5981769A (en) * 1996-03-01 1999-11-09 Basf Aktiengesellschaft Process for preparing 1,6- hexanediol and caprolactone
US6455464B1 (en) * 1996-03-21 2002-09-24 Engelhard Corporation Preparation and use of non-chrome catalysts for Cu/Cr catalyst applications
US6093677A (en) * 1996-09-05 2000-07-25 Basf Aktiengesellschaft Catalyst for dehydrogenating 1,4-butanediol to γ-butyrolactone

Also Published As

Publication number Publication date
JP5639070B2 (en) 2014-12-10
KR20110094040A (en) 2011-08-19
EP2364209A4 (en) 2012-12-05
EP2364209A2 (en) 2011-09-14
EP3243566A1 (en) 2017-11-15
WO2010054055A2 (en) 2010-05-14
US8828903B2 (en) 2014-09-09
US20100121080A1 (en) 2010-05-13
CN102271808A (en) 2011-12-07
TWI490038B (en) 2015-07-01
TW201026390A (en) 2010-07-16
CN102271808B (en) 2015-07-22
KR101660552B1 (en) 2016-09-27
JP2012508104A (en) 2012-04-05
MY159972A (en) 2017-02-15

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