WO2011017158A3 - Gasification of carbonaceous materials and gas to liquid processes - Google Patents

Gasification of carbonaceous materials and gas to liquid processes Download PDF

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Publication number
WO2011017158A3
WO2011017158A3 PCT/US2010/043532 US2010043532W WO2011017158A3 WO 2011017158 A3 WO2011017158 A3 WO 2011017158A3 US 2010043532 W US2010043532 W US 2010043532W WO 2011017158 A3 WO2011017158 A3 WO 2011017158A3
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WIPO (PCT)
Prior art keywords
gas
high shear
liquid product
liquid
synthesis gas
Prior art date
Application number
PCT/US2010/043532
Other languages
French (fr)
Other versions
WO2011017158A2 (en
Inventor
Aziz Hassan
Abbas Hassan
Rayford G. Anthony
Gregory Borsinger
Original Assignee
Hrd Corporation
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Publication date
Application filed by Hrd Corporation filed Critical Hrd Corporation
Priority to EA201290039A priority Critical patent/EA024157B1/en
Priority to CN2010800346616A priority patent/CN102471706A/en
Priority to IN461DEN2012 priority patent/IN2012DN00461A/en
Priority to AU2010281384A priority patent/AU2010281384B2/en
Priority to EP10806922.0A priority patent/EP2462208A4/en
Publication of WO2011017158A2 publication Critical patent/WO2011017158A2/en
Publication of WO2011017158A3 publication Critical patent/WO2011017158A3/en

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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/222Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid in the presence of a rotating device only
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516Multisteps
    • C07C29/1518Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
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    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/233Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
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    • B01F23/53Mixing liquids with solids using driven stirrers
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    • B01F27/2714Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed radially between the surfaces of the rotor and the stator the relative position of the stator and the rotor, gap in between or gap with the walls being adjustable
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    • C10J2300/1659Conversion of synthesis gas to chemicals to liquid hydrocarbons
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    • C10J2300/1665Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

Herein disclosed is a method of producing synthesis gas from carbonaceous material, the method comprising: (a) providing a mixture comprising carbonaceous material and a liquid medium; (b) subjecting the mixture to high shear under gasification conditions whereby a high shear-treated stream comprising synthesis gas is produced; and (c) separating a product comprising synthesis gas from the high shear-treated stream. Herein also disclosed is a method for producing a liquid product. The method comprises forming a dispersion comprising gas bubbles dispersed in a liquid phase in a high shear device, wherein the average gas bubble diameter is less than about 1.5 μm; contacting the dispersion with a multifunctional catalyst to form the liquid product; and recovering the liquid product. In an embodiment, the liquid product is selected from the group consisting of C2+ hydrocarbons, C2+ oxygenates, and combinations thereof.
PCT/US2010/043532 2009-08-04 2010-07-28 Gasification of carbonaceous materials and gas to liquid processes WO2011017158A2 (en)

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EA201290039A EA024157B1 (en) 2009-08-04 2010-07-28 Method of producing synthesis gas from carbonaceous material
CN2010800346616A CN102471706A (en) 2009-08-04 2010-07-28 Gasification of carbonaceous materials and gas to liquid processes
IN461DEN2012 IN2012DN00461A (en) 2009-08-04 2010-07-28
AU2010281384A AU2010281384B2 (en) 2009-08-04 2010-07-28 Gasification of carbonaceous materials and gas to liquid processes
EP10806922.0A EP2462208A4 (en) 2009-08-04 2010-07-28 Gasification of carbonaceous materials and gas to liquid processes

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US61/231,261 2009-08-04
US12/844,728 US8394861B2 (en) 2007-06-27 2010-07-27 Gasification of carbonaceous materials and gas to liquid processes
US12/844,728 2010-07-27

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