WO2012063157A1 - A tack free decorative ink composition comprising an aziridine derivative and a polyethylene / paraffin wax mixture, process and use thereof - Google Patents
A tack free decorative ink composition comprising an aziridine derivative and a polyethylene / paraffin wax mixture, process and use thereof Download PDFInfo
- Publication number
- WO2012063157A1 WO2012063157A1 PCT/IB2011/054796 IB2011054796W WO2012063157A1 WO 2012063157 A1 WO2012063157 A1 WO 2012063157A1 IB 2011054796 W IB2011054796 W IB 2011054796W WO 2012063157 A1 WO2012063157 A1 WO 2012063157A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dispersion
- acrylic resin
- composition
- aziridine
- aqueous
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/12—Printing inks based on waxes or bitumen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
Definitions
- the present invention relates to a composition of a decorative ink used on sheets and/or reels of cellulose and/or plastic in the field of the graphic arts.
- the present invention also relates to a process for obtaining such composition and its use.
- the present inventors have previously developed a new product laminated with cellulose that overcame
- compositions as described in the above mentioned model, on sheets and reels of cellulose and/or plastic materials is especially designed for graphic arts as graphic finishes, for advertising in paper products with high added value, in which base materials are used, in particular cellulose or plasticized cellulose and/or plastic material, of high cost.
- a first object of the present invention is to provide a composition of a decorative ink overcoming the drawbacks indicated in the previous section.
- This composition of a decorative ink is one that comprises a compound derived from aziridine and a combination of polyethylene waxes and paraffin waxes, in which the compound derived from aziridine is between 0.1 and 1.5% by weight, preferably between 0.35 and 1.5% by weight, and said combination of polyethylene waxes and paraffin waxes is between 0.1 and 3% by weight, preferably between 0.5 and 2% by weight, with regard to the total weight of the composition.
- the solvent used is Said composition further comprises one or more of following components:
- Dispossion in the present invention refers to a fluid in whose mass a body in suspension or in colloidal state is evenly contained.
- said fluid is preferably water, but it can also be any other non aqueous solvent.
- Resin in the present invention refers to a complex organic substance with a melting point not defined in which the solvent solution forms the binding proportion of the flexographic ink.
- Compound derived from aziridine in the present invention refers to aziridine-based compounds which include a diluent and a moisturizing agent as dispersing agents .
- Polyethylene waxes in the present invention refers to polyethylene of very low molecular weight, slightly branched, with melting temperatures of 100 to 130°C. They are more effective than paraffin waxes.
- “Laminated polyester” in the present invention refers to cut polyester sheets.
- Acrylic resin polymer dispersion with a pigment in the present invention refers to a dispersion of acrylic-based resin in which a pigment has been dispersed (organic or inorganic) preferably in an aqueous medium.
- Polyacrylic acid dispersion in the present invention refers to a dispersion containing a solvent, preferably water, and polyacrylic acid.
- Aliphatic polyurethane dispersion in the present invention refers to a dispersion containing a solvent, preferably water, and aliphatic polyurethane, which is an acyclic organic compound with open-chain molecular structure .
- Woodemite mineral dispersion in acrylic resin dispersion refers to a dispersion containing a solvent, preferably water, and a Willemite mineral, which in turn is inside an acrylic resin .
- Acrylic resin dispersion of titanium dioxide in the present invention refers to a dispersion containing an acrylic resin and titanium dioxide.
- “Expanding product dispersion in an acrylic base” in the present invention refers to a dispersion of an expanding product in an acrylic base.
- Piglescent pigment dispersion in acrylic resin refers to a dispersion containing a pearlescent pigment, (a concept known in the industry and publications and also known as pearl sheen) and acrylic resin
- Tianium dioxide dispersion in the present invention refers to a dispersion containing a solvent, preferably water, and titanium dioxide.
- Organic pigment dispersion in the present invention refers to a dispersion containing a solvent, preferably water, and organic pigments.
- “Inflatable dispersion in acrylic resin” in the present invention refers to a dispersion of an inflatable product (flexible outer membrane structure containing a gas inside) in acrylic resin.
- Said components can be found in any proportion in the composition provided that the two essential components (a compound derived from aziridine and a combination of polyethylene waxes and paraffin waxes) are included and the total weight is 100%.
- composition disclosed herein for decorative inks is construed as that said composition is used itself as a decorative ink.
- a second object of the present invention relates to a process for the manufacture of said composition.
- This procedure comprises the step of mixing the compound derived from aziridine, the combination of polyethylene waxes and paraffin waxes and a solution comprising one or more of the following components:
- a third object of the present invention relates to a laminate and/or reeled product printed with a decorative layer comprising a first cellulose-based and/or plastic material substrate, and at least a second associated substrate, and is characterized in that the second substrate comprises a synthetic material layer bonded by an adhesive that is irreversible to the first substrate, said second substrate covering partially or completely said first substrate, and in that the composition of the present invention according to different embodiments is applied on said first cellulose-based and/or plastic substrate .
- the manufacture of the laminate product comprises the steps of applying xerographically or by any other suitable method, for example, hollow engraving, flexography, stamping or inkjet, the composition of the present invention, according to different embodiments, on the first cellulose-based and/or plastic material substrate and the introduction of the product in a heat tunnel at a suitable temperature.
- the solvent used is water said temperature is between 80 and 160°C.
- a fourth object of the present invention relates to the use of the composition described herein to eliminate the phenomenon of tacking from the product, according to the third object of the invention, between the cellulose-based and/or plastic substrate and the substrate that covers it.
- compositions obtained in the examples are obtained by mixing the compound derived from aziridine, polyethylene waxes and paraffin waxes and a solution containing the other components. The mixtures are performed at room temperature.
- Example 16 polyethylene waxes and paraffin waxes 1.05%
Abstract
The present invention relates to a composition of a decorative ink used on sheets and/or reels of cellulose and/or plastic in the field of the graphic arts. The present invention also relates to a process for obtaining said composition, as well as to the laminate and/or reeled product with a printed decorative layer comprising said composition; to the manufacture of said product; and the use of the compositions of the invention to eliminate the "tacking" from the product.
Description
A TACK FREE DECORATIVE INK COMPOSITION COMPRISING AN AZIRIDINE DERIVATIVE AND A POLYETHYLENE / PARAFFIN WAX MIXTURE, PROCESS AND USE THEREOF
FIELD OF THE INVENTION
5 The present invention relates to a composition of a decorative ink used on sheets and/or reels of cellulose and/or plastic in the field of the graphic arts. The present invention also relates to a process for obtaining such composition and its use.
10
BACKGROUND OF THE INVENTION
The present inventors have previously developed a new product laminated with cellulose that overcame
15 different drawbacks of the state of the art, that is to say, it allowed to bear tactile and visual information from the application of a specific composition, it endured a continuous use and, in particular, it endured the continuous exposition to light and moisture from hands.
20 Said new product is protected under the Spanish Utility Model Application No. 200800964.
However, there have been several problems that still exist in relation to the cellulose-based substrate.
On the one hand, there is the phenomenon of
25 "tacking" between the cellulose-based substrate and the substrate covering it formed by materials of the pearly type with of without relief, polyester frost, "foam", phosphorescent paste, acrylic paints and glitter.
"Tacking" (term used in Graphic Arts) is the
30 undesired adhesion between the material deposited on a sheet and the next sheet when stacked or in the case of reels in the rewinding when they are wound. This undesired effect increases as more sheets coated with said substrate are stacked, in particular due to the pressure on the
35 deeper sheets or in the inner part of the reel.
When it comes to application of these compositions to textile materials, such as T-shirts, the tacking effect is very limited, partly because of the experience gained in the sector and also due to textile fibers providing good adhesion and because the pressure of the stacking is much lower due to the product's lower density.
It should be noted that the application of compositions, as described in the above mentioned model, on sheets and reels of cellulose and/or plastic materials is especially designed for graphic arts as graphic finishes, for advertising in paper products with high added value, in which base materials are used, in particular cellulose or plasticized cellulose and/or plastic material, of high cost.
Under these circumstances, it is essential to ensure optimal quality of the deposition of the material, and avoid tacking at all costs, because the lack of quality of the distributed product can adversely affect the editor, and even more, the advertiser.
On the other hand, there is also the problem that, when applied to the cellulose-based substrate, wrinkling occurred particularly on paper or cardboard, and likewise there was a lack of adherence, in particular on plastic materials. As indicated in the above mentioned Utility Model, said product laminated with cellulose is especially suitable when you want to provide a tactile experience apart from the visual, so that information can be supplied in two different sensory levels.
It can also be used in advertising, restaurants, for example for menus, as informative support for blind people, or for children's books to develop the sense of touch. Due to the large variety of everyday items where we can find this product, it is of vital importance to overcome the drawbacks mentioned above. In addition, due to its usefulness, not only visual but also tactile, it is
very important for the product to be resistant, uniform, without "tacking" and dried to prevent wrinkling.
There is therefore a clear need to improve the adhesion of the cellulose-based and/or plastic material substrate with the substrate that covers it in order to overcome the above mentioned drawbacks.
There are several documents in the state of art (WO2008/149067; US2006/0019043 ; US2001/0031344 and WO02/062894) disclosing similar compositions to those covered by the present invention. However, none of them discloses a composition used itself as a decorative ink, but they are used as coatings or substrates or receptor for inks which do not have a decorative purpose. The present invention does not relate to such combinations of ink along with a receptor because the composition disclosed herein is itself the ink to be used. By "decorative ink" in the state of art is understood an ink whose purpose is to provide luster, decorate, highlight an image or create an image over a given support .
DESCRIPTION OF THE INVENTION
A first object of the present invention is to provide a composition of a decorative ink overcoming the drawbacks indicated in the previous section. This composition of a decorative ink is one that comprises a compound derived from aziridine and a combination of polyethylene waxes and paraffin waxes, in which the compound derived from aziridine is between 0.1 and 1.5% by weight, preferably between 0.35 and 1.5% by weight, and said combination of polyethylene waxes and paraffin waxes is between 0.1 and 3% by weight, preferably between 0.5 and 2% by weight, with regard to the total weight of the composition. In a preferred embodiment the solvent used is
Said composition further comprises one or more of following components:
- acrylic resin dispersion
- laminated polyester
- acrylic resin polymer dispersion with pigment
- polyacrylic acid dispersion
- aliphatic polyurethane dispersion
- willemite mineral dispersion in acrylic resin dispersion
- acrylic resin dispersion with titanium dioxide
- expanding product dispersion in acrylic base
- pearlescent pigment dispersion in acrylic resin
- titanium dioxide dispersion
- organic pigment dispersion
inflatable dispersion in acrylic resin.
zinc sulphate doped with copper
aqueous acrylic resin dispersion with iodine aqueous dispersion of polyurethane acrylic copolymer
propylene glycol
butyl diglycol + urea solution in distilled water
Mixture of hydrophobic substances and polysiloxanes in polyglycol
Polyether-modified polydimethylsiloxane Solution of a polyether-modified siloxane in dipropylene glycol monomethyl ether Non ionic hydrosoluble polymethane
Mixture of polyols
Alcohol ether
In order to clarify and specify each of the components of the present composition, along with some of the concepts used in the present invention, the following
definitions are included as follows:
"Dispersion" in the present invention refers to a fluid in whose mass a body in suspension or in colloidal state is evenly contained. In the present invention, said fluid is preferably water, but it can also be any other non aqueous solvent.
"Resin" in the present invention refers to a complex organic substance with a melting point not defined in which the solvent solution forms the binding proportion of the flexographic ink.
"Compound derived from aziridine" in the present invention refers to aziridine-based compounds which include a diluent and a moisturizing agent as dispersing agents .
"Polyethylene waxes" in the present invention refers to polyethylene of very low molecular weight, slightly branched, with melting temperatures of 100 to 130°C. They are more effective than paraffin waxes.
"Laminated polyester" in the present invention refers to cut polyester sheets.
"Acrylic resin polymer dispersion with a pigment" in the present invention refers to a dispersion of acrylic-based resin in which a pigment has been dispersed (organic or inorganic) preferably in an aqueous medium.
"Polyacrylic acid dispersion" in the present invention refers to a dispersion containing a solvent, preferably water, and polyacrylic acid.
"Aliphatic polyurethane dispersion" in the present invention refers to a dispersion containing a solvent, preferably water, and aliphatic polyurethane, which is an acyclic organic compound with open-chain molecular structure .
"Willemite mineral dispersion in acrylic resin dispersion" in the present invention refers to a dispersion containing a solvent, preferably water, and a
Willemite mineral, which in turn is inside an acrylic resin .
"Acrylic resin dispersion of titanium dioxide" in the present invention refers to a dispersion containing an acrylic resin and titanium dioxide.
"Expanding product dispersion in an acrylic base" in the present invention refers to a dispersion of an expanding product in an acrylic base.
"Pearlescent pigment dispersion in acrylic resin" in the present invention refers to a dispersion containing a pearlescent pigment, (a concept known in the industry and publications and also known as pearl sheen) and acrylic resin
"Titanium dioxide dispersion" in the present invention refers to a dispersion containing a solvent, preferably water, and titanium dioxide.
"Organic pigment dispersion" in the present invention refers to a dispersion containing a solvent, preferably water, and organic pigments.
"Inflatable dispersion in acrylic resin" in the present invention refers to a dispersion of an inflatable product (flexible outer membrane structure containing a gas inside) in acrylic resin.
Said components can be found in any proportion in the composition provided that the two essential components (a compound derived from aziridine and a combination of polyethylene waxes and paraffin waxes) are included and the total weight is 100%.
In the context of the present invention the composition disclosed herein for decorative inks is construed as that said composition is used itself as a decorative ink.
A second object of the present invention relates to a process for the manufacture of said composition. This procedure comprises the step of mixing the compound
derived from aziridine, the combination of polyethylene waxes and paraffin waxes and a solution comprising one or more of the following components:
- acrylic resin dispersion
- laminated polyester
- acrylic resin polymer dispersion with pigment
- polyacrylic acid dispersion
- aliphatic polyurethane dispersion
- willemite mineral dispersion in acrylic resin dispersion
- acrylic resin dispersion with titanium dioxide
- expanding product dispersion in acrylic base
- pearlescent pigment dispersion in acrylic resin
- titanium dioxide dispersion
- organic pigment dispersion
inflatable dispersion in acrylic resin zinc sulphate doped with copper
aqueous acrylic resin dispersion with iodine aqueous dispersion of polyurethane acrylic copolymer
propylene glycol
butyl diglycol + urea solution in distilled water
Mixture of hydrophobic substances and polysiloxanes in polyglycol
Polyether-modified polydimethylsiloxane Solution of a polyether-modified siloxane in dipropylene glycol monomethyl ether Non ionic hydrosoluble polymethane
- Mixture of polyols
Alcohol ether.
A third object of the present invention relates to a laminate and/or reeled product printed with a decorative layer comprising a first cellulose-based and/or plastic material substrate, and at least a second associated
substrate, and is characterized in that the second substrate comprises a synthetic material layer bonded by an adhesive that is irreversible to the first substrate, said second substrate covering partially or completely said first substrate, and in that the composition of the present invention according to different embodiments is applied on said first cellulose-based and/or plastic substrate .
The manufacture of the laminate product comprises the steps of applying xerographically or by any other suitable method, for example, hollow engraving, flexography, stamping or inkjet, the composition of the present invention, according to different embodiments, on the first cellulose-based and/or plastic material substrate and the introduction of the product in a heat tunnel at a suitable temperature. When the solvent used is water said temperature is between 80 and 160°C.
A fourth object of the present invention relates to the use of the composition described herein to eliminate the phenomenon of tacking from the product, according to the third object of the invention, between the cellulose-based and/or plastic substrate and the substrate that covers it.
EXAMPLES
Next, a variety of examples to illustrate and better understand the present invention are provided, without intending that the scope of the invention may be limited by these.
The compositions obtained in the examples are obtained by mixing the compound derived from aziridine, polyethylene waxes and paraffin waxes and a solution containing the other components. The mixtures are
performed at room temperature.
Example 1 :
Chemical composition (% by weight) :
- aqueous acrylic resin dispersion 60.45% - aqueous aliphatic polyurethane dispersion 22.90%
- laminated polyester 13.52%
- aqueous polyacrylic acid dispersion 0.77%
- compound derived from aziridine 0.81%
- polyethylene waxes and paraffin waxes 1.55% - acrylic resin polymer dispersion of an aqueous pigment (variable depending on color)
Example 2 :
Chemical composition (% by weight) :
- aqueous dispersion of aliphatic polyurethane
laminated polyester 9.70%
- willemite mineral dispersion in aqueous
acrylic resin dispersion 21.10%
- aqueous acrylic resin dispersion with
titanium dioxide 66.40% - compound derived from aziridine 1.00%
- polyethylene waxes and paraffin waxes 1.00%
- acrylic resin polymer dispersion of an aqueous pigment (variable depending on color)
Example 3 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 10.78%
- aqueous acrylic resin dispersion with
titanium dioxide 87.22%
- compound derived from aziridine 1.00% - polyethylene waxes and paraffin waxes 1.00%
- acrylic resin polymer dispersion of an aqueous pigment (variable depending on color)
Example 4 :
Chemical composition (% by weight) :
- aqueous acrylic resin dispersion 56.20%
- aqueous aliphatic polyurethane dispersion 7.90%
- laminated polyester 12.86%
- pearlescent pigment dispersion in
acrylic resin 21.44% - compound derived from aziridine 0.78%
- polyethylene waxes and paraffin waxes 0.82%
- acrylic resin polymer dispersion of an aqueous pigment (variable depending on color)
Example 5 :
Chemical composition (% by weight) :
- aqueous polyacrylic acid dispersion 2.04%
- pearlescent pigment dispersion in
acrylic resin 96.45%
- compound derived from aziridine 0.51% - polyethylene waxes and paraffin waxes 1%
- acrylic resin polymer dispersion of an aqueous pigment (variable depending on color)
Example 6 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 10.33%
- aqueous acrylic resin dispersion with
titanium dioxide 36.14%
- expanding product dispersion in acrylic base 51.68%
- compound derived from aziridine 0.86% - polyethylene waxes and paraffin waxes 1.00%
- acrylic resin polymer dispersion of an aqueous pigment (variable depending on color)
Example 7 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 8.32%
- aqueous acrylic resin dispersion with
titanium dioxide 76.38%
- expanding product dispersion in acrylic base 13.40%
- compound derived from aziridine 0.91% - polyethylene waxes and paraffin waxes 0.75%
- aqueous dispersion of organic pigments (variable depending on color)
Example 8 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 10.38%
- aqueous titanium dioxide dispersion 26.17%
- inflatable dispersion in acrylic resin 61.90%
- compound derived from aziridine 0.51%
- polyethylene waxes and paraffin waxes 1.04% - acrylic resin polymer dispersion of an aqueous pigment (variable depending on color)
Example 9 :
Chemical composition (% by weight) :
- aqueous acrylic resin dispersion 61.95% - aqueous aliphatic polyurethane dispersion 27.24%
- laminated polyester 8.40%
- aqueous polyacrylic acid dispersion 0.31%
- compound derived from aziridine 0.42%
- polyethylene waxes and paraffin waxes 1.68%
Example 10 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 9.31%
- aqueous acrylic resin dispersion with
titanium dioxide 89.41% - compound derived from aziridine 0.37%
- polyethylene waxes and paraffin waxes 0.91%
Example 11 :
Chemical composition (% by weight) :
- aqueous acrylic resin dispersion 55.08% - aqueous aliphatic polyurethane dispersion 9.90%
- laminated polyester 8.40%
- pearlescent pigment dispersion in
acrylic resin 25.20%
- compound derived from aziridine 0.38% - polyethylene waxes and paraffin waxes 1.04%
Example 11 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 9.71%
- aqueous acrylic resin dispersion 52.16% - zinc sulphate doped with copper 36.75%
- compound derived from aziridine 0.41%
- polyethylene waxes and paraffin waxes 0.97% Example 12 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 10.29%
- aqueous acrylic resin dispersion with
titanium dioxide 36.12%
- expanding product dispersion in acrylic base 52.23%
- compound derived from aziridine 0.42% - polyethylene waxes and paraffin waxes 0.94%
Example 13 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 10.00%
- aqueous acrylic resin dispersion with
titanium dioxide 37.60%
- expanding product dispersion in acrylic base 52.06%
- compound derived from aziridine 0.42%
- polyethylene waxes and paraffin waxes 0.92% Example 14:
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 9.31%
- pearlescent pigment dispersion in
acrylic resin 89.29%
- compound derived from aziridine 0.47% - polyethylene waxes and paraffin waxes 0.93%
Example 15:
Chemical composition (% by weight) :
- aqueous acrylic resin dispersion 32.34%
- aqueous acrylic resin dispersion with
iodine 57.16%
- aqueous aliphatic polyurethane dispersion 8.19%
- aqueous polyacrylic acid dispersion 0.84%
- compound derived from aziridine 0.42%
- polyethylene waxes and paraffin waxes 1.05% Example 16 :
Chemical composition (% by weight) :
- aqueous dispersion of polyurethane
acrylic copolymer 69.55%
- aqueous aliphatic polyurethane dispersion 15.00% - propylene glycol 3.06%
- butyl diglycol + urea solution in
distilled water 7.84%
- Mixture of hydrophobic substances and
polysiloxanes in polyglycol 0.95% - Polyether-modified polydimethylsiloxane 0.15%
- Solution of a polyether-modified siloxane
in dipropylene glycol monomethyl ether 0.30%
- Non ionic hydrosoluble polymethane 0.05%
- compound derived from aziridine 0.10% - polyethylene waxes and paraffin waxes 3.00%
Example 17:
Chemical composition (% by weight) :
- aqueous dispersion of polyurethane
acrylic copolymer 84.55%
- propylene glycol 3.09%
- butyl diglycol + urea solution in
distilled water 7.60%
- Mixture of hydrophobic substances and
polysiloxanes in polyglycol 0.84%
- Polyether-modified polydimethylsiloxane 0.20%
- Solution of a polyether-modified siloxane
in dipropylene glycol monomethyl ether 3.10%
- Non ionic hydrosoluble polymethane 0.42% - compound derived from aziridine 0.10%
- polyethylene waxes and paraffin waxes 0.10% Example 18 :
Chemical composition (% by weight) :
- aqueous dispersion of polyurethane
acrylic copolymer 79.05%
- Alcohol ether 1.05%
- Mixture of polyols 0.73%
- Mixture of hydrophobic substances and
polysiloxanes in polyglycol 0.52%
- aqueous aliphatic polyurethane dispersion 17.85%
- Polyether-modified polydimethylsiloxane 0.20%
- Solution of a polyether-modified siloxane
in dipropylene glycol monomethyl ether 0.20% - Non ionic hydrosoluble polymethane 0.20%
- compound derived from aziridine 0.10%
- polyethylene waxes and paraffin waxes 0.10%
Example 19 :
Chemical composition (% by weight) :
- aqueous aliphatic polyurethane dispersion 9.20%
- aqueous acrylic resin dispersion with
titanium dioxide 37.40%
- expanding product aqueous dispersion in
acrylic base 52.06%
- compound derived from aziridine 0.42%
- polyethylene waxes and paraffin waxes 0.92%
Claims
1. Composition of a decorative ink comprising a compound derived from aziridine and a combination of polyethylene waxes and paraffin waxes, wherein the compound derived from aziridine is between 0.1 and 1.5% by weight and said combination of polyethylene waxes and paraffin waxes is between 0.1 and 3% by weight with regard to the total weight of the composition.
2. Composition according to claim 1, wherein the compound derived from aziridine is between 0.35 and 1.5% by weight and said combination of polyethylene waxes and paraffin waxes is between 0.5 and 2% by weight with regard to the total weight of the composition.
3. Composition according to claim 1 or 2, further comprising one or more of the following components:
- acrylic resin dispersion
- laminated polyester
- acrylic resin polymer dispersion with pigment
- polyacrylic acid dispersion
- aliphatic polyurethane dispersion
- willemite mineral dispersion in acrylic resin dispersion
- acrylic resin dispersion with titanium dioxide
- expanding product dispersion in acrylic base
- pearlescent pigment dispersion in acrylic resin
- titanium dioxide dispersion
- organic pigments dispersion
- inflatable dispersion in acrylic resin.
zinc sulphate doped with copper
aqueous acrylic resin dispersion with iodine aqueous dispersion of polyurethane acrylic copolymer propylene glycol
butyl diglycol + urea solution in distilled water
Mixture of hydrophobic substances and polysiloxanes in polyglycol
Polyether-modified polydimethylsiloxane Solution of a polyether-modified siloxane in dipropylene glycol monomethyl ether Non ionic hydrosoluble polymethane
- Mixture of polyols
Alcohol ether.
4. Composition according to any of the preceding claims wherein the solvent used is water.
5. Procedure for obtaining the composition according to any of claims 1 to 4, comprising the step of mixing the compound derived from aziridine, the combination of polyethylene waxes and paraffin waxes and a solution with one or more of the components according to claim 3 or 4.
6. Laminated and/or reeled product printed with a decorative layer comprising the composition according to any of claims 1 to 4.
7. Process for obtaining the product according to claim 6 comprising the steps of xerographically applying the composition according to any of claims 1 to 4 on a first cellulose and/or plastic material substrate and introducing the product obtained in a heat tunnel at a temperature between 80°C and 160°C, wherein the solvent used in the composition is water.
8. Process according to claim 7, wherein instead of applying xerography, hollow engraving, flexography, stamping or inkjet is applied.
9. Use of the composition according to any of claims 1 to 4 for removing the phenomenon of tacking from the product according to claim 6, between the cellulose- based substrate and the substrate that covers it.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES201031649A ES2353293B1 (en) | 2010-11-09 | 2010-11-09 | COMPOSITION FOR THE SECTOR OF GRAPHIC ARTS, PROCEDURE AND USE OF THE SAME. |
| ESP201031649 | 2010-11-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2012063157A1 true WO2012063157A1 (en) | 2012-05-18 |
Family
ID=43587009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IB2011/054796 WO2012063157A1 (en) | 2010-11-09 | 2011-10-27 | A tack free decorative ink composition comprising an aziridine derivative and a polyethylene / paraffin wax mixture, process and use thereof |
Country Status (2)
| Country | Link |
|---|---|
| ES (1) | ES2353293B1 (en) |
| WO (1) | WO2012063157A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449030A (en) * | 2014-12-05 | 2015-03-25 | 徐州市华阳油墨化学有限公司 | Solvent type gravure pearlescent ink and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3926636A (en) * | 1972-08-29 | 1975-12-16 | Basf Ag | Photocurable compositions |
| EP0697295A2 (en) * | 1994-07-18 | 1996-02-21 | Toppan Printing Co., Ltd. | Printed decorative paper having a three dimensional pattern and a process for the production thereof |
| US5534049A (en) * | 1991-09-03 | 1996-07-09 | Girobank A?S | Flexographic printing ink |
| US20010031344A1 (en) | 1997-12-08 | 2001-10-18 | Nordeen Charles Kevin | Image transfer process for ink-jet generated images |
| WO2002062894A1 (en) | 2001-02-05 | 2002-08-15 | Avery Dennison Corporation | Topcoat compositions, substrates containing a topcoat derived therefrom, and methods of preparing the same |
| US20060019043A1 (en) | 2004-07-20 | 2006-01-26 | Kimberly-Clark Worldwide, Inc. | Heat transfer materials and method of use thereof |
| WO2008094863A1 (en) * | 2007-01-29 | 2008-08-07 | Sun Chemical Corporation | Lithographic printing ink |
| WO2008149067A1 (en) | 2007-06-04 | 2008-12-11 | Arjowiggins Licensing | Transfer sheet and method of manufacturing a transfer sheet |
| CN101717596A (en) * | 2009-12-08 | 2010-06-02 | 杭华油墨化学有限公司 | Water-based ink for package printing of high-adhesion film and manufacturing method thereof |
-
2010
- 2010-11-09 ES ES201031649A patent/ES2353293B1/en not_active Expired - Fee Related
-
2011
- 2011-10-27 WO PCT/IB2011/054796 patent/WO2012063157A1/en active Application Filing
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3926636A (en) * | 1972-08-29 | 1975-12-16 | Basf Ag | Photocurable compositions |
| US5534049A (en) * | 1991-09-03 | 1996-07-09 | Girobank A?S | Flexographic printing ink |
| EP0697295A2 (en) * | 1994-07-18 | 1996-02-21 | Toppan Printing Co., Ltd. | Printed decorative paper having a three dimensional pattern and a process for the production thereof |
| US20010031344A1 (en) | 1997-12-08 | 2001-10-18 | Nordeen Charles Kevin | Image transfer process for ink-jet generated images |
| WO2002062894A1 (en) | 2001-02-05 | 2002-08-15 | Avery Dennison Corporation | Topcoat compositions, substrates containing a topcoat derived therefrom, and methods of preparing the same |
| US20060019043A1 (en) | 2004-07-20 | 2006-01-26 | Kimberly-Clark Worldwide, Inc. | Heat transfer materials and method of use thereof |
| WO2008094863A1 (en) * | 2007-01-29 | 2008-08-07 | Sun Chemical Corporation | Lithographic printing ink |
| WO2008149067A1 (en) | 2007-06-04 | 2008-12-11 | Arjowiggins Licensing | Transfer sheet and method of manufacturing a transfer sheet |
| CN101717596A (en) * | 2009-12-08 | 2010-06-02 | 杭华油墨化学有限公司 | Water-based ink for package printing of high-adhesion film and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE WPI Week 201046, Derwent World Patents Index; AN 2010-G97023, XP002669907 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449030A (en) * | 2014-12-05 | 2015-03-25 | 徐州市华阳油墨化学有限公司 | Solvent type gravure pearlescent ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2353293A1 (en) | 2011-03-01 |
| ES2353293B1 (en) | 2012-01-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5070718B2 (en) | Decorative sheet for insert molding | |
| US8349427B2 (en) | Dye migration-resistant heat transfer label | |
| WO2009087789A1 (en) | Fabric sheet changing in color with water | |
| BRPI0717264A2 (en) | SURFACE COLOR APPLICATION ARTICLES AND METHODS | |
| JP3271022B2 (en) | Decorative sheet | |
| CN103342920A (en) | Surface printed solidified matte ink and preparation method thereof | |
| KR101391622B1 (en) | The nail sticker and process method thereof | |
| CN109070536A (en) | The adhesive of unlined activates | |
| US20070264457A1 (en) | Material for Decoration | |
| JP2008087303A (en) | Decorative sheet for insert molding | |
| CN103865418B (en) | A kind of without rainbow line chemical treatment biaxial tension polyester precoating film and preparation method thereof | |
| WO2012063157A1 (en) | A tack free decorative ink composition comprising an aziridine derivative and a polyethylene / paraffin wax mixture, process and use thereof | |
| NO176832B (en) | Multilayer, flexible transfer belt, method of making this and use of the transfer belt | |
| JP2008110532A (en) | Decorative sheet and decorative material | |
| JP6815409B2 (en) | Raw material sheets and foamable paper containers used for foamable paper products | |
| DE69737697T2 (en) | ELECTRONICALLY CONTROLLED, CUTTING, MULTILAYER FILMS FOR IMAGE DISPLAYS | |
| JP2010202735A (en) | Self-adhesive sheet | |
| JP4601065B2 (en) | Pressure sensitive correction tape | |
| JP3131358U (en) | Pressure sensitive correction tape | |
| CN102325652B (en) | Film for the lamination of graphic media and production method thereof | |
| JPH06198830A (en) | Decorative sheet | |
| JP2007331136A (en) | Decorative sheet | |
| KR101078087B1 (en) | cover and manufacturing method thereof | |
| KR100553276B1 (en) | Top coated heat transfer film containing nano silver and preparation method thereof | |
| CN207659372U (en) | It is a kind of can UV printing soft wall patch |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 11784786 Country of ref document: EP Kind code of ref document: A1 |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 11784786 Country of ref document: EP Kind code of ref document: A1 |