WO2012074841A3 - Copper chromite hydrogenation catalysts for production of fatty alcohols - Google Patents

Copper chromite hydrogenation catalysts for production of fatty alcohols Download PDF

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Publication number
WO2012074841A3
WO2012074841A3 PCT/US2011/061867 US2011061867W WO2012074841A3 WO 2012074841 A3 WO2012074841 A3 WO 2012074841A3 US 2011061867 W US2011061867 W US 2011061867W WO 2012074841 A3 WO2012074841 A3 WO 2012074841A3
Authority
WO
WIPO (PCT)
Prior art keywords
fatty alcohols
catalysts
copper chromite
production
hydrogenation catalysts
Prior art date
Application number
PCT/US2011/061867
Other languages
French (fr)
Other versions
WO2012074841A2 (en
Inventor
Deepak S. Thakur
William Carrick
Original Assignee
Basf Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Corporation filed Critical Basf Corporation
Publication of WO2012074841A2 publication Critical patent/WO2012074841A2/en
Publication of WO2012074841A3 publication Critical patent/WO2012074841A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B01J35/613—
    • B01J35/633—
    • B01J35/635—
    • B01J35/66—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases

Abstract

Provided are hydrogenation catalysts for processing esters into fatty alcohols. More particularly, the catalysts are for vapor-phase hydrogenation of methyl esters to fatty alcohols under fixed-bed conditions, where conditions are typically in a temperature range of 200 to 250°C and a pressure range of 30 to 50 bar. Methods of making and using the same are also provided. These catalysts comprise a copper chromite, an alkali metal or alkaline earth metal component, and an inorganic matrix component, which are processed together to form the catalyst. The alkali metal component can comprise sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), or combinations thereof. The alkaline earth metal can comprise magnesium (Mg), calcium (Ca), barium (Ba), or combinations thereof.
PCT/US2011/061867 2010-11-30 2011-11-22 Copper chromite hydrogenation catalysts for production of fatty alcohols WO2012074841A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41806310P 2010-11-30 2010-11-30
US61/418,063 2010-11-30

Publications (2)

Publication Number Publication Date
WO2012074841A2 WO2012074841A2 (en) 2012-06-07
WO2012074841A3 true WO2012074841A3 (en) 2012-10-26

Family

ID=46127059

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/061867 WO2012074841A2 (en) 2010-11-30 2011-11-22 Copper chromite hydrogenation catalysts for production of fatty alcohols

Country Status (2)

Country Link
US (1) US9120086B2 (en)
WO (1) WO2012074841A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9120086B2 (en) * 2010-11-30 2015-09-01 Deepak S. Thakur Copper Chromite hydrogenation catalysts for production of fatty alcohols
US20160038917A1 (en) * 2014-08-11 2016-02-11 Basf Corporation Hydrogenation catalysts
BR112017020321B1 (en) * 2015-03-26 2021-01-26 Basf Corporation catalyst, method for making a catalyst, and, process
FR3065175A1 (en) * 2017-04-14 2018-10-19 IFP Energies Nouvelles PROCESS FOR PROCESSING ALCOHOLS WITH SOLID COPPER CATALYSTS AND AN ELEMENT SELECTED AMONG NA, CA, BA AND K
US11440863B2 (en) * 2019-06-12 2022-09-13 Evonik Operations Gmbh Process for preparing an alcohol from hydrocarbons

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4666879A (en) * 1985-09-11 1987-05-19 Harshaw/Filtrol Partnership Extruded copper chromite-alumina hydrogenation catalyst
US5030609A (en) * 1987-07-29 1991-07-09 Davy Mckee (London) Limited Process for producing a hydrogenation catalyst of copper chromite
US5043485A (en) * 1987-07-22 1991-08-27 Henkel Kommanditgesellschaft Auf Aktien Process for the hydrogenation of fatty acid methyl ester mixtures
EP0494898B1 (en) * 1989-10-04 1995-02-15 Henkel Kommanditgesellschaft auf Aktien Process for producing acid-resistant catalysts for the direct hydration of carboxylic acids into alcohols

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3216954A (en) * 1959-07-22 1965-11-09 Du Pont Mangano-chromia-manganite catalyst and process for its production
US3756964A (en) * 1972-04-26 1973-09-04 Supported copper chromite catalyst
US4199479A (en) * 1978-02-24 1980-04-22 Chevron Research Company Hydrogenation catalyst
JPS5620541A (en) * 1979-07-30 1981-02-26 Mitsubishi Chem Ind Ltd Preparation of cyclohexanone
JPS6045938B2 (en) * 1981-04-30 1985-10-12 宇部興産株式会社 Method for producing oxalic acid diester hydrogenation catalyst
DE3706658A1 (en) * 1987-03-02 1988-09-15 Henkel Kgaa ACID-RESISTANT CATALYST FOR FATTY ACID DIRECT REHYDRATION TO FATTY ALCOHOLS
US5345005A (en) 1989-09-12 1994-09-06 Engelhard Corporation Hydrogenation catalyst, process for preparing and process of using said catalyst
DE4000692A1 (en) * 1990-01-12 1991-07-18 Henkel Kgaa USE OF COLLOIDAL SILICA AS ALUMINUM FOR CATALYSTS
DE4037729C2 (en) * 1990-11-27 1996-05-30 Sued Chemie Ag Si0¶2¶-containing copper oxide-chromium oxide catalyst and its use for the hydrogenation of fatty acids and esters
US5124295A (en) 1990-12-13 1992-06-23 Engelhard Corporation Copper chromite catalyst and process for preparation said catalyst
US5977010A (en) 1995-06-15 1999-11-02 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
US6992037B2 (en) 2001-09-17 2006-01-31 Engelhard Corporation Precious metal catalyst for debenzylation
DE102004055189B4 (en) 2004-11-16 2007-02-08 Süd-Chemie AG Process for the hydrogenation of acetophenone
WO2011078354A1 (en) * 2009-12-25 2011-06-30 東ソー株式会社 Hydrogenation catalyst, process for production thereof, and use thereof
US9120086B2 (en) * 2010-11-30 2015-09-01 Deepak S. Thakur Copper Chromite hydrogenation catalysts for production of fatty alcohols

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4666879A (en) * 1985-09-11 1987-05-19 Harshaw/Filtrol Partnership Extruded copper chromite-alumina hydrogenation catalyst
US5043485A (en) * 1987-07-22 1991-08-27 Henkel Kommanditgesellschaft Auf Aktien Process for the hydrogenation of fatty acid methyl ester mixtures
US5030609A (en) * 1987-07-29 1991-07-09 Davy Mckee (London) Limited Process for producing a hydrogenation catalyst of copper chromite
EP0494898B1 (en) * 1989-10-04 1995-02-15 Henkel Kommanditgesellschaft auf Aktien Process for producing acid-resistant catalysts for the direct hydration of carboxylic acids into alcohols

Also Published As

Publication number Publication date
WO2012074841A2 (en) 2012-06-07
US9120086B2 (en) 2015-09-01
US20120136179A1 (en) 2012-05-31

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