WO2012088078A3 - Process to produce biofuels from biomass - Google Patents

Process to produce biofuels from biomass Download PDF

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Publication number
WO2012088078A3
WO2012088078A3 PCT/US2011/066101 US2011066101W WO2012088078A3 WO 2012088078 A3 WO2012088078 A3 WO 2012088078A3 US 2011066101 W US2011066101 W US 2011066101W WO 2012088078 A3 WO2012088078 A3 WO 2012088078A3
Authority
WO
WIPO (PCT)
Prior art keywords
biomass
aqueous
stream
digestive solvent
extracted
Prior art date
Application number
PCT/US2011/066101
Other languages
French (fr)
Other versions
WO2012088078A2 (en
Inventor
Joseph Broun Powell
Juben Nemchand Chheda
Original Assignee
Shell Oil Company
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Oil Company, Shell Internationale Research Maatschappij B.V. filed Critical Shell Oil Company
Priority to BR112013015552A priority Critical patent/BR112013015552A2/en
Priority to EP11815822.9A priority patent/EP2655218A2/en
Priority to AU2011349380A priority patent/AU2011349380B2/en
Priority to CN201180067593.8A priority patent/CN103370398B/en
Priority to CA2821511A priority patent/CA2821511A1/en
Publication of WO2012088078A2 publication Critical patent/WO2012088078A2/en
Publication of WO2012088078A3 publication Critical patent/WO2012088078A3/en
Priority to ZA2013/04321A priority patent/ZA201304321B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/44—Solvents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

Processes to produce biofuels from biomass is provided where the biomass is contacted with an aqueous media to form a extracted biomass and at least a portion of an aqueous liquor separated from the extracted biomass containing soluble carbohydrate is treated with a purification substrate to form a treated carbohydrate stream having less than 35% of the sulfur content and less than 35% of the nitrogen content, based on the untreated aqueous liquor stream prior to contact with an aqueous phase reforming catalyst to form a plurality of oxygenated intermediates that can be further processed to form a liquid fuel. An extracted biomass solids stream is also separated from the extracted biomass which is contacted with a first digestive solvent to form a pretreated biomass comprising celluloses and residual hemicelluloses and then a second digestive solvent to form a solubilized pulp comprising soluble carbohydrates. This solublilized pulp may be combined with the aqueous liquor stream or combined to an aqueous reforming reaction system or recycled to the aqueous media to be processed further for an effective process to produce the liquid fuel. At least a portion of the oxygenated intermediates is used as the second digestive solvent.
PCT/US2011/066101 2010-12-20 2011-12-20 Process to produce biofuels from biomass WO2012088078A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BR112013015552A BR112013015552A2 (en) 2010-12-20 2011-12-20 method and system
EP11815822.9A EP2655218A2 (en) 2010-12-20 2011-12-20 Process to produce biofuels from biomass
AU2011349380A AU2011349380B2 (en) 2010-12-20 2011-12-20 Process to produce biofuels from biomass
CN201180067593.8A CN103370398B (en) 2010-12-20 2011-12-20 The method of biofuel is produced from biomass
CA2821511A CA2821511A1 (en) 2010-12-20 2011-12-20 Process to produce biofuels from biomass
ZA2013/04321A ZA201304321B (en) 2010-12-20 2013-06-12 Process to produce biofuels from biomass

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201061424791P 2010-12-20 2010-12-20
US61/424,791 2010-12-20

Publications (2)

Publication Number Publication Date
WO2012088078A2 WO2012088078A2 (en) 2012-06-28
WO2012088078A3 true WO2012088078A3 (en) 2012-10-04

Family

ID=45563496

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/066101 WO2012088078A2 (en) 2010-12-20 2011-12-20 Process to produce biofuels from biomass

Country Status (8)

Country Link
US (1) US9102879B2 (en)
EP (1) EP2655218A2 (en)
CN (1) CN103370398B (en)
AU (1) AU2011349380B2 (en)
BR (1) BR112013015552A2 (en)
CA (1) CA2821511A1 (en)
WO (1) WO2012088078A2 (en)
ZA (1) ZA201304321B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012088092A2 (en) * 2010-12-20 2012-06-28 Shell Oil Company Process to produce biofuels from biomass
EP2720992B1 (en) 2011-06-14 2015-07-29 Shell Internationale Research Maatschappij B.V. Co-production of biofuels and glycols
CA2859319C (en) * 2011-12-16 2018-03-06 Shell Internationale Research Maatschappij B.V. Biomass conversion systems having a fluid circulation loop containing a centripetal force-based separation mechanism for control of cellulosic fines and methods for use thereof
US9416077B2 (en) 2012-09-14 2016-08-16 Sundrop Fuels, Inc. Renewable carbon content in methanol and other products from gasification of biomass
WO2014058686A1 (en) * 2012-10-08 2014-04-17 Shell Oil Company Lignocellulosic biomass conversion
CN104560102B (en) * 2013-10-29 2016-05-18 中国石油化工股份有限公司 A kind of method that improves quality of bio-oil
CN104974856A (en) * 2014-04-08 2015-10-14 中国石油化工股份有限公司 Preparation method of biodiesel
WO2017035240A1 (en) * 2015-08-27 2017-03-02 Solix Algredients, Inc. Methods and systems for extracting products from biological material using ion exchange resin
CN109609232B (en) * 2018-12-01 2021-04-16 郑州轻工业学院 Straw biomass pretreatment process
GB201903080D0 (en) * 2019-03-07 2019-04-24 Oxford Sustainable Fuels Ltd Process
CN110963463B (en) * 2019-12-27 2023-10-20 广东蓝玖新能源科技有限公司 Inflation packaging system and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3105095A (en) * 1959-04-07 1963-09-24 Inst Noguchi Process of liquefaction of lignin
US20080216391A1 (en) * 2007-03-08 2008-09-11 Cortright Randy D Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
US20080312346A1 (en) * 2007-06-15 2008-12-18 Mccall Michael J Conversion of Lignocellulosic Biomass to Chemicals and Fuels
WO2010025241A2 (en) * 2008-08-27 2010-03-04 Virent Energy Systems, Inc. Synthesis of liquid fuels from biomass

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012088092A2 (en) * 2010-12-20 2012-06-28 Shell Oil Company Process to produce biofuels from biomass
CN104039928B (en) * 2011-12-16 2016-04-13 国际壳牌研究有限公司 The system and method for conversion of biomass

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3105095A (en) * 1959-04-07 1963-09-24 Inst Noguchi Process of liquefaction of lignin
US20080216391A1 (en) * 2007-03-08 2008-09-11 Cortright Randy D Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
US20080312346A1 (en) * 2007-06-15 2008-12-18 Mccall Michael J Conversion of Lignocellulosic Biomass to Chemicals and Fuels
WO2010025241A2 (en) * 2008-08-27 2010-03-04 Virent Energy Systems, Inc. Synthesis of liquid fuels from biomass

Non-Patent Citations (11)

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Title
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ELINOR SCOTT ET AL.: "BIOMASS IN THE MANUFACTURE OF INDUSTRIAL PRODUCTS-THE USE OF PROTEINS AND AMINO ACIDS", APPL MICROBIOL BIOTECHNOL., vol. 75, 27 March 2007 (2007-03-27), pages 751 - 762, XP002679360 *
ELISABETE BARBARINO ET AL: "AN EVALUATION OF METHODS FOR EXTRACTION AND QUANTIFICATION OF PROTEIN FROM MARINE MACRO AND MICROALGAE", JOURNAL OF APPLIED PHYCOLOGY, vol. 17, 31 December 2005 (2005-12-31), pages 447 - 460, XP002679361 *
GEORGE W HUBER ET AL: "PRODUCTION OF LIQUID ALKANES BY AQUEOUS PHASE PROCESSING OF BIOMASS DERIVED CARBOHYDRATES", SCIENCE, vol. 308, 3 May 2005 (2005-05-03), pages 1446 - 1450, XP002677266 *
GEORGE W HUBER ET AL: "RENEWABLE ALKANES BY AQUEOUS PHSE REFORMING OF BIOMASS DERIVED OXYGENATES", RENEWABLE ALKANES BY AQUEOUS PHSE REFORMING OF BIOMASS DERIVED OXYGENATES,, vol. 43, 31 December 2004 (2004-12-31), pages 1549 - 1551, XP002677267 *
JEAN-PAUL LANGE ET AL: "VALERIC BIOFUELS: A PLATFORM OF CELLULOSIC TRANSPORTATION FUELS", VALERIC BIOFUELS: A PLATFORM OF CELLULOSIC TRANSPORTATION FUELS,, vol. 49, 6 May 2010 (2010-05-06), pages 4479 - 4483, XP002677265 *
JUAN CARLOS SERRANO-RUIZ ET AL: "CONVERSION OF CELLULOSE TO HYDROCARBON FUELS BY PROGRESSIVE REMOVAL OF OXYGEN", CONVERSION OF CELLULOSE TO HYDROCARBON FUELS BY PROGRESSIVE REMOVAL OF OXYGEN,, vol. 100, 4 August 2010 (2010-08-04), pages 184 - 189, XP002677264 *
KAZUHISA MURATA ET AL: "HYDROCRACKING OF BIOMASS DERIVED MATERIALS INTO ALKANES IN THE PRESENCE OF PLATINUM-BASED CATALYST AND HYDROGEN", HYDROCRACKING OF BIOMASS DERIVED MATERIALS INTO ALKANES IN THE PRESENCE OF PLATINUM-BASED CATALYST AND HYDROGEN,, vol. 140, 18 August 2010 (2010-08-18), pages 8 - 13, XP002677262 *
MARIEFEL B. VALENZUELA ET AL.: "BATCH AQUEOUS PHASE REFORMING OF WOODY BIOMASS", ENERGY AND FUELS, vol. 20, 22 June 2006 (2006-06-22), pages 1744 - 1752, XP002679148 *
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Also Published As

Publication number Publication date
ZA201304321B (en) 2014-03-26
US9102879B2 (en) 2015-08-11
BR112013015552A2 (en) 2016-09-20
US20120174471A1 (en) 2012-07-12
CN103370398A (en) 2013-10-23
CN103370398B (en) 2016-03-23
WO2012088078A2 (en) 2012-06-28
AU2011349380B2 (en) 2015-07-09
EP2655218A2 (en) 2013-10-30
CA2821511A1 (en) 2012-06-28
AU2011349380A1 (en) 2013-07-04

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