WO2012134715A3 - Branched vinyl terminated polymers and methods for production thereof - Google Patents

Branched vinyl terminated polymers and methods for production thereof Download PDF

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Publication number
WO2012134715A3
WO2012134715A3 PCT/US2012/027675 US2012027675W WO2012134715A3 WO 2012134715 A3 WO2012134715 A3 WO 2012134715A3 US 2012027675 W US2012027675 W US 2012027675W WO 2012134715 A3 WO2012134715 A3 WO 2012134715A3
Authority
WO
WIPO (PCT)
Prior art keywords
production
methods
vinyl terminated
terminated polymers
branched vinyl
Prior art date
Application number
PCT/US2012/027675
Other languages
French (fr)
Other versions
WO2012134715A2 (en
Inventor
Peijun Jiang
Patrick Brant
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to EP20120762766 priority Critical patent/EP2688923A4/en
Priority to JP2014501090A priority patent/JP5793820B2/en
Priority to CN2012800147768A priority patent/CN103443137A/en
Publication of WO2012134715A2 publication Critical patent/WO2012134715A2/en
Publication of WO2012134715A3 publication Critical patent/WO2012134715A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

Abstract

This invention relates to a process for polymerization, comprising (i) contacting, at a temperature greater than 35°C, one or more monomers comprising ethylene and/or propylene, with a catalyst system comprising a metallocene catalyst compound and an activator, (ii) converting at least 50 mol% of the monomer to polyolefin; and (iii) obtaining a branched polyolefin having greater than 50% allyl chain ends, relative to total unsaturated chain ends. The invention also relates to the branched polyolefins and functionalized branched polyolefins.
PCT/US2012/027675 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof WO2012134715A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP20120762766 EP2688923A4 (en) 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof
JP2014501090A JP5793820B2 (en) 2011-03-25 2012-03-05 Branched vinyl-terminated polymer and process for producing the same
CN2012800147768A CN103443137A (en) 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201161467681P 2011-03-25 2011-03-25
US61/467,681 2011-03-25
EP11165831 2011-05-12
EP11165831.6 2011-05-12

Publications (2)

Publication Number Publication Date
WO2012134715A2 WO2012134715A2 (en) 2012-10-04
WO2012134715A3 true WO2012134715A3 (en) 2013-01-17

Family

ID=46932222

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/027675 WO2012134715A2 (en) 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof

Country Status (4)

Country Link
EP (1) EP2688923A4 (en)
JP (1) JP5793820B2 (en)
CN (1) CN103443137A (en)
WO (1) WO2012134715A2 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014189776A (en) * 2013-03-28 2014-10-06 Mitsubishi Chemicals Corp Modified propylenic polymer composition
CN105377904B (en) 2013-07-17 2018-07-10 埃克森美孚化学专利公司 Metallocene and by its derivative carbon monoxide-olefin polymeric
WO2015009473A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
JP2016530360A (en) 2013-07-17 2016-09-29 エクソンモービル ケミカル パテンツ インコーポレイテッド Process using substituted metallocene catalysts and products derived therefrom
WO2015009479A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9644047B2 (en) 2013-07-17 2017-05-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
TWI559186B (en) 2013-12-13 2016-11-21 Ｌｇ化學股份有限公司 Touch sensor and display device
US9193813B2 (en) * 2014-03-31 2015-11-24 Exxonmobil Chemical Patents Inc. Phenylene-bridged salalen catalysts
US9988471B2 (en) 2015-12-16 2018-06-05 Exxonmobil Chemical Patents Inc Catalysts for producing polymers with enhanced properties
KR101810317B1 (en) * 2016-04-06 2017-12-19 롯데케미칼 주식회사 High melt strength polypropylene resin composition
EP3778669A4 (en) 2018-05-04 2021-07-28 Lg Chem, Ltd. Adhesive composition comprising ethylene/alpha-olefin copolymer
US20220282004A1 (en) * 2019-08-02 2022-09-08 Exxonmobil Chemical Patents Inc. Non-Coordinating Anion Type Activators for use with Polyolefin Polymerization Catalysts
KR20220152224A (en) * 2020-02-11 2022-11-15 엑손모빌 케미칼 패턴츠 인코포레이티드 Ethylene-alpha-olefin-diene monomer copolymer obtained using transition metal bis(phenolate) catalyst complex and method for homogeneous preparation thereof
JP7024842B2 (en) * 2020-10-16 2022-02-24 日本ポリプロ株式会社 Propene homopolymer

Citations (3)

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Publication number Priority date Publication date Assignee Title
US6197910B1 (en) * 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6897261B1 (en) * 1999-07-26 2005-05-24 Idemitsu Kosan Co., Ltd. Branched olefinic macromonomer, olefin graft copolymer, and olefin resin composition
US20060052553A1 (en) * 2002-12-04 2006-03-09 Basell Polyolefine Gmbh Process for preparing 1-butene polymers

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EP0268214B1 (en) 1986-11-13 1991-08-21 Idemitsu Kosan Company Limited Process for producing propylene oligomers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US20030050411A1 (en) * 2001-06-12 2003-03-13 Dow Global Technologies Inc. Use of polar monomers in olefin polymerization and polymers thereof
CN100588663C (en) * 2002-10-15 2010-02-10 埃克森美孚化学专利公司 Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) * 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
CN101724110B (en) * 2002-10-15 2013-03-27 埃克森美孚化学专利公司 Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7439312B2 (en) * 2002-10-24 2008-10-21 Exxonmobil Chemical Patents Inc. Branched crystalline polypropylene
US8288480B2 (en) * 2005-06-22 2012-10-16 Exxonmobil Chemical Patents Inc. In-reactor polymer blends
JP5286154B2 (en) * 2008-05-13 2013-09-11 日本ポリプロ株式会社 Propylene polymer
US8399725B2 (en) * 2008-06-20 2013-03-19 Exxonmobil Chemical Patents Inc. Functionalized high vinyl terminated propylene based oligomers
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US7799879B2 (en) * 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
WO2010074815A1 (en) * 2008-12-15 2010-07-01 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6197910B1 (en) * 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6897261B1 (en) * 1999-07-26 2005-05-24 Idemitsu Kosan Co., Ltd. Branched olefinic macromonomer, olefin graft copolymer, and olefin resin composition
US20060052553A1 (en) * 2002-12-04 2006-03-09 Basell Polyolefine Gmbh Process for preparing 1-butene polymers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
See also references of EP2688923A4 *
WENG, W. ET AL.: "Long Chain Branched Isotactic Polypropylene.", MACROMOLECULES, vol. 35, 2002, pages 3838 - 3843, XP002668104 *

Also Published As

Publication number Publication date
JP5793820B2 (en) 2015-10-14
EP2688923A2 (en) 2014-01-29
JP2014508848A (en) 2014-04-10
CN103443137A (en) 2013-12-11
WO2012134715A2 (en) 2012-10-04
EP2688923A4 (en) 2015-05-20

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