WO2013032283A2

WO2013032283A2 - Liquid crystal cell

Info

Publication number: WO2013032283A2
Application number: PCT/KR2012/007007
Authority: WO
Inventors: 오동현; 김경준; 민성준; 유정선
Original assignee: 주식회사 엘지화학
Priority date: 2011-08-31
Filing date: 2012-08-31
Publication date: 2013-03-07
Also published as: WO2013032283A3

Abstract

The present application relates to a liquid crystal cell, to a precursor of a liquid crystal layer, to a method for manufacturing the liquid crystal cell, and to usages of the liquid crystal cell. Exemplary liquid crystal cells of the present application can be simply and continuously manufactured through, for example, a roll-to-roll process or the like. The liquid crystal cell can also be implemented in a flexible device, and may ensure a superior contrast ratio. The above-described liquid crystal cell may be applied to various usages such as a smart window, a window protection film, a flexible display device, and an active retarder or view angle adjusting film for a 3D image display.

Description

Liquid crystal cell

The present application relates to a liquid crystal cell, a precursor of a liquid crystal layer, a method for producing a liquid crystal cell, and a use of a liquid crystal cell.

Liquid Crystal Display (LCD) orientates a nematic or smectic liquid crystal compound in a certain direction, and switches an orientation through application of a voltage to implement an image. The manufacturing process of the LCD is a costly process requiring a complicated process, so a large production line and equipment are required.

Among the proposed methods to solve the problem of the LCD manufacturing process, so-called Polymer Dispersed Liquid Crystal implemented by dispersing the liquid crystal in the polymer matrix, the term PDLC in the present specification is the so-called Polymer Network Liquid Crystal (PNLC) or Polymer Stabilized Liquid Crystal ) Is a higher concept including, etc.) Devices are known. Since PDLC can be manufactured by coating a liquid crystal solution, it can be manufactured by a simpler process than a conventional LCD.

Within the PDLC, the liquid crystal compound is usually in an unoriented state. Thus, PDLC is cloudy and opaque in the absence of voltage. When a voltage is applied to the PDLC, the liquid crystal compounds are aligned accordingly, thereby making it possible to switch between transparent and opaque states. However, compared to conventional LCDs in which black and white are switched between two polarizers, PDLC has a significantly lower contrast ratio.

The present application provides a liquid crystal cell, a precursor of the liquid crystal layer, a manufacturing method of the liquid crystal cell and the use of the liquid crystal cell.

An exemplary liquid crystal cell includes a liquid crystal layer. In the above, the liquid crystal layer may include an alignment network and a liquid crystal region. The liquid crystal region includes a liquid crystal compound and may be included inside the alignment network.

The term “liquid crystal region” refers to a region containing a liquid crystal compound, and may refer to a region dispersed in the network in a state separated from the orientation network.

The oriented network can be a network of precursors comprising an oriented compound. The term “network of precursors comprising an oriented compound” may mean, for example, a polymer network comprising a precursor comprising an oriented compound or a polymer network comprising such precursors crosslinked or polymerized.

The term "orientation compound" is, for example, aligned in a predetermined direction through irradiation of light or the like, and the adjacent liquid crystal compound is determined through an interaction such as anisotropic interaction in the aligned state. It can mean a compound that can be oriented in the direction. The compound may be a monomolecular compound, a monomeric compound, an oligomeric compound, or a high molecular compound. As an oriented compound, a photo-alignment compound can be used, for example. The photo-alignment compound may refer to a compound which can be aligned in a predetermined direction by irradiation of light, for example, irradiation of linearly polarized light, to induce alignment of adjacent liquid crystal compounds.

The photoalignable compound may be a compound including a photosensitive moiety. Various photo-alignment compounds that can be used for the alignment of the liquid crystal compound are known. Photo-alignment compounds include, for example, compounds aligned by trans-cis photoisomerization; Compounds aligned by photo-destruction, such as chain scission or photo-oxidation; Compounds ordered by photocrosslinking or photopolymerization such as [2 + 2] addition cyclization ([2 + 2] cycloaddition), [4 + 4] addition cyclization or photodimerization; Compounds aligned by photo-Fries rearrangement or compounds aligned by ring opening / closure reaction may be used. As the compound aligned by trans-cis photoisomerization, for example, azo compounds or stilbenes, such as sulfated diazo dyes or azo polymers, may be exemplified. And, as the compound aligned by photolysis, cyclobutane tetracarboxylic dianhydride (cyclobutane-1,2,3,4-tetracarboxylic dianhydride), aromatic polysilane or polyester, polystyrene or polyimide and the like can be exemplified. In addition, as a compound aligned by photocrosslinking or photopolymerization, a cinnamate compound, a coumarin compound, a cinnanam compound, a tetrahydrophthalimide compound, a maleimide compound , Benzophenone compounds, diphenylacetylene compounds, compounds having chalconyl residues (hereinafter referred to as chalconyl compounds) or compounds having anthracenyl residues (hereinafter referred to as anthracenyl compounds) as photosensitive residues; This may be exemplified, and examples of the compounds aligned by the optical freeze rearrangement include aromatic compounds such as benzoate compounds, benzoamide compounds, and methacrylamidoaryl methacrylate compounds. It may be exemplified, the compound aligned by the ring-opening / ring-closure reaction, such as a spiropyran compound A [4 + 2] π electron system ([4 + 2] π electronic system), but may be exemplified by compounds such as sorting by a ring opening / ring-closure reaction of, without being limited thereto.

The photo-alignment compound may be a monomolecular compound, a monomeric compound, an oligomeric compound, or a high molecular compound, or may be in the form of a blend of the photo-alignment compound and the polymer. The oligomeric or polymeric compound as described above may have a residue derived from the above-described photoalignable compound or a photosensitive residue described above in the main chain or in the side chain.

Polymers having residues or photosensitive residues derived from photo-alignment compounds or that can be mixed with the photo-alignment compounds include polynorbornene, polyolefins, polyarylates, polyacrylates, poly (meth) acrylates, poly Examples include mead, poly (amic acid), polymaleimide, polyacrylamide, polymethacrylamide, polyvinyl ether, polyvinyl ester, polystyrene, polysiloxane, polyacrylonitrile or polymethacrylonitrile It may be, but is not limited thereto.

Polymers that may be included in the oriented compound are typically polynorbornene cinnamates, polynorbornene alkoxy cinnamates, polynorbornene allylyloxy cinnamates, polynorbornene fluorinated cinnamates, polynorbornene chlorinated cinnamates or Polynorbornene discinnamate and the like can be exemplified, but is not limited thereto.

When the oriented compound is a polymeric compound, the compound may have, for example, a number average molecular weight of about 10,000 g / mol to about 500,000 g / mol, but is not limited thereto.

In the orientation network, the orientation compound is orientationally ordered, and the liquid crystal compound of the liquid crystal region may exist in a state that is oriented by the network in the alignment state without voltage application.

For example, the alignment compound may simply be included in the alignment network in the alignment state or crosslinked and / or polymerized in the alignment state to form the orientation network.

The oriented compound may include one or more crosslinkable or polymerizable functional groups to crosslink or polymerize to form an oriented network. As a crosslinkable or polymeric functional group, the functional group which reacts by application of heat or irradiation of active energy rays, such as an ultraviolet-ray, can be used, for example. Such functional groups include alkenyl groups such as hydroxy groups, carboxyl groups, vinyl groups or allyl groups, epoxy groups, oxetanyl groups, vinyl ether groups, cyano groups, acryloyl groups, methacryloyl groups, acryloyloxy groups or methacrylo Iloxy group and the like can be exemplified but is not limited thereto. Such functional groups include, for example, functional groups capable of participating in a crosslinking or polymerization reaction by radical reaction or cationic reaction by heat or irradiation of active energy rays or under a basic environment. Such functional groups may be introduced into, for example, the main chain or side chain of the alignment compound.

The precursor forming the oriented network may further comprise a crosslinking agent. The crosslinking agent may be added to control the afterimage or strength of the liquid crystal cell. As a crosslinking agent, the compound which can implement | achieve a crosslinked structure by reacting with an orientation compound by the application of heat or irradiation of an active energy ray, for example can be used. Various crosslinking agents which can implement a crosslinking structure are known according to a high molecular compound. For example, as a crosslinking agent, it is a polyhydric compound which has two or more functional groups, and isocyanate compound, an epoxy compound, an isothiocyanate compound, a vinyl ether compound, an alcohol, an amine compound, a thiol compound, a carboxylic acid compound, an aziridine compound, or a metal Chelating compounds and the like.

As a crosslinking agent capable of participating in a crosslinking reaction by irradiation of active energy rays such as ultraviolet rays, for example, alkenyl groups such as vinyl or allyl groups, epoxy groups, oxetanyl groups, vinyl ether groups, acryloyl groups, methacryloyl groups, Compounds containing two or more acryloyloxy groups or methacryloyloxy groups may be used. As such a compound, polyfunctional acrylate etc. can be illustrated typically. As polyfunctional acrylate, trimethylolpropane tri (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) ) Acrylate, dipentaerythritol hexa (meth) acrylate, triglycerol di (meth) acrylate, tripropylene glycol di (meth) acrylate, tetraethylene glycol di (meth) acrylate, pentaerythritol di (Meth) acrylate, 1,6-hexanediol di (meth) acrylate, glycerol di (meth) acrylate, tris [2- (acryloyloxy) ethyl] isocyanurate, urethane acrylate, glycerol 1 , 3-diglycerol di (meth) acrylate or tri (propylene glycol) glycerol diacrylate, and the like can be exemplified, but is not limited thereto.

The crosslinking agent may be included in an appropriate ratio in consideration of the degree of control and intensity of the afterimage, the phase separation characteristics of the liquid crystal region and the alignment network, the anchoring characteristics, the photosensitivity, the dielectric constant and the refractive index, and the like. For example, the precursor of the oriented network is 0.1 part by weight to 100 parts by weight, 5 parts by weight to 100 parts by weight, 10 parts by weight to 90 parts by weight, 10 parts by weight to 80 parts by weight, 10 parts by weight of 100 parts by weight of the orientation compound. It may comprise from about 70 parts by weight, about 10 parts by weight to about 60 parts by weight, or about 10 parts by weight to about 50 parts by weight of the crosslinking agent. The proportion of the crosslinking agent may be changed depending on the kind of the crosslinking agent and the alignment compound used. In the present specification, the unit weight part may mean a ratio of weight between components, unless otherwise specified.

Precursors of the oriented network may further comprise additives such as solvents, radical or cationic initiators, basic materials, other reactive compounds or surfactants capable of forming the network, if necessary.

The alignment network may satisfy the following Equation 1 together with the liquid crystal compound in the liquid crystal region.

Equation 1

(1-a) × {(2n _o ² + n _e ² ) / 3} ^0.5 <n _p <(1 + a) × {(2n _o ² + n _e ² ) / 3} ^0.5

In Equation 1, n _p is the refractive index of the oriented network, n _o is the ordinary refractive index of the liquid crystal compound, n _e is the extraordinary refractive index of the liquid crystal compound, a is 0 ≤ a <0.5 Is a number that satisfies

The refractive index may be, for example, a refractive index measured for light having a wavelength of 550 nm. In addition, when the normal refractive index and the abnormal refractive index of an oriented network differ, the term refractive index of an oriented network used in this specification means the normal refractive index of the said network. By selecting the orientation network and the liquid crystal compound so as to satisfy the above formula 1, it is possible to provide an element excellent in transparency and excellent in contrast ratio even under no voltage application.

In Equation 1, a may be, for example, less than 0.4, less than 0.3, less than 0.2, less than 0.1, or 0.

The oriented network may also have a dielectric anisotropy of at least 3, at least 3.5 or at least 4. It is possible to maintain excellent driving voltage characteristics of the liquid crystal cell in the dielectric constant range. The upper limit of the dielectric constant is not particularly limited and may be, for example, about 20 or less, about 15 or less, or about 10 or less.

The liquid crystal region dispersed in the orientation network contains a liquid crystal compound. As the liquid crystal compound, any kind of compound may be used as long as it can be phase-separated in the orientation network and exist in an orientation oriented by the orientation network. For example, a smectic liquid crystal compound, a nematic liquid crystal compound, or a cholesteric liquid crystal compound may be used as the liquid crystal compound. The liquid crystal compound may be in a phase-separated state, which is not coupled to the orientation network, and may change in orientation when a voltage is applied from the outside. For this purpose, for example, the liquid crystal compound may be a compound having no polymerizable group or crosslinkable group.

In one example, a nematic liquid crystal compound may be used as the liquid crystal compound. As said compound, the nematic liquid crystal compound which satisfy | fills following formula 2 can be used, for example.

[Formula 2]

(1.53-b) <{(2n _o ² + n _e ² ) / 3} ^0.5 <(1.53 + b)

In Equation 2, n _o is the normal refractive index of the liquid crystal compound defined in Equation 1, for example, the refractive index in the uniaxial direction of the nematic liquid crystal compound, n _e is the extraordinary index of the liquid crystal compound defined in Equation 1 refractive index), for example, a refractive index in the long axis direction of the nematic liquid crystal compound, and b is a number satisfying 0.1 = b = 1.

By selecting a liquid crystal compound that satisfies the formula (2), it is possible to produce a liquid crystal cell that ensures excellent transparency even when no voltage is applied.

In Formula 2, b may be 0.1 to 0.9, 0.1 to 0.7, 0.1 to 0.5, or 0.1 to 0.3 in another example.

Liquid crystal compounds also have a difference between an ideal dielectric constant (ε _e , an extraordinary dielectric anisotropy) and a normal dielectric constant (ε _o , an ordinary dielectric anisotropy, a uniaxial dielectric constant) of at least 3, at least 3.5, at least 4, at least 6, 8 or more or 10 or more. Having such a dielectric constant can provide a device having excellent driving voltage characteristics. The difference in the dielectric constant is that the higher the numerical value, the more the device can exhibit appropriate characteristics, and its upper limit is not particularly limited. For example, the liquid crystal compound has an ideal dielectric constant (ε _e , extraordinary dielectric anisotropy) of about 6 to 50, and a normal dielectric constant (ε _o , ordinary dielectric anisotropy, dielectric constant in the uniaxial direction) of about 2.5 to 7 Phosphorus compounds can be used.

The liquid crystal compound of the liquid crystal region in the liquid crystal cell is 100 parts by weight to 2,500 parts by weight, 100 parts by weight to 2,000 parts by weight, 100 parts by weight to 1,900 parts by weight, 100 parts by weight to 1,800 parts by weight, 100 parts by weight based on 100 parts by weight of the alignment network. To 1,700 parts by weight, 100 to 1,600 parts by weight, 100 to 1,500 parts by weight, 100 to 1,400 parts by weight, 100 to 1,300 parts by weight, 100 to 1,200 parts by weight, 100 parts by weight to 1,100 parts by weight, 100 parts by weight to 1,000 parts by weight, 100 parts by weight to 900 parts by weight, 100 parts by weight to 800 parts by weight, 100 parts by weight to 700 parts by weight, 100 parts by weight to 600 parts by weight, 100 parts by weight to 500 parts by weight 100 parts by weight to 400 parts by weight, 100 parts by weight to 300 parts by weight, or 150 parts by weight to about 250 parts by weight. The ratio of the liquid crystal compound can be changed as necessary. The liquid crystal cell can exhibit excellent transparency even in a state where no voltage is applied. For example, the liquid crystal cell may exhibit a light transmittance of 80% or more, 85% or more, 90% or more, or 95% or more in a voltage-free state. The light transmittance may be a light transmittance for a visible light region, for example, a wavelength in the range of about 400 nm to 700 nm.

The liquid crystal cell may further include one or two or more base layers. The liquid crystal layer may be formed on the surface of the substrate layer or between two or more substrate layers. For example, the liquid crystal cell further includes a base layer facing each other, and the liquid crystal layer may be present between the opposite base layer. FIG. 1 illustrates an example including a liquid crystal layer 102 that is disposed between

base layers

101A and 101B spaced apart from each other at predetermined intervals, and includes an orientation network 1021 and a liquid crystal region 1022. Typical liquid crystal cell is shown. In FIG. 1, the liquid crystal compound is indicated by an arrow in the liquid crystal region 1022.

As a base material layer, a well-known material can be used without a restriction | limiting in particular. For example, inorganic films, plastic films, etc., such as a glass film, a crystalline or amorphous silicon film, a quartz, or an Indium Tin Oxide (ITO) film, can be used. As a base material layer, the optically isotropic base material layer, the optically anisotropic base material layer like a retardation layer, a polarizing plate, a color filter substrate, etc. can be used.

Examples of the plastic substrate layer include triacetyl cellulose (TAC); COP (cyclo olefin copolymer) such as norbornene derivatives; Poly (methyl methacrylate); PC (polycarbonate); PE (polyethylene); PP (polypropylene); PVA (polyvinyl alcohol); DAC (diacetyl cellulose); Pac (Polyacrylate); PES (poly ether sulfone); PEEK (polyetheretherketon PPS (polyphenylsulfone), PEI (polyetherimide); PEN (polyethylenemaphthatlate); PET (polyethyleneterephtalate); PI (polyimide); PSF (polysulfone); PAR (polyarylate) or amorphous fluorine resin The substrate layer may include a coating layer of a silicon compound such as gold, silver, silicon dioxide or silicon monoxide, or a coating layer such as an antireflection layer, if necessary.

An electrode layer may be included on the surface of the substrate layer, for example, the surface of the substrate layer on the liquid crystal layer side (for example, the surface of the

substrate layer

101A or 101B in contact with the liquid crystal layer 102 in FIG. 1). For example, it may be formed by depositing a conductive polymer, a conductive metal, a conductive nanowire, or a metal oxide such as indium tin oxide (ITO), etc. The electrode layer may be formed to have transparency. Various materials and formation methods capable of forming the electrode layer are known, and all of these methods can be applied, and if necessary, the electrode layer formed on the surface of the base layer may be appropriately patterned.

The liquid crystal cell may further include a polarizing plate disposed on one side or both sides of the liquid crystal layer. As the polarizing plate, a conventional material used in an existing LCD may be used without particular limitation. When the polarizing plates are disposed on both sides of the liquid crystal cell, for example, the light absorption axes of the respective polarizing plates may be disposed to be perpendicular to each other.

The present application also relates to precursors capable of forming the liquid crystal layer described above. Exemplary precursors may include precursors and liquid crystal compounds of an oriented network. The precursor of the oriented network may comprise an oriented compound, for example the photoalignable compound. The precursor material may form an oriented network, and the liquid crystal compound may be phase-separated from the network to form the liquid crystal region in the process of forming the network.

As the oriented compound, a compound described above, for example, a photo-alignment compound or a precursor compound capable of forming the compound can be used, and the same compound as described above can also be used as the liquid crystal compound. The precursor is a compound capable of forming an oriented network together with the oriented compound, if necessary, and may suitably include the crosslinking agent described above. The types described above may be equally applied to the types and proportions of the alignment compound, the crosslinking agent, and the liquid crystal compound.

For example, the precursor and the liquid crystal compound of the alignment network may satisfy the following Equation 1.

Equation 1

In Equation 1, n _p is the refractive index of the oriented network formed by the precursor, n _o is the normal refractive index of the liquid crystal compound, n _e is the extraordinary refractive index of the liquid crystal compound, a Is a number satisfying 0 ≦ a <0.5.

The precursors of the oriented network may also be selected to form a network having a dielectric anisotropy of at least 3, at least 3.5 or at least 4.

In addition, the liquid crystal compound may be a nematic liquid crystal compound, for example, may be a nematic liquid crystal compound satisfying the following formula (2).

[Formula 2]

(1.53-b) <{(2n _o ² + n _e ² ) / 3} ^0.5 <(1.53 + b)

In Equation 2, n _o is the normal refractive index of the liquid crystal compound, for example, the refractive index in the uniaxial direction of the nematic liquid crystal compound, n _e is the extraordinary refractive index of the liquid crystal compound, for example, It is the refractive index of the long-axis direction of a nematic liquid crystal compound, b is a number which satisfy | fills 0.1 = b = 1.

The liquid crystal compound also has a difference between an ideal dielectric constant (ε _e , an extraordinary dielectric anisotropy) and a normal dielectric constant (ε _o , an ordinary dielectric anisotropy; , 8 or more or 10 or more. Having such a dielectric constant can provide a device having excellent driving voltage characteristics. The liquid crystal compound may have an abnormal dielectric constant (ε _e , permittivity in the major axis direction) of about 6 to 50, and a normal dielectric constant (ε _o , ordinary dielectric anisotropy, permittivity in the short axis direction) of about 2.5 to about 7.

The liquid crystal compound in the precursor, 100 parts by weight to 2,500 parts by weight, 100 parts by weight to 2,000 parts by weight, 100 parts by weight to 1,900 parts by weight, 100 parts by weight to 1,800 parts by weight, 100 parts by weight to 1,700 with respect to 100 parts by weight of the precursor Parts by weight, 100 parts by weight to 1,600 parts by weight, 100 parts by weight to 1,500 parts by weight, 100 parts by weight to 1,400 parts by weight, 100 parts by weight to 1,300 parts by weight, 100 parts by weight to 1,200 parts by weight, 100 parts by weight to 1,100 parts by weight , 100 parts by weight to 1,000 parts by weight, 100 parts by weight to 900 parts by weight, 100 parts by weight to 800 parts by weight, 100 parts by weight to 700 parts by weight, 100 parts by weight to 600 parts by weight, 100 parts by weight to 500 parts by weight, 100 parts by weight It may be included in the ratio of about 400 parts by weight, 100 parts by weight to 300 parts by weight, or about 150 parts by weight to 250 parts by weight, but this may be appropriately changed as necessary.

The precursor may further comprise a solvent if necessary. The solvent that can be used is not particularly limited and, for example, an appropriate kind can be selected from known solvents such as toluene, xylene, cyclopentanone or cyclohexanone.

Precursors may further contain, for example, appropriate radicals or catalysts such as cationic initiators and amines, or other reactive compounds or surfactants capable of forming a network, in order to promote network formation reactions such as an oriented compound and / or a crosslinking agent. It may further include an additive.

The present application also relates to a method for manufacturing a liquid crystal cell. The manufacturing method of the liquid crystal cell may include, for example, irradiating light to the layer of the precursor. By irradiating the layer of the precursor with light, it is possible to induce the formation of a network by the alignment, crosslinking and / or polymerization of the above-described alignment compound and phase separation of the liquid crystal compound.

The layer of precursor may be formed by coating the precursor on a suitable substrate, for example the substrate layer. The layer of precursor may be formed by conventional coating methods such as bar coating, comma coating, inkjet coating or spin coating, for example when the precursor is liquid. The above-mentioned transparent electrode layer may be formed in the surface of the base material layer in which the precursor layer is formed, for example.

After forming a layer of the precursor, the layer can be irradiated with light. Irradiation of light can be performed, for example, when a precursor contains a solvent etc., after drying the formed layer under suitable conditions and making the solvent volatilize. Such drying may be performed, for example, at a temperature of about 80 ° C. to 130 ° C. for about 1 minute to 10 minutes, but is not limited thereto.

Irradiation of light may be performed so that the alignment compound included in the layer of the precursor can be aligned. Typically the alignment of the orienting compound can be performed using linearly polarized light. The wavelength or intensity of the irradiated light can be selected to provide for proper alignment of the oriented compound. Typically oriented compounds, for example photoalignable compounds, are aligned by visible or near ultraviolet light, although far ultraviolet or near infrared light may be used if necessary. have.

Irradiation of light may be performed in an isotropic state of the liquid crystal compound. FIG. 2 is a diagram schematically illustrating a process of irradiating light to a layer 201 of a precursor including a liquid crystal compound (arrow) formed on the substrate layer 1011 and having an isotropic state. In order to maintain the liquid crystal compound in an isotropic state, for example, irradiation of light may be performed at an isotropic transition temperature (T _NI ) or higher temperature range of the liquid crystal compound.

Through the irradiation of light, the alignment compound is aligned in a state having a direction, and the liquid crystal compound dispersed therein may be aligned according to the alignment direction of the alignment compound. FIG. 3 is a diagram schematically showing the liquid crystal layer 102 including the alignment network 1021 and the liquid crystal region 1022 formed on the substrate layer 1011 after light irradiation.

If necessary, an appropriate heat application or exposure process may be performed before or after the irradiation process of light, or at the same time, in order to further promote formation of an oriented network.

After forming the liquid crystal layer through the above process, an additional base layer, for example, a base layer having a transparent electrode layer formed on the surface thereof is attached to the liquid crystal layer formed as necessary to form an element having a structure as shown in FIG. 1. It may be.

The manufacturing process of the liquid crystal cell as described above may be continuously performed by, for example, a roll to roll method.

The present application also relates to the use of the liquid crystal cell. Exemplary liquid crystal cells can be produced simply and continuously through, for example, a roll-to-roll process. The liquid crystal cell can also be implemented as a flexible element, and can secure an excellent contrast ratio.

The liquid crystal cell may be applied to various applications, and may be applied to various fields such as a smart window, a window protective film, a flexible display device, an active retarder for viewing 3D images, or a viewing angle control film.

Exemplary liquid crystal cells of the present application can be produced simply and continuously through, for example, a roll-to-roll process. The liquid crystal cell may also be implemented as a flexible device, and can secure an excellent contrast ratio. The liquid crystal cell may be applied to various applications, including, for example, a smart window, a window protective film, a flexible display device, an active retarder for viewing 3D images, a viewing angle adjusting film, and the like.

1 shows an exemplary liquid crystal cell.

2 and 3 are diagrams for explaining a manufacturing process of an exemplary liquid crystal cell.

4 is a photograph showing luminance variation between two polarizers of a liquid crystal cell manufactured in an embodiment.

5 is a graph showing the transmittance of the liquid crystal cell manufactured in the embodiment.

6 is a diagram illustrating a phase difference according to rotation of polarized visible light of a liquid crystal cell manufactured in an embodiment.

7 is a graph measuring the contrast ratio of the liquid crystal cell manufactured in the embodiment.

101A, 101B, 1011: substrate layer

102: liquid crystal layer

201: layer of precursor

1021: Orientation Network

1022 liquid crystal region

Hereinafter, the liquid crystal cell will be described in detail through examples according to the present application, but the range of the liquid crystal cell is not limited by the following examples.

실시예EXAMPLE

전구체의 조제Preparation of Precursors

7 g of a liquid crystal compound (ZGS-8017, JNC, abnormal refractive index: about 1.597, normal refractive index: about 1.487), a polynorbornene fluorinated cinnamate compound having a repeating unit of formula (1) as an oriented compound (PNBCi, weight average molecular weight 85,000, 3 g of a polydispersity index (PDI) of about 4.75) and 1 g of an ultraviolet curable compound (NOA-65, Norland Optical Adhesive 65) were combined with 100 g of toluene, and an appropriate amount of an initiator was added to prepare a precursor.

Formula 1

액정셀의 제조Manufacture of liquid crystal cell

A precursor prepared on the electrode layer of the transparent polycarbonate base layer having the ITO transparent electrode layer formed on the surface thereof was coated with a bar coater, and toluene as a solvent was volatilized to form a layer of a precursor having a thickness of about 7 μm. The layer of precursor was then placed on a hot plate with a WGP (Wire Grid Polarizer) placed thereon and the temperature of the hot plate was set to 90 ° C. After maintaining the layer of the precursor until it is transparent, the layer of the precursor in a transparent state was irradiated with linearly polarized ultraviolet rays (1,200 mJ / cm ² ) through the WGP to form a liquid crystal layer comprising an alignment network and a liquid crystal region. The refractive index measured using the prism coupler for the formed orientation network was about 1.573. Thereafter, the surface of the ITO transparent electrode layer of the polycarbonate film having the ITO transparent electrode layer formed on the surface was attached to the formed liquid crystal layer to prepare a liquid crystal cell.

시험예 1.Test Example 1.

The liquid crystal cell prepared in Example was positioned between two polarizing plates (upper and lower polarizing plates) arranged so that the light absorption axes were perpendicular to each other. Luminance was evaluated while irradiating light to the lower polarizing plate side in the state which arrange | positioned the orientation direction of the liquid crystal of a liquid crystal cell so that it may be 45 degree or 90 degree with the light transmission axis of an upper polarizing plate. 4 is a photograph showing the evaluation result, the left figure of FIG. 4 shows a case of 45 degrees with a light transmission axis, and the right figure shows a case of 90 degrees.

시험예 2.Test Example 2.

A liquid crystal cell was manufactured in the same manner as in Example, but the liquid crystal cell was manufactured while changing the irradiation intensity of light, and the transmittance thereof was measured and shown in FIG. 5. It can be seen from FIG. 5 that the transparency of the liquid crystal cell changes depending on the degree of alignment of the alignment network.

시험예 3.Test Example 3.

The liquid crystal cell was manufactured in the same manner as in the embodiment, but the liquid crystal cell was manufactured by changing the irradiation intensity of light, and the phase difference characteristic according to the rotation of polarized visible light according to the exposure amount was evaluated using an axostep equipment. 6 is shown.

시험예 4.Test Example 4.

The liquid crystal cell prepared in Example was positioned between two polarizing plates (upper and lower polarizing plates) arranged so that the light absorption axes were perpendicular to each other. The alignment direction of the liquid crystal cell was disposed to form 45 degrees with the light transmission axis of any one of the two polarizing plates. Subsequently, an AC power source was connected to the ITO transparent electrode layer of the upper and lower base layer (polycarbonate film), and the transmittance according to the driving voltage was measured using a photodiode laser, and this is illustrated in FIG. 7. As shown in FIG. 7, the liquid crystal cell of the embodiment exhibited a contrast ratio of about 400: 1 at a voltage of about 43V.

Claims

A liquid crystal cell comprising a liquid crystal layer having a liquid crystal region including an alignment network and a liquid crystal compound in the alignment network.
The liquid crystal cell of claim 1, wherein the oriented network is a network of precursors containing a photo-alignment compound.
3. The liquid crystal cell according to claim 2, wherein in the orientation network, the photo-orientation compound is in a state aligned so as to have directivity, and the liquid crystal compound in the liquid crystal region is aligned by the network in the alignment state.
The photo-alignment compound according to claim 2, wherein the photo-alignment compound is an azo compound, stilbene compound, cyclobutane tetracarboxylic dianhydride, aromatic polysilane, aromatic polyester, polystyrene, cinnamate compound, coumarin compound, cinnamic amide compound, tetrahydrophthalimide A liquid crystal cell which is a compound, a maleimide compound, a benzophenone compound, a diphenylacetylene compound, a chalcone compound, an anthracenyl compound, a benzoate compound, a benzoamide compound, a methacrylamidoaryl (meth) acrylate compound or a spiropyran compound.
The liquid crystal cell of claim 1, wherein the alignment network and the liquid crystal compound satisfy Formula 1 below:

Equation 1

(1-a) × {(2n o 2 + n e 2 ) / 3} 0.5 <n p <(1 + a) × {(2n o 2 + n e 2 ) / 3} 0.5

In Equation 1, n p is the refractive index of the orientation network, n o is the normal refractive index of the liquid crystal compound, n e is the abnormal refractive index of the liquid crystal compound, a is a number satisfying 0 ≤ a <0.5.
The liquid crystal cell according to claim 1, wherein the orientation network has a dielectric constant of 3 or more.
The liquid crystal cell of claim 1, wherein the liquid crystal compound is a nematic liquid crystal compound satisfying Formula 2 below:

[Formula 2]

(1.53-b) <{(2n o 2 + n e 2 ) / 3} 0.5 <(1.53 + b)

In Equation 2, n o is the normal refractive index of the liquid crystal compound, n e is the abnormal refractive index of the liquid crystal compound, b is a number that satisfies 0.1 = b = 1.
The liquid crystal cell according to claim 1, wherein a difference (ε e -ε o ) between the abnormal dielectric constant (ε e ) and the normal dielectric constant (ε o ) of the liquid crystal compound is three or more.
The liquid crystal cell of claim 1, wherein the liquid crystal layer comprises 100 parts by weight to 2,500 parts by weight of the liquid crystal compound with respect to 100 parts by weight of the oriented network.
The liquid crystal cell of claim 1, wherein light transmittance is 80% or more in a state where no voltage is applied.
The liquid crystal cell according to claim 1, further comprising two substrate layers disposed to face each other, wherein a liquid crystal layer is formed between the substrate layers.
The liquid crystal cell according to claim 11, wherein an electrode layer is formed on the liquid crystal layer side of the base layer.
The liquid crystal cell of claim 1, further comprising polarizing plates disposed on both sides of the liquid crystal layer.
A precursor of the liquid crystal layer of claim 1 comprising a precursor of an alignment network comprising an alignment compound and a liquid crystal compound.
The precursor of the liquid crystal layer according to claim 14, wherein the alignment network and the liquid crystal compound satisfy the following Equation 1:

Equation 1

(1-a) × {(2n o 2 + n e 2 ) / 3} 0.5 <n p <(1 + a) × {(2n o 2 + n e 2 ) / 3} 0.5

In Equation 1, n p is the refractive index of the oriented network formed from the oriented network precursor, n o is the normal refractive index of the liquid crystal compound, n e is the ideal refractive index of the liquid crystal compound, a satisfies 0 ≤ a <0.5 It is a number.
The precursor of the liquid crystal layer of claim 14, wherein the liquid crystal compound is a nematic liquid crystal compound satisfying Formula 2 below:

[Formula 2]

(1.53-b) <{(2n o 2 + n e 2 ) / 3} 0.5 <(1.53 + b)

In Equation 2, n o is the normal refractive index of the liquid crystal compound, n e is the abnormal refractive index of the liquid crystal compound, b is a number that satisfies 0.1 = b = 1.
The precursor of the liquid crystal layer according to claim 14, wherein a difference (ε e -ε o ) between the abnormal dielectric constant (ε e ) and the normal dielectric constant (ε o ) of the liquid crystal compound is three or more.
A method for manufacturing a liquid crystal cell comprising irradiating light to the layer of the precursor of claim 17.
The method for producing a liquid crystal cell according to claim 18, wherein the light to be irradiated is linearly polarized light.
The method of claim 18, wherein the irradiation of light is performed at an isotropic transition temperature of the liquid crystal compound or higher.