WO2013057319A3 - Methods of preparation and forming supported active metal catalysts and precursors - Google Patents

Methods of preparation and forming supported active metal catalysts and precursors Download PDF

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Publication number
WO2013057319A3
WO2013057319A3 PCT/EP2012/070897 EP2012070897W WO2013057319A3 WO 2013057319 A3 WO2013057319 A3 WO 2013057319A3 EP 2012070897 W EP2012070897 W EP 2012070897W WO 2013057319 A3 WO2013057319 A3 WO 2013057319A3
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WO
WIPO (PCT)
Prior art keywords
active metal
precursors
preparation
methods
metal catalysts
Prior art date
Application number
PCT/EP2012/070897
Other languages
French (fr)
Other versions
WO2013057319A2 (en
Inventor
Richard HYMAN
Original Assignee
Ingen Gtl Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB201118228A external-priority patent/GB201118228D0/en
Priority to CA2851988A priority Critical patent/CA2851988C/en
Priority to GB1408450.3A priority patent/GB2513488A/en
Priority to EA201400487A priority patent/EA027722B1/en
Priority to JP2014536285A priority patent/JP6180421B2/en
Priority to EP12783914.0A priority patent/EP2768612A2/en
Application filed by Ingen Gtl Limited filed Critical Ingen Gtl Limited
Priority to CN201280051673.9A priority patent/CN103889577B/en
Priority to AU2012324802A priority patent/AU2012324802B2/en
Priority to US14/351,920 priority patent/US9908110B2/en
Priority to BR112014009541-8A priority patent/BR112014009541B1/en
Publication of WO2013057319A2 publication Critical patent/WO2013057319A2/en
Publication of WO2013057319A3 publication Critical patent/WO2013057319A3/en
Priority to ZA2014/03535A priority patent/ZA201403535B/en
Priority to AU2017201067A priority patent/AU2017201067B2/en

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    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/13—Potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/17—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/37—Lanthanides
    • B01J2523/3712—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
    • B01J2523/41—Silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/84—Metals of the iron group
    • B01J2523/842—Iron

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  • Chemical & Material Sciences (AREA)
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  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention relates to a method of preparing a supported catalyst, which method comprises the steps of; (i) providing a porous catalyst support comprising a framework having an internal pore structure comprising one or more pores which internal pore structure comprises a precipitant; (ii) contacting the catalyst support with a solution or colloidal suspension comprising a catalytically active metal such that, on contact with the precipitant, particles comprising the catalytically active metal are precipitated within the internal pore structure of the framework of the catalyst support. The invention also relates to supported catalysts made according to the above method, and to use of the catalysts in catalysing chemical reactions, for example in the Fischer Tropsch synthesis of hydrocarbons.
PCT/EP2012/070897 2011-10-21 2012-10-22 Methods of preparation and forming supported active metal catalysts and precursors WO2013057319A2 (en)

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BR112014009541-8A BR112014009541B1 (en) 2011-10-21 2012-10-22 METHODS FOR PREPARATION AND FORMATION OF ACTIVE METAL SUPPORTED CATALYZERS AND PRECURSORS
AU2012324802A AU2012324802B2 (en) 2011-10-21 2012-10-22 Methods of preparation and forming supported active metal catalysts and precursors
EA201400487A EA027722B1 (en) 2011-10-21 2012-10-22 Methods of preparation and forming supported active metal catalysts and precursors
JP2014536285A JP6180421B2 (en) 2011-10-21 2012-10-22 Process for producing and forming supported active metal catalysts and precursors
EP12783914.0A EP2768612A2 (en) 2011-10-21 2012-10-22 Methods of preparation and forming supported active metal catalysts and precursors
CA2851988A CA2851988C (en) 2011-10-21 2012-10-22 Methods of preparation and forming supported active metal catalysts and precursors
CN201280051673.9A CN103889577B (en) 2011-10-21 2012-10-22 Methods of preparation and forming supported active metal catalysts and precursors
GB1408450.3A GB2513488A (en) 2011-10-21 2012-10-22 Methods of preparation and forming supported active metal catalysts and precursors
US14/351,920 US9908110B2 (en) 2011-10-21 2012-10-22 Methods of preparation and forming supported active metal catalysts and precursors
ZA2014/03535A ZA201403535B (en) 2011-10-21 2014-05-15 Methods of preparation and forming supported active metal catalysts and precursons
AU2017201067A AU2017201067B2 (en) 2011-10-21 2017-02-16 Methods of preparation and forming supported active metal catalysts and precursors

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GB201118228A GB201118228D0 (en) 2011-10-21 2011-10-21 Methods of preparation and forming supported active metal catalysts and precursors
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Families Citing this family (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2851988C (en) * 2011-10-21 2019-05-21 Igtl Technology Ltd Methods of preparation and forming supported active metal catalysts and precursors
CN103611537B (en) * 2013-11-01 2016-04-20 中国石油化工股份有限公司 A kind of iron-base fischer-tropsch synthesis catalyst and its preparation method and application
JP6344052B2 (en) * 2014-05-20 2018-06-20 株式会社Ihi Ammonia synthesis catalyst and ammonia synthesis method
CN106660034A (en) 2014-05-22 2017-05-10 沙特阿拉伯石油公司 Framework substituted zeolite catalyst for fluidized catalytic cracking and method for fluidized catalytic cracking
US9938157B2 (en) * 2014-07-23 2018-04-10 Chevron U.S.A. Inc. Interzeolite transformation and metal encapsulation in the absence of an SDA
KR102017207B1 (en) * 2015-12-09 2019-09-02 주식회사 엘지화학 Catalyst for oxidative dehydrogenation and method for preparing the catalyst
EP3398679A4 (en) * 2015-12-28 2018-11-07 Toyota Jidosha Kabushiki Kaisha Cluster supported catalyst and production method therefor
CN105944751B (en) * 2016-05-24 2019-06-21 江南大学 A kind of catalyst directly preparing aromatic compound for synthesis gas and its preparation and application
JP7060523B2 (en) * 2016-05-25 2022-04-26 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア Zeolite material with enclosed binary metal clusters
US9687825B1 (en) 2016-06-27 2017-06-27 Chevron U.S.A. Inc. Stable tungsten-phosphorus modified support for a Fischer-Tropsch catalyst
JP6978844B2 (en) * 2017-03-22 2021-12-08 岩谷産業株式会社 Hydrocarbon synthesis catalyst manufacturing method, hydrocarbon manufacturing method
CN110621398B (en) * 2017-05-05 2022-11-18 埃克森美孚化学专利公司 Polyoxometallate comprising a noble metal and a carboxylate end-capping group and metal clusters thereof
WO2018221701A1 (en) * 2017-05-31 2018-12-06 古河電気工業株式会社 Ammonia decomposition catalyst structure and fuel cell
JP7361604B2 (en) * 2017-05-31 2023-10-16 古河電気工業株式会社 Fischer-Tropsch synthesis catalyst structure, method for producing the same, method for producing liquid hydrocarbons using the catalyst structure, and hydrocarbon production apparatus having the catalyst structure
EP3632555A4 (en) 2017-05-31 2021-01-27 Furukawa Electric Co., Ltd. Hydrodesulfurization catalyst structure, hydrodesulfurization device provided with said catalyst structure, and production method of hydrodesulfurization catalyst structure
EP3632550A4 (en) * 2017-05-31 2021-03-03 National University Corporation Hokkaido University Functional structure and production method for functional structure
WO2018221702A1 (en) * 2017-05-31 2018-12-06 古河電気工業株式会社 Photocatalyst structure, photocatalyst structure composition, photocatalyst coating material, production method of photocatalyst structure, and decomposition method of aldehydes
WO2018221695A1 (en) * 2017-05-31 2018-12-06 古河電気工業株式会社 Structure for fluid catalytic cracking and production method therefor, and device for fluid catalytic cracking provided with the structure
US11161101B2 (en) 2017-05-31 2021-11-02 Furukawa Electric Co., Ltd. Catalyst structure and method for producing the catalyst structure
EP3632547A4 (en) * 2017-05-31 2020-12-16 Furukawa Electric Co., Ltd. Catalyst structure for catalytic cracking or hydrodesulfurization, catalytic cracking device and hydrodesulfurization device using said catalyst structure, and production method for catalyst structure for catalytic cracking or hydrodesulfurization
AU2018276618B2 (en) * 2017-05-31 2021-05-27 Furukawa Electric Co., Ltd. Functional structure and production method for functional structure
JPWO2018221704A1 (en) * 2017-05-31 2020-03-26 古河電気工業株式会社 Aromatic hydrocarbon production catalyst structure, aromatic hydrocarbon production apparatus including the aromatic hydrocarbon production catalyst structure, method for producing aromatic hydrocarbon production catalyst structure, and method for producing aromatic hydrocarbon
CN110678261B (en) * 2017-05-31 2023-10-24 古河电气工业株式会社 Catalyst structure for producing synthesis gas, synthesis gas production device provided with same, and method for producing catalyst structure for producing synthesis gas
CN110678262A (en) 2017-05-31 2020-01-10 古河电气工业株式会社 Exhaust gas purifying oxidation catalyst structure, method for producing same, exhaust gas treatment device for automobile, catalyst molded body, and gas purifying method
CN110709166A (en) * 2017-05-31 2020-01-17 古河电气工业株式会社 Methanol reforming catalyst structure, apparatus for methanol reforming, method for producing methanol reforming catalyst structure, and method for producing at least one of olefin and aromatic hydrocarbon
JP7323115B2 (en) * 2017-05-31 2023-08-08 国立大学法人北海道大学 Functional structure and manufacturing method thereof
EP3632545A4 (en) * 2017-05-31 2021-01-27 Furukawa Electric Co., Ltd. Steam reforming catalyst structure, reforming device provided with said steam reforming catalyst structure, and production method of steam reforming catalyst structure
EP3632541A4 (en) * 2017-05-31 2021-03-10 National University Corporation Hokkaido University Functional structure and production method for functional structure
WO2018221699A1 (en) * 2017-05-31 2018-12-06 古河電気工業株式会社 Ammonia synthesis catalyst structure and production method therefor, ammonia synthesis device and ammonia synthesis method
CN110709165A (en) * 2017-05-31 2020-01-17 国立大学法人北海道大学 Functional structure and method for manufacturing functional structure
WO2018221698A1 (en) * 2017-05-31 2018-12-06 古河電気工業株式会社 Co shift or reverse shift catalyst structure and production method thereof, co shift or reverse shift reaction device, production method of carbon dioxide and hydrogen, and production method of carbon monoxide and water
JP6845324B2 (en) * 2017-06-27 2021-03-17 トヨタ自動車株式会社 Cluster-supported porous carrier and its manufacturing method
JP6683656B2 (en) * 2017-06-27 2020-04-22 トヨタ自動車株式会社 Cluster-supported catalyst and method for producing the same
CN110496639B (en) * 2018-05-17 2022-05-27 中国科学院大连化学物理研究所 Catalyst for aromatic hydrocarbon synthesis and preparation method and application thereof
KR20200004501A (en) * 2018-07-04 2020-01-14 한국화학연구원 Catalyst having enhanced conversion ratio and selectivity for manufacturing olefin, and a manufacturing method thereof
WO2020027321A1 (en) * 2018-08-03 2020-02-06 古河電気工業株式会社 Light hydrocarbon synthesis catalyst structure, apparatus for producing light hydrocarbon, and method for producing light hydrocarbon
GB201813334D0 (en) * 2018-08-15 2018-09-26 Wang Tiesheng Nanocomposite materials and methods of manufacture thereof
CN109513457B (en) * 2018-11-22 2021-08-13 中国石油大学(华东) Molecular sieve catalyst with modified magnesium aluminate spinel as carrier and preparation method thereof
CN109351182A (en) * 2018-11-27 2019-02-19 蓝天环保设备工程股份有限公司 A kind of Sinter-plate Filter with VOCs remove
EP3892603A4 (en) * 2018-12-03 2022-08-31 Furukawa Electric Co., Ltd. Production device for hydrocarbons and production method for hydrocarbons
EP3892370A4 (en) * 2018-12-03 2023-01-25 National University Corporation Hokkaido University Functional structure precursor and functional structure
WO2020116478A1 (en) * 2018-12-03 2020-06-11 古河電気工業株式会社 Production device for hydrocarbons and production method for hydrocarbons
JP2020089811A (en) * 2018-12-03 2020-06-11 国立大学法人北海道大学 Functional structure, catalyst, and catalyst for ethylene gas oxidation
JPWO2020116472A1 (en) * 2018-12-03 2021-12-09 国立大学法人北海道大学 Functional structure
EP3892371A4 (en) * 2018-12-03 2023-03-22 National University Corporation Hokkaido University Functional structure
EP3892372A4 (en) * 2018-12-03 2022-08-31 Furukawa Electric Co., Ltd. Catalyst structural body and method for producing same, and method for producing hydrocarbon by use of catalyst structural body
JP2020089813A (en) * 2018-12-03 2020-06-11 古河電気工業株式会社 Fischer-tropsch synthetic catalyst structure and production method thereof, and production method of hydrocarbon using the catalyst structure
JP7449525B2 (en) * 2018-12-03 2024-03-14 国立大学法人北海道大学 Functional structure and its manufacturing method
EP3892374A4 (en) * 2018-12-03 2022-08-31 Furukawa Electric Co., Ltd. Syngas-production catalyst structure and precursor thereof, syngas production device, and method for producing syngas-production catalyst structure
EP3892375A4 (en) * 2018-12-03 2022-08-24 National University Corporation Hokkaido University Functional structure
JPWO2020116474A1 (en) * 2018-12-03 2021-10-21 古河電気工業株式会社 Equipment for producing lower olefin-containing gas and method for producing lower olefin-containing gas
CN113164937A (en) * 2018-12-03 2021-07-23 古河电气工业株式会社 Catalyst structure, method for producing same, and method for producing hydrocarbon using same
JP7353751B2 (en) * 2018-12-03 2023-10-02 古河電気工業株式会社 Fischer-Tropsch synthesis catalyst structure, method for producing the same, and method for producing hydrocarbons using the catalyst structure
WO2020116469A1 (en) * 2018-12-03 2020-06-11 国立大学法人北海道大学 Functional structure
WO2021193438A1 (en) * 2020-03-23 2021-09-30 株式会社Ihi Hydrocarbon generation system and hydrocarbon generation method
US11446645B2 (en) 2020-07-02 2022-09-20 Saudi Arabian Oil Company FCC catalyst compositions for fluid catalytic cracking and methods of using the FCC catalyst compositions
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US11142703B1 (en) 2020-08-05 2021-10-12 Saudi Arabian Oil Company Fluid catalytic cracking with catalyst system containing modified beta zeolite additive
JP7361072B2 (en) * 2021-07-16 2023-10-13 本田技研工業株式会社 carbon dioxide reduction catalyst
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US11618858B1 (en) 2021-12-06 2023-04-04 Saudi Arabian Oil Company Hydrodearylation catalysts for aromatic bottoms oil, method for producing hydrodearylation catalysts, and method for hydrodearylating aromatic bottoms oil with hydrodearylation catalysts
WO2023196364A1 (en) * 2022-04-08 2023-10-12 The Shepherd Chemical Company Acid-base mediated ion-exchange metal loaded zeolite
US11725149B1 (en) 2022-06-13 2023-08-15 Saudi Arabian Oil Company Fluidized catalytic cracking processes and additives for improving gasoline yield and quality

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4622308A (en) * 1981-05-18 1986-11-11 Research Association For Petroleum Alternatives Development Catalyst for the production of hydrocarbons from the synthesis gas
US5194244A (en) * 1988-11-23 1993-03-16 Shell Oil Company Basic alkali metal-zeolite compositions
EP1222027B1 (en) * 1999-10-12 2005-07-13 ExxonMobil Research and Engineering Company Preparation of catalysts for fischer-tropsch hydrocarbon synthesis
WO2009051353A2 (en) * 2007-10-15 2009-04-23 Korea Research Institute Of Chemical Technology Method of direct synthesis of light hydrocarbons from natural gas
US20100168258A1 (en) * 2008-12-29 2010-07-01 Chevron U.S.A Inc. Preparation of Cobalt-Ruthenium/zeolite fischer-tropsch catalysts

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4113658A (en) 1967-04-14 1978-09-12 Stamicarbon, N.V. Process for homogeneous deposition precipitation of metal compounds on support or carrier materials
US4192777A (en) 1978-03-01 1980-03-11 Exxon Research & Engineering Co. Preparation and use of supported potassium (or rubidium)-Group VIII-metal cluster catalysts in CO/H2 Fischer-Tropsch synthesis reactions
US4552855A (en) 1982-12-30 1985-11-12 Ozin Geoffrey A Metal zeolite catalyst preparation
US4537867A (en) 1983-12-14 1985-08-27 Exxon Research And Engineering Co. Promoted iron-cobalt spinel catalyst for Fischer-Tropsch processes
EP0370553A3 (en) * 1988-11-23 1990-09-05 Shell Internationale Researchmaatschappij B.V. Basic metal-zeolite compositions, their preparation and use in base catalyzed reactions
JPH07316120A (en) * 1994-05-23 1995-12-05 Tonen Corp Production of 2-phenylbytyronitrile
ZA996280B (en) 1999-10-04 2000-10-03 Sasol Tech Pty Ltd A method of modifying and controlling catalyst selectivity in a Fischer-Tropsch process.
US7459485B2 (en) 2002-04-16 2008-12-02 Sasol Technology (Proprietary) Limited Hydrocarbon synthesis process using a hydrocarbon synthesis catalyst and an acidic catalyst
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
JP4773116B2 (en) * 2005-03-24 2011-09-14 新日本製鐵株式会社 Method for producing catalyst for producing hydrocarbons from synthesis gas, and method for producing hydrocarbons from synthesis gas using the catalyst
US7393876B2 (en) 2005-12-16 2008-07-01 Eltron Research, Inc. Fischer-tropsch catalysts
CN100351013C (en) * 2006-02-27 2007-11-28 西安交通大学 CdS/Ti-MCM-41 loaded platinum photo catalyst and its preparation method
JP2009106863A (en) * 2007-10-30 2009-05-21 Toyama Univ Ft synthesis catalyst, and ft synthesis method
JP5474204B2 (en) * 2009-10-08 2014-04-16 ビーエーエスエフ ソシエタス・ヨーロピア Method for producing Si-bonded fluidized bed catalyst
EP2314557A1 (en) 2009-10-23 2011-04-27 Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) Production of lower olefins from synthesis gas
GB2475492B (en) * 2009-11-18 2014-12-31 Gtl F1 Ag Fischer-Tropsch synthesis
CA2851988C (en) * 2011-10-21 2019-05-21 Igtl Technology Ltd Methods of preparation and forming supported active metal catalysts and precursors

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4622308A (en) * 1981-05-18 1986-11-11 Research Association For Petroleum Alternatives Development Catalyst for the production of hydrocarbons from the synthesis gas
US5194244A (en) * 1988-11-23 1993-03-16 Shell Oil Company Basic alkali metal-zeolite compositions
EP1222027B1 (en) * 1999-10-12 2005-07-13 ExxonMobil Research and Engineering Company Preparation of catalysts for fischer-tropsch hydrocarbon synthesis
WO2009051353A2 (en) * 2007-10-15 2009-04-23 Korea Research Institute Of Chemical Technology Method of direct synthesis of light hydrocarbons from natural gas
US20100168258A1 (en) * 2008-12-29 2010-07-01 Chevron U.S.A Inc. Preparation of Cobalt-Ruthenium/zeolite fischer-tropsch catalysts

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BENGOA J F ET AL: "Fischer-Tropsch reaction on Fe/Zeolite-L system. Structure and catalytic behavior", MATERIALS LETTERS, NORTH HOLLAND PUBLISHING COMPANY. AMSTERDAM, NL, vol. 53, no. 1-2, 1 March 2002 (2002-03-01), pages 6 - 11, XP004335352, ISSN: 0167-577X, DOI: 10.1016/S0167-577X(01)00444-X *
SUK-HWAN KANG ET AL: "Fischer-Tropsch Synthesis Using Zeolite-supported Iron Catalysts for the Production of Light Hydrocarbons", CATALYSIS LETTERS, KLUWER ACADEMIC PUBLISHERS-PLENUM PUBLISHERS, NE, vol. 125, no. 3-4, 25 July 2008 (2008-07-25), pages 264 - 270, XP019640287, ISSN: 1572-879X, DOI: 10.1007/S10562-008-9586-2 *

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