WO2013128120A3 - Multifunctional bimetallic or trimetallic catalysts, method for preparing same, and use thereof in the conversion of lignocellulosic material - Google Patents

Multifunctional bimetallic or trimetallic catalysts, method for preparing same, and use thereof in the conversion of lignocellulosic material Download PDF

Info

Publication number
WO2013128120A3
WO2013128120A3 PCT/FR2013/050406 FR2013050406W WO2013128120A3 WO 2013128120 A3 WO2013128120 A3 WO 2013128120A3 FR 2013050406 W FR2013050406 W FR 2013050406W WO 2013128120 A3 WO2013128120 A3 WO 2013128120A3
Authority
WO
WIPO (PCT)
Prior art keywords
bimetallic
multifunctional
lignocellulosic material
conversion
preparing same
Prior art date
Application number
PCT/FR2013/050406
Other languages
French (fr)
Other versions
WO2013128120A2 (en
Inventor
Jean-Jacques Walter
Catherine Santini-Scampucci
Chérif LARABI
Walid AL MAKSOUD
Original Assignee
Synthopetrol
Centre National De La Recherche Scientifique
Ecole Superieure De Chimie-Physique-Electronique De Lyon
Universite Claude Bernard Lyon 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Synthopetrol, Centre National De La Recherche Scientifique, Ecole Superieure De Chimie-Physique-Electronique De Lyon, Universite Claude Bernard Lyon 1 filed Critical Synthopetrol
Publication of WO2013128120A2 publication Critical patent/WO2013128120A2/en
Publication of WO2013128120A3 publication Critical patent/WO2013128120A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J35/30—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

The invention relates to a multifunctional, in particular trifunctional, bimetallic or trimetallic catalyst, which consists of a heteropoly acid (HPA), a group IA or IIA element Z, one or two group VIIB or VIIIB metals M', and a group IB or IIB metal M". Said catalyst can be used in converting lignocellulosic material into organic molecules constituting a biofuel.
PCT/FR2013/050406 2012-02-27 2013-02-27 Novel multifunctional bimetallic or trimetallic catalysts, method for preparing same, and use thereof WO2013128120A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1251767A FR2987281A1 (en) 2012-02-27 2012-02-27 NEW TRIFUNCTIONAL BIMETALLIC CATALYSTS, PROCESS FOR THE PREPARATION THEREOF AND USE THEREOF
FR1251767 2012-02-27

Publications (2)

Publication Number Publication Date
WO2013128120A2 WO2013128120A2 (en) 2013-09-06
WO2013128120A3 true WO2013128120A3 (en) 2014-09-18

Family

ID=46852092

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2013/050406 WO2013128120A2 (en) 2012-02-27 2013-02-27 Novel multifunctional bimetallic or trimetallic catalysts, method for preparing same, and use thereof

Country Status (2)

Country Link
FR (1) FR2987281A1 (en)
WO (1) WO2013128120A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3371105B1 (en) * 2015-11-06 2022-11-30 ExxonMobil Chemical Patents Inc. Polyoxometalates comprising noble metals and corresponding metal clusters

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0713849A1 (en) * 1994-11-26 1996-05-29 Basf Aktiengesellschaft Process for the preparation of 1,2-propanediol
US20080216391A1 (en) * 2007-03-08 2008-09-11 Cortright Randy D Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
WO2012162403A1 (en) * 2011-05-23 2012-11-29 Virent, Inc. Production of chemicals and fuels from biomass

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2529036B1 (en) 2010-01-27 2017-11-22 Council of Scientific & Industrial Research A one pot and single step hydrolytic process for the conversion of lignocellulose into value added chemicals

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0713849A1 (en) * 1994-11-26 1996-05-29 Basf Aktiengesellschaft Process for the preparation of 1,2-propanediol
US20080216391A1 (en) * 2007-03-08 2008-09-11 Cortright Randy D Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
WO2012162403A1 (en) * 2011-05-23 2012-11-29 Virent, Inc. Production of chemicals and fuels from biomass

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
CHUN-HUI ZHOU ET AL: "Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels", CHEMICAL SOCIETY REVIEWS, vol. 40, no. 11, 1 January 2011 (2011-01-01), pages 5588, XP055054356, ISSN: 0306-0012, DOI: 10.1039/c1cs15124j *
HAI WOONG PARK ET AL: "Catalytic decomposition of 4-phenoxyphenol to aromatics over Pd/CsHPWO/ACA (=10, 20, 30, 40, and 50wt%) catalysts", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 437, 16 June 2012 (2012-06-16), pages 112 - 119, XP028449388, ISSN: 0926-860X, [retrieved on 20120626], DOI: 10.1016/J.APCATA.2012.06.024 *
OKUHARA T ET AL: "Insoluble heteropoly compounds as highly active catalysts for liquid-phase reactions", JOURNAL OF MOLECULAR CATALYSIS, ELSEVIER, vol. 74, 1 January 1992 (1992-01-01), pages 247 - 256, XP002511186, ISSN: 0304-5102, DOI: 10.1016/0304-5102(92)80242-9 *
PARK H W ET AL: "Decomposition of phenethyl phenyl ether to aromatics over CsxH3.0-xPW12O40 (X=2.0-3.0) heteropolyacid catalysts", CATALYSIS COMMUNICATIONS, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 12, no. 1, 25 October 2010 (2010-10-25), pages 1 - 4, XP027305353, ISSN: 1566-7367, [retrieved on 20100812] *

Also Published As

Publication number Publication date
FR2987281A1 (en) 2013-08-30
WO2013128120A2 (en) 2013-09-06

Similar Documents

Publication Publication Date Title
MX2014008253A (en) Hydrogenation catalysts with cobalt-modified supports.
WO2012166471A3 (en) Hydrocarbon transformations using carbocatalysts
WO2014072887A3 (en) Process for producing a carbon-supported nickel-cobalt-oxide catalyst and its use in rechargeable electrochemical metal-oxygen cells
DK2459310T3 (en) SILICO DIOXIDE-STABILIZED ULTRAFIN ANATASE-TITANIUM OXIDE, VANADIUM OXIDE CATALYSTS AND METHODS FOR THE PREPARATION
IN2013MU02899A (en)
WO2012012495A3 (en) Functionalization of organic molecules using metal-organic frameworks (mofs) as catalysts
WO2014145344A3 (en) Control of growth-induction-production phases
MX2017006156A (en) Cerium oxide particles and method for production thereof.
WO2010117856A3 (en) Vapor-liquid contacting apparatuses with vortex contacting stages
WO2011075636A3 (en) Wise binding agents and epitopes
IN2012DE00662A (en)
WO2011074784A3 (en) Cu-in-zn-sn-(se,s)-based thin film for solar cell and preparation method thereof
WO2012030065A3 (en) Catalyst composition for hydroformylation reaction and a hydroformylation process using the same
WO2013172897A3 (en) Energy harvesting system
EP4219395A3 (en) Novel metal hydrides and their use in hydrogen storage applications
WO2011096894A3 (en) Use of novel markers of pluripotent stem cells
EP2874745A4 (en) Catalysts for thermo-catalytic conversion of biomass, and methods of making and using
WO2015161468A8 (en) Methods and systems for producing isosorbide from biomass
WO2014102154A3 (en) A process for converting one or more c3-c12 oxygenates
WO2011117360A3 (en) Process for the preparation of 4-cyclohexyl-2-methyl-2-butanol
WO2014023758A3 (en) Selective catalytic deoxygenation of biomass and catalysts therefor
WO2012092512A8 (en) Catalytic anti-markovnikov oxidation and hydration of olefins
WO2011139704A3 (en) Crystalline 1h-1,2,3-triazol-5-ylidenes
WO2011075743A3 (en) Multihydric compound dehydration systems, catalyst compositions, and methods
WO2013128120A3 (en) Multifunctional bimetallic or trimetallic catalysts, method for preparing same, and use thereof in the conversion of lignocellulosic material

Legal Events

Date Code Title Description
122 Ep: pct application non-entry in european phase

Ref document number: 13714987

Country of ref document: EP

Kind code of ref document: A2