WO2016010303A1 - Environment-friendly and biodegradable non-woven fabric, and apparatus and method for producing same - Google Patents

Environment-friendly and biodegradable non-woven fabric, and apparatus and method for producing same Download PDF

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Publication number
WO2016010303A1
WO2016010303A1 PCT/KR2015/007101 KR2015007101W WO2016010303A1 WO 2016010303 A1 WO2016010303 A1 WO 2016010303A1 KR 2015007101 W KR2015007101 W KR 2015007101W WO 2016010303 A1 WO2016010303 A1 WO 2016010303A1
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Prior art keywords
pla
pulp
fiber
pla fiber
nonwoven fabric
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PCT/KR2015/007101
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French (fr)
Korean (ko)
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구기승
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구기승
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542Adhesive fibres
    • D04H1/55Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs

Definitions

  • Embodiments of the present invention relate to an eco-friendly biodegradable nonwoven fabric and a manufacturing apparatus and a manufacturing method thereof, and more particularly, to an eco-friendly biodegradable nonwoven fabric and an apparatus and a manufacturing method for improving the mechanical properties of absorbent and soft and bulky will be.
  • nonwoven refers to nonwoven fabric. That is, it refers to a fiber aggregate that is not based on spinning, weaving, or braiding, and means sheeting and bonding by physical and chemical means.
  • Conventional nonwoven fabrics were prepared by composite injection of high absorbency pulp and high polyethylene (PE) or polypropylene (PP) when used as a hygiene product.
  • PE polyethylene
  • PP polypropylene
  • PE polyethylene
  • PP polypropylene
  • Polylactic acid forms a market of 150,000 tons in the world, and is used not only for disposable products using the biodegradable properties of PLA, but also for general plastics such as food packaging materials, containers, and electronics cases. The scope of application is expanding.
  • polylactic acid is more expensive than polyethylene (PE) or polypropylene (PP), has a rough feel, has a small volume, and has a problem of low elasticity.
  • the present invention has been made to solve the conventional problems
  • An object of the present invention is to use the pulp layer having a soft property, absorbency and volume between the first PLA layer and the second PLA layer having excellent physical properties to improve the physical properties, improve the physical properties, 100% after disposal It is to provide an eco-friendly biodegradable nonwoven fabric and a manufacturing apparatus and a manufacturing method of the biodegradation is made.
  • Another object of the present invention is to provide an eco-friendly biodegradable nonwoven fabric, an apparatus and a manufacturing method thereof, which can improve the quality of the nonwoven fabric and reduce the manufacturing cost.
  • Eco-friendly biodegradable nonwoven manufacturing apparatus provided to achieve the above object is a first PLA fiber manufacturing apparatus for fiberizing PLA; A first mesh drum integrating the first PLA fibers sprayed from the first PLA fibers in a web form; A pulp supply unit provided at one side of the first mesh drum to stack pulp on one surface of the first PLA fiber integrated on the first mesh drum; A second PLA fiber making machine provided on one side of the pulp supply unit to fiberize PLA; A second mesh drum in which the second PLA fibers sprayed from the second PLA fiber maker are integrated in a web form and laminated on one surface of the pulp; A heat fusion unit for heat-sealing the laminates by applying heat to the laminates stacked in order of the first PLA fibers, the pulp, and the second PLA fibers; And controlling the injection amount of the first and second PLA fibers manufactured by the first and second PLA fiber makers by being electrically connected to the first and second PLA fiber makers and the pulp supply unit, and the pulp supply amount of the pulp supply unit.
  • Control unit for controlling is configured to
  • the first and second PLA fiber making machine is an extruder for melting and extruding PLA (biodegradable polylactic acid), a spray nozzle formed with hundreds of small orifices (orifice) for spraying the molten PLA in the extruder, and the injection nozzle
  • PLA biological polylactic acid
  • spray nozzle formed with hundreds of small orifices (orifice) for spraying the molten PLA in the extruder
  • injection nozzle A hot air fan for stretching PLA sprayed from the spray nozzle by spraying high-pressure hot air from both sides of the cooler, a cooler for cooling the stretched PLA, a cutter for cutting the PLA fiber determined by the stretching, and spraying the cut PLA fiber Characterized in that configured to include a jet.
  • the extruder and the injection nozzle is characterized in that it further comprises a filter device for filtering the molten PLA.
  • the extruder is divided into first to fifth regions, the first region is 150 to 160 °C, the second region is 200 to 210 °C, the third region is 220 to 230 °C, the fourth region is 230 to 240 °C,
  • the five regions are characterized in that a temperature of 250 to 260 ⁇ is set.
  • the pulp supply unit is characterized in that the carding machine for separating the pulp fibers consisting of sheets or mats into individual fibers are connected.
  • the control unit controls the injection amount of the first PLA fiber manufacturing machine so that the first PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric, and 25% to 80% by weight of pulp is supplied to the total weight of the nonwoven fabric.
  • the supply amount of the pulp supply unit is controlled so as to control the injection amount of the second PLA fiber maker so that the second PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric is injected.
  • Eco-friendly biodegradable nonwoven fabric manufacturing method is melted by putting PLA (biodegradable polylactic acid) into the extruder of the first and second fiber makers, respectively, and then through a spinning nozzle formed of hundreds of small orifices (Orifice) S10 step of producing the first PLA fibers and the second PLA fibers by spinning and cooling with high-pressure hot air sprayed at high speed from both sides of the spinning nozzle; Spraying the first PLA fiber produced in the first fiber maker on the first mesh drum to integrate in the form of a web (Web), and the second PLA fiber produced in the second fiber maker sprayed on the second mesh drum S20 step of integrating in the form of a web (Web); S30 step of supplying and interposing pulp between the first PLA fiber and the second PLA fiber integrated in the web form; It is prepared, including; S40 step of bonding the first PLA fibers, pulp, second PLA fibers by heat fusion bonding.
  • PLA biodegradable polylactic acid
  • the extruder has a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., a fourth region having a temperature of 230 to 240 ° C., and a 250 to 260 ° C.
  • the temperature is divided into a fifth region is set, the PLA is characterized in that complete melting through the first to fifth regions.
  • step S10 characterized in that it further comprises the step of filtering the molten PLA.
  • the PLA is characterized in that selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
  • the PLA has a melting point of 100 °C to 180 °C, the melt index is 75 to 120g / 10 minutes, the melt density is characterized in that it has a characteristic in the range of 0.98 to 2.24g / cm3 (260 °C).
  • the pulp is characterized in that the pulp fibers made of a sheet or mat put into a carding machine and separated into individual fibers.
  • the first PLA fibers are injected by injecting 10% by weight to 40% by weight of the total weight of the nonwoven fabric, and the pulp is fed by 25% by weight to 80% by weight of the total weight of the nonwoven fabric. 10% by weight to 40% by weight is characterized in that the injection is integrated.
  • the first PLA fiber layer integrated in the form of a web on the first mesh drum by the above production method; A pulp layer laminated on the first PLA fiber layer; The second PLA fiber layer is integrated on the second mesh drum in the form of a web and laminated on the upper surface of the pulp layer.
  • An embodiment of the present invention utilizes the soft properties, absorbency and volume of the pulp, the first PLA fiber and the second PLA fiber through the pulp having a soft property and absorbency and volume between the first and second PLA fibers having excellent physical properties
  • the pulp can reduce the manufacturing cost, 100% biodegradation after disposal, does not cause environmental problems, does not emit carcinogens or harmful substances to hygiene, hygiene and hygiene is excellent And it becomes possible to manufacture a nonwoven fabric with improved safety.
  • first and second PLA fibers hold the surface of the pulp, it is possible to wash, thereby producing a non-woven fabric that can be used repeatedly.
  • FIG. 1 is a schematic diagram for explaining the eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
  • Figure 2 is a block diagram for explaining the overall configuration of the eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
  • Figure 3 is a block diagram for explaining the configuration of the first, second PLA fiber manufacturing apparatus in an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
  • Figure 4 is a flow chart for explaining a method for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
  • Figure 5 is a cross-sectional view showing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
  • FIG. 1 is a schematic diagram for explaining an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention
  • Figure 2 is a block diagram for explaining the overall configuration of an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention
  • Figure 3 is a block diagram for explaining the configuration of the first, second PLA fiber manufacturing apparatus in an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
  • the apparatus for producing eco-friendly biodegradable nonwoven fabric includes a first PLA fiber maker 100, a first mesh drum 200, a second PLA fiber maker 300, and a second mesh drum 400. It includes a pulp supply unit 500, the control unit 600, the heat fusion unit 700.
  • the first and second PLA fiber makers 100 and 300 are extruders 110 and 310 for melting and extruding PLA (biodegradable polylactic acid) introduced as shown in FIG. 3, and hundreds of spraying molten PLA from the extruder.
  • Injection nozzles 130 and 330 having two small orifices formed therein, filter devices 120 and 320 provided between the extruder and the injection nozzle to filter the molten PLA, and PLAs which are provided on both sides of the injection nozzles and sprayed by the injection nozzles.
  • It comprises a hot air fan (140,340) for stretching, a cooler (150,350) for cooling the stretched PLA, cutters (160,360) for cutting the PLA fiber determined by the stretching, and injection holes (170,370) for spraying the cut PLA fiber do.
  • the injection port is provided with valves (171, 371) for controlling the injection amount of the PLA fiber is electrically connected to the control unit.
  • the extruders 110 and 310 are partitioned into first to fifth regions. Then, the partitioned first region is 150 to 160 ⁇ , the second region is 200 to 210 ⁇ , the third region is 220 to 230 ⁇ , the fourth region is 230 to 240 ⁇ and the fifth region is 250 to 260 ⁇ . Are set respectively.
  • the injection nozzles 130 and 330 have 0.88 mm per 12 to 16 cm, and hot air having a high velocity distribution forms various filaments between 0.1 ⁇ m and 500 ⁇ in diameter.
  • a first mesh drum 200 is disposed below the first PLA fiber maker 100, and a second mesh drum 400 is disposed below the second PLA fiber maker 300.
  • first mesh drum 200 integrates the first PLA fiber 10 sprayed from the first PLA fiber maker 100 into a web form
  • the second mesh drum 400 is the second PLA fiber maker 300. Integrate the second PLA fiber 30 is injected in the form of a web.
  • the pulp supply unit 500 is disposed between the first mesh drum 200 and the second mesh drum 400.
  • the pulp supply unit 500 supplies the pulp between the first mesh drum 200 and the second mesh drum 400 to integrate the first PLA fiber 10 and the second PLA fiber in a web form on the first mesh drum 200.
  • the pulp 20 is interposed between the second PLA fibers 30 integrated in the web form on the mesh drum 400.
  • the pulp supply unit 500 may directly supply pulp, but the pulp supply unit 500 is connected to a carding machine 510 which separates the pulp fibers made of sheets or mats into individual fibers to connect pulp fibers made of sheets or mats. The pulp of the separated individual fibers can also be fed.
  • the first PLA fiber maker 100, the second PLA fiber maker 300, and the pulp supply unit 500 is electrically connected to the control unit 600, respectively.
  • the control unit 600 controls the valves 171, 371, and 520 of the first PLA fiber maker 100, the second PLA fiber maker 300, and the pulp supply unit 500 to control the injection amount of the first and second PLA fibers and pulp.
  • the first and second PLA fibers are first sprayed to be integrated in a web form on the first and second mesh drums 200 and 400, and then the pulp is interposed between the first and second PLA fibers integrated in a web form.
  • the injection time difference between the first and second PLA and the pulp is controlled so as to be effective.
  • one side of the second mesh drum 400 is provided with a heat fusion unit 700.
  • the heat-sealed portion 700 is composed of a calendar through which a laminate stacked in the order of the first PLA fibers, pulp, and the second PLA fibers guided by the second mesh drum 400.
  • the calendar is a compression roller that lubricates paper or paper, and heat-bonds the first PLA fibers, the pulp, and the second PLA fibers of the laminate to be passed in a state where heat is applied.
  • the pattern is engraved on the calendar to increase the bonding force of the first PLA fiber, pulp, the second PLA fiber.
  • Figure 4 is a flow chart for explaining a method for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
  • Eco-friendly biodegradable nonwoven fabric is a PLA (biodegradable polylactic acid) is put into the extruder of the first and second fiber makers, respectively, melted and then spinning nozzles formed with hundreds of small orifices (Orifice) S10 step of producing the first PLA fiber and the second PLA fiber by stretching through and cooling with high-pressure hot air sprayed at high speed from both sides of the spinning nozzle; Injecting the first PLA fiber produced in the first fiber maker on the first mesh drum to integrate in the form of a web (Web), and by spraying the second PLA fiber produced in the second fiber maker on the second mesh drum S20 step of integrating in the form of a web (Web); S30 step of supplying the pulp interposed between the first PLA fiber and the second PLA fiber integrated in the web form; 1 PLA fiber, pulp, S40 step of bonding the second PLA fiber by heat fusion; It is prepared to include.
  • PLA biodegradable polylactic acid
  • Step S10 is made in the first PLA fiber manufacturing machine 100 and the second PLA fiber manufacturing machine (300).
  • PLA biologically polylactic acid
  • PLA has a melting point of 100 to 180 °C
  • the melt index is 20 to 40g / 10 minutes level
  • melt density of 0.98 to 2.24g / cm 3 (260 °C) is used that has a characteristic range.
  • PLA is used selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
  • the extruders 110 and 310 may include a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., and a fourth region having a temperature of 230 to 240 ° C. It is partitioned into the 5th area
  • PLA is completely dissolved while passing through the first to fifth regions of the extruders 110 and 310.
  • the completely dissolved PLA is filtered through the filter devices 120 and 320 and supplied to the injection nozzle 130, and the PLA supplied to the injection nozzles 130 and 330 is injected through hundreds of small orifices.
  • the injected PLA is stretched by the high pressure hot air sprayed at high speed by the hot air fans 140 and 340, and cooled and fiberized by the coolers 150 and 350.
  • the fiberized PLA is cut through the cutters 160 and 360 and sprayed through the injection holes 170 and 370.
  • the first PLA fibers 10 and the second PLA fibers 30, which are sprayed to the injection holes 170 and 370 are sprayed 10% to 40% by weight relative to the total weight of the nonwoven fabric.
  • step S20 the first PLA fiber 10 manufactured by the first fiber maker 100 is sprayed on the first mesh drum 200, and the first mesh drum 200 is sprayed on the first PLA fiber 10.
  • the second PLA fiber 30 manufactured in the second fiber maker 300 is sprayed on the second mesh drum 400, the second mesh drum 400 is sprayed on the second PLA fiber (30) Integrate in the form of Web.
  • the web formed by the Melt-Blown method has an isotrophic formation. That is, since the web is formed for hot air, the fibers are arbitrarily arranged in the machine direction and the machine width direction, and are not sufficiently cooled so that mutual bonding is achieved by thermal bonding between the fibers.
  • step S30 the pulp 20 injected from the pulp supply unit 500 is interposed between the first PLA fiber 10 and the second PLA fiber 30 which are integrated and transported in a web form. At this time, the pulp 20 is 25% by weight to 80% by weight relative to the total weight of the nonwoven fabric.
  • step S40 the laminate stacked in order of the first PLA fibers 10, the pulp 20, and the second PLA fibers 30 is passed through the heat-sealed portion 700 to thermally bond the laminates to each other.
  • the second PLA fiber layer laminated on one surface of the pulp layer is heat-sealed to produce a nonwoven fabric.
  • a nonwoven fabric was prepared by spraying 25 wt% of the total weight of the nonwoven fabric on a two-mesh drum and integrating the second PLA fiber layer laminated on one surface of the pulp layer by integrating a web.
  • the first PLA fiber layer integrated in the form of a web, a pulp layer laminated by spraying 20% by weight relative to the total weight of the nonwoven fabric on one surface of the first PLA fiber layer, 40 wt% of the nonwoven fabric was sprayed onto the two mesh drums and integrated in a web form to form a nonwoven fabric by mutually thermally bonding a second PLA fiber layer laminated on one surface of the pulp layer.
  • Examples 1, 2, and 3 show that the first PLA fiber layer and the second PLA fiber layer wrap the outer surface of the pulp layer to protect the pulp layer, and hold the pulp without breaking the pulp or dust. Played a role. In addition, it could be seen that due to the pulp layer to maintain a proper sense of volume, it was able to feel a soft texture, excellent absorbency.
  • the first PLA fiber layer and the second PLA fiber layer were formed so thick that the breakage of the first PLA fiber layer and the second PLA fiber layer occurred, the texture was rough, and the volume and absorbency were not good. That is, it can be seen that the first PLA fiber layer and the second PLA fiber layer is preferably used 40% by weight or less based on the total weight of the nonwoven fabric.
  • Comparative Example 2 was inferior in volume and feel compared to the examples, and the absorbency was also not good.
  • Example 1 exhibited an elongation of 35.6% at 20.5N before time elapse of the nonwoven fabric, followed by an elongation of 6.5% at 12.9N after 50 hours of nonwoven fabric, and after 75 hours of nonwoven fabric. Corrosion of the pulp progressed, the first PLA fiber and the second PLA fiber was not possible due to the progress of corrosion due to biodegradation.
  • Example 2 exhibited an elongation of 27.6% at 23.5 N before the time-lapse of the nonwoven fabric, an elongation of 8.5% at 15.9 N after 50 hours of nonwoven fabric, and corrosion of the pulp proceeded after 75 hours of nonwoven fabric.
  • the first PLA fiber and the second PLA fiber can not be measured because the tear due to the progress of corrosion.
  • Example 3 exhibited an elongation of 28.9% at 25.2N before the time-lapse of the nonwoven fabric, an elongation of 12.0% at 16.3N after 50 hours of nonwoven fabric, and corrosion of the pulp proceeded after 75 hours of nonwoven fabric.
  • the first PLA fibers and the second PLA fibers were torn due to the progress of corrosion and could not be measured.
  • the elongation was 8.0% at 5.1N before the time passed of the nonwoven fabric, the elongation was 4.0% at 3.5N after 50 hours of the nonwoven fabric, and the corrosion of the pulp proceeded after 75 hours of the nonwoven fabric.
  • the first PLA fiber and the second PLA fiber could not be measured due to breakage.
  • the present invention provides a nonwoven fabric by laminating the first PLA fiber, the pulp, and the second PLA fiber, which have biodegradation properties, thereby improving the softness, absorbency, and bulkiness of the pulp, and the first and second PLA fibers are made of pulp. It is held and protected to provide a nonwoven fabric that enhances the mechanical strength needed in practical use.
  • first and second PLA fibers to hold the surface of the pulp, which can be washed, thereby providing a non-woven fabric that can be used repeatedly.
  • the first PLA fiber manufacturing machine 200 the first mesh drum
  • pulp supply unit 510 carding machine
  • control unit 700 heat fusion unit

Abstract

Provided are environment-friendly and biodegradable non-woven fabric, and an apparatus and a method for producing same, the method for producing the non-woven fabric according to an embodiment of the present invention comprising: step S10 for producing a first PLA fiber and a second PLA fiber by inserting biodegradable PLA into respective extruders of first and second fiber-producing machines and melting, spinning by means of a spinning nozzle having hundreds of small orifices, and fiberizing by elongating and cooling by means of heated high-pressure air sprayed from both sides of the spinning nozzle at high speeds; step S20 for spraying the first PLA fiber produced from the first fiber-producing machine on a first mesh drum to accumulate into a web, and spraying the second PLA fiber produced from the second fiber-producing machine on a second mesh drum to accumulate into a web; step S30 for supplying and interposing pulp in between the first PLA fiber and second PLA fiber accumulated into webs; and step S40 for combining the first PLA fiber, pulp and second PLA fiber by thermal bonding. According to an embodiment of the present invention, the smoothness, absorbency and volumetric characteristic of the pulp are preserved by interposing pulp having smoothness, absorbency and volumetric characteristic in between the first and second PLA fibers having superb physical characteristics, non-woven fabric having superb product quality can be effectively produced as the first and second PLA layers hold and protect the pulp layer to impart the necessary mechanical strength during actual use, and the production cost can be reduced by means of a simplified process.

Description

친환경 생분해 부직포 및 그 제조장치 및 제조방법Eco-friendly biodegradable nonwoven fabric and its manufacturing apparatus and manufacturing method
본 발명의 실시 예는 친환경 생분해 부직포 및 그 제조장치 및 제조방법에 관한 것으로서, 좀 더 상세하게는 흡수성과 부드러움과 부피감을 살리고 기계적인 물성을 향상시키는 친환경 생분해 부직포 및 그 제조장치 및 제조방법에 관한 것이다.Embodiments of the present invention relate to an eco-friendly biodegradable nonwoven fabric and a manufacturing apparatus and a manufacturing method thereof, and more particularly, to an eco-friendly biodegradable nonwoven fabric and an apparatus and a manufacturing method for improving the mechanical properties of absorbent and soft and bulky will be.
일반적으로 부직포란 짜지 않은 섬유를 말한다. 즉, 방적, 제직, 편조에 의하지 않은 섬유 집합제를 뜻하며, 시트화시켜 물리적, 화학적 수단에 의하여 결합시킨 것을 뜻한다.In general, nonwoven refers to nonwoven fabric. That is, it refers to a fiber aggregate that is not based on spinning, weaving, or braiding, and means sheeting and bonding by physical and chemical means.
종래 부직포는 위생용품으로 사용시 흡수성이 좋은 펄프와 결합력이 높은 폴리 에틸렌(PE)이나 폴리 프로필렌(PP)을 복합분사하여 제조하였다.Conventional nonwoven fabrics were prepared by composite injection of high absorbency pulp and high polyethylene (PE) or polypropylene (PP) when used as a hygiene product.
그러나, 폴리 에틸렌(PE)이나 폴리 프로필렌(PP)은 유해성분이 분사되고 흡수가 되지 않아서 연약한 피부엔 홍반 가려움증 등 피부질환을 일으킬 수 있는 문제점이 있고, 썩지 않은 특성때문에 폐기 후 환경문제를 유발시키는 문제점이 있었다.However, polyethylene (PE) or polypropylene (PP) is a problem that can cause skin diseases such as itching and erythema in the soft skin because harmful components are not sprayed and absorbed, and the problem of causing environmental problems after disposal due to the non-rotating characteristics There was this.
최근 지구 온난화에 따라 이산화탄소를 줄이고자 하는 노력들이 지속 연구되고 있다. 특히, 화석연료로부터 생산되는 폴리머는 이산화탄소의 배출량을 높일 뿐만 아니라 매장량의 한계가 있기 때문에 천연식물로부터 합성되는 폴리머를 용융분사하여 섬유화할 수 있는 폴리유산 제품에 대한 연구가 진행되고 있다.Recently, efforts to reduce carbon dioxide due to global warming have been continuously studied. In particular, since the polymer produced from fossil fuel not only increases the amount of carbon dioxide emission but also has a limited reserve, research on polylactic acid products that can melt and polymerize the polymer synthesized from natural plants is being conducted.
폴리유산((Poly lactic acid; PLA)은 전세계에 15만톤 규모 시장을 형성하고 있고, PLA의 생분해성 특성을 이용한 일회용 제품은 물론 식품 포장재, 용기, 전자제품 케이스 등의 일반 플라스틱이 사용되었던 분야까지 그 적용 범위가 확대되고 있다. Polylactic acid (PLA) forms a market of 150,000 tons in the world, and is used not only for disposable products using the biodegradable properties of PLA, but also for general plastics such as food packaging materials, containers, and electronics cases. The scope of application is expanding.
그러나, 폴리유산((Poly lactic acid; PLA)는 폴리 에틸렌(PE)이나 폴리 프로필렌(PP)보다 가격이 높고, 감촉이 거칠며, 부피감이 적을 뿐만 아니라 신축성이 낮은 문제점이 있었다.However, polylactic acid (PLA) is more expensive than polyethylene (PE) or polypropylene (PP), has a rough feel, has a small volume, and has a problem of low elasticity.
[선행기술문헌][Preceding technical literature]
한국공개특허: 10-2012-0107092 (공개일 2012. 09. 28)Korean Publication Patent: 10-2012-0107092 (Published 2012. 09. 28)
한국등록특허: 10-1075004 (공고일 2011. 10. 19)Korea Patent Registration: 10-1075004 (Notice date 2011. 10. 19)
본 발명은 종래의 문제점을 해결하기 위해 안출 된 것으로서,The present invention has been made to solve the conventional problems,
본 발명의 목적은 물성이 우수한 제 1 PLA층과 제 2 PLA층 사이에 부드러운 특성과 흡수성과 부피감을 갖는 펄프층을 개재하여 흡수성과 부드러움과 부피감을 살리고, 물리적 성질을 향상시키며, 폐기 후 100% 생분해가 이루어지는 친환경 생분해 부직포 및 그 제조장치 및 제조방법을 제공하는 데 있다.An object of the present invention is to use the pulp layer having a soft property, absorbency and volume between the first PLA layer and the second PLA layer having excellent physical properties to improve the physical properties, improve the physical properties, 100% after disposal It is to provide an eco-friendly biodegradable nonwoven fabric and a manufacturing apparatus and a manufacturing method of the biodegradation is made.
본 발명의 다른 목적은 부직포의 품질을 향상시키고, 제조비용을 절감시킬 수 있는 친환경 생분해 부직포 및 그 제조장치 및 제조방법을 제공하는 데 있다.Another object of the present invention is to provide an eco-friendly biodegradable nonwoven fabric, an apparatus and a manufacturing method thereof, which can improve the quality of the nonwoven fabric and reduce the manufacturing cost.
상기와 같은 목적을 달성하기 위해 제공되는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포 제조장치는 PLA를 섬유화시키는 제 1 PLA섬유제조기; 상기 제 1 PLA섬유제조기에서 분사되는 제 1 PLA섬유를 웹 형태로 집적하는 제 1 메쉬드럼; 상기 제 1 메쉬드럼 일측에 구비되어 상기 제 1 메쉬드럼 상에 집적된 제 1 PLA섬유 일면에 펄프를 적층시키는 펄프공급부; 상기 펄프공급부의 일측에 구비되어 PLA를 섬유화시키는 제 2 PLA섬유제조기; 상기 제 2 PLA섬유제조기에서 분사되는 제 2 PLA섬유를 웹 형태로 집적하여 상기 펄프의 일면에 적층시키는 제 2 메쉬드럼; 상기 제 1 PLA섬유, 펄프, 제 2 PLA섬유 순으로 적층된 적층물에 열을 가하여 상기 적층물들을 상호 열융착시키는 열융착부; 및 상기 제 1, 제 2 PLA섬유제조기, 펄프공급부와 전기적으로 연결되어 상기 제 1, 제 2 PLA섬유제조기에서 제조되는 제 1, 제 2 PLA섬유의 분사량을 제어하고, 상기 펄프공급부의 펄프공급량을 제어하는 제어부;를 포함하여 구성된다.Eco-friendly biodegradable nonwoven manufacturing apparatus according to an embodiment of the present invention provided to achieve the above object is a first PLA fiber manufacturing apparatus for fiberizing PLA; A first mesh drum integrating the first PLA fibers sprayed from the first PLA fibers in a web form; A pulp supply unit provided at one side of the first mesh drum to stack pulp on one surface of the first PLA fiber integrated on the first mesh drum; A second PLA fiber making machine provided on one side of the pulp supply unit to fiberize PLA; A second mesh drum in which the second PLA fibers sprayed from the second PLA fiber maker are integrated in a web form and laminated on one surface of the pulp; A heat fusion unit for heat-sealing the laminates by applying heat to the laminates stacked in order of the first PLA fibers, the pulp, and the second PLA fibers; And controlling the injection amount of the first and second PLA fibers manufactured by the first and second PLA fiber makers by being electrically connected to the first and second PLA fiber makers and the pulp supply unit, and the pulp supply amount of the pulp supply unit. Control unit for controlling; is configured to include.
상기 제 1, 제 2 PLA섬유제조기는 PLA(생분해성 폴리유산)를 용융 및 압출시키는 압출기와, 상기 압출기에서 용융된 PLA를 분사하는 수백 개의 작은 오리피스(Orifice)가 형성된 분사노즐과, 상기 분사노즐의 양옆에서 고압열풍을 분사하여 분사노즐에서 분사되는 PLA를 연신시키는 열풍기와, 상기 연신된 PLA를 냉각시키는 냉각기와, 상기 연신에 의해 결정된 PLA섬유를 절단하는 절단기와, 상기 절단된 PLA섬유를 분사하는 분사구를 포함하여 구성되는 것을 특징으로 한다.The first and second PLA fiber making machine is an extruder for melting and extruding PLA (biodegradable polylactic acid), a spray nozzle formed with hundreds of small orifices (orifice) for spraying the molten PLA in the extruder, and the injection nozzle A hot air fan for stretching PLA sprayed from the spray nozzle by spraying high-pressure hot air from both sides of the cooler, a cooler for cooling the stretched PLA, a cutter for cutting the PLA fiber determined by the stretching, and spraying the cut PLA fiber Characterized in that configured to include a jet.
상기 압출기와 분사노즐 사이에는 용융된 PLA를 필터링하는 필터장치가 더 포함되는 것을 특징으로 한다.Between the extruder and the injection nozzle is characterized in that it further comprises a filter device for filtering the molten PLA.
상기 압출기는 제 1 내지 제 5 영역으로 구획되고, 제 1 영역은 150∼160℃, 제 2 영역은 200∼210℃, 제 3 영역은 220∼230℃, 제 4 영역은 230∼240℃, 제 5 영역은 250∼260℃의 온도가 설정되는 것을 특징으로 한다.The extruder is divided into first to fifth regions, the first region is 150 to 160 ℃, the second region is 200 to 210 ℃, the third region is 220 to 230 ℃, the fourth region is 230 to 240 ℃, The five regions are characterized in that a temperature of 250 to 260 캜 is set.
상기 펄프공급부에는 시트 또는 매트로 이루어진 펄프섬유를 개별섬유로 분리시키는 소면기가 연결되는 것을 특징으로 한다.The pulp supply unit is characterized in that the carding machine for separating the pulp fibers consisting of sheets or mats into individual fibers are connected.
상기 제어부는 부직포 전체 중량에 대하여 10중량%∼40중량%의 제 1 PLA섬유가 분사되도록 제 1 PLA섬유제조기의 분사량을 제어하고, 부직포 전체 중량에 대하여 25중량%∼80중량%의 펄프가 공급되도록 펄프공급부의 공급량을 제어하며, 부직포 전체 중량에 대하여 10중량%∼40중량%의 제 2 PLA섬유가 분사되도록 제 2 PLA섬유제조기의 분사량을 제어하는 것을 특징으로 한다.The control unit controls the injection amount of the first PLA fiber manufacturing machine so that the first PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric, and 25% to 80% by weight of pulp is supplied to the total weight of the nonwoven fabric. The supply amount of the pulp supply unit is controlled so as to control the injection amount of the second PLA fiber maker so that the second PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric is injected.
본 발명의 일 실시 예에 따른 친환경 생분해 부직포 제조방법은 PLA(생분해성 폴리유산)를 제 1, 제 2 섬유제조기의 압출기에 각각 넣어 용융시킨 다음 수백 개의 작은 오리피스(Orifice)가 형성된 방사 노즐을 통해 방사하고 상기 방사 노즐 양옆에서 고속으로 분사되는 고압 열풍으로 연신 및 냉각시켜 제 1 PLA섬유 및 제 2 PLA섬유를 각각 제조하는 S10단계; 상기 제 1 섬유제조기에서 제조된 제 1 PLA섬유를 제 1 메쉬드럼 상에 분사하여 웹(Web) 형태로 집적하고, 상기 제 2 섬유제조기에서 제조된 제 2 PLA섬유를 제 2 메쉬드럼 상에 분사하여 웹(Web) 형태로 집적하는 S20단계; 상기 웹 형태로 집적된 제 1 PLA섬유와 제 2 PLA섬유 사이에 펄프를 공급하여 개재시키는 S30단계; 상기 제 1 PLA섬유, 펄프, 제 2 PLA섬유를 열융착하여 결합시키는 S40단계;를 포함하여 제조된다.Eco-friendly biodegradable nonwoven fabric manufacturing method according to an embodiment of the present invention is melted by putting PLA (biodegradable polylactic acid) into the extruder of the first and second fiber makers, respectively, and then through a spinning nozzle formed of hundreds of small orifices (Orifice) S10 step of producing the first PLA fibers and the second PLA fibers by spinning and cooling with high-pressure hot air sprayed at high speed from both sides of the spinning nozzle; Spraying the first PLA fiber produced in the first fiber maker on the first mesh drum to integrate in the form of a web (Web), and the second PLA fiber produced in the second fiber maker sprayed on the second mesh drum S20 step of integrating in the form of a web (Web); S30 step of supplying and interposing pulp between the first PLA fiber and the second PLA fiber integrated in the web form; It is prepared, including; S40 step of bonding the first PLA fibers, pulp, second PLA fibers by heat fusion bonding.
상기 압출기는 150∼160℃ 온도가 설정된 제 1 영역, 200∼210℃ 온도가 설정된 제 2 영역, 220∼230℃ 온도가 설정된 제 3 영역, 230∼240℃ 온도가 설정된 제 4 영역, 250∼260℃ 온도가 설정된 제 5 영역으로 구획되고, 상기 PLA는 제 1 내지 제 5 영역을 통과하여 완전용해가 이루어지는 것을 특징으로 한다.The extruder has a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., a fourth region having a temperature of 230 to 240 ° C., and a 250 to 260 ° C. The temperature is divided into a fifth region is set, the PLA is characterized in that complete melting through the first to fifth regions.
그리고, 상기 S10단계에는 용융된 PLA를 필터링하는 단계가 더 포함되는 것을 특징으로 한다.And, the step S10 characterized in that it further comprises the step of filtering the molten PLA.
또한, 상기 PLA는 폴리-D-유산, 폴리-L-유산, D-유산과 L-유산의 공중합체로 이루어진 군으로부터 선택된 것을 특징으로 한다.In addition, the PLA is characterized in that selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
또한, 상기 PLA는 융점이 100℃∼180℃ 이고, 용융지수 75∼120g/10분이며, 용융밀도는 0.98 내지 2.24g/㎤(260℃) 범위의 특성을 갖는 것을 특징으로 한다.In addition, the PLA has a melting point of 100 ℃ to 180 ℃, the melt index is 75 to 120g / 10 minutes, the melt density is characterized in that it has a characteristic in the range of 0.98 to 2.24g / cm3 (260 ℃).
상기 펄프는 시트 또는 매트로 이루어진 펄프섬유를 소면기에 넣어 개별섬유로 분리시킨 것이 사용되는 것을 특징으로 한다.The pulp is characterized in that the pulp fibers made of a sheet or mat put into a carding machine and separated into individual fibers.
상기 제 1 PLA섬유는 부직포 전체 중량의 10중량%∼40중량% 분사되어 집적되고, 상기 펄프는 부직포 전체 중량의 25중량%∼80중량% 공급되어 집적되며, 제 2 PLA섬유는 부직포 전체 중량의 10중량%∼40중량% 분사되어 집적되는 것을 특징으로 한다.The first PLA fibers are injected by injecting 10% by weight to 40% by weight of the total weight of the nonwoven fabric, and the pulp is fed by 25% by weight to 80% by weight of the total weight of the nonwoven fabric. 10% by weight to 40% by weight is characterized in that the injection is integrated.
본 발명의 일 실시 예에 따른 친환경 생분해 부직포는 상기의 제조방법에 의하여, 제 1 메쉬드럼 상에서 웹 형태로 집적된 제 1 PLA섬유층; 상기 제 1 PLA섬유층 상부에 적층되는 펄프층; 제 2 메쉬드럼 상에 웹(Web) 형태로 집적되어 상기 펄프층 상면에 적층되는 제 2 PLA섬유층이 상호 열융착되어 제조되는 것을 특징으로 한다.Eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention, the first PLA fiber layer integrated in the form of a web on the first mesh drum by the above production method; A pulp layer laminated on the first PLA fiber layer; The second PLA fiber layer is integrated on the second mesh drum in the form of a web and laminated on the upper surface of the pulp layer.
본 발명의 실시 예는 물성이 우수한 제 1, 제 2 PLA섬유 사이에 부드러운 특성과 흡수성과 부피감을 갖는 펄프를 개재하여 펄프의 부드러운 특성과 흡수성과 부피감을 살리고, 제 1 PLA섬유와 제 2 PLA섬유가 펄프를 잡아주고 보호하여 실제 사용시 필요한 기계적 강도를 갖게 함으로써 품질이 우수한 부직포를 효율적으로 제조할 수 있고, 간단한 공정을 통해 제조비용을 절감시킬 수 있는 효과가 있다.An embodiment of the present invention utilizes the soft properties, absorbency and volume of the pulp, the first PLA fiber and the second PLA fiber through the pulp having a soft property and absorbency and volume between the first and second PLA fibers having excellent physical properties By holding and protecting the pulp to have the mechanical strength required in actual use, it is possible to efficiently manufacture high-quality nonwoven fabrics, and to reduce the manufacturing cost through a simple process.
또한, 펄프를 이용함으로써 제조단가를 절감시킬 수 있고, 폐기 후 100% 생분해가 이루어짐에 따라 환경문제를 유발시키지 않으며, 발암물질이나 위생에 해로운 물질을 방출하지 않을 뿐만 아니라 통기성과 청량감이 우수하여 위생성 및 안전성이 향상되는 부직포를 제조할 수 있게 된다.In addition, by using the pulp can reduce the manufacturing cost, 100% biodegradation after disposal, does not cause environmental problems, does not emit carcinogens or harmful substances to hygiene, hygiene and hygiene is excellent And it becomes possible to manufacture a nonwoven fabric with improved safety.
또한, 제 1, 제 2 PLA섬유가 펄프의 표면을 잡고 있어서 세척이 가능하고 이로 인하여 여러 번 반복 사용이 가능한 부직포를 제조할 수 있게 된다.In addition, since the first and second PLA fibers hold the surface of the pulp, it is possible to wash, thereby producing a non-woven fabric that can be used repeatedly.
도 1은 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치를 설명하기 위한 개략도.1 is a schematic diagram for explaining the eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
도 2는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치의 전체 구성을 설명하기 위한 블럭도.Figure 2 is a block diagram for explaining the overall configuration of the eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
도 3은 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치에서 제 1, 제 2 PLA섬유제조기의 구성을 설명하기 위한 블럭도.Figure 3 is a block diagram for explaining the configuration of the first, second PLA fiber manufacturing apparatus in an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
도 4는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조방법을 설명하기 위한 순서도.Figure 4 is a flow chart for explaining a method for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
도 5는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포를 도시한 단면도.Figure 5 is a cross-sectional view showing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
본 발명의 상기와 같은 목적, 특징 및 다른 장점들은 첨부도면을 참조하여 본 발명의 바람직한 실시 예를 상세히 설명함으로써 더욱 명백해질 것이다. 이하, 첨부된 도면을 참조하여 본 발명의 친환경 생분해 부직포 및 그 제조장치 및 제조방법을 상세히 설명하기로 한다. 본 명세서를 위해서, 도면에서의 동일한 참조번호들은 달리 지시하지 않는 한 동일한 구성 부분을 나타낸다.The above objects, features and other advantages of the present invention will become more apparent by describing the preferred embodiments of the present invention in detail with reference to the accompanying drawings. Hereinafter, with reference to the accompanying drawings will be described in detail the eco-friendly biodegradable non-woven fabric and its manufacturing apparatus and manufacturing method of the present invention. For the purposes of this specification, like reference numerals in the drawings denote like parts unless otherwise indicated.
도 1은 본 발명의 일 실시 예에 따른 친환경 생분해 부직포 제조장치를 설명하기 위한 개략도이고, 도 2는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포 제조장치의 전체 구성을 설명하기 위한 블럭도이며, 도 3은 본 발명의 일 실시 예에 따른 친환경 생분해 부직포 제조장치에서 제 1, 제 2 PLA섬유제조기의 구성을 설명하기 위한 블럭도이다.1 is a schematic diagram for explaining an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention, Figure 2 is a block diagram for explaining the overall configuration of an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention, Figure 3 is a block diagram for explaining the configuration of the first, second PLA fiber manufacturing apparatus in an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
도 1, 도 2에 도시된 바와 같이 친환경 생분해 부직포의 제조장치는 제 1 PLA섬유제조기(100), 제 1 메쉬드럼(200), 제 2 PLA섬유제조기(300), 제 2 메쉬드럼(400), 펄프공급부(500), 제어부(600), 열융착부(700)를 포함한다.As shown in FIG. 1, FIG. 2, the apparatus for producing eco-friendly biodegradable nonwoven fabric includes a first PLA fiber maker 100, a first mesh drum 200, a second PLA fiber maker 300, and a second mesh drum 400. It includes a pulp supply unit 500, the control unit 600, the heat fusion unit 700.
먼저, 제 1, 제 2 PLA섬유제조기(100,300)는 도 3에 도시된 바와 같이 투입되는 PLA(생분해성 폴리유산)를 용융 및 압출시키는 압출기(110,310)와, 압출기에서 용융된 PLA를 분사하는 수백 개의 작은 오리피스(Orifice)가 형성된 분사노즐(130,330)과, 압출기와 분사노즐 사이에 구비되어 용융된 PLA를 필터링하는 필터장치(120,320)와, 분사노즐의 양옆에 구비되어 분사노즐로 분사되는 PLA을 연신시키는 열풍기(140,340)와, 연신된 PLA를 냉각시키는 냉각기(150,350)와, 연신에 의해 결정된 PLA섬유를 절단하는 절단기(160,360)와, 절단된 PLA섬유를 분사하는 분사구(170,370)를 포함하여 구성된다. 그리고, 분사구에는 제어부와 전기적으로 연결되어 분사되는 PLA섬유의 분사량을 조절하는 밸브(171,371)가 구비된다.First, the first and second PLA fiber makers 100 and 300 are extruders 110 and 310 for melting and extruding PLA (biodegradable polylactic acid) introduced as shown in FIG. 3, and hundreds of spraying molten PLA from the extruder. Injection nozzles 130 and 330 having two small orifices formed therein, filter devices 120 and 320 provided between the extruder and the injection nozzle to filter the molten PLA, and PLAs which are provided on both sides of the injection nozzles and sprayed by the injection nozzles. It comprises a hot air fan (140,340) for stretching, a cooler (150,350) for cooling the stretched PLA, cutters (160,360) for cutting the PLA fiber determined by the stretching, and injection holes (170,370) for spraying the cut PLA fiber do. And, the injection port is provided with valves (171, 371) for controlling the injection amount of the PLA fiber is electrically connected to the control unit.
여기서, 압출기(110,310)는 제 1 내지 제 5 영역으로 구획된다. 그리고, 구획된 제 1 영역은 150∼160℃, 제 2 영역은 200∼210℃, 제 3 영역은 220∼230℃, 제 4 영역은 230∼240℃, 제 5 영역은 250∼260℃의 온도가 각각 설정된다.Here, the extruders 110 and 310 are partitioned into first to fifth regions. Then, the partitioned first region is 150 to 160 캜, the second region is 200 to 210 캜, the third region is 220 to 230 캜, the fourth region is 230 to 240 캜 and the fifth region is 250 to 260 캜. Are set respectively.
그리고, 분사노즐(130,330)은 12∼16cm당 0.88mm를 갖으며, 높은 속도분배를 갖는 고온의 공기는 직경 0.1μ으로부터 500μ 사이의 다양한 필라멘트를 형성시킨다.The injection nozzles 130 and 330 have 0.88 mm per 12 to 16 cm, and hot air having a high velocity distribution forms various filaments between 0.1 μm and 500 μ in diameter.
제 1 PLA섬유제조기(100) 하부에는 제 1 메쉬드럼(200)이 배치되고, 제 2 PLA섬유제조기(300) 하부에는 제 2 메쉬드럼(400)이 배치된다.A first mesh drum 200 is disposed below the first PLA fiber maker 100, and a second mesh drum 400 is disposed below the second PLA fiber maker 300.
그리고, 제 1 메쉬드럼(200)은 제 1 PLA섬유제조기(100)에서 분사되는 제 1 PLA섬유(10)를 웹 형태로 집적하고, 제 2 메쉬드럼(400)은 제 2 PLA섬유제조기(300)에서 분사되는 제 2 PLA섬유(30)를 웹 형태로 집적한다. In addition, the first mesh drum 200 integrates the first PLA fiber 10 sprayed from the first PLA fiber maker 100 into a web form, and the second mesh drum 400 is the second PLA fiber maker 300. Integrate the second PLA fiber 30 is injected in the form of a web.
제 1 메쉬드럼(200)과 제 2 메쉬드럼(400) 사이에는 펄프공급부(500)가 배치된다.The pulp supply unit 500 is disposed between the first mesh drum 200 and the second mesh drum 400.
펄프공급부(500)는 제 1 메쉬드럼(200)과 제 2 메쉬드럼(400) 사이에 펄프를 공급하여 제 1 메쉬드럼(200) 상에서 웹 형태로 집적된 제 1 PLA섬유(10)와 제 2 메쉬드럼(400) 상에서 웹 형태로 집적된 제 2 PLA섬유(30) 사이에 펄프(20)를 개재시킨다. The pulp supply unit 500 supplies the pulp between the first mesh drum 200 and the second mesh drum 400 to integrate the first PLA fiber 10 and the second PLA fiber in a web form on the first mesh drum 200. The pulp 20 is interposed between the second PLA fibers 30 integrated in the web form on the mesh drum 400.
여기서, 펄프공급부(500)는 펄프를 직접 공급할 수도 있으나, 펄프공급부(500)에는 시트 또는 매트로 이루어진 펄프섬유를 개별섬유로 분리시키는 소면기(510)가 연결되어 시트 또는 매트로 이루어진 펄프섬유를 분리시킨 개별섬유의 펄프를 공급할 수도 있다. Here, the pulp supply unit 500 may directly supply pulp, but the pulp supply unit 500 is connected to a carding machine 510 which separates the pulp fibers made of sheets or mats into individual fibers to connect pulp fibers made of sheets or mats. The pulp of the separated individual fibers can also be fed.
제 1 PLA섬유제조기(100)와, 제 2 PLA섬유제조기(300)와, 펄프공급부(500)는 각각 제어부(600)와 전기적으로 연결된다.The first PLA fiber maker 100, the second PLA fiber maker 300, and the pulp supply unit 500 is electrically connected to the control unit 600, respectively.
제어부(600)는 제 1 PLA섬유제조기(100)와, 제 2 PLA섬유제조기(300)와, 펄프공급부(500)의 밸브(171,371,520)를 제어하여 제 1, 제 2 PLA섬유 및 펄프의 분사량을 제어한다. 또한, 제 1, 제 2 PLA섬유가 먼저 분사되어 제 1, 제 2 메쉬드럼 (200,400)상에서 웹 형태로 집적되게 한 후 펄프가 분사되어 웹 형태로 집적된 제 1, 제 2 PLA섬유 사이에 개재되도록 제 1, 제 2 PLA와 펄프의 분사 시간차를 제어한다. The control unit 600 controls the valves 171, 371, and 520 of the first PLA fiber maker 100, the second PLA fiber maker 300, and the pulp supply unit 500 to control the injection amount of the first and second PLA fibers and pulp. To control. In addition, the first and second PLA fibers are first sprayed to be integrated in a web form on the first and second mesh drums 200 and 400, and then the pulp is interposed between the first and second PLA fibers integrated in a web form. The injection time difference between the first and second PLA and the pulp is controlled so as to be effective.
그리고, 제 2 메쉬드럼(400)의 일측에는 열융착부(700)가 구비된다.Then, one side of the second mesh drum 400 is provided with a heat fusion unit 700.
열융착부(700)는 제 2 메쉬드럼(400)에 의해 안내되는 제 1 PLA섬유, 펄프, 제 2 PLA섬유 순으로 적층된 적층물이 통과되는 켈린더로 구성된다. 켈린더는 종이나 피륙에 윤을 내는 압착롤러로서 열이 가해진 상태에서 통과되는 적층물의 제 1 PLA섬유, 펄프, 제 2 PLA섬유를 상호 열융착시킨다. 이때, 켈린더에는 제 1 PLA섬유, 펄프, 제 2 PLA섬유의 결합력을 높이도록 무늬가 조각된다. The heat-sealed portion 700 is composed of a calendar through which a laminate stacked in the order of the first PLA fibers, pulp, and the second PLA fibers guided by the second mesh drum 400. The calendar is a compression roller that lubricates paper or paper, and heat-bonds the first PLA fibers, the pulp, and the second PLA fibers of the laminate to be passed in a state where heat is applied. At this time, the pattern is engraved on the calendar to increase the bonding force of the first PLA fiber, pulp, the second PLA fiber.
도 4는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조방법을 설명하기 위한 순서도이다.Figure 4 is a flow chart for explaining a method for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조방법은 PLA(생분해성 폴리유산)를 제 1, 제 2 섬유제조기의 압출기에 각각 넣어 용융시킨 다음 수백 개의 작은 오리피스(Orifice)가 형성된 방사 노즐을 통해 방사하고 상기 방사 노즐 양옆에서 고속으로 분사되는 고압 열풍으로 연신 및 냉각시켜 제 1 PLA섬유 및 제 2 PLA섬유를 각각 제조하는 S10단계; 제 1 섬유제조기에서 제조된 제 1 PLA섬유를 제 1 메쉬드럼 상에 분사하여 웹(Web) 형태로 집적하고, 상기 제 2 섬유제조기에서 제조된 제 2 PLA섬유를 제 2 메쉬드럼 상에 분사하여 웹(Web) 형태로 집적하는 S20단계; 웹 형태로 집적된 제 1 PLA섬유와 제 2 PLA섬유 사이에 펄프를 공급하여 개재시키는 S30단계; 제 1 PLA섬유, 펄프, 제 2 PLA섬유를 열융착하여 결합시키는 S40단계;를 포함하여 제조된다.Eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention is a PLA (biodegradable polylactic acid) is put into the extruder of the first and second fiber makers, respectively, melted and then spinning nozzles formed with hundreds of small orifices (Orifice) S10 step of producing the first PLA fiber and the second PLA fiber by stretching through and cooling with high-pressure hot air sprayed at high speed from both sides of the spinning nozzle; Injecting the first PLA fiber produced in the first fiber maker on the first mesh drum to integrate in the form of a web (Web), and by spraying the second PLA fiber produced in the second fiber maker on the second mesh drum S20 step of integrating in the form of a web (Web); S30 step of supplying the pulp interposed between the first PLA fiber and the second PLA fiber integrated in the web form; 1 PLA fiber, pulp, S40 step of bonding the second PLA fiber by heat fusion; It is prepared to include.
S10단계는 제 1 PLA섬유제조기(100) 및 제 2 PLA섬유제조기(300)에서 이루어진다.Step S10 is made in the first PLA fiber manufacturing machine 100 and the second PLA fiber manufacturing machine (300).
먼저, 제 1 PLA섬유제조기(100) 및 제 2 PLA섬유제조기(300)의 압출기(110,310)에 각각 PLA(생분해성 폴리유산)를 넣어 용융시킨다. First, PLA (biodegradable polylactic acid) is put into the extruders 110 and 310 of the first PLA fiber maker 100 and the second PLA fiber maker 300 to melt.
여기서, PLA는 융점이 100∼180℃이고, 용융지수는 20∼40g/10분 수준이며, 용융밀도는 0.98 내지 2.24g/㎤(260℃) 범위의 특성을 갖는 것이 사용된다. 또한, PLA는 폴리-D-유산, 폴리-L-유산, D-유산과 L-유산의 공중합체로 이루어진 군으로부터 선택된 것이 사용된다.Here, PLA has a melting point of 100 to 180 ℃, the melt index is 20 to 40g / 10 minutes level, melt density of 0.98 to 2.24g / cm 3 (260 ℃) is used that has a characteristic range. In addition, PLA is used selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
그리고, 압출기(110,310)는 150∼160℃ 온도가 설정된 제 1 영역, 200∼210℃ 온도가 설정된 제 2 영역, 220∼230℃ 온도가 설정된 제 3 영역, 230∼240℃ 온도가 설정된 제 4 영역, 250∼260℃ 온도가 설정된 제 5 영역으로 구획되어 있다. The extruders 110 and 310 may include a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., and a fourth region having a temperature of 230 to 240 ° C. It is partitioned into the 5th area | region set at 250-260 degreeC temperature.
따라서, PLA는 압출기(110,310)의 제 1 내지 제 5 영역을 통과하면서 완전용해가 이루어진다.Therefore, PLA is completely dissolved while passing through the first to fifth regions of the extruders 110 and 310.
이어, 완전용해가 이루어진 PLA는 필터장치(120,320)에 필터링되어 분사노즐(130)로 공급되고, 분사노즐(130,330)로 공급된 PLA는 수백 개의 작은 오리피스(Orifice)를 통해 분사된다. Subsequently, the completely dissolved PLA is filtered through the filter devices 120 and 320 and supplied to the injection nozzle 130, and the PLA supplied to the injection nozzles 130 and 330 is injected through hundreds of small orifices.
이어, 분사된 PLA는 열풍기(140,340)에서 고속 분사하는 고압 열풍에 의해 연신되고 냉각기(150,350)에 의해 냉각되어 섬유화된다. Subsequently, the injected PLA is stretched by the high pressure hot air sprayed at high speed by the hot air fans 140 and 340, and cooled and fiberized by the coolers 150 and 350.
그리고 섬유화된 PLA는 절단기(160,360)에 절단되어 분사구(170,370)를 통해 분사된다. 이때, 분사구(170,370)로 분사되는 제 1 PLA섬유(10) 및 제 2 PLA섬유(30)는 각각 부직포 전체 중량에 대하여 10중량%∼40중량% 분사된다.The fiberized PLA is cut through the cutters 160 and 360 and sprayed through the injection holes 170 and 370. At this time, the first PLA fibers 10 and the second PLA fibers 30, which are sprayed to the injection holes 170 and 370 are sprayed 10% to 40% by weight relative to the total weight of the nonwoven fabric.
S20단계는 제 1 섬유제조기(100)에서 제조된 제 1 PLA섬유(10)는 제 1 메쉬드럼(200) 상에 분사되고, 제 1 메쉬드럼(200)은 분사되는 제 1 PLA섬유(10)를 웹(Web) 형태로 집적한다. 그리고, 제 2 섬유제조기(300)에서 제조된 제 2 PLA섬유(30)는 제 2 메쉬드럼(400) 상에 분사되고, 제 2 메쉬드럼(400)은 분사되는 제 2 PLA섬유(30)를 웹(Web) 형태로 집적한다. In step S20, the first PLA fiber 10 manufactured by the first fiber maker 100 is sprayed on the first mesh drum 200, and the first mesh drum 200 is sprayed on the first PLA fiber 10. In the form of a Web. Then, the second PLA fiber 30 manufactured in the second fiber maker 300 is sprayed on the second mesh drum 400, the second mesh drum 400 is sprayed on the second PLA fiber (30) Integrate in the form of Web.
이때, Melt-Blown 방식에 의해 형성된 웹은 등방향구조(Isotrophic Formation)를 갖는다. 즉, 웹이 고온의 공기에 위해 형성되기 때문에 섬유가 기계방향과 기계 폭 방향으로 임의로 배열되고, 충분히 냉각된 상태가 아니어서 섬유 간 열 접착으로 상호 결합이 이루어진다.In this case, the web formed by the Melt-Blown method has an isotrophic formation. That is, since the web is formed for hot air, the fibers are arbitrarily arranged in the machine direction and the machine width direction, and are not sufficiently cooled so that mutual bonding is achieved by thermal bonding between the fibers.
S30단계는 웹 형태로 집적되어 이송되는 제 1 PLA섬유(10)와 제 2 PLA섬유 (30)사이에 펄프공급부(500)에서 분사되는 펄프(20)를 개재시킨다. 이때, 펄프(20)는 부직포 전체 중량에 대하여 25중량%∼80중량%가 개재된다.In step S30, the pulp 20 injected from the pulp supply unit 500 is interposed between the first PLA fiber 10 and the second PLA fiber 30 which are integrated and transported in a web form. At this time, the pulp 20 is 25% by weight to 80% by weight relative to the total weight of the nonwoven fabric.
S40단계는 제 1 PLA섬유(10), 펄프(20), 제 2 PLA섬유(30) 순으로 적층된 적층물을 열융착부(700)에 통과시켜 적층물을 상호 열융착시킨다. In step S40, the laminate stacked in order of the first PLA fibers 10, the pulp 20, and the second PLA fibers 30 is passed through the heat-sealed portion 700 to thermally bond the laminates to each other.
상기의 제조방법에 의하여 도 5에 도시된 바와 같이 제 1 메쉬드럼 상에서 웹 형태로 집적된 제 1 PLA섬유층과, 제 1 PLA섬유층 일면에 적층되는 펄프층과, 제 2 메쉬드럼 상에서 웹 형태로 집적되어 펄프층의 일면에 적층되는 제 2 PLA섬유층이 열융착되어 부직포가 제조된다.As shown in FIG. 5, the first PLA fiber layer integrated in a web form on the first mesh drum, the pulp layer laminated on one surface of the first PLA fiber layer, and the web form integrated on the second mesh drum by the above manufacturing method. The second PLA fiber layer laminated on one surface of the pulp layer is heat-sealed to produce a nonwoven fabric.
(실시 예 1)(Example 1)
제 1 메쉬드럼 상에 부직포 전체 중량에 대하여 10중량%가 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 제 1 PLA섬유층 일면에 부직포 전체 중량에 대하여 80중량%가 분사되어 적층되는 펄프층, 제 2 메쉬드럼 상에 부직포 전체 중량에 대하여 10중량%가 분사되고 웹 형태로 집적되어 펄프층의 일면에 적층되는 제 2 PLA섬유층을 상호 열융착하여 부직포를 제조하였다.10% by weight relative to the total weight of the nonwoven fabric on the first mesh drum, the first pulp fiber layer integrated in the form of a web, pulp layer laminated by spraying 80% by weight relative to the total weight of the nonwoven fabric on one surface of the first PLA fiber layer, 10 wt% of the total weight of the nonwoven fabric was sprayed onto the two-mesh drum, and the second PLA fiber layer laminated on one surface of the pulp layer was integrated in a web form to prepare a nonwoven fabric.
(실시 예 2)(Example 2)
제 1 메쉬드럼 상에 부직포 전체 중량에 대하여 25중량%가 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 제 1 PLA섬유층 일면에 부직포 전체 중량에 대하여 50중량%가 분사되어 적층되는 펄프층, 제 2 메쉬드럼 상에 부직포 전체 중량에 대하여 25중량%가 분사되고 웹 형태로 집적되어 펄프층의 일면에 적층되는 제 2 PLA섬유층을 상호 열융착하여 부직포를 제조하였다.25% by weight of the total weight of the nonwoven fabric is sprayed onto the first mesh drum, and the pulp layer is laminated by spraying 50% by weight of the total weight of the nonwoven fabric on one surface of the first PLA fiber layer and the first PLA fiber layer. A nonwoven fabric was prepared by spraying 25 wt% of the total weight of the nonwoven fabric on a two-mesh drum and integrating the second PLA fiber layer laminated on one surface of the pulp layer by integrating a web.
(실시 예 3)(Example 3)
제 1 메쉬드럼 상에 부직포 전체 중량에 대하여 40중량%가 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 제 1 PLA섬유층 일면에 부직포 전체 중량에 대하여 20중량%가 분사되어 적층되는 펄프층, 제 2 메쉬드럼 상에 부직포 전체 중량에 대하여 40중량%가 분사되고 웹 형태로 집적되어 펄프층의 일면에 적층되는 제 2 PLA섬유층을 상호 열융착하여 부직포를 제조하였다.40% by weight relative to the total weight of the nonwoven fabric on the first mesh drum, the first PLA fiber layer integrated in the form of a web, a pulp layer laminated by spraying 20% by weight relative to the total weight of the nonwoven fabric on one surface of the first PLA fiber layer, 40 wt% of the nonwoven fabric was sprayed onto the two mesh drums and integrated in a web form to form a nonwoven fabric by mutually thermally bonding a second PLA fiber layer laminated on one surface of the pulp layer.
(비교 예 1)(Comparative Example 1)
제 1 메쉬드럼 상에 부직포 전체 중량에 대하여 45중량%가 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 제 1 PLA섬유층 일면에 부직포 전체 중량에 대하여 10중량%가 분사되어 적층되는 펄프층, 제 2 메쉬드럼 상에 부직포 전체 중량에 대하여 45중량%가 분사되고 웹 형태로 집적되어 펄프층의 일면에 적층되는 제 2 PLA섬유층을 상호 열융착하여 부직포를 제조하였다.45% by weight relative to the total weight of the nonwoven fabric on the first mesh drum, a pulp layer laminated by spraying 10% by weight relative to the total weight of the nonwoven fabric on one surface of the first PLA fiber layer integrated in the web form, the first PLA fiber layer, 45 wt% of the total weight of the nonwoven fabric was sprayed onto the two-mesh drum, and the second PLA fiber layer laminated on one surface of the pulp layer was integrated in a web form, thereby manufacturing a nonwoven fabric.
(비교 예 2)(Comparative Example 2)
펄프20 중량%와 폴리 에틸렌(PE) 40중량%와, 폴리 프로필렌(PP) 40중량%를 혼합하고 복합분사하여 부직포를 제조하였다.20% by weight of pulp, 40% by weight of polyethylene (PE), and 40% by weight of polypropylene (PP) were mixed and composite sprayed to prepare a nonwoven fabric.
<시험 1><Test 1>
실시 예 1, 2, 3 및 비교 예 1, 2의 부직포 각각에 대하여 부드러움, 부피감, 흡수성을 평가하여 [표 1]에 나타내었다.Softness, volume, and water absorption were evaluated for each of the nonwoven fabrics of Examples 1, 2, and 3 and Comparative Examples 1 and 2, and are shown in [Table 1].
표 1
실시 예 1 실시 예 2 실시 예 3 비교 예 1 비교 예 2
부드러움 ×
부피감
흡수성 ×
Table 1
Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2
Soft ×
Bulky
Absorbency ×
[표 1]에 나타낸 바와 같이 실시 예 1, 2, 3은 제 1 PLA섬유층과 제 2 PLA섬유층이 펄프층의 외면을 감싸서 펄프층을 보호하고, 펄프가 깨지거나 분진이 날리지 않게 펄프를 잡아주는 역할을 하였다. 또한, 펄프층으로 인하여 적당한 부피감을 유지시키는 것을 알 수 있었고, 부드러운 감촉을 느낄 수 있었으며, 흡수성이 우수함을 알 수 있었다. As shown in Table 1, Examples 1, 2, and 3 show that the first PLA fiber layer and the second PLA fiber layer wrap the outer surface of the pulp layer to protect the pulp layer, and hold the pulp without breaking the pulp or dust. Played a role. In addition, it could be seen that due to the pulp layer to maintain a proper sense of volume, it was able to feel a soft texture, excellent absorbency.
비교 예 1은 제 1 PLA섬유층과 제 2 PLA섬유층이 너무 두껍게 형성되어 제 1 PLA섬유층과 제 2 PLA섬유층의 부서짐이 발생하였고, 감촉이 거칠었으며, 부피감과 흡수성이 양호하지 못하였다. 즉, 제 1 PLA섬유층과 제 2 PLA섬유층은 각각 부직포 전체 중량에 대하여 40중량% 이하가 사용되는 것이 바람직함을 알 수 있었다. In Comparative Example 1, the first PLA fiber layer and the second PLA fiber layer were formed so thick that the breakage of the first PLA fiber layer and the second PLA fiber layer occurred, the texture was rough, and the volume and absorbency were not good. That is, it can be seen that the first PLA fiber layer and the second PLA fiber layer is preferably used 40% by weight or less based on the total weight of the nonwoven fabric.
또한, 비교 예 2는 부피감과 감촉이 실시 예들에 비하여 떨어졌으며, 흡수성도 양호하지 못하였다.In addition, Comparative Example 2 was inferior in volume and feel compared to the examples, and the absorbency was also not good.
<시험 2> <Test 2>
실시 예 1, 2, 3 및 비교 예 1, 2의 부직포 각각에 대하여 내환경성을 평가하였다. 즉, 부직포가 땅에 매립되었을 때와 동일한 환경의 조건으로 시간경과 전, 50시간(hr)과 75시간(hr) 경과 한 부직포의 전면에서 스프레이를 하여 부직포의 상태를 측정하여 [표 2]에 나타내었다.Environmental resistance was evaluated about each of the nonwoven fabrics of Examples 1, 2 and 3 and Comparative Examples 1 and 2. That is, the state of the nonwoven fabric is measured by spraying the front surface of the nonwoven fabric 50 hours (hr) and 75 hours (hr) before the time elapsed under the same conditions as when the nonwoven fabric is buried in the ground. Indicated.
표 2
실시 예 1 실시 예 2 실시 예 3 비교 예 1 비교 예 2
Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%)
시간경과전 20.5 35.6 23.5 27.6 25.2 28.9 5.1 8.0 19.2 31.6
50시간경과 12.9 6.5 15.9 8.5 16.3 12.0 3.5 4.0 9.0 21.0
75시간경과 측정불가 측정불가 측정불가 측정불가 5.9 9.5
TABLE 2
Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2
Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%)
Before time-lapse 20.5 35.6 23.5 27.6 25.2 28.9 5.1 8.0 19.2 31.6
50 hours 12.9 6.5 15.9 8.5 16.3 12.0 3.5 4.0 9.0 21.0
75 hours Not measurable Not measurable Not measurable Not measurable 5.9 9.5
[표 2]에 나타낸 바와 같이 실시 예 1은 부직포의 시간경과 전 20.5N에서 연신률 35.6%를 나타내었고, 부직포의 50시간 경과 후 12.9N에서 연신률 6.5%을 나타내었으며, 부직포의 75시간 경과 후에는 펄프의 부식이 진행되고, 제 1 PLA섬유와 제 2 PLA 섬유는 생분해로 인한 부식이 진행되어 측정이 불가하였다. As shown in [Table 2], Example 1 exhibited an elongation of 35.6% at 20.5N before time elapse of the nonwoven fabric, followed by an elongation of 6.5% at 12.9N after 50 hours of nonwoven fabric, and after 75 hours of nonwoven fabric. Corrosion of the pulp progressed, the first PLA fiber and the second PLA fiber was not possible due to the progress of corrosion due to biodegradation.
그리고, 실시 예 2는 부직포의 시간경과 전 23.5N에서 연신률 27.6%를 나타내었고, 부직포의 50시간 경과 후 15.9N에서 연신률 8.5%을 나타내었으며, 부직포의 75시간 경과 후에는 펄프의 부식이 진행되고, 제 1 PLA섬유와 제 2 PLA 섬유는 부식의 진행으로 인한 찢어짐이 발생하여 측정이 불가하였다. In addition, Example 2 exhibited an elongation of 27.6% at 23.5 N before the time-lapse of the nonwoven fabric, an elongation of 8.5% at 15.9 N after 50 hours of nonwoven fabric, and corrosion of the pulp proceeded after 75 hours of nonwoven fabric. In addition, the first PLA fiber and the second PLA fiber can not be measured because the tear due to the progress of corrosion.
그리고, 실시 예 3은 부직포의 시간경과 전 25.2N에서 연신률 28.9%를 나타내었고, 부직포의 50시간 경과 후 16.3N에서 연신률 12.0%을 나타내었으며, 부직포의 75시간 경과 후 펄프의 부식이 진행되고, 제 1 PLA섬유와 제 2 PLA 섬유는 부식이 진행으로 인한 찢어짐이 발생하여 측정이 불가하였다. In addition, Example 3 exhibited an elongation of 28.9% at 25.2N before the time-lapse of the nonwoven fabric, an elongation of 12.0% at 16.3N after 50 hours of nonwoven fabric, and corrosion of the pulp proceeded after 75 hours of nonwoven fabric. The first PLA fibers and the second PLA fibers were torn due to the progress of corrosion and could not be measured.
그리고, 비교 예 1은 부직포의 시간경과 전 5.1N에서 연신률 8.0%를 나타내었고, 부직포의 50시간 경과 후 3.5N에서 연신률 4.0%을 나타내었으며, 부직포의 75시간 경과 후 펄프의 부식이 진행되고, 제 1 PLA섬유와 제 2 PLA 섬유는 부서짐으로 인하여 측정이 불가하였다.In Comparative Example 1, the elongation was 8.0% at 5.1N before the time passed of the nonwoven fabric, the elongation was 4.0% at 3.5N after 50 hours of the nonwoven fabric, and the corrosion of the pulp proceeded after 75 hours of the nonwoven fabric. The first PLA fiber and the second PLA fiber could not be measured due to breakage.
그리고, 비교 예 2는 부직포의 시간경과 전 19.2N에서 연신률 31.6%를 나타내었고, 부직포의 50시간 경과 후 9.0N에서 연신률 21.0%을 나타내었으며, 부직포의 75시간 경과 후 5.9N에서 연신률 9.5%를 나타내었다. 즉, 펄프의 부식은 진행되었으나, 폴리 에틸렌(PE)과, 폴리 프로필렌(PP)이 그대로 존재하였다.In Comparative Example 2, the elongation was 31.6% at 19.2N before time elapse of the nonwoven fabric, the elongation was 21.0% at 9.0N after 50 hours of nonwoven fabric, and the 9.5% elongation at 5.9N after 75 hours of nonwoven fabric. Indicated. That is, the corrosion of the pulp proceeded, but polyethylene (PE) and polypropylene (PP) were present as they were.
이와 같이 본 발명은 생분해 특성을 갖는 제 1 PLA섬유, 펄프, 제 2 PLA섬유순으로 적층하여 부직포를 제조함으로써 펄프의 부드러운 특성과 흡수성과 부피감이 향상되고, 제 1, 제 2 PLA섬유가 펄프를 잡아주고 보호하게 되어 실제 사용시 필요한 기계적 강도가 향상되는 부직포를 제공하게 된다.As described above, the present invention provides a nonwoven fabric by laminating the first PLA fiber, the pulp, and the second PLA fiber, which have biodegradation properties, thereby improving the softness, absorbency, and bulkiness of the pulp, and the first and second PLA fibers are made of pulp. It is held and protected to provide a nonwoven fabric that enhances the mechanical strength needed in practical use.
또한, 펄프를 이용함으로써 제조비용을 절감시킬 수 있고, 폐기 후 100% 생분해가 이루어짐에 따라 환경문제를 유발시키지 않는 부직포를 제공하게 된다.In addition, by using the pulp can reduce the manufacturing cost, and 100% biodegradation after disposal is provided to provide a non-woven fabric does not cause environmental problems.
또한, 발암물질이나 위생에 해로운 물질을 방출하지 않고, 통기성과 청량감이 우수하여 위생성 및 안전성이 향상되는 부직포를 제공하게 된다. In addition, it is possible to provide a non-woven fabric that is excellent in breathability and refreshing comfort without emitting carcinogens or substances harmful to hygiene, thereby improving hygiene and safety.
또한, 제 1, 제 2 PLA섬유가 펄프의 표면을 잡고 있어서 세척이 가능하고 이로 인하여 여러 번 반복 사용이 가능한 부직포를 제공하게 된다.In addition, the first and second PLA fibers to hold the surface of the pulp, which can be washed, thereby providing a non-woven fabric that can be used repeatedly.
[부호의 설명][Description of the code]
100: 제 1 PLA섬유제조기 200: 제 1 메쉬드럼 100: the first PLA fiber manufacturing machine 200: the first mesh drum
300: 제 2 PLA섬유제조기 110,310: 압출기300: the second PLA fiber manufacturing machine 110,310: extruder
120,320: 필터장치 130,330: 분사노즐120,320: filter device 130,330: injection nozzle
140,340: 열풍기 150,350: 냉각기140,340: Hot air fan 150,350: Cooler
160,360: 절단기 170,370: 분사구160,360: cutter 170,370: nozzle
171,371,520: 밸브 400: 제 2 메쉬드럼171,371,520 valve 400: second mesh drum
500: 펄프공급부 510: 소면기500: pulp supply unit 510: carding machine
600: 제어부 700: 열융착부600: control unit 700: heat fusion unit

Claims (14)

  1. PLA를 섬유화시키는 제 1 PLA섬유제조기;A first PLA fiber maker for fiberizing PLA;
    상기 제 1 PLA섬유제조기에서 분사되는 제 1PLA섬유를 웹 형태로 집적하는 제 1 메쉬드럼;A first mesh drum for integrating the first PLA fibers injected from the first PLA fiber maker into a web form;
    상기 제 1 메쉬드럼 일측에 구비되어 상기 제 1 메쉬드럼 상에 집적된 제 1 PLA 섬유 일면에 펄프를 적층시키는 펄프공급부;A pulp supply unit provided on one side of the first mesh drum and stacking pulp on one surface of the first PLA fiber integrated on the first mesh drum;
    상기 펄프공급부의 일측에 구비되어 PLA를 섬유화시키는 제 2 PLA섬유제조기;A second PLA fiber making machine provided on one side of the pulp supply unit to fiberize PLA;
    상기 제 2 PLA섬유제조기에서 분사되는 제 2 PLA섬유를 웹 형태로 집적하여 상기 펄프의 일면에 적층시키는 제 2 메쉬드럼;A second mesh drum in which the second PLA fibers sprayed from the second PLA fiber maker are integrated in a web form and laminated on one surface of the pulp;
    상기 제 1 PLA섬유, 펄프, 제 2 PLA섬유 순으로 적층된 적층물에 열을 가하여 상기 적층물들을 상호 열융착시키는 열융착부; 및A heat fusion unit for heat-sealing the laminates by applying heat to the laminates stacked in order of the first PLA fibers, the pulp, and the second PLA fibers; And
    상기 제 1, 제 2 PLA섬유제조기, 펄프공급부와 전기적으로 연결되어 상기 제 1, 제 2 PLA섬유제조기에서 제조되는 제 1, 제 2 PLA섬유의 분사량을 제어하고, 상기 펄프공급부의 펄프공급량을 제어하는 제어부;The first and second PLA fiber makers are electrically connected to the pulp supply unit to control the injection amount of the first and second PLA fibers produced in the first and second PLA fiber makers, and to control the pulp supply amount of the pulp supply unit A control unit;
    를 포함하는 친환경 생분해 부직포 제조장치.Eco-friendly biodegradable nonwoven manufacturing apparatus comprising a.
  2. 제 1 항에 있어서,The method of claim 1,
    상기 제 1, 제 2 PLA섬유제조기는 PLA(생분해성 폴리유산)를 용융 및 압출시키는 압출기와, 상기 압출기에서 용융된 PLA를 분사하는 수백 개의 작은 오리피스(Orifice)가 형성된 분사노즐과, 상기 분사노즐의 양옆에서 고압열풍을 분사하여 분사노즐에서 분사되는 PLA를 연신시키는 열풍기와, 상기 연신된 PLA를 냉각시키는 냉각기와, 상기 연신에 의해 결정된 PLA섬유를 절단하는 절단기와, 상기 절단된 PLA섬유를 분사하는 분사구를 포함하여 구성되는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.The first and second PLA fiber making machine is an extruder for melting and extruding PLA (biodegradable polylactic acid), a spray nozzle formed with hundreds of small orifices (orifice) for spraying the molten PLA in the extruder, and the injection nozzle A hot air fan for stretching PLA sprayed from the spray nozzle by spraying high-pressure hot air from both sides of the cooler, a cooler for cooling the stretched PLA, a cutter for cutting the PLA fiber determined by the stretching, and spraying the cut PLA fiber Eco-friendly biodegradable nonwoven fabric manufacturing apparatus characterized in that it comprises a nozzle to.
  3. 제 2 항에 있어서,The method of claim 2,
    상기 압출기와 분사노즐 사이에는 용융된 PLA를 필터링하는 필터장치가 더 포함되는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.Eco-friendly biodegradable nonwoven fabric manufacturing apparatus, characterized in that further comprising a filter device for filtering the molten PLA between the extruder and the injection nozzle.
  4. 제 2 항에 있어서,The method of claim 2,
    상기 압출기는 제 1 내지 제 5 영역으로 구획되고, 제 1 영역은 150∼160℃, 제 2 영역은 200∼210℃, 제 3 영역은 220∼230℃, 제 4 영역은 230∼240℃, 제 5 영역은 250∼260℃의 온도가 설정되는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.The extruder is divided into first to fifth regions, the first region is 150 to 160 ℃, the second region is 200 to 210 ℃, the third region is 220 to 230 ℃, the fourth region is 230 to 240 ℃, Eco-friendly biodegradable nonwoven fabric production apparatus, characterized in that the five areas are set the temperature of 250 ~ 260 ℃.
  5. 제 1 항에 있어서,The method of claim 1,
    상기 펄프공급부에는 시트 또는 매트로 이루어진 펄프섬유를 개별섬유로 분리시키는 소면기가 연결되는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.The pulp supply unit is an eco-friendly biodegradable nonwoven fabric manufacturing apparatus, characterized in that the carding machine for separating the pulp fibers made of a sheet or mat into individual fibers are connected.
  6. 제 1 항에 있어서,The method of claim 1,
    상기 제어부는 부직포 전체 중량에 대하여 10중량%∼40중량%의 제 1 PLA섬유가 분사되도록 제 1 PLA섬유제조기의 분사량을 제어하고, 부직포 전체 중량에 대하여 25중량%∼80중량%의 펄프가 공급되도록 펄프공급부의 공급량을 제어하며, 부직포 전체 중량에 대하여 10중량%∼40중량%의 제 2 PLA섬유가 분사되도록 제 2 PLA섬유제조기의 분사량을 제어하는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.The control unit controls the injection amount of the first PLA fiber manufacturing machine so that the first PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric, and 25% to 80% by weight of pulp is supplied to the total weight of the nonwoven fabric. Controlling the supply amount of the pulp supply unit so as to, the eco-friendly biodegradable nonwoven fabric manufacturing apparatus, characterized in that for controlling the injection amount of the second PLA fiber manufacturing machine so that the second PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric.
  7. PLA(생분해성 폴리유산)를 제 1, 제 2 섬유제조기의 압출기에 각각 넣어 용융시킨 다음 수백 개의 작은 오리피스(Orifice)가 형성된 방사 노즐을 통해 방사하고 상기 방사 노즐 양옆에서 고속으로 분사되는 고압 열풍으로 연신 및 냉각시켜 제 1 PLA섬유 및 제 2 PLA섬유를 각각 제조하는 S10단계; PLA (biodegradable polylactic acid) was put into the extruder of the first and second fiber makers, respectively, and melted, and then spun through a spinning nozzle formed with hundreds of small orifices, and then sprayed with high pressure hot air sprayed at high speed from both sides of the spinning nozzle. S10 step of producing the first PLA fiber and the second PLA fiber by stretching and cooling;
    상기 제 1 섬유제조기에서 제조된 제 1 PLA섬유를 제 1 메쉬드럼 상에 분사하여 웹(Web) 형태로 집적하고, 상기 제 2 섬유제조기에서 제조된 제 2 PLA섬유를 제 2 메쉬드럼 상에 분사하여 웹(Web) 형태로 집적하는 S20단계;Spraying the first PLA fiber produced in the first fiber maker on the first mesh drum to integrate in the form of a web (Web), and the second PLA fiber produced in the second fiber maker sprayed on the second mesh drum S20 step of integrating in the form of a web (Web);
    상기 웹 형태로 집적된 제 1 PLA섬유와 제 2 PLA섬유 사이에 펄프를 공급하여 개재시키는 S30단계; S30 step of supplying and interposing pulp between the first PLA fiber and the second PLA fiber integrated in the web form;
    상기 제 1 PLA섬유, 펄프, 제 2 PLA섬유를 열융착하여 결합시키는 S40단계;S40 step of bonding the first PLA fibers, pulp, second PLA fibers by heat fusion;
    를 포함하는 친환경 생분해 부직포 제조방법. Eco-friendly biodegradable nonwoven manufacturing method comprising a.
  8. 제 7 항에 있어서, The method of claim 7, wherein
    상기 압출기는 150∼160℃ 온도가 설정된 제 1 영역, 200∼210℃ 온도가 설정된 제 2 영역, 220∼230℃ 온도가 설정된 제 3 영역, 230∼240℃ 온도가 설정된 제 4 영역, 250∼260℃ 온도가 설정된 제 5 영역으로 구획되고, 상기 PLA는 제 1 내지 제 5 영역을 통과하여 완전용해가 이루어지는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The extruder has a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., a fourth region having a temperature of 230 to 240 ° C., and a 250 to 260 ° C. Eco-friendly biodegradable non-woven fabric manufacturing method characterized in that partitioned into a fifth zone is set, the PLA is completely dissolved through the first to fifth zones.
  9. 제 7 항에 있어서, The method of claim 7, wherein
    상기 S10단계에는 용융된 PLA를 필터링하는 단계가 더 포함되는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The step S10 is eco-friendly biodegradable nonwoven fabric manufacturing method characterized in that it further comprises the step of filtering the molten PLA.
  10. 제 7 항에 있어서, The method of claim 7, wherein
    상기 PLA는 폴리-D-유산, 폴리-L-유산, D-유산과 L-유산의 공중합체로 이루어진 군으로부터 선택된 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The PLA is an eco-friendly biodegradable nonwoven fabric manufacturing method, characterized in that selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
  11. 제 7 항에 있어서,The method of claim 7, wherein
    상기 PLA는 융점이 100℃∼180℃ 이고, 용융지수 75∼120g/10분이며, 용융밀도는 0.98 내지 2.24g/㎤(260℃) 범위의 특성을 갖는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The PLA has a melting point of 100 ℃ to 180 ℃, the melt index is 75 to 120 g / 10 minutes, melt density is 0.98 to 2.24 g / cm 3 (260 ℃) characterized in that the eco-friendly biodegradable non-woven fabric manufacturing method.
  12. 제 7 항에 있어서,The method of claim 7, wherein
    상기 펄프는 시트 또는 매트로 이루어진 펄프섬유를 소면기에 넣어 개별섬유로 분리시킨 것이 사용되는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The pulp is an eco-friendly biodegradable non-woven fabric manufacturing method characterized in that the pulp fibers made of a sheet or mat put into a carding machine and separated into individual fibers.
  13. 제 7 항에 있어서,The method of claim 7, wherein
    상기 제 1 PLA섬유는 부직포 전체 중량의 10중량%∼40중량% 분사되어 집적되고, 상기 펄프는 부직포 전체 중량의 25중량%∼80중량% 공급되어 집적되며, 제 2 PLA섬유는 부직포 전체 중량의 10중량%∼40중량% 분사되어 집적되는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The first PLA fibers are injected by injecting 10% by weight to 40% by weight of the total weight of the nonwoven fabric, and the pulp is fed by 25% by weight to 80% by weight of the total weight of the nonwoven fabric. Eco-friendly biodegradable non-woven fabric manufacturing method characterized in that the injection by 10% by weight to 40% by weight.
  14. 제 7 항 내지 제 13 항 중 어느 한 항의 제조방법에 의하여, 제 1 메쉬드럼 상에서 웹 형태로 집적된 제 1 PLA섬유층; 상기 제 1 PLA섬유층 상부에 적층되는 펄프층; 제 2 메쉬드럼 상에 웹(Web) 형태로 집적되어 상기 펄프층 상면에 적층되는 제 2 PLA섬유층이 상호 열융착되어 제조되는 것을 포함하는 친환경 생분해 부직포.According to any one of claims 7 to 13, the first PLA fiber layer integrated in the form of a web on the first mesh drum; A pulp layer laminated on the first PLA fiber layer; Eco-friendly biodegradable non-woven fabric comprising a second PLA fiber layer is integrated in the form of a web (Web) on the second mesh drum is laminated on the upper surface of the pulp layer is manufactured by mutual heat-sealing.
PCT/KR2015/007101 2014-07-14 2015-07-08 Environment-friendly and biodegradable non-woven fabric, and apparatus and method for producing same WO2016010303A1 (en)

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