WO2016034651A1 - Detergent composition comprising rare earth metal and a stilbene brightening agent - Google Patents

Detergent composition comprising rare earth metal and a stilbene brightening agent Download PDF

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Publication number
WO2016034651A1
WO2016034651A1 PCT/EP2015/070094 EP2015070094W WO2016034651A1 WO 2016034651 A1 WO2016034651 A1 WO 2016034651A1 EP 2015070094 W EP2015070094 W EP 2015070094W WO 2016034651 A1 WO2016034651 A1 WO 2016034651A1
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WIPO (PCT)
Prior art keywords
detergent composition
brightening
rare earth
earth metal
nanoparticles
Prior art date
Application number
PCT/EP2015/070094
Other languages
French (fr)
Inventor
Tim Bast
Thomas Leucht
Original Assignee
Tim Bast
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Publication of WO2016034651A1 publication Critical patent/WO2016034651A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof

Definitions

  • stilbene derivatives in detergent compositions as a brightening agent or brightener is well known.
  • a granular detergent composition comprising a stilbene brightener is described.
  • the present invention provides a detergent composition comprising a cleaning agent and a brightening agent.
  • the detergent composition further comprises a brightening booster component.
  • the brightening booster component comprises rare earth metal atoms.
  • the present invention further provides a detergent composition wherein the brightening booster component comprises holmium atoms.
  • the present invention further provides a detergent composition wherein the brightening agent comprises a salt of a rare earth metal.
  • the present invention further provides a detergent composition wherein the brightening agent comprises acetate of a rare earth metal.
  • the present invention further provides a detergent composition wherein the brightening agent comprises an oxide of a rare earth metal.
  • the present invention further provides a detergent composition wherein detergent composition is liquid at ambient conditions.
  • the present invention further provides a detergent composition wherein the brightening booster component comprises nanoparticles, the nanoparticles comprising the rare earth metal atoms.
  • the present invention further provides a detergent composition wherein the
  • nanoparticles comprise rare earth metal oxide nanoparticles.
  • the present invention further provides a detergent composition wherein the
  • nanoparticles comprise holmium oxide nanoparticles.
  • the present invention further provides a detergent composition wherein the brightening agent is selected from the group of stilbene and stilbene derivatives.
  • the present invention further provides a method cleaning a textile comprising the steps of soaking the textile in an aqueous solution of a detergent composition, the detergent composition comprising a brightening agent and nanoparticles, and of drying the textile.
  • the present invention further provides a method for the treatment of textile fibers comprising the steps of soaking the textile fibers in an aqueous solution of a detergent composition, the detergent composition comprising a brightening agent and
  • the present invention relates to a detergent composition.
  • the detergent composition is useful for cleaning purposes in a dilute solution, preferably dilute aqueous solution.
  • the present invention relates to a laundry detergent composition.
  • the laundry detergent composition is useful cleaning textiles, fabrics, garment, and other implements which are suitable for being laundered in a laundry machine.
  • Fabric “Fabric”, “textile” and “garment” are used interchangeably herein to refer to an implement that is made using any suitable means including, but not limited to weaving, felting, knitting, crocheting and combinations thereof, of natural fibers, synthetic fibers and combinations thereof. Nonwovens are also meant to be encompassed by these terms.
  • the implement may be pliable.
  • Crop is used herein in the broadest sense to mean removal of unwanted substances from fabric. “Cleaning” includes, but is not limited to, the removal of soil from fabric and prevention of re-deposition of soil onto fabric.
  • the detergent composition according to the present invention may be a liquid detergent composition.
  • “Liquid detergent composition” as used herein, refers to compositions that are in a form selected from the group of: “pourable liquid”; “gel”; “cream”; and combinations thereof.
  • “Pourable liquid” as defined herein refers to a liquid having a viscosity of less than about 2000 mPa*s at 25°C and a shear rate of 20 sec "1 .
  • the viscosity of the pourable liquid may be in the range of from about 200 to about 1000 mPa*s at 25°C at a shear rate of 20 sec "1 .
  • the viscosity of the pourable liquid may be in the range of from about 200 to about 500 mPa*s at 25°C at a shear rate of 20 sec 1 .
  • Gel refers to a transparent or translucent liquid having a viscosity of greater than about 2000 mPa*s at 25°C and at a shear rate of 20 sec "1 .
  • the viscosity of the gel may be in the range of from about 3000 to about 10,000 mPa*s at 25°C at a shear rate of 20 sec "1 and greater than about 5000 mPa*s at 25°C at a shear rate of 0.1 sec 1 .
  • “Cream” and “paste” are used interchangeably and as defined herein refer to opaque liquid compositions having a viscosity of greater than about 2000 mPa*s at 25°C and a shear rate of 20 sec "1 .
  • the viscosity of the cream may be in the range of from about 3000 to about 10,000 mPa*s at 25°C at a shear rate of 20 sec 1 , or greater than about 5000 mPa*s at 25°C at a shear rate of 0.1 sec "1 .
  • the detergent composition of the present invention comprises a cleaning agent.
  • the cleaning agent of the present invention may comprise a surfactant system.
  • the cleaning agent may comprise a surfactant system in an amount sufficient to provide desired cleaning properties.
  • the liquid cleaning composition comprises, by weight of the composition, from about 0.1% to about 60% of a surfactant system.
  • the liquid cleaning composition comprises, by weight of the composition, from about 1% to about 50% of the surfactant system.
  • the liquid cleaning composition comprises, by weight of the composition, from about 5% to a bout 45% of the surfactant system.
  • the surfactant system may comprise a detersive surfactant selected from nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants, and mixtures thereof.
  • the surfactant system comprises anionic surfactant, nonionic surfactant, or mixtures thereof.
  • a detersive surfactant encompasses any surfactant or mixture of surfactants that provide cleaning, stain removing, or other laundering benefit to fabrics during the laundering process.
  • a suitable surfactant system for the present invention is for example described in US 2014/0026331 Al. The disclosure of US 2014/0026331 Al together with any documents directly or indirectly referenced therein is incorporated herein by reference.
  • the detergent composition of the present invention comprises a brightening agent such as an optical brightener, an optical brightening agent, a fluorescent brightening agent, an optical whitening agent, or a fluorescent whitening agent.
  • the brightening may include chemical compounds that absorb light in the ultraviolet and violet region (usually 340- 370 nm) of the electromagnetic spectrum, and re-emit light in the blue region (typically 420-470 nm).
  • Brightening agents are generally used to enhance the appearance of color of textiles, garments, and fabrics, causing a "whitening" effect, making materials look less yellow by increasing the overall amount of blue light reflected.
  • the brightening agent may be incorporated at levels of from about 0.01% to about 1.2%, by weight of the composition, into the detergent compositions described herein.
  • Brightening agents are also referred to as fluorescent whitening agents or fluorescent brightening agents provide optical compensation for the yellow cast in fabric substrates. With brightening agents yellowing is replaced by light emitted from brightening agents present in the area commensurate in scope with yellow color. The violet to blue light supplied by the brightening agents combines with other light reflected from the location to provide a substantially complete or enhanced bright white appearance. This additional light is produced by the brightener through fluorescence. Brightening agents absorb light in the ultraviolet range 275 through 400 nm and emit light in the ultraviolet blue spectrum 400 500 nm. Fluorescent compounds belonging to the brightening agent family are typically aromatic or aromatic heterocyclic materials often containing condensed ring system.
  • Brightening agents for use in detergent compositions will depend upon a number of factors, such as the type of detergent, the nature of other components present in the detergent composition, the temperature of the wash water, the degree of agitation, and the ratio of the material washed to the tub size.
  • the brightener selection is also dependent upon the type of material to be cleaned, e.g., cottons, synthetics, etc. Since most laundry detergent products are used to clean a variety of fabrics, the detergent compositions should contain a mixture of brighteners that are effective for a variety of fabrics. It is of course necessary that the individual components of such a brightener mixture be compatible. Brightening agents useful in the present invention are commercially available and will be appreciated by those skilled in the art.
  • Brightening agents which may be useful in the present invention can be classified into subgroups, which include, but are not necessarily limited to, derivatives of stilbene, pyrazoline, coumarin, carboxylic acid, methinecyanines, dibenzothiophene-5,5-dioxide, azoles, 5- and 6-membered-ring heterocycles and other miscellaneous agents. Examples of these types of brighteners are disclosed in "The Production and Application of Fluorescent Brightening Agents", M. Zahradnik, Published by John Wiley & Sons, New York (1982), the disclosure of which is incorporated herein by reference.
  • Stilbene derivatives which may be useful in the present invention include, but are not necessarily limited to, derivatives of bis(triazinyl)amino-stilbene; bisacylamino derivatives of stilbene; triazole derivatives of stilbene; oxadiazole derivatives of stilbene; oxazole derivatives of stilbene; and styryl derivatives of stilbene.
  • the detergent composition of the present invention can include, for example, about 0 to about 2 weight-%, about 0.05 to about 1 weight-%, about 0.1 to about 0.5 weight-%, or about 0.1 to about 0.2 weight-% brightening agent.
  • the brightening agent is present at about 0.1 weight-% or at about 0.25 weight-%.
  • the composition can include any of these ranges or any other amount suitable under the circumstances as selected by the skilled practitioner.
  • the detergent composition of the present invention further comprises a brightening booster component comprising rare earth metal atoms.
  • the brightening booster component of the present may one comprise one type of rare earth metal atoms, two types of rare earth metal atoms, three types of rare earth metal atoms, or a plurality of rare earth metal atoms.
  • the rare earth metals suitable for the brightening booster component of the present invention include without limitation Sc (Scandium), Y (Yttrium), La (Lanthanum), Ce (Cerium), Pr (Praseodymium), Nd (Neodymium), Pm (Promethium), Sm (Samarium), Eu (Europium), Gd (Gadolinium), Tb (Terbium) Dy (Dysprosium), Ho (Holmium), Er (Erbium) ,Tm (Thulium), Yb (Ytterbium), and Lu
  • the rare earth metals suitable for the brightening booster component of the present invention include without limitation Ac (Actinium), Th (Thorium), Pa
  • the brightening booster component comprises rare earth metal atoms selected from the group of gadolinium, terbium, dysprosium, holmium, erbium, thulium, and ytterbium. More preferably, the brightening booster component comprises rare earth metal atoms selected from the group of terbium, dysprosium, holmium, erbium, and thulium. Yet more preferably, the brightening booster component comprises rare earth metal atoms selected from the group of dysprosium, holmium, and erbium. Yet more preferably, the brightening booster component comprises holmium atoms.
  • the rare earth metal atoms comprised in the brightening booster component are comprised in the form a salt of the rare earth atoms.
  • Salts are ionic compounds that result from the neutralization reaction of an acid and a base. They are composed of related numbers of cations (positively charged ions) and anions (negative ions) so that the product is electrically neutral (without a net charge).
  • These component ions can be inorganic, such as chloride (Cl " ), or organic, such as acetate (C2H3O2 " ); and can be monatomic, such as fluoride (F " ), or polyatomic, such as sulfate (S0 4 2 ⁇ ).
  • the brightening booster agent in the detergent composition of the present invention may comprise an acetate of the rare earth metal (salt formed of a rare earth metal with an acetate ion [CH 3 COO]-).
  • the rare earth metal atoms comprised in the brightening booster agent of the present invention may be comprised in the form of an oxide of the rare earth metal.
  • An oxide is a compound comprising one or more oxygen atoms and another element, in the present invention one or more rare earth metal atoms.
  • the rare earth metal in the oxide may have any existing oxidation state for relevant element.
  • the rare earth metal in the oxide may have the +3 oxidation state such as in Holmium (III) Oxide Ho 2 0 3 .
  • the brightening booster component of the present invention may comprise one rare earth metal oxide, two rare earth metal oxides, three rare earth metal oxides, or a plurality of rare earth metal oxides. If the brightening booster component comprises more than rare earth metal oxide, the oxides may include the same rare earth metal in different oxidation states or may comprise oxides from different rare earth metals.
  • Suitable oxides for use in the brightening booster component of the present invention include without limitation Y 2 0 3 , La 2 0 3 , Ce0 2 , Pr 6 On, Nd 2 0 3 , Sm 2 0 3 , Eu 2 0 3 , Gd 2 0 3 , Tb 4 0 7 , Dy 2 0 3 , Ho 2 0 3 , Er 2 0 3 , Yb 2 0 3 , Lu 2 0 3 , Sc 2 0 3 , and Tm 2 0 3 .
  • the laundry detergent composition of the present invention can be in any form, namely, in the form of a liquid; a solid such as a powder, granules, agglomerate, paste, tablet, pouches, bar, gel; an emulsion; types delivered in dual- or multi-compartment containers or pouches; a spray or foam detergent; pre-moistened wipes (i.e., the cleaning composition in combination with a nonwoven material such as that discussed in U.S. Pat. No. 6,121,165); dry wipes (i.e., the cleaning composition in combination with a nonwoven materials, such as that discussed in U.S. Pat. No.
  • Liquid laundry detergent composition refers to compositions that are in a form selected from the group of: “pourable liquid”; “gel”; “cream”; and combinations thereof.
  • “Pourable liquid” as defined herein refers to a liquid having a viscosity of less than about 2000 mPa*s at 25°C and a shear rate of 20 sec "1 . In some embodiments, the viscosity of the pourable liquid may be in the range of from about 200 to about 1000 mPa*s at 25°C at a shear rate of 20 sec "1 .
  • the viscosity of the pourable liquid may be in the range of from about 200 to about 500 mPa*s at 25°C at a shear rate of 20 sec "1 .
  • "Gel” as defined herein refers to a transparent or translucent liquid having a viscosity of greater than about 2000 mPa*s at 25°C and at a shear rate of 20 sec "1 .
  • the viscosity of the gel may be in the range of from about 3000 to about 10,000 mPa*s at 25°C at a shear rate of 20 sec "1 and greater than about 5000 mPa*s at 25°C at a shear rate of 0.1 sec 1 .
  • “Cream” and “paste” are used interchangeably and as defined herein refer to opaque liquid compositions having a viscosity of greater than about 2000 mPa*s at 25°C and a shear rate of 20 sec "1 .
  • the viscosity of the cream may be in the range of from about 3000 to about 10,000 mPa*s at 25°C at a shear rate of 20 sec "1 , or greater than about 5000 mPa*s at 25°C at a shear rate of 0.1 sec 1 .
  • the laundry detergent composition of the present invention may be in the form of a gel detergent composition comprising an organic solvent selected from the group consisting of low molecular weight aliphatic or aromatic alcohols, low molecular weight alkylene glycols, low molecular weight a Ikylene glycol ethers, low molecular weight esters, low molecular weight alkylene amines, low molecular weight alkanolamines, and mixtures thereof.
  • an organic solvent selected from the group consisting of low molecular weight aliphatic or aromatic alcohols, low molecular weight alkylene glycols, low molecular weight a Ikylene glycol ethers, low molecular weight esters, low molecular weight alkylene amines, low molecular weight alkanolamines, and mixtures thereof.
  • the laundry detergent composition of the present invention may be in particulate form, such as an agglomerate, a spray-dried powder, an extrudate, a flake, a needle, a noodle, a bead, or any combination thereof.
  • the composition may be in compacted-particulate form, such as in the form of a tablet.
  • the composition may be in some other unit dose form, such as a pouch; typically being at least partially, preferably essentially completely, enclosed by a water-soluble film, such as polyvinyl alcohol.
  • the composition is in free-flowing particulate form; by free-flowing particulate form, it is typically meant that the composition is in the form of separate discrete particles.
  • the composition may be made by any suitable method including agglomeration, spray-drying, extrusion, mixing, dry-mixing, liquid spray-on, roller compaction, spheronisation, tabletting or any combination thereof.
  • the composition typically has a bulk density of from 450 g/l to 1,000 g/l, preferred low bulk density detergent compositions have a bulk density of from 550 g/l to 650 g/l and preferred high bulk density detergent compositions have a bulk density of from 750 g/l to 900 g/l.
  • the composition is typically contacted with water to give a wash liquor having a pH of from above 7 to less than 13, preferably from above 7 to less than 10.5. This is the optimal pH to provide good cleaning whilst also ensuring a good fabric care profile.
  • the detergent composition of the present invention may comprise nanoparticles whereby the nanoparticles comprise the rare earth metal atoms.
  • nanoparticles refers to particles defined as a small object that behaves as a whole unit with respect to its transport and properties.
  • a nanoparticle generally comprises more than one individual atom or more than one individual molecule. Nanoparticles may be made up from a plurality of the same individual atoms or the same individual molecules. Alternatively, nanoparticles may be made up from a plurality of different individual atoms and/or different individual molecules.
  • the nanoparticles have a size suitable to support achieving the objectives of the present invention.
  • size refers to average cross-section of a particle, such as diameter.
  • the nanoparticles may have a size where at least about 70% by weight, more preferably at least about 80%, yet more preferably at least about 90%, yet more preferably at least about 95% of the nanoparticles have a size from about 1 nm to about 200 nm.
  • the nanoparticles may have a size where at least about 70% by weight, more preferably at least about 80%, yet more preferably at least about 90%, yet more preferably at least about 95% of the nanoparticles have a size from about 1 nm to about 150 nm.
  • the nanoparticles may have a size where at least about 70% by weight, more preferably at least about 80%, yet more preferably at least about 90%, yet more preferably at least about 95% of the nanoparticles have a size from about 1 nm to about 100 nm.
  • the nanoparticles may have a size where at least about 70% by weight, more preferably at least about 80%, yet more preferably at least about 90%, yet more preferably at least about 95% of the nanoparticles have a size from about 1 nm to about 80 nm.
  • the nanoparticles have a surface area suitable to support achieving the objectives of the present invention. Increased surface area may be better achieved via small sized particles rather than particles with high porosity.
  • the nanoparticles may have a surface area of at least about 5 m 2 /g. Alternatively, The nanoparticles may have a surface area of at least about 10 m 2 /g. Alternatively, The nanoparticles may have a surface area of at least about 15 m 2 /g. Alternatively, The nanoparticles may have a surface area of at least about 20 m 2 /g. Alternatively, The nanoparticles may have a surface area of at least about 25 m 2 /g. Alternatively, The nanoparticles may have a surface area of at least about 30 m 2 /g.
  • the nanoparticles have a morphology suitable for the objectives of the present invention. Suitable examples of the one or more morphologies the nanoparticles include without limitation spherical, substantially spherical, oval, popcorn-like, plate-like, cubic, pyramidal, cylindrical, and the like. The nanoparticles may be crystalline, partially crystalline, or amorphous.
  • Nanoparticles suitable for the present invention are commercially available. Alternative, the nanoparticles can be obtained through a variety of processes known in the state of the art, including attrition, pyrolysis, radiolysis, and a sol-gel process.
  • the nanoparticles comprised in the detergent composition of the present invention may comprise rare earth metal oxide nanoparticles.
  • the detergent composition of the present invention may comprise holmium oxide nanoparticles.
  • Holmium Oxide (Ho203) nanopowder or nanoparticles, nanodots or nanocrystals may be spherical or faceted high surface area oxide magnetic nanostructure particles.
  • the holmium oxide nanoparticles may be 20-80 nanometers (nm) in diameter with specific surface area in the 10 - 50 m 2 /g range.
  • the holmium oxide nanoparticles may have a diameter in thelOO nm range with a specific surface area of approximately 7- 10 m 2 /g.
  • the brightening agent for the detergent composition of the present invention may be selected from the group of stilbene and stilbene derivatives.
  • Stilbene derivatives which may be useful in the present invention include, but are not necessarily limited to, derivatives of bis(triazinyl)amino-stilbene; bisacylamino derivatives of stilbene; triazole derivatives of stilbene; oxadiazole derivatives of stilbene; oxazole derivatives of stilbene; and styryl derivatives of stilbene.
  • the brightening agents suitable for the present invention include those belonging to the class of triazine-stilbenes (di-, tetra- or hexa-sulfonated).
  • the brightening agents suitable for the present invention include those belonging to the class of biphenyl-stilbenes.
  • the brightening agents suitable for the present invention include those belonging to the class of diaminostilbene-sulphonic acid derivatives.
  • Typical fluorescent whitening agents are Parawhite KX, supplied by Paramount Minerals and Chemicals, Mumbai, India; Tinopal ® DMS and Tinopal ® CBS available from Ciba-Geigy AG, Basel, Switzerland.
  • Tinopal ® DMS is the disodium salt of 4,4'-bis-(2-morpholino-4 anilino-s-triazin-6-ylamino)stilbene disulphonate.
  • the brightening agents are supplied and used in the form of their alkali metal salts, for example, the sodium salts.
  • the total amount of the brightening agent or agents used in laundry treatment composition is generally from 0.005 to 2 wt %, more preferably 0.01 to 0.1 wt %.
  • Suitable stilbene derivatives include without limitation:
  • stilbene derivatives include without limitation the stilbene derivatives disclosed in WO 2001/066681 Al, incorporated herein by reference.
  • the detergent composition of present invention may further comprise additional components including without limitation cleaning enzymes (such as amylases, proteases, and other enzymes), fatty acids, other adjunct cleaning additives, chelating agents, builders, structu rants, thickeners, clay soil removal agents, anti-redeposition agents, polymeric soil release agents, alkoxylated polyamine polymers, polymeric grease cleaning agents, enzyme stabilizing systems, bleaching compounds, bleaching agents, bleach activators, bleach catalysts, fabric hueing agents, dye transfer inhibiting agents, suds suppressors, fabric softeners, conditioning agents, humectants, suspending agents, suds boosters, fillers, and carriers.
  • cleaning enzymes such as amylases, proteases, and other enzymes
  • fatty acids such as amylases, proteases, and other enzymes
  • other adjunct cleaning additives such as amylases, proteases, and other enzymes
  • chelating agents such as amylases, proteases, and other enzymes
  • builders structu
  • Suitable additional components for the present invention such as the aforementioned are for example described in US 2014/0026331 Al and in US8716208B1.
  • the disclosures of US 2014/0026331 Al and US8716208 together with any documents directly or indirectly referenced therein are incorporated herein by reference.
  • the present invention further provides a method for the preparation of a detergent composition comprising the steps of providing the components of the detergent composition of the present invention and combining the components to form the detergent composition of the present invention.
  • Suitable processes for providing and combining the components are known in the state of the art and may be selected as appropriate under the circumstances by the skilled artisan.
  • the present invention further provides a method cleaning a textile comprising the steps of soaking the textile in an aqueous solution of a detergent composition, the detergent composition comprising a brightening agent and nanoparticles - drying the textile
  • the present invention further provides a method for the treatment of textile fibers soaking the textile fibers in an aqueous solution of a detergent composition, the detergent composition comprising a brightening agent and nanoparticles drying the textile fibers
  • a method for cleaning fabrics Such method includes the steps of providing one or more fabrics to which stains are adhered, and contacting said fabrics with a wash solution.
  • the wash solution comprises water; and a detergent composition as described herein.
  • the cleaning fabrics may optionally be rinsed after contact with the wash solution.
  • the compositions may be employed at concentrations of from about 200 ppm to about 10,000 ppm in solution.
  • the water temperatures may range from about 5° C. to about 100° C.
  • the water to fabric ratio may be from about 1:1 to about 20:1.
  • the following four inventive detergent compositions (examples Al, A2, Bl, and B2) have been prepared and tested. All four compositions comprise a brightening booster in accordance with the present invention and exhibit certain inventive benefits described herein.
  • the exemplary detergent composition Al is a solid composition comprising about
  • composition Al Components (exemplary detergent composition Al) Weight%
  • Foam inhibitor concentrate (12% silicone supported on inorganic
  • Phosphonate commercial designation "Dequest ® 2066", 25 %
  • Brightening booster (holmium oxide) 0.08 ( ⁇ 0.01)
  • the exemplary detergent composition A2 is a solid composition comprising about
  • compositions (exemplary detergent composition A2) Weight%
  • Foam inhibitor concentrate (12% silicone supported on inorganic
  • Phosphonate commercial designation "Dequest ® 2066", 25 %
  • Brightening booster (holmium acetate) 0.12 ( ⁇ 0.02)
  • Tetra acetyl ethylene diamine active content 90.0% to 94.0%)
  • the exemplary detergent composition Bl is a liquid composition comprising about
  • composition Bl Weight%
  • Anionic surfactant 8.0 ( ⁇ 0.8)
  • Citric acid sodium citrate 1.2 ( ⁇ 0.12)
  • Chelating agent diethylene triamine pentaacetic acid 0.3 ( ⁇ 0.05)
  • Brightening booster (holmium oxide) 0.08 ( ⁇ 0.01)
  • the exemplary detergent composition B2 is a liquid composition comprising about
  • composition B2 Components (exemplary detergent composition B2) Weight%
  • Anionic surfactant 8.0 ( ⁇ 0.8)
  • Citric acid sodium citrate 1.2 ( ⁇ 0.12)
  • Brightening booster (holmium acetate) 0.12 ( ⁇ 0.01)

Abstract

The present invention provides a detergent composition comprising a cleaning agent and a brightening agent. The detergent composition further comprises a brightening booster component. The brightening booster component comprises rare earth metal atoms. The present invention further provides a method cleaning a textile using the detergent composition. The present invention further provides a method treating a textile using the detergent composition.

Description

DETERGENT COMPOSITION COMPRISING RARE EARTH METAL AND A STILBENE BRIGHTENING AGENT
BACKGROUND
The use of stilbene derivatives in detergent compositions as a brightening agent or brightener is well known. For example in EP 0 724 012 Al, a granular detergent composition comprising a stilbene brightener is described.
It has been found, however, that textiles which have been laundered with detergent compositions comprising the known stilbene brighteners will cause the textiles to exhibit a dull yellowish color after the laundry. This effect is apparent in particular when the textiles is illuminated with a light sources such as F, D65 and TL 84 which resemble the light emitted by neon tubes and energy saving light bulbs.
It is the object of the present invention to enlarge the state of the art. It is another object of the present invention to overcome the disadvantages of prior art detergent compositions. More specifically, it is one object of the present invention to reduce the yellowish appearance of textiles which have been laundered with a detergent composition comprising a stilbene brightener.
SUMMARY OF THE INVENTION
The present invention provides a detergent composition comprising a cleaning agent and a brightening agent. The detergent composition further comprises a brightening booster component. The brightening booster component comprises rare earth metal atoms.
The present invention further provides a detergent composition wherein the brightening booster component comprises holmium atoms.
The present invention further provides a detergent composition wherein the brightening agent comprises a salt of a rare earth metal. The present invention further provides a detergent composition wherein the brightening agent comprises acetate of a rare earth metal.
The present invention further provides a detergent composition wherein the brightening agent comprises an oxide of a rare earth metal. The present invention further provides a detergent composition wherein detergent composition is liquid at ambient conditions.
The present invention further provides a detergent composition wherein the brightening booster component comprises nanoparticles, the nanoparticles comprising the rare earth metal atoms. The present invention further provides a detergent composition wherein the
nanoparticles comprise rare earth metal oxide nanoparticles.
The present invention further provides a detergent composition wherein the
nanoparticles comprise holmium oxide nanoparticles.
The present invention further provides a detergent composition wherein the brightening agent is selected from the group of stilbene and stilbene derivatives.
The present invention further provides a method cleaning a textile comprising the steps of soaking the textile in an aqueous solution of a detergent composition, the detergent composition comprising a brightening agent and nanoparticles, and of drying the textile.
The present invention further provides a method for the treatment of textile fibers comprising the steps of soaking the textile fibers in an aqueous solution of a detergent composition, the detergent composition comprising a brightening agent and
nanoparticles, and of drying the textile fibers. DETAILED DESCRIPTION OF THE INVENTION
The present invention relates to a detergent composition. The detergent composition is useful for cleaning purposes in a dilute solution, preferably dilute aqueous solution. In one aspect, the present invention relates to a laundry detergent composition. The laundry detergent composition is useful cleaning textiles, fabrics, garment, and other implements which are suitable for being laundered in a laundry machine.
"Fabric", "textile" and "garment" are used interchangeably herein to refer to an implement that is made using any suitable means including, but not limited to weaving, felting, knitting, crocheting and combinations thereof, of natural fibers, synthetic fibers and combinations thereof. Nonwovens are also meant to be encompassed by these terms. The implement may be pliable.
"Cleaning" is used herein in the broadest sense to mean removal of unwanted substances from fabric. "Cleaning" includes, but is not limited to, the removal of soil from fabric and prevention of re-deposition of soil onto fabric.
The detergent composition according to the present invention may be a liquid detergent composition. "Liquid detergent composition" as used herein, refers to compositions that are in a form selected from the group of: "pourable liquid"; "gel"; "cream"; and combinations thereof.
"Pourable liquid" as defined herein refers to a liquid having a viscosity of less than about 2000 mPa*s at 25°C and a shear rate of 20 sec"1. In some embodiments, the viscosity of the pourable liquid may be in the range of from about 200 to about 1000 mPa*s at 25°C at a shear rate of 20 sec"1. In some embodiments, the viscosity of the pourable liquid may be in the range of from about 200 to about 500 mPa*s at 25°C at a shear rate of 20 sec 1.
"Gel" as defined herein refers to a transparent or translucent liquid having a viscosity of greater than about 2000 mPa*s at 25°C and at a shear rate of 20 sec"1. In some embodiments, the viscosity of the gel may be in the range of from about 3000 to about 10,000 mPa*s at 25°C at a shear rate of 20 sec"1 and greater than about 5000 mPa*s at 25°C at a shear rate of 0.1 sec 1 . "Cream" and "paste" are used interchangeably and as defined herein refer to opaque liquid compositions having a viscosity of greater than about 2000 mPa*s at 25°C and a shear rate of 20 sec"1. In some embodiments, the viscosity of the cream may be in the range of from about 3000 to about 10,000 mPa*s at 25°C at a shear rate of 20 sec 1, or greater than about 5000 mPa*s at 25°C at a shear rate of 0.1 sec"1.
The detergent composition of the present invention comprises a cleaning agent. The cleaning agent of the present invention may comprise a surfactant system.
The cleaning agent may comprise a surfactant system in an amount sufficient to provide desired cleaning properties. In some examples, the liquid cleaning composition comprises, by weight of the composition, from about 0.1% to about 60% of a surfactant system. In other examples, the liquid cleaning composition comprises, by weight of the composition, from about 1% to about 50% of the surfactant system. In further examples, the liquid cleaning composition comprises, by weight of the composition, from about 5% to a bout 45% of the surfactant system. The surfactant system may comprise a detersive surfactant selected from nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants, and mixtures thereof. In a more specific embodiment, the surfactant system comprises anionic surfactant, nonionic surfactant, or mixtures thereof. Those of ordinary skill in the art will understand that a detersive surfactant encompasses any surfactant or mixture of surfactants that provide cleaning, stain removing, or other laundering benefit to fabrics during the laundering process. A suitable surfactant system for the present invention is for example described in US 2014/0026331 Al. The disclosure of US 2014/0026331 Al together with any documents directly or indirectly referenced therein is incorporated herein by reference.
The detergent composition of the present invention comprises a brightening agent such as an optical brightener, an optical brightening agent, a fluorescent brightening agent, an optical whitening agent, or a fluorescent whitening agent. The brightening may include chemical compounds that absorb light in the ultraviolet and violet region (usually 340- 370 nm) of the electromagnetic spectrum, and re-emit light in the blue region (typically 420-470 nm). Brightening agents are generally used to enhance the appearance of color of textiles, garments, and fabrics, causing a "whitening" effect, making materials look less yellow by increasing the overall amount of blue light reflected.
The brightening agent may be incorporated at levels of from about 0.01% to about 1.2%, by weight of the composition, into the detergent compositions described herein.
Brightening agents are also referred to as fluorescent whitening agents or fluorescent brightening agents provide optical compensation for the yellow cast in fabric substrates. With brightening agents yellowing is replaced by light emitted from brightening agents present in the area commensurate in scope with yellow color. The violet to blue light supplied by the brightening agents combines with other light reflected from the location to provide a substantially complete or enhanced bright white appearance. This additional light is produced by the brightener through fluorescence. Brightening agents absorb light in the ultraviolet range 275 through 400 nm and emit light in the ultraviolet blue spectrum 400 500 nm. Fluorescent compounds belonging to the brightening agent family are typically aromatic or aromatic heterocyclic materials often containing condensed ring system. An important feature of these compounds is the presence of an uninterrupted chain of conjugated double bonds associated with an aromatic ring. The number of such conjugated double bonds is dependent on the substituents as well as the planarity of the fluorescent part of the molecule. Most brightener compounds are derivatives of stilbene or 4,4'-diamino stilbene, biphenyl, five membered heterocycles (triazoles, oxazoles, imidazoles, etc.) or six membered heterocycles (cumarins, naphthalamides, triazines, etc.). The choice of Brightening agents for use in detergent compositions will depend upon a number of factors, such as the type of detergent, the nature of other components present in the detergent composition, the temperature of the wash water, the degree of agitation, and the ratio of the material washed to the tub size. The brightener selection is also dependent upon the type of material to be cleaned, e.g., cottons, synthetics, etc. Since most laundry detergent products are used to clean a variety of fabrics, the detergent compositions should contain a mixture of brighteners that are effective for a variety of fabrics. It is of course necessary that the individual components of such a brightener mixture be compatible. Brightening agents useful in the present invention are commercially available and will be appreciated by those skilled in the art. Commercial brightening agents which may be useful in the present invention can be classified into subgroups, which include, but are not necessarily limited to, derivatives of stilbene, pyrazoline, coumarin, carboxylic acid, methinecyanines, dibenzothiophene-5,5-dioxide, azoles, 5- and 6-membered-ring heterocycles and other miscellaneous agents. Examples of these types of brighteners are disclosed in "The Production and Application of Fluorescent Brightening Agents", M. Zahradnik, Published by John Wiley & Sons, New York (1982), the disclosure of which is incorporated herein by reference. Stilbene derivatives which may be useful in the present invention include, but are not necessarily limited to, derivatives of bis(triazinyl)amino-stilbene; bisacylamino derivatives of stilbene; triazole derivatives of stilbene; oxadiazole derivatives of stilbene; oxazole derivatives of stilbene; and styryl derivatives of stilbene.
The detergent composition of the present invention can include, for example, about 0 to about 2 weight-%, about 0.05 to about 1 weight-%, about 0.1 to about 0.5 weight-%, or about 0.1 to about 0.2 weight-% brightening agent. In an embodiment, the brightening agent is present at about 0.1 weight-% or at about 0.25 weight-%. The composition can include any of these ranges or any other amount suitable under the circumstances as selected by the skilled practitioner. The detergent composition of the present invention further comprises a brightening booster component comprising rare earth metal atoms. The brightening booster component of the present may one comprise one type of rare earth metal atoms, two types of rare earth metal atoms, three types of rare earth metal atoms, or a plurality of rare earth metal atoms. The rare earth metals suitable for the brightening booster component of the present invention include without limitation Sc (Scandium), Y (Yttrium), La (Lanthanum), Ce (Cerium), Pr (Praseodymium), Nd (Neodymium), Pm (Promethium), Sm (Samarium), Eu (Europium), Gd (Gadolinium), Tb (Terbium) Dy (Dysprosium), Ho (Holmium), Er (Erbium) ,Tm (Thulium), Yb (Ytterbium), and Lu
(Lutetium). The rare earth metals suitable for the brightening booster component of the present invention include without limitation Ac (Actinium), Th (Thorium), Pa
(Protactinium), U (Uranium), Np (Neptunium), Pt (Plutonium), Am (Americium), Cm (Curium), Bk (Berkelium), Cf (Californium), Es (Einsteinium), Fm (Fermium), Md
(Mendelevium), No (Nobelium), and Lf (Lawrencium).
Preferably, the brightening booster component comprises rare earth metal atoms selected from the group of gadolinium, terbium, dysprosium, holmium, erbium, thulium, and ytterbium. More preferably, the brightening booster component comprises rare earth metal atoms selected from the group of terbium, dysprosium, holmium, erbium, and thulium. Yet more preferably, the brightening booster component comprises rare earth metal atoms selected from the group of dysprosium, holmium, and erbium. Yet more preferably, the brightening booster component comprises holmium atoms. The rare earth metal atoms comprised in the brightening booster component are comprised in the form a salt of the rare earth atoms. Salts are ionic compounds that result from the neutralization reaction of an acid and a base. They are composed of related numbers of cations (positively charged ions) and anions (negative ions) so that the product is electrically neutral (without a net charge). These component ions can be inorganic, such as chloride (Cl"), or organic, such as acetate (C2H3O2"); and can be monatomic, such as fluoride (F"), or polyatomic, such as sulfate (S04 2~). The brightening booster agent in the detergent composition of the present invention may comprise an acetate of the rare earth metal (salt formed of a rare earth metal with an acetate ion [CH3COO]-). Alternatively, the rare earth metal atoms comprised in the brightening booster agent of the present invention may be comprised in the form of an oxide of the rare earth metal. An oxide is a compound comprising one or more oxygen atoms and another element, in the present invention one or more rare earth metal atoms. The rare earth metal in the oxide may have any existing oxidation state for relevant element. The rare earth metal in the oxide may have the +3 oxidation state such as in Holmium (III) Oxide Ho203. The brightening booster component of the present invention may comprise one rare earth metal oxide, two rare earth metal oxides, three rare earth metal oxides, or a plurality of rare earth metal oxides. If the brightening booster component comprises more than rare earth metal oxide, the oxides may include the same rare earth metal in different oxidation states or may comprise oxides from different rare earth metals. Suitable oxides for use in the brightening booster component of the present invention include without limitation Y203, La203, Ce02, Pr6On, Nd203, Sm203, Eu203, Gd203, Tb407, Dy203, Ho203, Er203, Yb203, Lu203, Sc203, and Tm203.
The laundry detergent composition of the present invention (at ambient conditions) can be in any form, namely, in the form of a liquid; a solid such as a powder, granules, agglomerate, paste, tablet, pouches, bar, gel; an emulsion; types delivered in dual- or multi-compartment containers or pouches; a spray or foam detergent; pre-moistened wipes (i.e., the cleaning composition in combination with a nonwoven material such as that discussed in U.S. Pat. No. 6,121,165); dry wipes (i.e., the cleaning composition in combination with a nonwoven materials, such as that discussed in U.S. Pat. No.
5,980,931) activated with water by a consumer; and other homogeneous or multiphase consumer cleaning product forms.
"Liquid laundry detergent composition" as used herein, refers to compositions that are in a form selected from the group of: "pourable liquid"; "gel"; "cream"; and combinations thereof. "Pourable liquid" as defined herein refers to a liquid having a viscosity of less than about 2000 mPa*s at 25°C and a shear rate of 20 sec"1. In some embodiments, the viscosity of the pourable liquid may be in the range of from about 200 to about 1000 mPa*s at 25°C at a shear rate of 20 sec"1. In some embodiments, the viscosity of the pourable liquid may be in the range of from about 200 to about 500 mPa*s at 25°C at a shear rate of 20 sec"1. "Gel" as defined herein refers to a transparent or translucent liquid having a viscosity of greater than about 2000 mPa*s at 25°C and at a shear rate of 20 sec"1. In some embodiments, the viscosity of the gel may be in the range of from about 3000 to about 10,000 mPa*s at 25°C at a shear rate of 20 sec"1 and greater than about 5000 mPa*s at 25°C at a shear rate of 0.1 sec 1. "Cream" and "paste" are used interchangeably and as defined herein refer to opaque liquid compositions having a viscosity of greater than about 2000 mPa*s at 25°C and a shear rate of 20 sec"1. In some embodiments, the viscosity of the cream may be in the range of from about 3000 to about 10,000 mPa*s at 25°C at a shear rate of 20 sec"1, or greater than about 5000 mPa*s at 25°C at a shear rate of 0.1 sec 1.
The laundry detergent composition of the present invention may be in the form of a gel detergent composition comprising an organic solvent selected from the group consisting of low molecular weight aliphatic or aromatic alcohols, low molecular weight alkylene glycols, low molecular weight a Ikylene glycol ethers, low molecular weight esters, low molecular weight alkylene amines, low molecular weight alkanolamines, and mixtures thereof.
The laundry detergent composition of the present invention may be in particulate form, such as an agglomerate, a spray-dried powder, an extrudate, a flake, a needle, a noodle, a bead, or any combination thereof. The composition may be in compacted-particulate form, such as in the form of a tablet. The composition may be in some other unit dose form, such as a pouch; typically being at least partially, preferably essentially completely, enclosed by a water-soluble film, such as polyvinyl alcohol. Preferably, the composition is in free-flowing particulate form; by free-flowing particulate form, it is typically meant that the composition is in the form of separate discrete particles. The composition may be made by any suitable method including agglomeration, spray-drying, extrusion, mixing, dry-mixing, liquid spray-on, roller compaction, spheronisation, tabletting or any combination thereof. The composition typically has a bulk density of from 450 g/l to 1,000 g/l, preferred low bulk density detergent compositions have a bulk density of from 550 g/l to 650 g/l and preferred high bulk density detergent compositions have a bulk density of from 750 g/l to 900 g/l. During the laundering process, the composition is typically contacted with water to give a wash liquor having a pH of from above 7 to less than 13, preferably from above 7 to less than 10.5. This is the optimal pH to provide good cleaning whilst also ensuring a good fabric care profile.
The detergent composition of the present invention may comprise nanoparticles whereby the nanoparticles comprise the rare earth metal atoms.
The term "nanoparticles" as used herein refers to particles defined as a small object that behaves as a whole unit with respect to its transport and properties. A nanoparticle generally comprises more than one individual atom or more than one individual molecule. Nanoparticles may be made up from a plurality of the same individual atoms or the same individual molecules. Alternatively, nanoparticles may be made up from a plurality of different individual atoms and/or different individual molecules.
The nanoparticles have a size suitable to support achieving the objectives of the present invention. In this connection, size refers to average cross-section of a particle, such as diameter. The nanoparticles may have a size where at least about 70% by weight, more preferably at least about 80%, yet more preferably at least about 90%, yet more preferably at least about 95% of the nanoparticles have a size from about 1 nm to about 200 nm. Alternatively, the nanoparticles may have a size where at least about 70% by weight, more preferably at least about 80%, yet more preferably at least about 90%, yet more preferably at least about 95% of the nanoparticles have a size from about 1 nm to about 150 nm. Alternatively, the nanoparticles may have a size where at least about 70% by weight, more preferably at least about 80%, yet more preferably at least about 90%, yet more preferably at least about 95% of the nanoparticles have a size from about 1 nm to about 100 nm. Alternatively, the nanoparticles may have a size where at least about 70% by weight, more preferably at least about 80%, yet more preferably at least about 90%, yet more preferably at least about 95% of the nanoparticles have a size from about 1 nm to about 80 nm.
The nanoparticles have a surface area suitable to support achieving the objectives of the present invention. Increased surface area may be better achieved via small sized particles rather than particles with high porosity. The nanoparticles may have a surface area of at least about 5 m2/g. Alternatively, The nanoparticles may have a surface area of at least about 10 m2/g. Alternatively, The nanoparticles may have a surface area of at least about 15 m2/g. Alternatively, The nanoparticles may have a surface area of at least about 20 m2/g. Alternatively, The nanoparticles may have a surface area of at least about 25 m2/g. Alternatively, The nanoparticles may have a surface area of at least about 30 m2/g.
The nanoparticles have a morphology suitable for the objectives of the present invention. Suitable examples of the one or more morphologies the nanoparticles include without limitation spherical, substantially spherical, oval, popcorn-like, plate-like, cubic, pyramidal, cylindrical, and the like. The nanoparticles may be crystalline, partially crystalline, or amorphous.
Nanoparticles suitable for the present invention are commercially available. Alternative, the nanoparticles can be obtained through a variety of processes known in the state of the art, including attrition, pyrolysis, radiolysis, and a sol-gel process. The nanoparticles comprised in the detergent composition of the present invention may comprise rare earth metal oxide nanoparticles. The detergent composition of the present invention may comprise holmium oxide nanoparticles.
Holmium Oxide (Ho203) nanopowder or nanoparticles, nanodots or nanocrystals may be spherical or faceted high surface area oxide magnetic nanostructure particles. The holmium oxide nanoparticles may be 20-80 nanometers (nm) in diameter with specific surface area in the 10 - 50 m2/g range. Alternatively, the holmium oxide nanoparticles may have a diameter in thelOO nm range with a specific surface area of approximately 7- 10 m 2 /g. The brightening agent for the detergent composition of the present invention may be selected from the group of stilbene and stilbene derivatives.
Stilbene derivatives which may be useful in the present invention include, but are not necessarily limited to, derivatives of bis(triazinyl)amino-stilbene; bisacylamino derivatives of stilbene; triazole derivatives of stilbene; oxadiazole derivatives of stilbene; oxazole derivatives of stilbene; and styryl derivatives of stilbene.
The brightening agents suitable for the present invention include those belonging to the class of triazine-stilbenes (di-, tetra- or hexa-sulfonated). The brightening agents suitable for the present invention include those belonging to the class of biphenyl-stilbenes. The brightening agents suitable for the present invention include those belonging to the class of diaminostilbene-sulphonic acid derivatives. Typical fluorescent whitening agents are Parawhite KX, supplied by Paramount Minerals and Chemicals, Mumbai, India; Tinopal® DMS and Tinopal® CBS available from Ciba-Geigy AG, Basel, Switzerland. Tinopal® DMS is the disodium salt of 4,4'-bis-(2-morpholino-4 anilino-s-triazin-6-ylamino)stilbene disulphonate. Usually, the brightening agents are supplied and used in the form of their alkali metal salts, for example, the sodium salts. The total amount of the brightening agent or agents used in laundry treatment composition is generally from 0.005 to 2 wt %, more preferably 0.01 to 0.1 wt %. Suitable stilbene derivatives include without limitation:
• benzenesulfonic acid, 2,2'-(l,2-ethenediyl)bis[5-[[4-[bis(2-hydroxyethyl) amino]- 6-(phenylamino)-l,3,5-triazin-2-yl]amino]- Benzenesulfonic acid, 2,2'-(l,2- ethenediyl)bis[5-[[4-[bis(2-hydroxyethyl) amino]-6-(phenylamino)-l,3,5-triazin-2- yl]amino]-, disodium salt
• Benzenesulfonic acid, 2,2'-(l,2-ethenediyl)bis[5-[[4-[(2-hydroxyethyl)
methylamino]-6-(phenylamino)-l,3,5-triazin-2-yl]amino]-, disodium salt
Benzenesulfonic acid, 2,2'-(l,2-ethenediyl)bis[5-[[4-(4-morpholinyl)-6- (phenylamino)-l,3,5-triazin-2-yl]amino]-, disodium salt
• Benzenesulfonic acid, 2,2'-(l,2-ethenediyl)bis[5-[[4-[bis(2-hydroxyethyl)amino]-6- [(4-sulfophenyl)amino]-l,3,5-triazin-2-yl]amino]-, tetrasodium salt
Benzenesulfonic acid, 2,2'-(l,2-ethenediyl)bis[5-[[4-[(3-amino-3-oxopropyl) (2- hydroxyethyl)amino]-6-[(4-sulfophenyl)amino]-l,3,5-triazin-2-yl]amino]-, tetrasodium salt
• Benzenesulfonic acid, 2,2'-(l,2-ethenediyl)bis[5-[[4-[(3-amino-3-oxopropyl) (2- hydroxyethyl)amino]-6-[(4-sulfophenyl)amino]-l,3,5-triazin-2-yl]amino]-, tetrasodium salt
Other suitable stilbene derivatives include without limitation the stilbene derivatives disclosed in WO 2001/066681 Al, incorporated herein by reference.
The detergent composition of present invention may further comprise additional components including without limitation cleaning enzymes (such as amylases, proteases, and other enzymes), fatty acids, other adjunct cleaning additives, chelating agents, builders, structu rants, thickeners, clay soil removal agents, anti-redeposition agents, polymeric soil release agents, alkoxylated polyamine polymers, polymeric grease cleaning agents, enzyme stabilizing systems, bleaching compounds, bleaching agents, bleach activators, bleach catalysts, fabric hueing agents, dye transfer inhibiting agents, suds suppressors, fabric softeners, conditioning agents, humectants, suspending agents, suds boosters, fillers, and carriers. Suitable additional components for the present invention such as the aforementioned are for example described in US 2014/0026331 Al and in US8716208B1. The disclosures of US 2014/0026331 Al and US8716208 together with any documents directly or indirectly referenced therein are incorporated herein by reference. The present invention further provides a method for the preparation of a detergent composition comprising the steps of providing the components of the detergent composition of the present invention and combining the components to form the detergent composition of the present invention. Suitable processes for providing and combining the components are known in the state of the art and may be selected as appropriate under the circumstances by the skilled artisan.
The present invention further provides a method cleaning a textile comprising the steps of soaking the textile in an aqueous solution of a detergent composition, the detergent composition comprising a brightening agent and nanoparticles - drying the textile
The present invention further provides a method for the treatment of textile fibers soaking the textile fibers in an aqueous solution of a detergent composition, the detergent composition comprising a brightening agent and nanoparticles drying the textile fibers Also described herein is a method for cleaning fabrics. Such method includes the steps of providing one or more fabrics to which stains are adhered, and contacting said fabrics with a wash solution. The wash solution comprises water; and a detergent composition as described herein. The cleaning fabrics may optionally be rinsed after contact with the wash solution. The compositions may be employed at concentrations of from about 200 ppm to about 10,000 ppm in solution. The water temperatures may range from about 5° C. to about 100° C. The water to fabric ratio may be from about 1:1 to about 20:1. The following four inventive detergent compositions (examples Al, A2, Bl, and B2) have been prepared and tested. All four compositions comprise a brightening booster in accordance with the present invention and exhibit certain inventive benefits described herein. EXAMPLE Al
The exemplary detergent composition Al is a solid composition comprising about
Components (exemplary detergent composition Al) Weight%
Linear sodium alkylbenzene sulfonate 8.8 (± 0.5)
Fatty alcohol ethoxylate C12-14 (7EO) 4.7 (± 0.3)
Sodium soap 3.2 (± 0.2)
Foam inhibitor concentrate (12% silicone supported on inorganic
3.9 (± 0.3) substrate)
Sodium aluminosilicate zeolite 4a (80% active material) 28.3 (± 1.0)
Sodium carbonate 11.6 (± 1.0)
Poly(acrylic acid-co-maleic acid), sodium salt 2.4 (± 0.2)
Sodium silicate (Si02:Na20 = 3.3:1) 3.0 (± 0.2)
Carboxymethyl cellulose 1.2 (± 0.1)
Phosphonate (commercial designation "Dequest® 2066", 25 %
2.8 (± 0.2) active acid)
Optical brightener for cotton (stilbene derivative, commercially
designated "RUCO-BLANC ADS" available from Rudolf GmbH, 0.2 (± 0.02) Altvaterst^e 58 - 64, 82538 Geretsried, Germany)
Brightening booster (holmium oxide) 0.08 (± 0.01)
Sodium sulfate 6.5 (± 0.5)
Protease (Savinase® 8.0) 0.4 (± 0.04)
Sodium perborate tetrahydrate (10% to 10.4% available oxygen)
20.0 (separate additive) Tetra acetyl ethylene diamine (active content 90.0% to 94.0%)
3.0 (separate additive)
EXAMPLE A2
The exemplary detergent composition A2 is a solid composition comprising about
Components (exemplary detergent composition A2) Weight%
Linear sodium alkylbenzene sulfonate 8.8 (± 0.5)
Fatty alcohol ethoxylate -14 (7EO) 4.7 (± 0.3)
Sodium soap 3.2 (± 0.2)
Foam inhibitor concentrate (12% silicone supported on inorganic
3.9 (± 0.3) substrate)
Sodium aluminosilicate zeolite 4a (80% active material) 28.3 (± 1.0)
Sodium carbonate 11.6 (± 1.0)
Poly(acrylic acid-co-maleic acid), sodium salt 2.4 (± 0.2)
Sodium silicate (Si02:Na20 = 3.3:1) 3.0 (± 0.2)
Carboxymethyl cellulose 1.2 (± 0.1)
Phosphonate (commercial designation "Dequest® 2066", 25 %
2.8 (± 0.2) active acid)
Optical brightener for cotton (stilbene derivative, commercially
designated "RUCO-BLANC ADS" available from Rudolf GmbH, 0.2 (± 0.02) Altvaterst^e 58 - 64, 82538 Geretsried, Germany)
Brightening booster (holmium acetate) 0.12 (± 0.02)
Sodium sulfate 6.5 (± 0.5)
Protease (Savinase® 8.0) 0.4 (± 0.04)
Sodium perborate tetrahydrate (10% to 10.4% available oxygen)
20.0 (separate additive)
Tetra acetyl ethylene diamine (active content 90.0% to 94.0%)
3.0 (separate additive) EXAMPLE Bl: STILBENDERIVAT + 0,12% HOLMIUMACETAT
The exemplary detergent composition Bl is a liquid composition comprising about
Components (exemplary detergent composition Bl) Weight%
Linear sodium alkylbenzene sulfonate 12.0 (± 0.6)
Anionic surfactant 8.0 (± 0.8)
Citric acid (sodium citrate) 1.2 (± 0.12)
Fatty acid (C24 sodium salt) 4.0 (± 0.6)
Alkali (NaOH) 2.65
Chelating agent (diethylene triamine pentaacetic acid) 0.3 (± 0.05)
Stabilizer (propanediol/neutralizing agent) 8.13 (± 1.2)
Preservative (borax) 1.0 (± 0.1)
Optical brightener for cotton (stilbene derivative, commercially
designated "RUCO-BLANC ADS" available from Rudolf GmbH, 0.04 (± 0.01) Altvaterst^e 58 - 64, 82538 Geretsried, Germany)
Brightening booster (holmium oxide) 0.08 (± 0.01)
Water / other additives rest
EXAMPLE B2
The exemplary detergent composition B2 is a liquid composition comprising about
Components (exemplary detergent composition B2) Weight%
Linear sodium alkylbenzene sulfonate 12.0 (± 0.6)
Anionic surfactant 8.0 (± 0.8)
Citric acid (sodium citrate) 1.2 (± 0.12)
Fatty acid (C24 sodium salt) 4.0 (± 0.6)
Alkali (NaOH) 2.65 Chelating agent (diethylene triamine pentaacetic acid) 0.3 (± 0.05)
Stabilizer (propanediol/neutralizing agent) 8.13 (± 1.2)
Preservative (borax) 1.0 (± 0.1)
Optical brightener for cotton (stilbene derivative, commercially
designated "RUCO-BLANC ADS" available from Rudolf GmbH, 0.04 (± 0.01) Altvaterst^e 58 - 64, 82538 Geretsried, Germany)
Brightening booster (holmium acetate) 0.12 (± 0.01)
Water / other additives rest
Every document cited herein, including any cross referenced or related patent or application is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern. While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims

1. Detergent composition comprising
- a cleaning agent
and
- a brightening agent
characterized in that
the detergent composition further comprises
- a brightening booster component,
the brightening booster component comprising a rare earth metal atoms.
2. Detergent composition according to Claim 1
wherein
the brightening booster component comprises holmium atoms.
3. Detergent composition according to Claim 1 or 2
wherein
the brightening agent comprises a salt of a rare earth metal.
4. Detergent composition according to Claim 3
wherein
the brightening agent comprises an acetate of a rare earth metal.
5. Detergent composition according to Claim 1 or 2
wherein
the brightening agent comprises an oxide of a rare earth metal.
6. Detergent composition according to Claim 1
wherein
detergent composition is liquid at ambient conditions.
7. Detergent composition according to Claim 1
wherein
the brightening booster component comprises nanoparticles, the nanoparticles comprising the rare earth metal atoms.
8. Detergent composition according to Claim 1
wherein
the nanoparticles comprise rare earth metal oxide nanoparticles.
9. Detergent composition according to Claim 6
wherein
the nanoparticles comprise holmium oxide nanoparticles.
10. Detergent composition according to Claim 1
wherein
the brightening agent is selected from the group of stilbene and stilbene derivatives.
11. Method for cleaning a textile comprising the steps of
- soaking the textile in an aqueous solution of a detergent composition according to any of Claim 1 through Claim 10
- drying the textile
12. Method for the treatment of textile fibers comprising the step of
- soaking the textile fibers in an aqueous solution of a detergent composition according to any of Claim 1 through Claim 10
13. Method for the treatment of textile fibers wherein the method further comprises the step of
- drying the textile fibers
PCT/EP2015/070094 2014-09-03 2015-09-02 Detergent composition comprising rare earth metal and a stilbene brightening agent WO2016034651A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14183466.3 2014-09-03
EP14183466.3A EP2993222A1 (en) 2014-09-03 2014-09-03 Detergent composition comprising rare earth metal and a stilbene brightening agent

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AT388928B (en) * 1988-03-22 1989-09-25 Lang Chem Tech Prod Detergent additive and detergent
EP0724012A1 (en) 1995-01-27 1996-07-31 The Procter & Gamble Company Detergent compositions comprising bleaching agent and brightener
US5980931A (en) 1996-10-25 1999-11-09 The Procter & Gamble Company Cleansing products having a substantially dry substrate
US6121165A (en) 1997-07-31 2000-09-19 The Procter & Gamble Company Wet-like cleaning articles
WO2001066681A1 (en) 2000-03-08 2001-09-13 Ciba Specialty Chemicals Holding Inc. Use of optical brighteners from the class of the stilbene compounds as antimicrobially active substances
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US20120115767A1 (en) * 2007-06-18 2012-05-10 Van Buskirk Gregory Oxidizing Bleach Composition
US20140026331A1 (en) 2012-07-26 2014-01-30 The Procter & Gamble Company Liquid cleaning compositions
US8716208B2 (en) 2010-03-01 2014-05-06 The Procter & Gamble Company Composition comprising polyethylene glycol polymer and amylase
EP2762556A1 (en) * 2011-09-28 2014-08-06 Song, Zikui Color enhancing detergent for colored textile and preparation method therefor

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1247997A (en) * 1968-08-14 1971-09-29 Unilever Ltd Bleach composition
AT388928B (en) * 1988-03-22 1989-09-25 Lang Chem Tech Prod Detergent additive and detergent
EP0724012A1 (en) 1995-01-27 1996-07-31 The Procter & Gamble Company Detergent compositions comprising bleaching agent and brightener
US5980931A (en) 1996-10-25 1999-11-09 The Procter & Gamble Company Cleansing products having a substantially dry substrate
US6121165A (en) 1997-07-31 2000-09-19 The Procter & Gamble Company Wet-like cleaning articles
US7012053B1 (en) * 1999-10-22 2006-03-14 The Procter & Gamble Company Fabric care composition and method comprising a fabric care polysaccharide and wrinkle control agent
WO2001066681A1 (en) 2000-03-08 2001-09-13 Ciba Specialty Chemicals Holding Inc. Use of optical brighteners from the class of the stilbene compounds as antimicrobially active substances
US20120115767A1 (en) * 2007-06-18 2012-05-10 Van Buskirk Gregory Oxidizing Bleach Composition
US8716208B2 (en) 2010-03-01 2014-05-06 The Procter & Gamble Company Composition comprising polyethylene glycol polymer and amylase
EP2762556A1 (en) * 2011-09-28 2014-08-06 Song, Zikui Color enhancing detergent for colored textile and preparation method therefor
US20140026331A1 (en) 2012-07-26 2014-01-30 The Procter & Gamble Company Liquid cleaning compositions

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Title
M. ZAHRADNIK: "The Production and Application of Fluorescent Brightening ents", 1982, JOHN WILEY & SONS

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