WO2016076957A1 - Methods for recovering cesium or rubidium values from ore or other materials - Google Patents
Methods for recovering cesium or rubidium values from ore or other materials Download PDFInfo
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- WO2016076957A1 WO2016076957A1 PCT/US2015/053064 US2015053064W WO2016076957A1 WO 2016076957 A1 WO2016076957 A1 WO 2016076957A1 US 2015053064 W US2015053064 W US 2015053064W WO 2016076957 A1 WO2016076957 A1 WO 2016076957A1
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- WIPO (PCT)
- Prior art keywords
- ore
- cesium
- rubidium
- reactant
- salt
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the present invention relates to liberating and or recovering at least one metallic element from ore. More particularly, the present invention relates to methods for recovering cesium, rubidium, or both from ore or other material.
- Cesium salts such as cesium formate
- deposits of "primary" ore that is, ore that contains high amounts of cesium with insignificant amounts of undesirable impurities, are rare, and operators have long sought techniques to enhance recovery of cesium and/or rubidium from known deposits of ore, such as primary ore and secondary ore, or other materials containing cesium and/or rubidium. It would be highly desirable to develop methods that work well no matter what the cesium and/or rubidium content is in the ore. In other words, it would be useful to have methods that work well with primary ore and/or secondary ore, or other materials containing cesium and/or rubidium.
- a feature of the present invention is to provide a method to effectively recover cesium, rubidium, or both, from all types of cesium bearing ore and/or rubidium ore, whether high yield bearing ore or low yielding bearing ore.
- a further feature of the present invention is to provide methods to utilize the cesium, rubidium, or both, recovered from ore in the production of cesium-containing fluids, such as cesium formate and the like.
- the present invention relates to methods to recover cesium, rubidium, or both from ore and/or other materials containing cesium and/or rubidium.
- the method involves heating ore or other material containing at least cesium, rubidium, or both with at least one reactant.
- the reactant is an oxide of a metal, or a carbonate of a metal, or a hydroxide of a metal, or a hydrate of a metal, that is capable of displacing cesium oxide, rubidium oxide, or both from the ore or other material.
- the heating is at a temperature sufficient to liberate at least a portion of the cesium, rubidium, or both from the ore or other material.
- this temperature can be 1,000° C or higher.
- the reactant include, but are not limited to, lime, hydrated lime, lime in solution, or calcium carbonate, or any combinations thereof.
- the present invention further relates to cesium oxide or rubidium oxide or both obtained from any of the methods of the present invention.
- Fig. 1 is a flow diagram showing one process of the present invention for recovering cesium, rubidium, or both, from ore.
- Fig. 2 is a flow diagram showing a further process of the present invention for recovering cesium, rubidium, or both.
- the present invention relates to methods for recovering at least cesium, rubidium, or both from ore or other material containing cesium and/or rubidium.
- the present invention also relates to cesium oxide or rubidium oxide obtained from these methods.
- the cesium and/or rubidium can be of any form in the ore or other material containing the cesium and/or rubidium.
- the cesium can be present in any ore or other material as a cesium oxide.
- the rubidium can be present in any ore or other material as rubidium oxide.
- the ore includes cesium, such as pollucite (a cesium aluminosilicate ore) with the preferred formula of CsAlSi 2 0 6 .
- the cesium aluminosilicates also include rubidium.
- the ore can be a high-assay ore or a low-assay ore.
- a low-assay ore, also considered a secondary ore can comprise 25 wt% Cs 2 0 or less based on the overall weight of the ore.
- the ore can be or include 20 wt% Cs 2 0 or less, 15 wt% Cs 2 0 or less, 10 wt% Cs 2 0 or less, from 1 wt% to 15 wt% Cs 2 0, from 1 wt% to 10 wt% Cs 2 0, from 0.25 wt% to 5 wt% Cs 2 0, less than 1 wt% Cs 2 0 or about 0.1 wt% Cs 2 0 or more or other low amounts of cesium containing ore, or other amounts within or outside of any one of these ranges based on the total wt% of the ore.
- the Rb 2 0 can be present in these same amounts alone or with the Cs 2 0.
- the ore can be or include 20 wt% Cs 2 0 or more, 25 wt% Cs 2 0 or more, 35 wt% Cs 2 0 or mores, from 20 wt% to 35 wt% Cs 2 0, from 21 wt% to 35 wt% Cs 2 0, from 25 wt% to 35 wt% Cs 2 0 or more or other higher amounts of cesium containing ore, or other amounts within or outside of any one of these ranges based on the total wt% of the ore.
- the Rb 2 0 can be present in these same amounts alone or with the Cs 2 0.
- the ore can include, comprise, consist essentially of, or consist of pollucite, nanpingite, carnallite, rhodozite, pezzottaite, rubicline, borate ramanite, beryls, voloshonite, cesstibtantite, avogadrite, margaritasite, kupletskite, nalivkinite, petalite, spodumene, lepidolite, biotite, mica, muscovite, feldspar, microcline, Li-muscovite, lithiophilite, amblygonite, illite, cookeite, albite, analcime, squi, amphiboles, lithian mica, amphibolite, lithiophospahe, apatite and/or londonite, or any combinations thereof.
- the ore can comprise, consist essentially of, or consist of pollucite, an aluminosilicate mineral having the general formula (Cs>Na)[AlSi 2 0 6 ]H 2 0.
- the ore can have at least 1 wt% pollucite based on the weight of the ore, or from 1 to 5 wt% pollucite based on the weight of the ore, or at least 3 wt% pollucite based on the weight of the ore. Other amounts are from 1 wt% to 40 wt% or from 1 wt% to 35 wt%, or from 1 wt% to 30 wt%, or from 1 wt% to 25 wt% pollucite based on the weight of the ore.
- the ore or other material containing at least cesium and/or rubidium can be in any shape or size.
- the ore or other material is in the form of particulates, powder, or a plurality of particles.
- the ore or other material can be of a size of -200 mesh or smaller. For instance, at least 50% by weight (or at least 60 wt%, at least 70 wt%, at least 80 wt%, at least 90 wt%, at least 95 wt%, from 50 wt% to 100 wt %) of the ore or other material can be present as a powder or particulates having a mesh of -200 mesh.
- the ore or other material can be present as particulates or powder and have an average particle size of from about 1 mm to about 15 mm.
- the average particle size can be from about 2 mm to about 12 mm.
- any crusher can be used that can reduce large rocks into smaller rocks or individual pieces.
- crushers include, but are not limited to, a jaw crusher, a gyratory crusher, a cone crusher, an impact crusher, such as a horizontal shaft impactor, hammer mill, or vertical shaft impactor.
- Other examples of crushers that can be used include compound crushers and mineral sizers.
- a rock breaker can be used before crushing to reduce oversized material too large for a crusher.
- more than one crusher can be used and/or more than one type of crusher can be used in order to obtain desirable sizes and processing speeds.
- the ore can be crushed to obtain crushed ore that is or includes powder or particles or particulates, where at least 50% by weight (e.g., or least 60% or at least 70% or at least 80%, or at least 90%, or at least 95% or 100% by weight) of the crushed ore has a size capable of passing through a mesh/screen of 200 mesh, or passing through a mesh/screen of 175 mesh, or passing through a mesh/screen of 150 mesh, or passing through a mesh/screen of 125 mesh, or passing through a mesh/screen of -200 mesh, but not passing through +100 mesh (all U.S. mesh sizes).
- at least 50% by weight e.g., or least 60% or at least 70% or at least 80%, or at least 90%, or at least 95% or 100% by weight
- the crushed ore has a size capable of passing through a mesh/screen of 200 mesh, or passing through a mesh/screen of 175 mesh, or passing through a mesh/screen of 150 mesh, or passing through a mesh/screen of 125 mesh,
- examples of "other material” that contain at least cesium and/or rubidium that can be subjected to the methods of the present invention include, but are not limited to, tailings, and recycled material.
- this reactant can be one or more reactants.
- the reactant can be an oxide of a metal, or a carbonate of a metal, or a hydroxide of a metal, or a hydrate of a metal.
- the reactant is capable of displacing cesium oxide, rubidium oxide, or both from the ore or other material.
- Examples of the reactant include, but are not limited to, lime, hydrated lime, lime in solution, or calcium carbonate or any combination thereof.
- the reactant can be an oxide and/or hydrate and/or hydroxide and/or carbonate of calcium.
- the reactant can be an oxide of strontium, an oxide of barium, an oxide of lithium, or any combination thereof.
- the reactant can be an oxide and/or hydrate and/or hydroxide and/or carbonate of strontium, and/or can be an oxide and/or hydrate and/or hydroxide and/or carbonate of barium, and/or can be an oxide and/or hydrate and/or hydroxide and/or carbonate of lithium.
- the reactant is not magnesium oxide.
- the reactants can be present as a powder or particulates or particles or in other forms.
- the reactant can be present as particulates or particles having a size of -200 mesh or smaller. For instance, at least 50% by weight (e.g., or at least 60%, or at 70%, or at least 80%, or at least 90%, or at least 95%, or at least 100% by weight) of the reactant can have a size of - 200 mesh.
- the reactant can be present as particulates having an average particle size of from about 1 mm to about 15 mm, or from about 2 mm to about 12 mm.
- the ore or other material and the reactant have similar or the same particle sizes.
- the ore or other material and the reactant can each have a particle size (e.g., average particle size) that is within 50% of each other or within 25% of each other, or within 10% of each other, or within 5% of each other.
- the ore or other material is in intimate contact with the reactant. This can be achieved by mixing the ore or other material with the reactant so that the reactant is substantially uniformly distributed throughout the ore or other material. Alternatively, the reactant can be non-uniformly distributed throughout the ore or other material.
- the ore or other material and the at least one reactant can be used in various weight ratios.
- the ore or other material and the at least one reactant have a weight ratio of ore or other material : reactant of from about 15:85 to about 85:15 or, for instance, from about 5:95 to about 95:5 or from about 40:60 to about 60:40.
- the ore or other material and the reactant(s) can be mixed together prior to and/or during the heating step.
- Any mixer can be used to accomplish the mixing of the two, such as an auger, mixer, blender, and the like.
- the heating is generally at a temperature of 1 ,000° C or higher.
- the temperature is a reference to the average temperature achieved by the ore or other material.
- the temperature can be from about 1,000° C to about 3,000° C or more, for instance, from about 1,025° C to about 1,750° C, or from about 1,000° C to about 2,000° C, or from about 1,025° C to about 3,000° C, or the temperature of the heating can be at a temperature sufficient to volatize said cesium, rubidium, or both, that is present in the ore or other material, and this can be temperatures as stated here or above 3,000° C.
- the heating can be accomplished in any apparatus or device typically used to heat minerals or ore.
- the heating can occur in a furnace (e.g., rotary furnace) or in an oven and the like.
- the heating that is used in the present invention can be a single step heating process or staged heating or have multiple heating steps.
- the heating temperature can be achieved by ramping up the temperature. For instance, the ramping of the temperature to the desired temperature to achieve liberation can be ramped up at least 1° C per minute, at least 5° C per minute, at least 10° C per minute, or at least 15° C per minute, or more.
- the heating can be done under pressure or under an inert atmosphere or in an oxygen-containing atmosphere, or under vacuum or under a reductive environment (such as in a bed of carbon).
- the heating can be for a period of 5 minutes or more, such as from about 5 minutes to 100 hours or more. Generally, the heating occurs until the available amount (or portion thereof) of cesium and/or rubidium is liberated from the ore or other material. Generally, the process can liberate at least 50% by weight, at least 60% by weight, at least 70% by weight, at least 80%) by weight, at least 90% by weight, at least 95% by weight, at least 98% by weight, at least 99% by weight, or 100 wt% of all available cesium and/or rubidium present in the ore or other material.
- the cesium and/or rubidium can be liberated, for instance, in the form of a gas.
- the gas can be typically a cesium oxide and/or rubidium oxide.
- the cesium or rubidium or both, in the form of a gas can be recovered using various techniques.
- the cesium and/or rubidium gas can be recovered by scrubbing the gas with an aqueous solution or non-aqueous solution.
- the scrubbing of the gas can be done with water or a salt solution or other solution.
- the recovery of the cesium oxide or rubidium oxide from the gas formed can be done by subjecting the gas to condensation temperatures, for instance, spraying the gas with water or other aqueous or non-aqueous solutions.
- the ore or other material, after the cesium and/or rubidium are liberated can be at least partially converted to calcium silicate, calcium aluminosilicate, or both, when calcium is used as one of the reactants or as all of the reactant.
- the reaction efficiency of liberating cesium and/or rubidium values from the ore or other material can be to a yield that is near complete extraction of the cesium oxide and/or rubidium oxide values that are present in the ore or minerals or other materials.
- Figure 1 sets forth a block diagram showing the various steps of the methods of the present invention including optional steps.
- the blocks or rectangles defined by dashed lines are optional steps.
- cesium bearing or ore material and/or rubidium bearing or ore material is obtained (10) and optionally subjected to crushing or milling to reduce the size of the material (12) preferably to the particle sizes mentioned herein.
- the material is introduced into an oven or furnace or other heating device (14) and a reactant (16) is also introduced.
- the reactant and cesium/rubidium bearing material can be mixed prior to being introduced into the furnace, or can be mixed in the furnace.
- the reactant and/or cesium/bearing material can be introduced as batches, continuously, semi-continuously, and the like. Heat (18) is then introduced to the material and then cesium and/or rubidium are liberated or displaced (20) such as cesium oxide and/or rubidium oxide. As an option, the cesium oxide/rubidium can be liberated as a gas. The cesium/rubidium is separated from the remaining ore/material (22). The remaining ore/material can be discarded, or returned to the process (10 and/or 14) and/or for further processing.
- the liberated cesium and/or rubidium (24) can then be converted to a liquid or subjected to condensation (28) and then converted to cesium and/or rubidium salts or other products such as cesium formate, cesium hydroxide, cesium sulfate (32), and the like. Similar rubidium materials can be formed from rubidium when rubidium is the source material.
- the ore/material can contain one or more salts.
- the one or more salts can be naturally part of the ore/material (present in the starting ore/material).
- the one or more salts can be added to the ore/material before and/or during the process of the present invention.
- the presence of one or more salts can permit a further reaction between the liberated cesium, rubidium, or both, and the salt, and this can form cesium salts and/or rubidium salts, such as but not limited to, cesium sulfate and/or rubidium sulfate.
- the adding of one or more salts can be done prior to liberating of the cesium, rubidium or both from the ore or other material, and/or can be done during the liberating of the cesium, rubidium or both, and/or can be done after the liberating of the cesium, rubidium, or both.
- the one or more salts are added before or during the liberating of the cesium, rubidium, or both. For instance, as the ore or other material is heated with at least one reactant, the cesium and/or rubidium begin to decompose and eventually are liberated. If one or more salts are present, the cesium and/or rubidium being release from the ore or other material will then react with the one or more salts.
- the cesium and/or rubidium can begin to decompose and be available to react with any salt present at temperature of about 1080° C to 1090° C and higher.
- the reaction of the cesium and/or rubidium from the ore or other material generally reacts completely and quickly at temperatures of 1100° C or higher.
- a salt(s) it will not react until the cesium and/or rubidium is decomposed or liberated from the ore or other material (e.g., when the cesium and/or rubidium is present as an oxide), or, otherwise rendered available for further reaction with a salt.
- the reaction of the salt with cesium and/or rubidium is best conducted when the salt reaction is advanced to and beyond temperatures that where liquid phase diffusion is promoted, or enabled, and/or, up to such temperatures that promote the vapor phase release of the comprised cesium and/or rubidium inventory (e.g., when the inventory of cesium and/or rubidium is in the vapor phase and the salt is in the vapor phase).
- water can be added to the ore or other material to leach any salt present in the ore or other material and as an option, the ore or other material can be heated to concentrate the salt solution that was formed from the leaching.
- the salt solution can be concentrated to 30% to 50% by weight in solution or more.
- the salt that can be naturally present or added (to the ore or other material) can be, for instance, a sulfate salt, like a sulfate salt from Group I or Ila or lib of the Periodic Table of the Elements, such as, for example, Li, Na, K, Rb, Cs, Mg, Ca, Sr, and/or Ba sulfates.
- the salt can be a metal chloride salt (Li, Na, K, Rb, Cs, Mg, Ca, Sr, and/or Ba chloride).
- the salt used can be in any shape or size.
- the salt is in a form that is capable of being in intimate contact with the liberated cesium and/or rubidium.
- the salt can be in powder form, wherein at least 80 wt% of the powder is about -200 mesh.
- the two reactants can be mixed together. If added, the weight ratio of salt to liberated cesium and/or rubidium is from 30%. to about 85% by weight liberated cesium or rubidium to 15% to about 70% by weight salt.
- the mixture of salt and liberated cesium and/or rubidium can be subjected to heat and up to temperature of from 500°C to 3,000°C or higher. This can be done by rotary kiln, or heating device or furnace.
- the heating time can be from minutes to hours (e.g., 10 minutes to 10 hours or more).
- the cesium and/or rubidium salt formed from this second reaction can then be subjected to evaporation techniques to concentrate the cesium salt and/or rubidium salt (e.g., cesium sulfate) so as to precipitate out the cesium salt and/or rubidium salt for easier recovery.
- cesium salt and/or rubidium salt e.g., cesium sulfate
- the cesium and/or rubidium inventory e.g., cesium salt, rubidium salt, or both
- the cesium and/or rubidium values, and/or, the cesium salt and/or rubidium salt which can be in the vapor phase, can be scrubbed or otherwise contacted with water to form a salt solution, which can then be concentrated as a salt solution by heating to remove or evaporate some of the water.
- the cesium and/or rubidium values, liberated as a vapor phase can be scrubbed or otherwise contacted with an acid (e.g., formic acid, acetic acid, etc..) to form a formate or acetate of the cesium and/or rubidium, and the like (e.g., cesium formate, cesium acetate, rubidium formate, and/or rubidium acetate).
- an acid e.g., formic acid, acetic acid, etc..
- the cesium formate, cesium acetate, rubidium formate, and/or rubidium acetate can be scrubbed or otherwise contacted with a base.
- Figure 2 further sets forth a block diagram showing the various steps of the methods of the present invention including optional steps involving the presence and/or addition of salts to the process.
- the blocks or rectangles defined by dashed lines are optional steps.
- cesium bearing or ore material and/or rubidium bearing or ore material is obtained (10) and optionally subjected to crushing or milling to reduce the size of the material (12) preferably to the particle sizes mentioned herein.
- the material is introduced into an oven or furnace or other heating device (14) and a reactant (16) is also introduced.
- One or more salts (36) can be introduced at any point or multiple points in the process as shown by the dashed arrows. One or more of these locations can be used to add salt.
- salt(s) can be present as part of the ore or material (10).
- the reactant and cesium/rubidium bearing material can be mixed prior to being introduced into the furnace, or can be mixed in the furnace.
- the reactant and/or cesium/bearing material can be introduced as batches, continuously, semi-continuously, and the like.
- Heat (18) is then introduced to the material and then cesium and/or rubidium (e.g., cesium oxide and/or rubidium oxide) are liberated or displaced (20).
- cesium oxide/rubidium can be liberated as a gas.
- the cesium and/or rubidium (20) reacts with the salt(s) (38) to form cesium salt(s) and/or rubidium salt(s).
- the cesium salt(s) and/or rubidium salt(s) can be formed in the vapor phase.
- the cesium salt and/or rubidium material is separated from the remaining ore/material (22).
- the remaining ore/material can be discarded, or returned to the process (10 and/or 14) and/or for further processing.
- the cesium salt(s) and/or rubidium salt(s) can be recovered (48).
- the cesium salt(s) and/or rubidium salt(s) can be scrubbed with water or acid or an organic liquid (40) to obtain a solution (42) (e.g., a salt solution, a salt of the acid solution, an cesium and/or rubidium organic solution).
- a solution (42) e.g., a salt solution, a salt of the acid solution, an cesium and/or rubidium organic solution.
- the solution can be subjected to evaporation or other techniques to concentrate the solution (44).
- Similar rubidium materials can be formed from rubidium when rubidium is the source material.
- the method can maintain a slight CO presence (e.g., 1 wt% or less, such as 500 ppm or less in the solution, based on wt of solution), which can be advantageous to facilitate the recovery of the cesium and/or rubidium.
- a slight CO presence e.g., 1 wt% or less, such as 500 ppm or less in the solution, based on wt of solution
- the recovered Cs 2 0 can then be processed for a variety of uses.
- the Cs 2 0 can be used to form cesium compounds, such as cesium formate.
- the Cs 2 0 can be recovered and subjected to further recovery processes by reacting the Cs 2 0 with at least one salt, where the salt is capable of recovering at least one metallic element, such as cesium, to form a reaction product that includes at least one metallic element.
- the salt can be a sulfate salt. Details of this further processing step can be found in U.S. Patent No. 7,323,150, incorporated in its entirety by reference herein.
- the cesium can be converted to a precursor salt, such as cesium sulfate, from which other cesium salts are produced.
- a precursor salt such as cesium sulfate
- Other methodology similarly can produce alternative cesium salts from precursors like cesium hydroxide and cesium carbonate.
- the cesium can be formed into a cesium formate which subsequently can then be converted to a different cesium metal salt.
- Another process to form cesium salts is described in U.S. Patent No. 6,652,820, which is incorporated in its entirety by reference herein.
- This method involves forming a cesium salt by reacting cesium sulfate with lime to form cesium hydroxide which can then be converted to a cesium salt, such as cesium formate.
- cesium compounds can be very desirable as drilling fluids or other fluids used for hydrocarbon recovery, such as completion fluids, packer fluids, and the like.
- the present invention includes the following aspects/embodiments/features in any order and/or in any combination:
- a method for recovering at least cesium, rubidium, or both from an ore or other material comprising:
- heating is at a temperature sufficient to liberate at least a portion of said cesium, rubidium, or both from said ore or other material
- said reactant is an oxide of a metal, or a carbonate of a metal, hydroxide of a metal or a hydrate of a metal, that is capable of displacing cesium oxide, rubidium oxide, or both from said ore or other material.
- said ore or other material further comprises at least one salt, and wherein said at least one salt reacts with said at least a portion of said cesium, rubidium, or both to form a cesium salt or a rubidium salt or both.
- cesium salt or rubidium salt comprises cesium sulfate, cesium chloride, rubidium sulfate, or rubidium chloride.
- method further comprises scrubbing said cesium salt or rubidium salt or both in vapor phase with water or an acid or a base.
- method further comprises scrubbing said cesium salt or rubidium salt or both in vapor phase with water or an acid or a base.
- the present invention can include any combination of these various features or embodiments above and/or below as set forth in sentences and/or paragraphs. Any combination of disclosed features herein is considered part of the present invention and no limitation is intended with respect to combinable features.
Abstract
Description
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Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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AU2015347280A AU2015347280B2 (en) | 2014-11-12 | 2015-09-30 | Methods for recovering cesium or rubidium values from ore or other materials |
DE112015005125.2T DE112015005125T5 (en) | 2014-11-12 | 2015-09-30 | Process for recovering cesium or rubidium stocks from ore or other materials |
SE1750567A SE542168C2 (en) | 2014-11-12 | 2015-09-30 | Methods for recovering cesium or rubidium values from ore or other materials |
CN201580061543.7A CN107109517B (en) | 2014-11-12 | 2015-09-30 | Method for collecting the valuables of caesium or rubidium from ore or other materials |
CA2967308A CA2967308C (en) | 2014-11-12 | 2015-09-30 | Methods for recovering cesium or rubidium values from ore or other materials |
BR112017010016-9A BR112017010016B1 (en) | 2014-11-12 | 2015-09-30 | METHODS FOR THE RECOVERY OF VALUES OF CESIUM OR RUBIDE FROM ORE OR OTHER MATERIALS AND RECOVERED CESIUM OR RUBIDE OXIDE |
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US201462078431P | 2014-11-12 | 2014-11-12 | |
US62/078,431 | 2014-11-12 |
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PCT/US2015/053064 WO2016076957A1 (en) | 2014-11-12 | 2015-09-30 | Methods for recovering cesium or rubidium values from ore or other materials |
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US (1) | US20160130682A1 (en) |
CN (1) | CN107109517B (en) |
AU (1) | AU2015347280B2 (en) |
BR (1) | BR112017010016B1 (en) |
CA (1) | CA2967308C (en) |
DE (1) | DE112015005125T5 (en) |
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CN107354323B (en) * | 2017-07-26 | 2019-01-08 | 河北工程大学 | A method of separation and Extraction rubidium, caesium from coal |
CN111533138B (en) * | 2020-05-06 | 2022-08-26 | 中国科学院青海盐湖研究所 | Method for preparing potassium chloride by utilizing carnallite |
CN113955777A (en) * | 2020-07-21 | 2022-01-21 | 承德石油高等专科学校 | Method for extracting rubidium salt from soil by wet method |
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- 2015-09-29 US US14/868,415 patent/US20160130682A1/en not_active Abandoned
- 2015-09-30 BR BR112017010016-9A patent/BR112017010016B1/en active IP Right Grant
- 2015-09-30 DE DE112015005125.2T patent/DE112015005125T5/en not_active Ceased
- 2015-09-30 WO PCT/US2015/053064 patent/WO2016076957A1/en active Application Filing
- 2015-09-30 AU AU2015347280A patent/AU2015347280B2/en active Active
- 2015-09-30 SE SE1750567A patent/SE542168C2/en unknown
- 2015-09-30 CN CN201580061543.7A patent/CN107109517B/en active Active
- 2015-09-30 CA CA2967308A patent/CA2967308C/en active Active
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US20160130682A1 (en) | 2016-05-12 |
CN107109517B (en) | 2019-03-08 |
CA2967308C (en) | 2020-09-22 |
SE542168C2 (en) | 2020-03-03 |
AU2015347280B2 (en) | 2018-05-10 |
AU2015347280A1 (en) | 2017-05-25 |
CN107109517A (en) | 2017-08-29 |
SE1750567A1 (en) | 2017-05-09 |
CA2967308A1 (en) | 2016-05-19 |
BR112017010016A2 (en) | 2018-07-03 |
BR112017010016B1 (en) | 2021-06-22 |
DE112015005125T5 (en) | 2017-08-10 |
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