WO2016134615A1 - Device for generating electrolyzed water vapor - Google Patents

Device for generating electrolyzed water vapor Download PDF

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Publication number
WO2016134615A1
WO2016134615A1 PCT/CN2016/000093 CN2016000093W WO2016134615A1 WO 2016134615 A1 WO2016134615 A1 WO 2016134615A1 CN 2016000093 W CN2016000093 W CN 2016000093W WO 2016134615 A1 WO2016134615 A1 WO 2016134615A1
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Prior art keywords
water
electrolysis
electrolyzed
electrode
gap
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PCT/CN2016/000093
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French (fr)
Chinese (zh)
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罗民雄
黎明
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罗民雄
黎明
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Publication of WO2016134615A1 publication Critical patent/WO2016134615A1/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/28Methods of steam generation characterised by form of heating method in boilers heated electrically
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals

Definitions

  • the invention relates to a device for generating electrolyzed water vapor, belonging to the technical field of membrane-free electrolyzed water.
  • the invention proposes a device for generating electrolyzed water vapor, which is created and designed for the convenience of using electrolyzed water vapor.
  • Applicants have found through research that the basis of electrolyzed water vapor is based on the fact that electrolyzed water must have a relatively high and stable electrolyzed water index under boiling conditions. Therefore, it is necessary to use a membrane-free electrolyzed water technology with higher electrolysis efficiency to achieve electrolyzed water vapor. Certain indicator requirements. It is of great significance to improve the practicality of the electrolyzed water bathing device by adopting the new principle and new method of electrolyzed water discovered and invented by the applicant to obtain higher electrolyzed water efficiency and electrolyzed water index.
  • the water electrolysis efficiency or electrolysis water efficiency can be generally defined as: a representative index of electrolyzed water produced by electrolysis of a certain amount of water and electrolysis for a certain period of time (for example, ORP negative value or hydrogen content of electrolytically reduced water). The ratio of the quantity) to the amount of electricity consumed. In other words, in an electrolysis method or an electrolysis device, the smaller the electric energy consumed by the same amount of electrolysis to reach the same electrolyzed water index, the higher the electrolysis water efficiency of the device.
  • the new principle of electrolyzed water discovered by the applicant and the method for significantly improving the efficiency of electrolyzed water are rooted in the deep research on the main defects of the electrolysis water principle of the traditional electrolysis machine.
  • the traditional electrolysis water principle is limited to the so-called ion chemical reaction equilibrium equation generated by water molecule electrolysis, completely ignoring the electrons and impurity particles generated by electrolysis of water impurities during electrolysis, and its importance for improving electrolysis water index and electrolysis efficiency.
  • impurities are electrolyzed to produce free electrons and impurity particles which are beneficial to improve the index of electrolyzed water.
  • impurity electrolysis effect forms a certain electrolysis current, which causes the water molecules to disintegrate into hydrogen, oxygen ions or hydroxide ions.
  • the electrolysis process should strengthen the "impurity electrolysis effect" as much as possible to produce more active electrons; the newly discovered three: small gaps of different polarity electrodes (especially small gaps less than 1 mm) for strengthening "impurity electrolysis” "effect” has a significant effect, although the previous non-isolated membrane electrolyzed water technology also mentioned the design considerations of different polarity electrode spacing less than 3mm, but did not understand the practical significance of small spacing, and the matching process measures are even more difficult to talk about.
  • Electrolytic effect improve water electrolysis efficiency and electrolyzed water reduction index; in-depth study of the flowability in the electrolysis water process, explains why the electrolysis water efficiency does not rise and fall after the electrolysis current increases to a certain value.
  • the important reason is that if the flow of water in the electrode gap is not good, the ion concentration in the electrode gap will be too high, which will affect the electrolysis efficiency.
  • the channel for installing the electrolysis electrode assembly adopts a design in which the outlet passage (outlet) is appropriately narrower than the inlet passage (inlet), and the flow rate of water passing through the electrolysis electrode assembly can be reduced. Thereby increasing the time and opportunity for impurities and water molecules to be electrolyzed, and increasing the index of electrolyzed water.
  • electrolyzed water process firstly, the process of generating active electrons by electrolysis of impurities in water, forming electric current, and converting electric energy into decomposition energy of water molecules. Therefore, more water molecules are decomposed by obtaining larger electric energy, which is the basis for obtaining higher electrolysis efficiency, but obtaining higher electrolysis efficiency requires additional important conditions.
  • the electrolysis process is also a process in which various ions (especially active electrons) released by electrolysis are physicochemically treated with various hydroxide ions and ion roots generated by decomposition of water molecules, in order to increase water. There are two important conditions for the electrolysis efficiency.
  • the electrolysis water index may be higher, and the electrolysis efficiency may also be higher.
  • the probability of combining the electron ions released by the electrolysis with the hydroxide ions is higher, the electrolyzed water index may be higher, and the electrolysis efficiency is higher.
  • the higher ORP negative value and the hydrogen content of electrolytically reduced water the applicant briefly refers to the two indicators as the "negative hydrogen" index), which requires more active electrons to participate. Therefore, impurities in the water are electrolyzed to release more electrons. And the combination of electrons and hydrogen ions with a higher probability of negative hydrogen can increase the negative hydrogen index and the electrolysis efficiency.
  • the applicant's new principle of electrolyzed water reveals that it is necessary to adopt a three-pronged process to improve the efficiency of electrolytic reduction water production. It is necessary to strengthen the electrolysis of impurities in water, and to increase the electrons released by the electrolysis of impurities, and to increase the probability of the electrons released by electrolysis being combined with hydrogen to form negative hydrogen.
  • Applicant's research found a specific electrolysis process to achieve this three-pronged process: one is to appropriately reduce the distance between the electrolysis gaps of electrodes of different polarities, and the other is to appropriately enlarge the area of the electrolysis gap of electrodes of different polarities, and the third is to properly maintain
  • the fluidity of water in and out of the gap between different polar electrodes in the electrolysis water process the coordinated realization of these three technological conditions can better balance the effect of strengthening the impurity electrolysis and improving the reduction index, thereby significantly improving the efficiency of electrolysis water.
  • the apparatus of the present invention for generating electrolyzed water vapor requires the use of a highly efficient membraneless electrolyzed water technique.
  • the new method of electrolyzed water invented by the applicant is a better choice for improving the efficiency and performance of the device and the cost performance.
  • the invention relates to a device for generating electrolyzed water vapor, which comprises: a steam generator having a water inlet and a steam outlet, a controllable electrolysis power source, an electrolysis electrode assembly, and a heating system capable of heating the water stored in the steam generator.
  • the controllable electrolysis power source supplies electrolysis current to the electrolysis electrode assembly, and the electrolysis electrode group electrolyzes the water stored in the steam generator; the heating system heats the electrolyzed water in the steam generator to boiling to generate steam; the electrolyzed water vapor is output from the steam outlet;
  • the electrolytic electrode assembly adopts a higher efficiency membrane-free electrolyzed water technical scheme, and can effectively electrolyze the water storage tank in a wide temperature range including boiling water, so that the electrolyzed water vapor reaches a certain index required.
  • the spacing of the gaps between the electrodes of different polarities is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to enhance the impurities and water in the water.
  • the characteristics of the electrolysis electrode assembly and its installation process conditions are: in the process of electrolyzing water, water can flow smoothly in the gap of different polarity electrodes, so that the electrolyzed water in the gap of different polarity electrodes can be replaced, and more Impurities and water molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
  • the third aspect of the present invention the electrolysis electrode assembly, if necessary, the spacing between the electrodes of different polarity of the electrolysis electrode assembly can be as small as 1 mm or less, which is advantageous for strengthening under certain electrolysis power and certain electrolysis electrode assembly structure.
  • the electrolysis of impurities and water molecules in water improves the efficiency of water electrolysis.
  • the electrolysis electrode assembly can make daily drinking water and water into electrolytic reduced water having a negative oxidation-reduction potential and a hydrogen content greater than zero.
  • the electro-electrode assembly has different polarity electrode structures designed such that when water in the electrode gap is electrolyzed to generate fluidity, water and ions in the electrode gap can flow with each other so that more water flows through different poles.
  • the electrode gap replaces the electrolyzed water in the gap, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the current between the electrodes of different polarities, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes. Improve the efficiency of water electrolysis.
  • the electrolysis electrode assembly has a certain space outside the two port positions of the electrode gap, so that when water flows during the process of electrolysis, the water can smoothly flow in the gap of different polarity electrodes, and the water is improved. The efficiency of electrolysis.
  • the electrolysis electrode assembly by increasing the area of the electrode gap in a certain space occupied by the electrolysis electrode assembly, the time during which the flowing water is electrolyzed in the electrode gap can be prolonged, so that more impurities and water molecules are Electrodes with different polarities are repeatedly electrolyzed several times to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
  • the electrode in the electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as an electrode, the electrode can be appropriately connected as an electrolytic electrode, the gap area of the electrolytic electrode is increased, and the electrolysis of water is improved. effectiveness.
  • the electrolysis electrode assembly is composed of two electrodes of different polarities, one of the electrodes is in the shape of a cylinder, the number of the cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube can be free of gaps or There is a gap, the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other; the second electrode is columnar, and the positions of the respective columns are mechanically fixed and electrically connected to each other, and the number of columns of the columnar electrodes is M, M is equal to or greater than 1; Hollow or solid, no gap or notch; the height of the cylindrical electrode and the columnar electrode is not limited, as needed; the cylindrical electrode is inserted into the columnar electrode, that is, the columnar electrode is inserted into each corresponding cylinder hole, A gap for electrolysis of water is left between the surface of the inserted column electrode and the opposite surface of the barrel electrode; during the electrolysis work, water in the electrode gap can flow; the electrode gap has
  • the invention has a device for generating electrolyzed water vapor, characterized in that: a steam generator including a water inlet and a steam outlet, a controllable electrolysis power source, an electrolysis electrode assembly, and a water storage in the steam generator a heating heating system; the controllable electrolysis power source supplies an electrolysis current to the electrolysis electrode assembly, and the electrolysis electrode group electrolyzes the water stored in the steam generator; the heating system heats the electrolysis water in the steam generator to boiling to generate steam; electrolyzes water vapor from the steam Output port output; Electrolytic electrode assembly adopts high efficiency membrane-free electrolyzed water technology scheme, which can effectively electrolyze the water storage in a wide temperature range including boiling water in the water storage container, so that the electrolyzed water vapor reaches a certain index required.
  • the electrolysis electrode assembly the spacing of the gaps between the electrodes of different polarities is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to strengthen the impurities in the water.
  • Electrolysis of water molecules in a certain space occupied by electrolytic electrode assemblies, the area of the gap between electrodes of different polarities is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be repeatedly repeated in the electrode gap.
  • Electrolysis Electrolytic electrode assembly and its installation process conditions are characterized in that in the process of electrolyzing water, water can flow smoothly in the gap of different polarity electrodes, so that the electrolyzed water in the gap of different polarity electrodes can be replaced, and Multiple impurities and water molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
  • the electrolysis electrode assembly if necessary, the spacing between the electrodes of different polarity of the electroplating electrode assembly can be as small as 1 mm or less, so as to favor a certain electrolysis power and a certain electrolysis electrode assembly structure. Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.
  • the electrolysis electrode assembly can make daily drinking water and water into electrolytic reduction water with a negative oxidation-reduction potential and a hydrogen content greater than zero.
  • the fourth technical scheme the electrolysis electrode assembly, the electrode structure of different polarities is designed such that when water in the electrode gap is electrolyzed to generate fluidity, water and ions in the electrode gap can flow with each other so that more water flows through the water.
  • the polar electrode gap replaces the electrolyzed water in the gap, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the currents of different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes. To improve the efficiency of water electrolysis.
  • the electrolysis electrode assembly has a certain space outside the two port positions of the electrode gap, so that when the water flows during the electrolysis process, the water can flow smoothly in the gap of the different polarity electrodes, thereby improving Water The efficiency of electrolysis.
  • the electrolysis electrode assembly can prolong the time of electrolysis of the flowing water in the electrode gap by increasing the area of the electrode gap in a certain space occupied by the electrolysis electrode assembly, so that more impurities and water molecules are obtained. It is repeatedly electrolyzed by electrodes of different polarities to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
  • the electrolysis electrode assembly in the case where the material and shape of the electrolytic cell wall of the electrolysis electrode assembly are suitable as an electrode, the appropriate connection can be used as an electrolysis electrode, the gap area of the electrolysis electrode is increased, and the water is increased. Electrolysis efficiency.
  • the electrolysis electrode assembly is composed of two electrodes of different polarities, one of the electrodes is in the shape of a cylindrical hole, the number of cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube can be unnotched.
  • the position of each of the barrel electrodes is mechanically fixed and electrically connected to each other;
  • the second electrode is columnar, each column position is mechanically fixed and electrically connected to each other, the number of columns of the columnar electrode is M, M is equal to or greater than 1;
  • the column is hollow or solid, and may be unnotched or notched; the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement; the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, the columnar electrodes are inserted into the corresponding cylindrical holes.
  • Embodiment 1 is a device for generating electrolyzed water vapor according to Embodiment 1 of the present invention
  • a device for generating electrolyzed water vapor comprising a steam generator 14, a water inlet 18, a steam outlet 13, a heating system 5, a controllable electrolysis power source 9, an electrolysis consisting of electrodes 1 and 2, and an electrolysis cell 10.
  • the electrode assembly, 15 is a water level line, and the heating system 5 heats the water stored in the steam generator 14; the controllable electrolysis power source 9 supplies power to the different polarity electrodes 1, 2 of the electrolysis electrode assembly 10 through the wires 6, 7 to generate steam.
  • the device 14 stores water for electrolysis; the heating system 5 heats the steam generator 14 to boiling, and outputs electrolyzed water vapor from the steam outlet 13; the electrolysis electrode assembly 10 adopts a higher efficiency membraneless electrolyzed water solution for the steam generator 14
  • the medium-wide temperature range includes boiling water storage for effective electrolysis, so that the electrolyzed water vapor can reach a certain required index; 8 is the wall of the electrolysis cell, the upper and lower portions 16, 17 are permeable, and the electrolysis electrode assembly is composed of two different
  • the polar electrodes 1 and 2 are formed, and the electrode 1 is in the shape of a cylinder (hereinafter referred to as a hole). Three hole-shaped electrodes are schematically illustrated in the figure.
  • each column position is mechanically fixed and electrically connected to each other, and 1 and 2 can be correspondingly inserted, that is, the column of the columnar electrode 2 is inserted into the corresponding hole of the hole electrode, and an electrolytic gap is left between the surface of the column and the surface of the hole.
  • the gap is tubular.
  • the gap 3 between the three columnar electrodes and the hole electrode is schematically illustrated in FIG. 1.
  • the gap spacing may be selected within a certain range, such as less than 5 mm to more than 0 mm; if necessary, Interval 3
  • the distance may be a small value, such as equal to or less than 1 mm, in order to strengthen the electrolysis effect of water and impurities therein, so that when the device requires raw water such as pure water or distilled water with low electrolytic conductivity, high electrolysis water efficiency and index can be obtained.
  • the probability and quantity of impurities and water molecules being electrolyzed are proportional to the gap area. Therefore, the larger the area of the gap 3 can improve the electrolysis efficiency; in Fig. 1, the wall 8 of the electrolytic cell is suitable for the electrolysis electrode.
  • the material used is connected to the electrolytic power source via the wire 7 to form a part of the electrode 2, and constitutes an electrolytic gap 4 with the electrode 1 to enhance the electrolysis effect; 11, 12 are the lower part and the upper space of the electrolytic cell 10, respectively, and the space 11 is at the bottom of the electrolytic cell. Between 16 and the bottom of the electrode assembly, a certain volume is designed for the spaces 11 and 12 to facilitate smooth flow of water in the electrode gap.
  • the water molecules in the gap are electrolytically decomposed, hydrogen and oxygen are generated, and the hydrogen and oxygen bubbles will flow upward along the gap, thereby causing the water in the gap 3 to flow upward, flowing out from the upper port of the gap 3 to
  • the space 12 flows to the outside of the electrolytic cell, which causes water to flow into the space 11 from the source below the lower portion 16 of the electrolytic cell, and then flows into the electrode gap 3 for supplementation.
  • the 11 and 12 are too narrow, the flow of water in the electrode gap may be affected. Thereby reducing the electrolysis efficiency of water.
  • impurities and water molecules in the water are repeatedly electrolyzed by the electrolysis current in the gap.
  • the water in the steam generator 14 repeatedly flows from the bottom of the 8 into the electrode gap of the electrolytic cell and is repeatedly electrolyzed to continuously strengthen the electrolysis effect; in summary, the gap 3 is reasonably selected to have a smaller pitch and a larger area. And to meet the gap 3 water has a certain circulation, these three aspects of coordination of the technical solutions can significantly improve the electrolysis efficiency and electrolyzed water indicators.
  • the electrolyzed water has a high index, for example, the negative ORP value and the hydrogen content of the electrolyzed water, and the negative ion content in the electrolyzed water vapor is high.
  • Table 1 Apparatus for generating electrolyzed water vapor according to the present invention.
  • Example 1 Three kinds of electrolytic electrode structures and conditions measured data
  • the invention relates to a device for generating electrolyzed water vapor, wherein the electrolysis electrode assembly is not limited to the specific structure adopted by the embodiment 1.
  • the electrolysis electrode assembly is not limited to the specific structure adopted by the embodiment 1.
  • any of the membrane-free electrolysis electrode structural components which can achieve the electrolyzed water index required for the product are Can be applied.

Abstract

A device for generating electrolyzed water vapor comprises: a vapor generator (14), provided with a water inlet (18) and a vapor outlet (13); a controllable electrolytic power supply (9); an electrolytic electrode assembly; and a heating system (5), capable of heating water stored in the vapor generator (14). The controllable electrolytic power supply (9) supplies an electrolytic current to the electrolytic electrode assembly. The electrolytic electrode assembly electrolyzes the water stored in the vapor generator (14). The heating system (5) heats the electrolyzed water in the vapor generator (14) to boil so as to generate vapor. The electrolyzed water vapor is output from the vapor outlet (13). The electrolytic electrode assembly uses a membraneless electrolyzed-water technical scheme with a higher efficiency, so that water stored in the water storage container in a wide temperature range, comprising boiled water, can be effectively electrolyzed, so as to make the electrolyzed water vapor reach certain required indicators. The size of a gap (3) between electrodes (1, 2), having different polarities, of the electrolytic electric assembly is designed according to a principle of a smaller distance, and the area of the gap (3) is designed according to a principle of a reasonable larger area; the water can smoothly flow in the gap (3) between the electrodes (1, 2) having different polarities, and indicators of the electrolyzed water and the water vapor thereof are improved.

Description

一种发生电解水蒸汽的装置Device for generating electrolyzed water vapor 技术领域Technical field
本发明涉及一种发生电解水蒸汽的装置,属于无膜电解水技术领域。The invention relates to a device for generating electrolyzed water vapor, belonging to the technical field of membrane-free electrolyzed water.
背景技术Background technique
当今,人们已经广泛使用水蒸汽蒸制食品、蒸脸美容,以及做蒸汽浴保健治病等,而负电位富含氢的电解水蒸汽更是具有抗氧化与杀菌去污、美容洁肤的功效,用于蒸制食品还有去除食物异味、改善食物味道的作用,可见将电解水技术与蒸汽发生器结合,创造一种发生电解水蒸汽的装置,是很有实用价值及多方面意义的。那么,为何迄今未见可输出电解水蒸汽的装置问世呢?原因之一是因为流行电解水机采用低效率的有膜电解水技术,只能电解常温水,水温超过50-60摄氏度时电解水指标就会消失,而且存在必须同时输出酸碱性两种水、出水量小、耗电大等严重缺陷,显然不具备设计制造可发生电解水蒸汽的装置的基本条件;原因之二是现有无膜电解水技术虽然展现了有膜电解水技术所未有的优势,例如:可以电解任意温度原水并且只输出一种电解水等独特优点,但是缺陷是电解效率或指标还是偏低,因此尚局限于做杯壶型等电解自然静止水装置以提供饮用水等方面的用途。申请人发现:采用电解效率较高的无膜电解水技术,可以制造出具有实用价值的发生电解水蒸汽的装置。Nowadays, people have widely used steam steamed food, steamed face beauty, and steam bath health treatment, and the negative potential hydrogen-rich electrolyzed water vapor has anti-oxidation and sterilization decontamination, beauty cleansing effect. It is used for steaming foods, removing food odors and improving the taste of foods. It can be seen that the combination of electrolyzed water technology and steam generators creates a device for generating electrolyzed water vapor, which is of practical value and multi-faceted significance. So why haven't there been any devices that can output electrolyzed water vapor? One of the reasons is that the popular electrolyzed water machine adopts the low-efficiency membrane electrolyzed water technology, which can only electrolyze normal temperature water. When the water temperature exceeds 50-60 degrees Celsius, the electrolyzed water index will disappear, and there must be both acid and alkaline water. Serious defects such as small amount of water and large power consumption, obviously do not have the basic conditions for designing and manufacturing devices that can generate electrolyzed water vapor; the second reason is that the existing membrane-free electrolyzed water technology shows that there is no membrane electrolyzed water technology. The advantages, such as: the ability to electrolyze any temperature raw water and only output a kind of electrolyzed water, but the defect is that the electrolysis efficiency or index is still low, so it is limited to making electrolyzed natural static water devices such as cups and pots to provide drinking water. Other uses. Applicant found that the use of membrane-free electrolyzed water technology with high electrolysis efficiency can produce a practical device for generating electrolyzed water vapor.
发明内容Summary of the invention
本发明提出一种发生电解水蒸汽的装置,是为了人们可以方便地使用电解水蒸汽而创造与设计。申请人经研究发现:电解水蒸汽的基础基于电解水必需在沸腾状态下具有较高及较稳定的电解水指标,因此,需要采用较高电解效率的无膜电解水技术,以达到电解水蒸汽一定的指标要求。采用申请人发现与发明的电解水新原理与新方法能获得较高电解水效率与电解水指标,对于提高电解水沐浴装置的实用性有很大意义。水电解效率或称电解水效率,一般可以定义为:在电解一定量的水以及电解一定时间情况下,所制成的电解水某种代表性指标(例如电解还原水的ORP负值或含氢量数值)与所耗电量之比。换言之,某种电解方法或电解装置,电解同样水量达到同一电解水指标所耗电能越小,该装置电解水效率就越高。The invention proposes a device for generating electrolyzed water vapor, which is created and designed for the convenience of using electrolyzed water vapor. Applicants have found through research that the basis of electrolyzed water vapor is based on the fact that electrolyzed water must have a relatively high and stable electrolyzed water index under boiling conditions. Therefore, it is necessary to use a membrane-free electrolyzed water technology with higher electrolysis efficiency to achieve electrolyzed water vapor. Certain indicator requirements. It is of great significance to improve the practicality of the electrolyzed water bathing device by adopting the new principle and new method of electrolyzed water discovered and invented by the applicant to obtain higher electrolyzed water efficiency and electrolyzed water index. The water electrolysis efficiency or electrolysis water efficiency can be generally defined as: a representative index of electrolyzed water produced by electrolysis of a certain amount of water and electrolysis for a certain period of time (for example, ORP negative value or hydrogen content of electrolytically reduced water). The ratio of the quantity) to the amount of electricity consumed. In other words, in an electrolysis method or an electrolysis device, the smaller the electric energy consumed by the same amount of electrolysis to reach the same electrolyzed water index, the higher the electrolysis water efficiency of the device.
申请人发现的电解水新原理及显着提高电解水效率的方法,根源于对传统电解水机电解水原理存在重大缺陷的深层研究。传统电解水原理仅局限于所谓水分子电解产生的离子化学反应平衡方程,完全忽视了电解过程中水的杂质被电解所产生的电子与杂质微粒,及其对提高电解水指标与电解效率的重要意义,因此无从解释阴极区碱性水具有较高还原水关键指标即较高氧化还原电位(ORP)负值与较高含氢(H、H2、H-)量的现象,完全忽视了阴极区水形成较高ORP负值与负氢(H-)含量需要相当数量活性电子的关键现象,因此无法解决现有电解技术效率太低、即使加大电解电流也达不到预想较高电解水指标的难题。申请人长期研究获得六个新发现: The new principle of electrolyzed water discovered by the applicant and the method for significantly improving the efficiency of electrolyzed water are rooted in the deep research on the main defects of the electrolysis water principle of the traditional electrolysis machine. The traditional electrolysis water principle is limited to the so-called ion chemical reaction equilibrium equation generated by water molecule electrolysis, completely ignoring the electrons and impurity particles generated by electrolysis of water impurities during electrolysis, and its importance for improving electrolysis water index and electrolysis efficiency. Significance, therefore, it is impossible to explain that the alkaline water in the cathode region has a higher index of higher reducing water, ie, a higher redox potential (ORP) negative value and a higher hydrogen content (H, H 2 , H ), completely ignoring the cathode. The formation of higher ORP negative and negative hydrogen (H - ) content in the zone water requires a significant amount of active electrons, so it cannot solve the problem that the existing electrolysis technology is too low, even if the electrolysis current is increased, it does not reach the expected higher electrolyzed water. The problem of indicators. The applicant's long-term research has won six new discoveries:
新发现之一:电解水过程,为了提高电解水效率,首要的是电解水中的杂质。杂质被电解产生自由电子及有利于提高电解水指标的杂质微粒,本文简称“杂质电解效应”,杂质电解效应形成一定电解电流,令水分子解体成为氢、氧离子或氢氧离子根,本文简称为“水分子电解效应”。电解水效率与指标是“杂质电解效应”与“水分子电解效应”共同作用的结果;新发现之二:揭示了“杂质电解效应”产生的活性电子对于提高电解效率的双重意义,活性电子不仅可增加电解电流,并且对于电解制作还原水还具有另一重要意义,就是满足一定电解水指标例如电解还原水的ORP(负氧化还原电位)负值及其相应的氢含量(负氢含量)对电子之所需。故欲提高电解效率,电解工艺应尽可能强化“杂质电解效应”,以产生较多活性电子;新发现之三:是不同极性电极小间隙(尤其小于1mm的小间隙)对于强化“杂质电解效应”具有显著效果,尽管此前的无隔离膜电解水技术也曾提及不同极性电极间距小于3mm的设计考虑,但是并未了解小间距的实际意义,与之相配的工艺举措更无从谈起,不能达到显著提高电解水效率的效果;新发现之四:电解电极间隙小间距设计的另一重要意义,是可以创造活性电子与活性氢H结合为负氢的较多机会与较好条件,从而显著提高电解制作还原水的效率;新发现之五:不同极性电极小间隙小到某值,电解效率不升反降,这是什么原因呢?研究证实:要强化“杂质电解效应”,还需要在电解过程中保证水在不同极性电极间隙有一定流通性,这可促使较多水分子及杂质较多次反复被电解,从而强化“杂质电解效应”,提高水电解效率与电解水还原指标;对电解水过程中流通性的深入研究,解释了为什么电解电流增加到一定值后,电解水效率不升反降。重要原因在于:若电极间隙中水的流通性不好,会使得电极间隙中离子浓度过高,从而影响电解效率;新发现之六:对于电解外力驱动的流水例如自来水而言,在电极组件所占一定空间内,采取合理增加电解间隙面积的设计方案,有利于水中较多杂质与水分子较多次反复电解,可以提高水电解效率与电解指标。另外,在电解流速过快的流水情况下,对安装电解电极组件的通道,采取出水通道(出水口)比进水通道(进水口)适当狭窄的设计,可以降低水经过电解电极组件的流速,从而增加杂质与水分子被电解的时间与机会,提高电解水的指标。One of the new discoveries: in the process of electrolyzing water, in order to improve the efficiency of electrolyzed water, the first thing is to electrolyze impurities in water. Impurities are electrolyzed to produce free electrons and impurity particles which are beneficial to improve the index of electrolyzed water. This article is referred to as “impurity electrolysis effect”. The impurity electrolysis effect forms a certain electrolysis current, which causes the water molecules to disintegrate into hydrogen, oxygen ions or hydroxide ions. For "water molecule electrolysis effect." The efficiency and index of electrolyzed water are the result of the interaction between “impurity electrolysis effect” and “water molecule electrolysis effect”; the second discovery: reveals the dual meaning of active electrons generated by “impurity electrolysis effect” to improve electrolysis efficiency. It can increase the electrolysis current, and it has another important significance for electrolytically producing reduced water, which is to satisfy the negative value of ORP (negative redox potential) and its corresponding hydrogen content (negative hydrogen content) of certain electrolyzed water indexes such as electrolytically reduced water. The need for electronics. Therefore, in order to improve the electrolysis efficiency, the electrolysis process should strengthen the "impurity electrolysis effect" as much as possible to produce more active electrons; the newly discovered three: small gaps of different polarity electrodes (especially small gaps less than 1 mm) for strengthening "impurity electrolysis" "effect" has a significant effect, although the previous non-isolated membrane electrolyzed water technology also mentioned the design considerations of different polarity electrode spacing less than 3mm, but did not understand the practical significance of small spacing, and the matching process measures are even more difficult to talk about. The effect of significantly improving the efficiency of electrolyzed water cannot be achieved; the fourth finding: another important significance of the design of the small spacing of the electrolysis electrode gap is that it can create more opportunities and better conditions for the combination of active electrons and active hydrogen H into negative hydrogen. Thereby significantly improving the efficiency of electrolytic production of reduced water; the new discovery of five: the small gap of different polarity electrodes is small to a certain value, the electrolysis efficiency does not rise and fall, what is the reason? Studies have confirmed that to strengthen the "impurity effect of impurities", it is also necessary to ensure that the water has a certain flow in the gap between different polar electrodes during the electrolysis process, which can promote more water molecules and impurities to be electrolyzed repeatedly, thereby strengthening the "impurities". Electrolytic effect", improve water electrolysis efficiency and electrolyzed water reduction index; in-depth study of the flowability in the electrolysis water process, explains why the electrolysis water efficiency does not rise and fall after the electrolysis current increases to a certain value. The important reason is that if the flow of water in the electrode gap is not good, the ion concentration in the electrode gap will be too high, which will affect the electrolysis efficiency. The newly discovered six: for the electrolysis externally driven flowing water such as tap water, in the electrode assembly Within a certain space, adopting a design scheme that reasonably increases the area of the electrolytic gap is beneficial to the repeated electrolysis of more impurities and water molecules in the water, which can improve the water electrolysis efficiency and the electrolysis index. In addition, in the case of flowing water with too fast electrolysis flow rate, the channel for installing the electrolysis electrode assembly adopts a design in which the outlet passage (outlet) is appropriately narrower than the inlet passage (inlet), and the flow rate of water passing through the electrolysis electrode assembly can be reduced. Thereby increasing the time and opportunity for impurities and water molecules to be electrolyzed, and increasing the index of electrolyzed water.
申请人通过对于上述六个新发现的综合分析,提出下述电解水新原理:电解水过程,首先,是电解水中杂质产生活跃电子,形成电流,将电能量转换为水分子的分解能量的过程,因此使得较多水分子获得较大电能而分解,是取得较高电解效率的基础,但获得较高电解效率,还需要具备另外的重要条件。这是因为电解过程同时还是:杂质被电解所释放的各种离子(尤其活跃电子)与水分子分解产生的各种氢氧离子、离子根发生理化作用的过程,在此过程中,为提高水的电解效率有两个重要条件,第一,若较多杂质被电解,其释放的电子、离子较多,其与氢氧离子组合的几率就较高,电解水指标可能较高,电解效率也就较高;第二,若能创造条件,使得杂质被电解释放的电子离子与氢氧离子组合的几率较高,电解水指标可能较高,电解效率也就较高。例如电解还原水的较高ORP负值与含氢量(申请人将两指标简要合称为“负氢”指标),需要较多的活跃电子参与,因此,水中杂质被电解而释放较多电子以及电子与氢离子组合为负氢的几率较高,就可以提高负氢指标与电解效率。Through comprehensive analysis of the above six new findings, the applicant proposed the following new principle of electrolyzed water: electrolyzed water process, firstly, the process of generating active electrons by electrolysis of impurities in water, forming electric current, and converting electric energy into decomposition energy of water molecules. Therefore, more water molecules are decomposed by obtaining larger electric energy, which is the basis for obtaining higher electrolysis efficiency, but obtaining higher electrolysis efficiency requires additional important conditions. This is because the electrolysis process is also a process in which various ions (especially active electrons) released by electrolysis are physicochemically treated with various hydroxide ions and ion roots generated by decomposition of water molecules, in order to increase water. There are two important conditions for the electrolysis efficiency. First, if more impurities are electrolyzed, more electrons and ions are released, and the probability of combining with hydroxide ions is higher. The electrolysis water index may be higher, and the electrolysis efficiency may also be higher. Secondly, if conditions can be created, the probability of combining the electron ions released by the electrolysis with the hydroxide ions is higher, the electrolyzed water index may be higher, and the electrolysis efficiency is higher. For example, the higher ORP negative value and the hydrogen content of electrolytically reduced water (the applicant briefly refers to the two indicators as the "negative hydrogen" index), which requires more active electrons to participate. Therefore, impurities in the water are electrolyzed to release more electrons. And the combination of electrons and hydrogen ions with a higher probability of negative hydrogen can increase the negative hydrogen index and the electrolysis efficiency.
申请人的电解水新原理揭示:提高电解制作还原水效率要采取三管齐下的工艺方法, 既要强化水中杂质的电解,又要提高杂质电解释放的电子,还要增加电解所释放的电子与氢结合为负氢的几率。申请人研究发现了实现这三管齐下的具体电解工艺方法:一是适当减小不同极性电极电解间隙之间的距离,二是适当扩大不同极性电极电解间隙的面积,三是适当保持在电解水过程不同极性电极间隙中水进出的流动性,这三个工艺技术条件的协调实现,可以较好地兼顾强化杂质电解并提高还原指标的功效,从而显著提高电解水效率。本发明一种发生电解水蒸汽的装置,需要使用较高效率的无膜电解水技术。采用申请人发明的电解水新方法是提高装置效率与性能及性价比的较好选择。The applicant's new principle of electrolyzed water reveals that it is necessary to adopt a three-pronged process to improve the efficiency of electrolytic reduction water production. It is necessary to strengthen the electrolysis of impurities in water, and to increase the electrons released by the electrolysis of impurities, and to increase the probability of the electrons released by electrolysis being combined with hydrogen to form negative hydrogen. Applicant's research found a specific electrolysis process to achieve this three-pronged process: one is to appropriately reduce the distance between the electrolysis gaps of electrodes of different polarities, and the other is to appropriately enlarge the area of the electrolysis gap of electrodes of different polarities, and the third is to properly maintain The fluidity of water in and out of the gap between different polar electrodes in the electrolysis water process, the coordinated realization of these three technological conditions can better balance the effect of strengthening the impurity electrolysis and improving the reduction index, thereby significantly improving the efficiency of electrolysis water. The apparatus of the present invention for generating electrolyzed water vapor requires the use of a highly efficient membraneless electrolyzed water technique. The new method of electrolyzed water invented by the applicant is a better choice for improving the efficiency and performance of the device and the cost performance.
本发明一种发生电解水蒸汽的装置,其特征是:包括有进水口与蒸汽输出口的蒸汽发生器、可控电解电源、电解电极组件、可对蒸汽发生器中储水进行加热的加热系统;可控电解电源给电解电极组件提供电解电流,电解电极组对蒸汽发生器中储水作电解;加热系统将蒸汽发生器中电解水加热至沸腾产生蒸汽;电解水蒸汽从蒸汽输出口输出;电解电极组件采用较高效率无膜电解水技术方案,对于储水容器中宽温度范围包括沸腾的储水可作有效电解,使得电解水蒸汽达到所需要的一定指标。The invention relates to a device for generating electrolyzed water vapor, which comprises: a steam generator having a water inlet and a steam outlet, a controllable electrolysis power source, an electrolysis electrode assembly, and a heating system capable of heating the water stored in the steam generator. The controllable electrolysis power source supplies electrolysis current to the electrolysis electrode assembly, and the electrolysis electrode group electrolyzes the water stored in the steam generator; the heating system heats the electrolyzed water in the steam generator to boiling to generate steam; the electrolyzed water vapor is output from the steam outlet; The electrolytic electrode assembly adopts a higher efficiency membrane-free electrolyzed water technical scheme, and can effectively electrolyze the water storage tank in a wide temperature range including boiling water, so that the electrolyzed water vapor reaches a certain index required.
本发明内容之二:所述电解电极组件,其不同极性电极之间所留间隙的间距按合理较小化原则设计,间隙距离在小于5mm、大于0mm之间,以利于强化水中杂质与水分子的电解;在电解电极组件所占一定空间内,不同极性电极之间间隙的面积按合理较大化原则设计,使得水中较多杂质及水分子能在电极间隙中较多次反复被电解;电解电极组件及其安装工艺条件的特征是:在电解水过程中,水在不同极性电极间隙中能较顺利流动,使不同极性电极间隙中被电解的水得以更换,并使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,从而提高水的电解效率。According to the second aspect of the present invention, the spacing of the gaps between the electrodes of different polarities is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to enhance the impurities and water in the water. Molecular electrolysis; in the space occupied by the electrolysis electrode assembly, the area of the gap between the electrodes of different polarities is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be electrolyzed repeatedly in the electrode gap. The characteristics of the electrolysis electrode assembly and its installation process conditions are: in the process of electrolyzing water, water can flow smoothly in the gap of different polarity electrodes, so that the electrolyzed water in the gap of different polarity electrodes can be replaced, and more Impurities and water molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
本发明内容之三:所述电解电极组件,必要时,电解电极组件不同极性电极之间的间距可以小至1mm或更小,以较利于在一定电解功率与一定电解电极组件结构下,强化水中杂质与水分子的电解,提高水电解的效率。The third aspect of the present invention: the electrolysis electrode assembly, if necessary, the spacing between the electrodes of different polarity of the electrolysis electrode assembly can be as small as 1 mm or less, which is advantageous for strengthening under certain electrolysis power and certain electrolysis electrode assembly structure. The electrolysis of impurities and water molecules in water improves the efficiency of water electrolysis.
本发明内容之四:所述电解电极组件,可以将日常饮水与用水制作成氧化还原电位为负值、含氢量大于零的电解还原水。According to the fourth aspect of the present invention, the electrolysis electrode assembly can make daily drinking water and water into electrolytic reduced water having a negative oxidation-reduction potential and a hydrogen content greater than zero.
本发明内容之五:所述电解电极组件,不同极性电极结构设计使得:当电极间隙中水被电解而产生流动性时,电极间隙中水与离子能够顺势流动,以便更多水流过不同极性电极间隙,更换间隙中被电解的水,使较多水中杂质与水分子能被不同极性电极间电流较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。According to the fifth aspect of the present invention, the electro-electrode assembly has different polarity electrode structures designed such that when water in the electrode gap is electrolyzed to generate fluidity, water and ions in the electrode gap can flow with each other so that more water flows through different poles. The electrode gap replaces the electrolyzed water in the gap, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the current between the electrodes of different polarities, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes. Improve the efficiency of water electrolysis.
本发明内容之六:所述电解电极组件,电极间隙两端口位置外部留有一定空间,使得水在被电解的过程中产生流动时,水能在不同极性电极间隙中较顺利流动,提高水电解的效率。According to the sixth aspect of the present invention, the electrolysis electrode assembly has a certain space outside the two port positions of the electrode gap, so that when water flows during the process of electrolysis, the water can smoothly flow in the gap of different polarity electrodes, and the water is improved. The efficiency of electrolysis.
本发明内容之七:所述电解电极组件,在电解电极组件所占一定空间内,通过合理增加电极间隙的面积,可延长流水在电极间隙中被电解的时间,使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。 According to the seventh aspect of the present invention, in the electrolysis electrode assembly, by increasing the area of the electrode gap in a certain space occupied by the electrolysis electrode assembly, the time during which the flowing water is electrolyzed in the electrode gap can be prolonged, so that more impurities and water molecules are Electrodes with different polarities are repeatedly electrolyzed several times to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
本发明内容之八:所述电解电极组件,在包裹电解电极组件的电解槽壁材质与形状适合作电极的情况下,可将其适当连接作为电解电极,增加电解电极间隙面积,提高水的电解效率。According to the eighth aspect of the present invention, in the electrolytic electrode assembly, when the material and shape of the electrolytic cell wall of the electrolytic electrode assembly are suitable as an electrode, the electrode can be appropriately connected as an electrolytic electrode, the gap area of the electrolytic electrode is increased, and the electrolysis of water is improved. effectiveness.
本发明内容之九:所述电解电极组件,由两个不同极性的电极构成,电极之一为筒孔形状,筒状电极数目为N个,N等于或大于1,筒壁可无缺口或有缺口,各筒孔电极的位置为机械固定并相互电连接;电极之二为柱状,各个柱位置为机械固定并相互电连接,柱状电极的柱数目为M个,M等于或大于1;柱为空心或实心、可无缺口或有缺口;筒状电极与柱状电极的高度不限,据所需选择;筒状电极与柱状电极对应插接,即柱状电极各柱插入各对应筒孔中,对插的柱电极表面与筒孔电极相对表面之间留有对水作电解的间隙;在电解工作过程中,电极间隙内的水可以流动;电极间隙两个端口位置的外部留有一定空间,以便水在被电解的过程中,能在电极间隙中流动。According to the nineth aspect of the present invention, the electrolysis electrode assembly is composed of two electrodes of different polarities, one of the electrodes is in the shape of a cylinder, the number of the cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube can be free of gaps or There is a gap, the positions of the electrodes of the respective barrel holes are mechanically fixed and electrically connected to each other; the second electrode is columnar, and the positions of the respective columns are mechanically fixed and electrically connected to each other, and the number of columns of the columnar electrodes is M, M is equal to or greater than 1; Hollow or solid, no gap or notch; the height of the cylindrical electrode and the columnar electrode is not limited, as needed; the cylindrical electrode is inserted into the columnar electrode, that is, the columnar electrode is inserted into each corresponding cylinder hole, A gap for electrolysis of water is left between the surface of the inserted column electrode and the opposite surface of the barrel electrode; during the electrolysis work, water in the electrode gap can flow; the electrode gap has a certain space outside the two port positions. So that water can flow in the electrode gap during the process of being electrolyzed.
基本技术方案:本发明一种发生电解水蒸汽的装置,其特征是:包括有进水口与蒸汽输出口的蒸汽发生器、可控电解电源、电解电极组件、可对蒸汽发生器中储水进行加热的加热系统;可控电解电源给电解电极组件提供电解电流,电解电极组对蒸汽发生器中储水作电解;加热系统将蒸汽发生器中电解水加热至沸腾产生蒸汽;电解水蒸汽从蒸汽输出口输出;电解电极组件采用较高效率无膜电解水技术方案,对于储水容器中宽温度范围包括沸腾的储水可作有效电解,使得电解水蒸汽达到所需要的一定指标。Basic technical solution: The invention has a device for generating electrolyzed water vapor, characterized in that: a steam generator including a water inlet and a steam outlet, a controllable electrolysis power source, an electrolysis electrode assembly, and a water storage in the steam generator a heating heating system; the controllable electrolysis power source supplies an electrolysis current to the electrolysis electrode assembly, and the electrolysis electrode group electrolyzes the water stored in the steam generator; the heating system heats the electrolysis water in the steam generator to boiling to generate steam; electrolyzes water vapor from the steam Output port output; Electrolytic electrode assembly adopts high efficiency membrane-free electrolyzed water technology scheme, which can effectively electrolyze the water storage in a wide temperature range including boiling water in the water storage container, so that the electrolyzed water vapor reaches a certain index required.
具体技术方案之一::所述电解电极组件,其不同极性电极之间所留间隙的间距按合理较小化原则设计,间隙距离在小于5mm、大于0mm之间,以利于强化水中杂质与水分子的电解;在电解电极组件所占一定空间内,不同极性电极之间间隙的面积按合理较大化原则设计,使得水中较多杂质及水分子能在电极间隙中较多次反复被电解;电解电极组件及其安装工艺条件的特征是:在电解水过程中,水在不同极性电极间隙中能较顺利流动,使不同极性电极间隙中被电解的水得以更换,并使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,从而提高水的电解效率。One of the specific technical solutions: the electrolysis electrode assembly, the spacing of the gaps between the electrodes of different polarities is designed according to the principle of reasonable miniaturization, and the gap distance is less than 5 mm and greater than 0 mm, so as to strengthen the impurities in the water. Electrolysis of water molecules; in a certain space occupied by electrolytic electrode assemblies, the area of the gap between electrodes of different polarities is designed according to the principle of reasonable enlargement, so that more impurities and water molecules in the water can be repeatedly repeated in the electrode gap. Electrolysis; Electrolytic electrode assembly and its installation process conditions are characterized in that in the process of electrolyzing water, water can flow smoothly in the gap of different polarity electrodes, so that the electrolyzed water in the gap of different polarity electrodes can be replaced, and Multiple impurities and water molecules are repeatedly electrolyzed by different polarity electrodes to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the electrolysis efficiency of water.
具体技术方案之二::所述电解电极组件,必要时,电解电极组件不同极性电极之间的间距可以小至1mm或更小,以较利于在一定电解功率与一定电解电极组件结构下,强化水中杂质与水分子的电解,提高水电解的效率。The second specific technical solution: the electrolysis electrode assembly, if necessary, the spacing between the electrodes of different polarity of the electroplating electrode assembly can be as small as 1 mm or less, so as to favor a certain electrolysis power and a certain electrolysis electrode assembly structure. Strengthen the electrolysis of impurities and water molecules in water to improve the efficiency of water electrolysis.
具体技术方案之三::所述电解电极组件,可以将日常饮水与用水制作成氧化还原电位为负值、含氢量大于零的电解还原水。The third technical scheme: the electrolysis electrode assembly can make daily drinking water and water into electrolytic reduction water with a negative oxidation-reduction potential and a hydrogen content greater than zero.
具体技术方案之四::所述电解电极组件,不同极性电极结构设计使得:当电极间隙中水被电解而产生流动性时,电极间隙中水与离子能够顺势流动,以便更多水流过不同极性电极间隙,更换间隙中被电解的水,使较多水中杂质与水分子能被不同极性电极间电流较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。The fourth technical scheme: the electrolysis electrode assembly, the electrode structure of different polarities is designed such that when water in the electrode gap is electrolyzed to generate fluidity, water and ions in the electrode gap can flow with each other so that more water flows through the water. The polar electrode gap replaces the electrolyzed water in the gap, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the currents of different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes. To improve the efficiency of water electrolysis.
具体技术方案之五::所述电解电极组件,电极间隙两端口位置外部留有一定空间,使得水在被电解的过程中产生流动时,水能在不同极性电极间隙中较顺利流动,提高水 电解的效率。The fifth specific technical solution: the electrolysis electrode assembly has a certain space outside the two port positions of the electrode gap, so that when the water flows during the electrolysis process, the water can flow smoothly in the gap of the different polarity electrodes, thereby improving Water The efficiency of electrolysis.
具体技术方案之六::所述电解电极组件,在电解电极组件所占一定空间内,通过合理增加电极间隙的面积,可延长流水在电极间隙中被电解的时间,使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。The sixth technical scheme: the electrolysis electrode assembly can prolong the time of electrolysis of the flowing water in the electrode gap by increasing the area of the electrode gap in a certain space occupied by the electrolysis electrode assembly, so that more impurities and water molecules are obtained. It is repeatedly electrolyzed by electrodes of different polarities to increase the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving the efficiency of water electrolysis.
具体技术方案之七::所述电解电极组件,在包裹电解电极组件的电解槽壁材质与形状适合作电极的情况下,可将其适当连接作为电解电极,增加电解电极间隙面积,提高水的电解效率。Specific technical solution seven: the electrolysis electrode assembly, in the case where the material and shape of the electrolytic cell wall of the electrolysis electrode assembly are suitable as an electrode, the appropriate connection can be used as an electrolysis electrode, the gap area of the electrolysis electrode is increased, and the water is increased. Electrolysis efficiency.
具体技术方案之八::所述电解电极组件,由两个不同极性的电极构成,电极之一为筒孔形状,筒状电极数目为N个,N等于或大于1,筒壁可无缺口或有缺口,各筒孔电极的位置为机械固定并相互电连接;电极之二为柱状,各个柱位置为机械固定并相互电连接,柱状电极的柱数目为M个,M等于或大于1;柱为空心或实心、可无缺口或有缺口;筒状电极与柱状电极的高度不限,据所需选择;筒状电极与柱状电极对应插接,即柱状电极各柱插入各对应筒孔中,对插的柱电极表面与筒孔电极相对表面之间留有对水作电解的间隙;在电解工作过程中,电极间隙内的水可以流动;电极间隙两个端口位置的外部留有一定空间,以便水在被电解的过程中,能在电极间隙中流动。Specific technical solution VIII: The electrolysis electrode assembly is composed of two electrodes of different polarities, one of the electrodes is in the shape of a cylindrical hole, the number of cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube can be unnotched. Or the gap, the position of each of the barrel electrodes is mechanically fixed and electrically connected to each other; the second electrode is columnar, each column position is mechanically fixed and electrically connected to each other, the number of columns of the columnar electrode is M, M is equal to or greater than 1; The column is hollow or solid, and may be unnotched or notched; the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement; the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, the columnar electrodes are inserted into the corresponding cylindrical holes. There is a gap between the surface of the inserted column electrode and the opposite surface of the barrel electrode for electrolysis; during the electrolysis work, the water in the electrode gap can flow; the electrode gap has a certain space outside the two ports. So that water can flow in the electrode gap during the process of being electrolyzed.
附图说明DRAWINGS
下面通过附图对本发明作进一步阐释。The invention is further illustrated by the following figures.
图1是本发明实施例1一种发生电解水蒸汽的装置1 is a device for generating electrolyzed water vapor according to Embodiment 1 of the present invention;
具体实施方式detailed description
以下结合实施例1附图1阐述实施例基本结构及基本工作原理。The basic structure and basic working principle of the embodiment will be described below with reference to FIG. 1 of Embodiment 1.
实施例1Example 1
如图1,一种发生电解水蒸汽的装置,包括蒸汽发生器14、进水口18、蒸汽输出口13、加热系统5、可控电解电源9、由电极1与2、电解槽10构成的电解电极组件,15是水位线,加热系统5对蒸汽发生器14内储水进行加热;可控电解电源9通过导线6、7给电解电极组件10的不同极性电极1、2供电,对蒸汽发生器14储水作电解;加热系统5将蒸汽发生器14水加热至沸腾,从蒸汽输出口13输出电解水蒸汽;电解电极组件10采用较高效率无膜电解水技术方案,对于蒸汽发生器14中宽温度范围包括沸腾的储水可作有效电解,使得电解水蒸汽能达到所需要的一定指标;8为电解槽壁,其上、下部16、17是透水的,电解电极组件由两个不同极性电极1、2构成,电极1为筒孔状(下文简称孔状),图中示意画出3个孔状电极,各个筒孔位置机械固定、孔壁相互电连接,电极2为柱状,图中示意画出3个柱,各个柱位置机械固定、相互电连接,1与2可对应插接,即柱状电极2的柱插入孔状电极的对应孔中,柱表面与孔表面之间留有电解间隙3,该间隙呈管状,图1中示意性画出了3个柱状电极与孔状电极构成的间隙3,间隙间距可视需要在一定范围内选择,如小于5mm至大于0mm的范围;必要时,间隙3的间 距可取较小值,如等于或小于1mm,以便强化水及其中杂质的电解效果,这样设计在装置需要电解电导率低的纯净水、蒸馏水等原水时,可以获得较高的电解水效率与指标;在电极间隙距离一定情况下,杂质与水分子被电解的几率及数量与间隙面积成正比,因此间隙3面积较大化可提高电解效率;图1中,电解槽壁8为适合做电解电极使用的材料,经由导线7连接到电解电源成为电极2的一部分,与电极1构成电解间隙4,加强装置电解效果;11、12分别为电解槽10的下部与上部空间,空间11处于电解槽底16与电解电极组件底部之间,给空间11与12设计一定的体积,有助于电极间隙中水畅顺流动。因为在电解水过程中,间隙中的水分子被电解分解后,会产生氢气、氧气,氢、氧气泡会沿着间隙向上飘逸,从而带动间隙3中水向上流动,从间隙3上部端口流出到空间12再流到电解槽外,这导致水从电解槽下部16下面源源流入空间11,再流入电极间隙3作补充,显然,若11、12过于狭窄,可能影响水在电极间隙的流通性,从而降低水的电解效率。水在间隙流动过程中,水中杂质与水分子会在间隙中被电解电流反复电解。如此循环往复,蒸汽发生器14中的水会反复从8的底部流入电解槽的电极间隙中被反复电解,不断强化电解效果;综上所述,间隙3合理选择较小的间距与较大面积并满足间隙3中水具有一定流通性,这三方面协调兼顾的工艺技术方案可以显著提高电解效率与电解水指标。而电解水指标高,例如电解水的ORP负值与氢含量高,电解水蒸汽中的负离子含量就高。1, a device for generating electrolyzed water vapor, comprising a steam generator 14, a water inlet 18, a steam outlet 13, a heating system 5, a controllable electrolysis power source 9, an electrolysis consisting of electrodes 1 and 2, and an electrolysis cell 10. The electrode assembly, 15 is a water level line, and the heating system 5 heats the water stored in the steam generator 14; the controllable electrolysis power source 9 supplies power to the different polarity electrodes 1, 2 of the electrolysis electrode assembly 10 through the wires 6, 7 to generate steam. The device 14 stores water for electrolysis; the heating system 5 heats the steam generator 14 to boiling, and outputs electrolyzed water vapor from the steam outlet 13; the electrolysis electrode assembly 10 adopts a higher efficiency membraneless electrolyzed water solution for the steam generator 14 The medium-wide temperature range includes boiling water storage for effective electrolysis, so that the electrolyzed water vapor can reach a certain required index; 8 is the wall of the electrolysis cell, the upper and lower portions 16, 17 are permeable, and the electrolysis electrode assembly is composed of two different The polar electrodes 1 and 2 are formed, and the electrode 1 is in the shape of a cylinder (hereinafter referred to as a hole). Three hole-shaped electrodes are schematically illustrated in the figure. The positions of the respective holes are mechanically fixed, the walls of the holes are electrically connected to each other, and the electrodes 2 are columnar. Shown in the figure Three columns are arranged, each column position is mechanically fixed and electrically connected to each other, and 1 and 2 can be correspondingly inserted, that is, the column of the columnar electrode 2 is inserted into the corresponding hole of the hole electrode, and an electrolytic gap is left between the surface of the column and the surface of the hole. The gap is tubular. The gap 3 between the three columnar electrodes and the hole electrode is schematically illustrated in FIG. 1. The gap spacing may be selected within a certain range, such as less than 5 mm to more than 0 mm; if necessary, Interval 3 The distance may be a small value, such as equal to or less than 1 mm, in order to strengthen the electrolysis effect of water and impurities therein, so that when the device requires raw water such as pure water or distilled water with low electrolytic conductivity, high electrolysis water efficiency and index can be obtained. In the case where the distance between the electrodes is constant, the probability and quantity of impurities and water molecules being electrolyzed are proportional to the gap area. Therefore, the larger the area of the gap 3 can improve the electrolysis efficiency; in Fig. 1, the wall 8 of the electrolytic cell is suitable for the electrolysis electrode. The material used is connected to the electrolytic power source via the wire 7 to form a part of the electrode 2, and constitutes an electrolytic gap 4 with the electrode 1 to enhance the electrolysis effect; 11, 12 are the lower part and the upper space of the electrolytic cell 10, respectively, and the space 11 is at the bottom of the electrolytic cell. Between 16 and the bottom of the electrode assembly, a certain volume is designed for the spaces 11 and 12 to facilitate smooth flow of water in the electrode gap. Because in the process of electrolyzing water, the water molecules in the gap are electrolytically decomposed, hydrogen and oxygen are generated, and the hydrogen and oxygen bubbles will flow upward along the gap, thereby causing the water in the gap 3 to flow upward, flowing out from the upper port of the gap 3 to The space 12 flows to the outside of the electrolytic cell, which causes water to flow into the space 11 from the source below the lower portion 16 of the electrolytic cell, and then flows into the electrode gap 3 for supplementation. Obviously, if the 11 and 12 are too narrow, the flow of water in the electrode gap may be affected. Thereby reducing the electrolysis efficiency of water. During the flow of water in the gap, impurities and water molecules in the water are repeatedly electrolyzed by the electrolysis current in the gap. In this cycle, the water in the steam generator 14 repeatedly flows from the bottom of the 8 into the electrode gap of the electrolytic cell and is repeatedly electrolyzed to continuously strengthen the electrolysis effect; in summary, the gap 3 is reasonably selected to have a smaller pitch and a larger area. And to meet the gap 3 water has a certain circulation, these three aspects of coordination of the technical solutions can significantly improve the electrolysis efficiency and electrolyzed water indicators. The electrolyzed water has a high index, for example, the negative ORP value and the hydrogen content of the electrolyzed water, and the negative ion content in the electrolyzed water vapor is high.
表1:本发明一种发生电解水蒸汽的装置实施例1三种电解电极结构与条件实测数据Table 1: Apparatus for generating electrolyzed water vapor according to the present invention. Example 1 Three kinds of electrolytic electrode structures and conditions measured data
Figure PCTCN2016000093-appb-000001
Figure PCTCN2016000093-appb-000001
注:电解电压8V,原水:ORP=+408mv,氢含量=0,常温Note: Electrolytic voltage 8V, raw water: ORP=+408mv, hydrogen content=0, normal temperature
从A、B栏或A、C栏检测数据比较可见电解电极间隙3面积相差一半,或者电极间隙中水流动性差异,电解水效率不同,而蒸汽指标也显著不同,既证实了申请人提出的电解水新原理以及新方法,同时也验证本发明装置的电解水蒸汽指标水平已经达到相当高的水平,具有很高的实用性。 From the A, B column or A, C column data, it can be seen that the area difference of the electrolysis electrode gap 3 is half, or the water flow difference in the electrode gap, the electrolysis water efficiency is different, and the steam index is also significantly different, which confirms the applicant's proposal. The new principle and new method of electrolyzed water also verified that the electrolyzed water vapor index level of the device of the invention has reached a relatively high level and has high practicability.
本发明一种发生电解水蒸汽的装置,其电解电极组件并不限于使用实施例1所采取的具体结构,原则上,任何一种可以达到产品所需要电解水指标的无膜电解电极结构组件均可以应用。 The invention relates to a device for generating electrolyzed water vapor, wherein the electrolysis electrode assembly is not limited to the specific structure adopted by the embodiment 1. In principle, any of the membrane-free electrolysis electrode structural components which can achieve the electrolyzed water index required for the product are Can be applied.

Claims (9)

  1. 一种发生电解水蒸汽的装置,其特征是:包括有进水口与蒸汽输出口的蒸汽发生器、可控电解电源、电解电极组件、可对蒸汽发生器中储水进行加热的加热系统;可控电解电源给电解电极组件提供电解电流,电解电极组对蒸汽发生器中储水作电解;加热系统将蒸汽发生器中电解水加热至沸腾产生蒸汽;电解水蒸汽从蒸汽输出口输出;电解电极组件采用较高效率无膜电解水技术方案,对于储水容器中宽温度范围包括沸腾的储水可作有效电解,使得电解水蒸汽达到所需要的一定指标。The invention relates to a device for generating electrolyzed water vapor, which comprises: a steam generator having a water inlet and a steam outlet, a controllable electrolysis power source, an electrolysis electrode assembly, and a heating system capable of heating the water stored in the steam generator; The electrolysis power source supplies electrolysis current to the electrolysis electrode assembly, and the electrolysis electrode group electrolyzes the water stored in the steam generator; the heating system heats the electrolyzed water in the steam generator to boiling to generate steam; the electrolyzed water vapor is output from the steam outlet; the electrolysis electrode The module adopts a high-efficiency membrane-free electrolyzed water technology scheme, which can effectively electrolyze the water storage tank in a wide temperature range including boiling water, so that the electrolyzed water vapor reaches a certain index required.
  2. 根据权利要求1所述的一种发生电解水蒸汽的装置,其特征是:所述电解电极组件,其不同极性电极之间所留间隙的间距按合理较小化原则设计,间隙距离在小于5mm、大于0mm之间,以利于强化水中杂质与水分子的电解;在电解电极组件所占一定空间内,不同极性电极之间间隙的面积按合理较大化原则设计,使得水中较多杂质及水分子能在电极间隙中较多次反复被电解;电解电极组件及其安装工艺条件的特征是:在电解水过程中,水在不同极性电极间隙中能较顺利流动,使不同极性电极间隙中被电解的水得以更换,并使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,从而提高水的电解效率。A device for generating electrolyzed water vapor according to claim 1, wherein said electrolysis electrode assembly has a spacing of gaps between electrodes of different polarities designed according to a principle of reasonable miniaturization, and the gap distance is less than 5mm, greater than 0mm, in order to strengthen the electrolysis of impurities and water molecules in the water; in the space occupied by the electrolytic electrode assembly, the area of the gap between the electrodes of different polarities is designed according to the principle of reasonable enlargement, so that more impurities in the water And water molecules can be electrolyzed repeatedly in the electrode gap; the characteristics of the electrolysis electrode assembly and its installation process conditions are: in the process of electrolyzing water, the water can flow smoothly in the gap of different polarity electrodes, so that different polarities The electrolyzed water in the electrode gap is replaced, and more impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, thereby improving water electrolysis. effectiveness.
  3. 根据权利要求1所述的一种发生电解水蒸汽的装置,其特征是:所述电解电极组件,必要时,电解电极组件不同极性电极之间的间距可以小至1mm或更小,以较利于在一定电解功率与一定电解电极组件结构下,强化水中杂质与水分子的电解,提高水电解的效率。A device for generating electrolyzed water vapor according to claim 1, wherein said electrolysis electrode assembly, if necessary, the spacing between electrodes of different polarity of the electroplating electrode assembly can be as small as 1 mm or less to It is beneficial to strengthen the electrolysis of impurities and water molecules in water under certain electrolysis power and certain electrolysis electrode assembly structure, and improve the efficiency of water electrolysis.
  4. 根据权利要求1所述的一种发生电解水蒸汽的装置,其特征是:所述电解电极组件,可以将日常饮水与用水制作成氧化还原电位为负值、含氢量大于零的电解还原水。The device for generating electrolyzed water vapor according to claim 1, wherein the electrolysis electrode assembly can make daily drinking water and water into electrolytic reduced water having a negative oxidation-reduction potential and a hydrogen content greater than zero. .
  5. 根据权利要求1所述的一种发生电解水蒸汽的装置,其特征是:所述电解电极组件,不同极性电极结构设计使得:当电极间隙中水被电解而产生流动性时,电极间隙中水与离子能够顺势流动,以便更多水流过不同极性电极间隙,更换间隙中被电解的水,使较多水中杂质与水分子能被不同极性电极间电流较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。A device for generating electrolyzed water vapor according to claim 1, wherein said electrolysis electrode assembly has a structure of electrodes of different polarities such that when water is electrolyzed in the electrode gap to generate fluidity, the electrode gap is Water and ions can flow in the same direction, so that more water flows through the gaps of different polarity electrodes, and the water that is electrolyzed in the gap is replaced, so that more impurities and water molecules in the water can be repeatedly electrolyzed by the currents of different polarity electrodes to increase impurities. The probability and number of electrolysis of water molecules with different polar electrodes increases the efficiency of water electrolysis.
  6. 根据权利要求1所述的一种发生电解水蒸汽的装置,其特征是:所述电解电极组件,电极间隙两端口位置外部留有一定空间,使得水在被电解的过程中产生流动时,水能在不同极性电极间隙中较顺利流动,提高水电解的效率。A device for generating electrolyzed water vapor according to claim 1, wherein said electrolysis electrode assembly has a space outside the two port positions of the electrode gap, so that water flows when it is electrolyzed, and water It can smoothly flow in the gap of different polarity electrodes, improving the efficiency of water electrolysis.
  7. 根据权利要求1所述的一种发生电解水蒸汽的装置,其特征是:所述电解电极组件,在电解电极组件所占一定空间内,通过合理增加电极间隙的面积,可延长流水在电极间隙中被电解的时间,使较多杂质与水分子被不同极性电极较多次反复电解,增加杂质与水分子被不同极性电极电解的几率与数量,提高水电解的效率。The device for generating electrolyzed water vapor according to claim 1, wherein the electrolysis electrode assembly can extend the flow of water in the electrode gap by appropriately increasing the area of the electrode gap within a certain space occupied by the electrolysis electrode assembly. During the time of electrolysis, more impurities and water molecules are repeatedly electrolyzed by different polarity electrodes, increasing the probability and quantity of impurities and water molecules being electrolyzed by different polarity electrodes, and improving the efficiency of water electrolysis.
  8. 根据权利要求1所述的一种发生电解水蒸汽的装置,其特征是:所述电解电极组件,在包裹电解电极组件的电解槽壁材质与形状适合作电极的情况下,可将其适当连接作为电解电极,增加电解电极间隙面积,提高水的电解效率。The device for generating electrolyzed water vapor according to claim 1, wherein the electrolysis electrode assembly can be appropriately connected in the case where the material and shape of the electrolytic cell wall of the electrolysis electrode assembly are suitable as electrodes. As the electrolysis electrode, the gap area of the electrolysis electrode is increased to improve the electrolysis efficiency of water.
  9. 根据权利要求1所述的一种发生电解水蒸汽的装置,其特征是:所述电解电极组 件,由两个不同极性的电极构成,电极之一为筒孔形状,筒状电极数目为N个,N等于或大于1,筒壁可无缺口或有缺口,各筒孔电极的位置为机械固定并相互电连接;电极之二为柱状,各个柱位置为机械固定并相互电连接,柱状电极的柱数目为M个,M等于或大于1;柱为空心或实心、可无缺口或有缺口;筒状电极与柱状电极的高度不限,据所需选择;筒状电极与柱状电极对应插接,即柱状电极各柱插入各对应筒孔中,对插的柱电极表面与筒孔电极相对表面之间留有对水作电解的间隙;在电解工作过程中,电极间隙内的水可以流动;电极间隙两个端口位置的外部留有一定空间,以便水在被电解的过程中,能在电极间隙中流动。 A device for generating electrolyzed water vapor according to claim 1, wherein said electrolysis electrode group The piece is composed of two electrodes of different polarities, one of the electrodes is in the shape of a cylinder hole, the number of the cylindrical electrodes is N, N is equal to or greater than 1, and the wall of the tube can be free of gaps or gaps, and the positions of the electrodes of the respective barrel holes are Mechanically fixed and electrically connected to each other; the second electrode is columnar, each column position is mechanically fixed and electrically connected to each other, the number of columns of the columnar electrode is M, M is equal to or greater than 1; the column is hollow or solid, and may be unnotched or Notch; the height of the cylindrical electrode and the columnar electrode is not limited, and is selected according to the requirement; the cylindrical electrode is inserted correspondingly to the columnar electrode, that is, each column of the columnar electrode is inserted into each corresponding cylindrical hole, and the surface of the cylindrical electrode and the cylindrical electrode are inserted There is a gap between the opposite surfaces for electrolysis of water; during the electrolysis work, the water in the electrode gap can flow; there is a certain space outside the two port positions of the electrode gap, so that the water can be in the process of being electrolyzed. Flows in the electrode gap.
PCT/CN2016/000093 2015-02-26 2016-02-24 Device for generating electrolyzed water vapor WO2016134615A1 (en)

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