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US005128504A

United States Patent [19] [in Patent Number: 5,128,504

McGaffigan et al. [45] Date of Patent: Jul. 7,1992

[54] REMOVABLE HEATING ARTICLE FOR USE IN ALTERNATING MAGNETIC FIELD

[75] Inventors: Thomas H. McGaffigan, Half Moon Bay, Calif.; Ernest R. Fenton, Topsfield, Mass.

[73] Assignee: Metcal, Inc., Menlo Park, Calif.

[21] Appl. No.: 511,746

[22] Filed: Apr. 20, 1990

[51] Int. CI.* H05B 6/10

[52] U.S. CI 219/10.43; 219/10.491;

219/10.53; 219/10.75; 219/85.11; 156/272.4

[58] Field of Search 219/10.491, 10.53, 10.43,

219/10.41, 10.57, 10.75, 10.79, 85.11, 10.55 F, 10.55 R; 156/272.4, 274.2, 379.6, 380.2

[56] References Cited

U.S. PATENT DOCUMENTS

1.975.436 10/1934 Sorrel et al 219/13

1.975.437 10/1934 Sorrel et al 219/13

1.975.438 10/1934 Sorrel 219/13

3,191,132 5/1965 Mayer .

3,309,633 3/1967 Mayer .

3,391,846 7/1968 White 229/17

3,461,014 8/1969 James 156/272

3,510,619 5/1970 Leatherman 219/10.53

3,528,867 9/1970 Leatherman 156/272

3,548,140 12/1970 O'Neill 219/10.53

3,551,223 12/1970 Deal et al 149/15

3,709,775 1/1973 James 161/162

3,902,940 9/1975 Heller et al 156/79

3,945,867 3/1976 Heller, Jr. et al 156/143

4,035,547 7/1977 Heller, Jr. et al 219/10.53

4,107,506 8/1978 Pelegri 219/85 A

4,223,209 9/1980 Diaz 219/549

4,256,945 3/1981 Carter et al 219/10.75

4,307,277 12/1981 Maeda et al 219/10.55 R

4,341,936 7/1982 Virgin 219/10.79

4,347,487 8/1982 Martin .

4,369,284 1/1983 Chen 524/476

4,499,438 2/1985 CorneJlius et al. .

4,555,422 11/1985 Nakamura et al. .

4,654,511 3/1987 Horsma et al 219/548

4,665,309 5/1987 Derbyshire 219/551

4.695.712 9/1987 Busch 219/10.41

4.695.713 9/1987 Krumme 219/553

4,699,743 10/1987 Nakamura et al. .

[graphic]

4,749,833 6/1988 Novorsky 219/10.53

4,777,063 10/1988 Dubrow et al 427/44

4,789,767 12/1988 Doljack 219/9.5

4,814,546 3/1989 Whitney et al. .

4,823,106 4/1989 Lovell 338/212

4,865,905 12/1989 Uken 428/220

4,914,267 4/1990 Derbyshire 219/85.1

FOREIGN PATENT DOCUMENTS

52-30938 3/1977 Japan 219/10.55 M

1076772 3/1964 United Kingdom .

OTHER PUBLICATIONS

Lee, E. W., Magnetism, An Introductory Survey, (1970) pp. 201-204.

Murakami, K. IEEE Transactions on Magnetics (Jun. 1965) pp. 96-100.

Smit. et al., Ferrites (1959) pp. 155-160.
Smith et al., Adv. Electronics, 6:69 (1954).

Primary Examiner—Philip H. Leung

Attorney, Agent, or Firm—Burns, Doane, Swecker &

Mathis

[57] ABSTRACT

This invention provides a system for providing heat to a substrate in an alternating magnetic field using lossy heating particles. This invention in particular discloses an article which is a combination of a base material and lossy heating particles capable of producing the desired heat and capable of being self-regulating at a preselected Curie temperature when subjected to an alternating magnetic field. The article of this invention is adapted to be placed on a substrate in order to heat the substrate in an alternating magnetic field and is adapted to provide the removal of the particles from the substrate after the heating is completed. Preferred materials for the article of this invention are gel materials having a cone penetration of at least about 50(10-1 mm) and at least about 100% elongation. Preferred magnetic particles for use in this invention include the combination of lossy heating particles, alone or in combination with nonlossy particles for maintaining the magnetic circuit coupling while the lossy heating particles are at the Curie temperature.

19 Claims, 2 Drawing Sheets

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U.S. Patent July 7, 1992 Sheet 2 of 2 5,128,504

[graphic][merged small]

1 2

In one aspect, this invention is an article adapted for

REMOVABLE HEATING ARTICLE FOR USE IN providing heat to a substrate in an alternating magnetic

ALTERNATING MAGNETIC FIELD field comprising in combination:

a base material; and

RELATED APPLICATIONS 5 lossy heating particles carried by the base material

This application is a continuation-in-part of U.S. Ser. whi,_ch Particles have a Curie temperature at least equal

No. 07/242,208 filed Sept. 9, 1988 now abandoned and to 'he temperature to which the substrate is to be heated

is a continuation-in-part of U.S. Ser. No. 07/404,621 ««d which have sufficiently high permeability and are

filed SeDt 8 1989 sufficiently highly lossy to produce the desired heat

10 when subjected to an alternating magnetic field,

FIELD OF THE INVENTION wherein the base material carrying the particles is

This invention relates to articles, methods and sys- adaPted l° placed on a surface of the substrate for

terns for providing heat to selected substrates by sub- heatIng the ^bstrate and is adapted for removal of the

jecting the substrate and a removable article comprising 15 Pmfes from the ^strate after heating the substrate in

magnetic particles to an alternating magnetic field. an alternating magnetic field.

In one preferred aspect of this invention, the above

BACKGROUND OF THE INVENTION article is adapted to be removably placed on the sub

-m. r r i j i_ strate and is removed from the substrate after the de

The use of fernte particles to produce heating in ......

.. .. .. _ ,, . , . . . j. sired heating has been accomplished, thereby removing

alternating magnetic fields is known in the art. As dis- m „ . • , r i_ .

closed in U.S. Pat. No. 3,391,846 to White, and U.S. Pat. the particles from the substrate.

No. 3,902,940 to Heller et al., ferrite particles have been „In Preferred .asP?? °L thls ,nvent,°n' the ', . * . .'. . , • above article is provided with adhesive means for reused to produce heat where it is desired to cause chemi- ,. ,, .r ., . , - - . ,

. . . • i i movably adhering the article to a surface of the base cal reactions, melt materials, evaporate solvents, pro- . :, , , °, ... , .. , , , duce ases and for other u oses 25 matena' whereby the article can be applied to the subtil??6!' an . 0r ... /nwno /a v strate to be heated, then the particles removed from the PCT International Publication WO84/02098 (Apph- e . . . ,., , .. , , . XT .„.«. t Ji Vfc. surface of the base material after the heating has been cation No. PCT/US83/01851 corresponding to the U.S. , , r , , ,. ...f ,. ., TM Vt I-i t. r accomplished, for example, by washing with a liquid. Pat. No. 4,914,267) of Derbyshire discloses the use of Ifl ... feTTJ Jct of thif inventioJ the

ferromagnetic materials having the desired Curie tern- h m ^ form of a havJ at ^ m%

perature in electrically conductive layers to provide 30 ^ ^ fe ^ ferabJ a j.

auto-regulated heating to the Cune temperature of the havm at ^ 2QQ% d ti which ovides the

material upon application of an alternating current to artide the c biHt of bein stretched onto a substrate

the conductive layer of ferromagnetic material. The for heatin fa m a,ternati m netic field so that the

power applied to the ferromagnetic layer is in the form win ch dimension with the substrate when it

of an alternating current source which produces skin ch dimension or shape when heated) such as heat

effect or eddy current heating m the continuous ferro- recoverable substrates

magnetic layer. As the ferromagnetic layer reaches the In another preferred aspect of this invention, the Curie temperature, the permeability of the layer drops magnetic particles present in the article comprise a and the skin depth increases, thereby spreading the ^ combination of lossy heating particles for producing current through the wider area of the ferromagnetic heat and non_iossy particles for providing consistent or layer until the Cune temperature is achieved through- improved magnetic circuit coupling during heating, out and the desired heating is achieved. In another aspect, this invention is a method of heatIn my copending applications referred to above and jng a substrate comprising: incorporated herein by reference, I disclose the use of 45 placing on a surface of the substrate an article cornmagnetic particles in combination with heat-recovera- prising a base material and lossy heating particles carble articles in alternating magnetic fields to effect recov- rjed by the base material which particles have a Curie ery. In connection with those systems, I have observed temperature at least equal to the temperature to which that it would be desirable to have a different form of the substrate is to be heated and which have sufficiently self-regulating, self-heating articles which can be used 50 high permeability and are sufficiently highly lossy to more conveniently in some applications to heat various produce the desired heat when subjected to an alternatsubstrates and materials. ing magnetic field wherein the article is adapted to Therefore, it is an object of this invention to provide provide removal of the particles after heating the suban improved article and an improved system for provid- strate;

ing heat to substrates using alternating magnetic fields. 55 subjecting the substrate having said article on a sur

SUMMARY OF THE INVENTION It^l^f TM *ieTMf»STMen«ic field to Produce

the desired heating of the substrate; and

I have now found that the above objects and other removing the article from the substrate, utilities and benefits can be achieved by providing an In another aspect, this invention is a system for heatarticle which can be placed on the surface of the sub- 6fj ing a substrate comprising, in combination: strate to be heated wherein the article comprises lossy a substrate to be heated;

heating particles which produce the desired heat and an article on a surface of the substrate comprising a

accomplish the heating of the substrate when subjected base material and lossy heating particles carried by the

to an'alternating magnetic field, wherein the article is base material which particles have a Curie temperature

adapted to provide removal of the particles from the 65 at least equal to the temperature to which the substrate

substrate, after heating the substrate either by removing is to be heated and which have sufficiently high permea

the article carrying the particles or by removing the bility and are sufficiently highly lossy to produce the

particles from the article. desired heat when subjected to an alternating magnetic

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