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(12) United States Patent ao) Patent No.: us 6,350,697 Bi

Richardson et al. (45) Date of Patent: Feb. 26,2002

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(21) Appl. No.: 09/469,286

(22) Filed: Dec. 22, 1999

(51) Int. CI.7 H01L 21/302

(52) U.S. CI 438/710; 438/725; 134/1.1

(58) Field of Search 438/695, 696,

438/706, 710, 733, 720, 725; 134/1.1, 21,

22

(56) References Cited

U.S. PATENT DOCUMENTS

4,657,616 A 4/1987 Benzing et al 156/345

4,786,352 A 11/1988 Benzing 156/345

4,816,113 A 3/1989 Yamazaki 156/643

4,842,683 A 6/1989 Cheng et al 156/345

4,857,139 A 8/1989 Tashiro et al 156/643

5,006,192 A 4/1991 Deguchi 156/345

5,129,958 A 7/1992 Nagashima et al 134/22.1

5,158,644 A 10/1992 Cheung et al 156/643

5,207,836 A 5/1993 Chang 134/1

5,356,478 A 10/1994 Chen et al 134/1

5,639,341 A 6/1997 Tabara 156/643.1

5,647,953 A 7/1997 Williams et al 156/643.1

5,756,400 A * 5/1998 Ye et al 438/710

5,817,574 A * 10/1998 Gardner 438/637

5,877,032 A * 3/1999 Guinn et al 438/9

6,136,211 A * 10/2000 Qian et al 216/37

6,156,663 A * 12/2000 Watanabe et al 438/695

FOREIGN PATENT DOCUMENTS

EP 0648858 A 4/1995

JP 57-201016 9/1982

JP 61-250185 11/1986

JP 3-62520 3/1991

* cited by examiner

Primary Examiner—Benjamin L. Utech

Assistant Examiner—Kin-Chan Chen

(74) Attorney, Agent, or Firm—Burns, Doane, Swecker &

Mathis, LLP

(57) ABSTRACT

A method for cleaning and conditioning interior surfaces of a plasma chamber in which substrates such as silicon wafers are processed. The method includes cleaning the chamber such as by a wet clean or in-situ plasma clean, introducing a conditioning gas into the chamber, energizing the conditioning gas into a plasma state, depositing a polymer coating on the interior surfaces and processing a substrate. The conditioning step can be performed without a substrate such as a wafer in the chamber and the processing step can be carried out without running conditioning wafers through the chamber prior to processing production wafers. In the case of a plasma chamber used for etching aluminum, the conditioning gas can include a fluorine-containing gas, a carbon-containing gas and a chlorine-containing gas.

21 Claims, 5 Drawing Sheets

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