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United States Patent m

Matsuhisa et al.

[li] Patent Number: [45] Date of Patent:

5,348,802 Sep. 20, 1994

[54] CARBON FIBER MADE FROM ACRYLIC FIBER AND PROCESS FOR PRODUCTION THEREOF

[75] Inventors: Yoji Matsuhisa, Iyo; Torn

Hiramatsu, Matsuyama; Kazuo
Yoshida, Akigawa; Gen Katagiri,
Otsu, all of Japan

[73] Assignees: Toray Industries, Inc.; Toray
Research Center, Inc., Japan

[21] Appl. No.: 899,952

[22] Filed: Jnn. 17,1992

Related U.S. Application Data

[63] Continuation of Ser. No. 456,317, Dec. 26, 1989, abandoned.

[30] Foreign Application Priority Data

Dec. 26, 1988 [JP] Japan 63-329940

Sep. 27, 1989 [JP] Japan 1-256024

[51] Int. C1.5 B32B 9/00; D02G 3/00

[52] U.S. CI 428/367; 428/364;

428/372; 428/379; 428/400; 423/447.2;

423/447.4

[58] Field of Search 428/367, 400;

423/447.2, 447.4

[56] References Cited

U.S. PATENT DOCUMENTS

Re. 33,537 2/1991 Hiramatsu et al 423/447.2

3,925,524 12/1975 Kimmel et al 423/447.4

4,024,227 5/1977 Kishimoto et al 423/447.4

4,600,572 7/1986 Hiramatsu 423/447.2

Primary Examiner—Patrick J. Ryan
Assistant Examiner—J. M. Gray
Attorney, Agent, or Firm—Austin R. Miller

[57] ABSTRACT

Disclosed is a carbon fiber made from an acrylic fiber, the carbon crystal of which has a crystal size Lc of 15 to 65 A as determined by the wide angle X-ray diffractometry. This carbon fiber has regions with a lower crystallinity in the surface layer portion thereof than that of the central portion thereof, and the compressive strength cre/(GPa) of the single filament thereof determined by the loop method satisfies formula (I):

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