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(12) United States Patent ao) Patent No.: us 6,399,668 Bi

Miyake et al. (45) Date of Patent: *Jun. 4,2002

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(21) Appl. No.: 09/112,150

(22) Filed: Jul. 9, 1998

Related U.S. Application Data

(62) Division of application No. 08/453,705, filed on May 30, 1995, now Pat. No. 5,830,543.

(30) Foreign Application Priority Data

May 30, 1994 (JP) 6-116947

(51) Int. CI. C08J 9 04

(52) U.S. CI 521/92; 521/125; 521/149;

521/91

(58) Field of Search 428/35.2, 35.5,

428/34.4, 34.5, 35.8, 35.9, 36.5, 913, 76; 206/204, 524.7; 383/37, 200; 521/92, 94, 125, 149, 91

(56) References Cited

U.S. PATENT DOCUMENTS

3,812,856 A 5/1974 Duncan et al 128/285

4,124,116 A 11/1978 McCabe, Jr. 206/204

4,169,004 A 9/1979 Kock et al 156/227

4,341,215 A 7/1982 Eldridge 128/285

4,654,039 A 3/1987 Brandt et al 604/368

4,725,465 A 2/1988 Lastovich 428/35

4,748,069 A * 5/1988 Cullen 206/204

4,749,600 A 6/1988 Cullen et al 428/35

4,839,395 A 6/1989 Masamizu et al 521/56

5,118,719 A 6/1992 Lind 521/92

5,147,343 A 9/1992 Kellenberger 604/368

5,149,335 A 9/1992 Kellenberger et al 604/372

5,154,713 A 10/1992 Lind 604/358

5,300,358 A 4/1994 Evers 428/286

5,314,420 A 5/1994 Smith et al 604/358

5,356,678 A 10/1994 Heitzhaus et al 428/35.6

5,415,643 A 5/1995 Kolb 604/367

5,422,405 A 6/1995 Dairoku et al 525/384

5,424,265 A 6/1995 Weinstein 502/400

5,462,972 A 10/1995 Smith et al 521/53

5.601.542 A 2/1997 Melius et al 604/368

5,610,208 A 3/1997 Dairoku et al 525/384

5,610,220 A 3/1997 Klimmek et al 524/417

5,712,316 A 1/1998 Dahmen et al 521/72

5.830.543 A * 11/1998 Miyake et al 428/35.5

FOREIGN PATENT DOCUMENTS

EP 0 494 599 A2 7/1992

EP 0 532 002 Al 9/1992

JP 4-235783 A 8/1992

WO WO 91/15368 10/1991

* cited by examiner

Primary Examiner—Rena L. Dye

(74) Attorney, Agent, or Firm—Kubovcik & Kubovcik

(57) ABSTRACT

A gelling material is composed of water-absorbent resin 12 wrapped in a bag composed of two laminated water-soluble sheets 1.1, the water-absorbent resin being prepared so as to enable the bag to be disintegrated by an inner pressure generated when an expanded volume of the water-absorbent resin by absorbing water through the bag exceeds a maximum volume capacity. When the gelling material is added to the aqueous fluid, the water-absorbent resin 12 is spread in the aqueous fluid at a stroke, and is diffused uniformly. Thus, the water-absorbent resin 12 is brought fully in contact with the aqueous fluid. Since this enables the aqueous fluid to be gelled in a short period of time, the aqueous fluid can be processed speedily. Even the aqueous fluids, which are difficult to be handled by the conventional gelling material, can be gelled conveniently in a short period of time, and the resulting gell can be easily handled, thereby enabling an easy disposal of the aqueous fluids, i.e., the gell. Additionally, since the water-absorbent resin is spread in the aqueous fluid at a stroke, and is diffused uniformly, a troublesome operation of agitating the aqueous fluid can be eliminated during the gelling process, thereby enabling a simplified gelling process.

17 Claims, 4 Drawing Sheets

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